CN108754091A - The quick laser heating high-temperature molten salt of Thin Strip Steel and its heating means - Google Patents
The quick laser heating high-temperature molten salt of Thin Strip Steel and its heating means Download PDFInfo
- Publication number
- CN108754091A CN108754091A CN201810611673.9A CN201810611673A CN108754091A CN 108754091 A CN108754091 A CN 108754091A CN 201810611673 A CN201810611673 A CN 201810611673A CN 108754091 A CN108754091 A CN 108754091A
- Authority
- CN
- China
- Prior art keywords
- fused salt
- salt
- heating
- temperature
- temperature molten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/34—Methods of heating
- C21D1/44—Methods of heating in heat-treatment baths
- C21D1/46—Salt baths
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Soft Magnetic Materials (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
Abstract
The invention discloses a kind of quick laser heating high-temperature molten salts of Thin Strip Steel and its heating means, the fused salt to be made of barium chloride and any one or more in calcium chloride, potassium chloride or sodium chloride, and the fusing point of the fused salt is 600-700 DEG C.The composition of fused salt of the present invention, meeting technological temperature makes fused salt be liquid.Quickly, uniformly thin electrical steel strip it can be heated to the technological temperature needed between 900~1200 DEG C.
Description
Technical field
The invention belongs to be heat-treated heating fused salt technical field, and in particular to a kind of quick laser heating high temperature of Thin Strip Steel
Fused salt and its heating means.
Background technology
Modern cold rolling electric production is annealed.Existing annealing is completed using continuous annealing furnace, general annealing
It is directly heating using fuel gas buring, is then heated again with completely isolated radiant tube.Cold rolling electric continuous annealing furnace is used
Protective gas (nitrogen hydrogen mixeding gas) prevents the hair of surface oxidation under (reduction) hot conditions, internal oxidition and Inner nitridation phenomenons
It is raw, improve cold rolling electric performance.The protective gas maintenance positive pressure outer gas of prevention stove enters in stove.
The heating speed of cold rolling electric continuous annealing has a significant impact the performance of final products, and heating speed height can be with
Improve properties of product.In addition degree of oxidation similarly has a significant impact properties of product, this point on high grade electric steel particularly
It is prominent.
In order to improve electrical sheet heating speed, Japanese Unexamined Patent Publication 5-59441 (JPH0559441A, 1993.03.09) is profit
With the resistance of electrical steel strip, it is powered and the temperature of electrical sheet is increased to the temperature completed recrystallization and needed by resistance heating.But
It is the tie point of electrical circuit, since the movement of electrical sheet, plate shape cause the huge fluctuation of contact resistance, to make steel band can not
Soaking is heated.
Equally, the patent CN02814192.X- of nippon《Highfield iron loss and the excellent superelevation magnetic flux of coating characteristic
Density one-way oriented electric steel plate and its manufacturing method》In order to obtain the orientation silicon steel of high magnetic strength, low iron loss, wanted before decarburizing annealing
Seek 100 DEG C/s of heating speed >, really 300 DEG C/s or 400 DEG C/s.The patent CN200780014827.6- of nippon
《The manufacturing method of the grain-oriented magnetic steel sheet of high magnetic flux density》And CN200780018947.3-《The directionality of high magnetic flux density
The manufacturing method of electromagnetic steel plate》Heating speed is also required that, for quick heating requirements sensing heating.
The patent CN200880011115.3- of nippon《The continuous annealing method of steel band with curie point and
Continuous annealing apparatus》When with the heat treatment of the tools of the manufactures such as high-speed steel or mold (bulk), in order to ensure the uniform of heating
(preventing, Reducing distortion), prevent oxidation and quickly, using salt bath heating.Since the workpiece of this heat treatment process is small, salt bath furnace
It is small, salt is static.Meanwhile for the dissolving of carbide in steel, heating time is long.Due to the heat treatment temperature of workpiece
Relatively high, the fusing point of same salt bath is also high.
During steel band laser heating, the temperature of steel band is related with furnace temp and the speed of service (time).Therefore steel
The impacted factor of temperature of band is more, and fluctuation is big, and state of oxidation control is relatively difficult.
Heated at high speed in electrical sheet heat treatment process can improve magnetic property, but since there are curie point (ferromagnetism for steel
Disappearance temperature), when improving steel band heating temperature using sensing heating, the efficiency of the above sensing heating of Curie-point temperature significantly drops
Low, heating speed receives restriction.And the heating speed of other methods is difficult to improve, and needs new heated at high speed method.
The salt bath heating of tool steel is carried out for small workpiece, and (fusing point, oxidation are not adapted to for steel tape heating
Property, heating time, mobility etc.).The fluidized-bed of tool steel heats, and what is utilized is conductive powder, is electrical heating.
Cold rolling electric mostly uses continuous annealing production line at present, and annealing product thickness is thin, generally 0.50mm,
0.35mm, 0.3mm, 0.25mm, 0.2mm etc., width is generally in 1000mm~1250mm, and the speed of service is in 100m/min or more；
To realize that higher heating speed, general annealed wire heating furnace front end use scale-free heating (NOF), the side burnt using open fire
Formula heats strip, and heating speed general control cannot still meet product quality into one at tens of DEG C (20~30 DEG C/s)
Improved demand is walked, additionally inevitably belt steel surface is caused to aoxidize, causes the drop of strip property (especially iron loss)
It is low；And follow-on mode of heating is to heat (RTF) using radiant tube, but heating speed is substantially reduced (≤20 DEG C/s).Using
Both heating means can influence belt plate shape toward contact because heating is uneven to cause thermal stress.
Invention content
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, present invention offer is a kind of thin
The quick laser heating high-temperature molten salt of strip and its heating means, it is therefore an objective to improve heating effect, pass through this fused salt Continuous Heat
The magnetic property for handling the electrical steel strip after line improves.
To achieve the goals above, the technical solution that the present invention takes is：
A kind of quick laser heating high-temperature molten salt of Thin Strip Steel, the fused salt is by barium chloride and calcium chloride, potassium chloride or chlorine
Change any one or more composition in sodium, the fusing point of the fused salt is 600-700 DEG C.
The fused salt is made of barium chloride and calcium chloride, and in each mole of fused salt, the content of calcium chloride is rubbed for 0.52-0.70
You.
The content of the calcium chloride is 0.64 mole, and the fusing point of fused salt is 608 DEG C.
The fused salt is made of barium chloride and potassium chloride, and in each mole of fused salt, the content of potassium chloride is rubbed for 0.55-0.73
You.
The content of the sodium chloride is 0.555 mole, and the fusing point of fused salt is 649 DEG C.
The fused salt is made of barium chloride and sodium chloride, and in each mole of fused salt, the content of sodium chloride is rubbed for 0.50-0.70
You.
The content of the sodium chloride is 0.601 mole, and the fusing point of fused salt is 650 DEG C.
The present invention also provides a kind of methods that the high-temperature molten salt heats Thin Strip Steel, and the method is to heat high-temperature molten salt
It to annealing temperature, is sprayed onto on strip from the strip outlet end of heating furnace later, the heating fused salt being then sprayed into inversely is transported with strip
It is dynamic, and strip is made to be submerged by fused salt, last fused salt exits into molten bath from the strip input end of heating furnace.
Preferably, pass through circulating-heating transport system between the fused salt import and molten bath of the strip outlet end setting of heating furnace
Heated and conveyed fused salt.Circulating-heating transport system includes fused salt transfer pipeline, the inlet and outlet difference of fused salt transfer pipeline
It imports and exports and connects with the fused salt of heating furnace, the system also includes the input ends from fused salt transfer pipeline to outlet extreme direction successively
The fused salt preheater and molten salt heater group of setting.
The molten salt heater group includes the combustion heater heated for the fused salt after being preheated to preheater and use
The electric heater that fused salt after being heated to combustion heater further heats.
Fused salt after being preheated preheater by pump for liquid salts imports molten salt heater group and heats, and is conveyed later from fused salt
The outlet of pipeline imports the import of heating furnace.
The pump for liquid salts is set on the conveyance conduit between preheater and combustion heater.
In the above method, fused salt is heated to 800~1100 DEG C outside stove, by pipeline, is then sprayed by nozzle
Enter on the outlet strip of heating furnace in continuous annealing furnace.The fused salt heated and strip reverse movement, strip are submerged by fused salt.It is logical
Contact of the electrical steel strip with fused salt is crossed, to complete quick heat exchange.Meanwhile the temperature of strip is not above fused salt and enters continuously
Temperature when annealing furnace heating furnace.The fused salt outlet that fused salt is arranged from the strip arrival end of heating furnace later flows into molten bath, molten bath
Liquid salt heated after, then flow to the fused salt entrance of strip continuous furnace, form heating, cooling cycle, complete steel band
Laser heating.
Beneficial effects of the present invention：Using salt bath heating, liquid salt and steel band are in direct contact, heating speed is high, temperature and
Controllability height is aoxidized, the belt steel temperature heated is uniform, deformation is small.Liquid salt is that steel plate is completely covered, homogeneous heating, significantly
Steel plate stress caused by reducing temperature difference so as to cause steel plate deformation.Strip is completely covered in liquid salt, and strip is made to add
With the isolation of oxygen in thermal process, the generation of oxidation is reduced.The mitigation quickly heated and aoxidized can be realized using this method, made
Strip magnetic property after annealing improves.Since surface oxidation mitigates, annealing temperature can be subsequently improved, iron loss reduces, and improves production
Product surface quality.
The composition of fused salt of the present invention, meeting technological temperature makes fused salt be liquid.Can quickly, uniformly thin electrical sheet
Band is heated to the technological temperature needed between 900~1200 DEG C.
Description of the drawings
This specification includes the following drawings, and shown content is respectively：
Fig. 1 is the structural schematic diagram of the present invention；
Fig. 2 is the structural schematic diagram of present invention setting purifier.
In figure label for：
1, strip, 2, heating furnace, 3, soaking pit, 4, preheater, 5, pump for liquid salts, 6, combustion heater, 7, electric heater, 8,
Nozzle, 9, introduce pipe, 10, container, 11, outlet, 12, vacuum tube, 13, vacuum plant.
Specific implementation mode
Below against attached drawing, by the description of the embodiment, making to the specific implementation mode of the present invention further details of
Explanation, it is therefore an objective to those skilled in the art be helped to have more complete, accurate and deep reason to the design of the present invention, technical solution
Solution, and contribute to its implementation.
By smelting, continuous casting, hot rolling, then the electrical steel strip of pickling and cold-rolling to finished product thickness and width, is moved back
Fire obtains the performance needed.The present invention provides a kind of fused salt of wide temperature range liquid, passes through this fused salt continuous heat-treatment lines
The magnetic property of electrical sheet afterwards improves.The fused salt is carried out specifically below：
A kind of quick laser heating high-temperature molten salt of Thin Strip Steel, the fused salt is by barium chloride and calcium chloride, potassium chloride or chlorination
The fusing point of any one or more composition in sodium, fused salt is 600-700 DEG C.This high-temperature molten salt can be (1000 DEG C in high temperature
More than) under stablize, high-temperature heating effect is good, is improved by the magnetic property of the electrical sheet after this fused salt continuous heat-treatment lines.
High-temperature molten salt as one preferred, the fused salt are made of barium chloride and calcium chloride, in each mole of fused salt, chlorination
The content of calcium is 0.52-0.70 moles.Using the fused salt of the proportioning, the steel strip surface temperature liter into heating furnace disclosure satisfy that
High, surface crystallization can be melted rapidly.The content of calcium chloride is preferably 0.64 mole, and the fusing point of fused salt is 608 DEG C.
As second of preferred high-temperature molten salt, which is made of barium chloride and potassium chloride, in each mole of fused salt, chlorine
The content for changing potassium is 0.55-0.73 moles.Using the fused salt of the proportioning, the steel strip surface temperature liter into heating furnace disclosure satisfy that
High, surface crystallization can be melted rapidly.Using the fused salt of the proportioning, the steel strip surface temperature liter into heating furnace disclosure satisfy that
High, surface crystallization can be melted rapidly.The content of sodium chloride is preferably 0.555 mole, and the fusing point of fused salt is 649 DEG C.
As the third preferred high-temperature molten salt, which is made of barium chloride and sodium chloride, in each mole of fused salt, chlorine
The content for changing sodium is 0.50-0.70 moles.Using the fused salt of the proportioning, the steel strip surface temperature liter into heating furnace disclosure satisfy that
High, surface crystallization can be melted rapidly.Using the fused salt of the proportioning, the steel strip surface temperature liter into heating furnace disclosure satisfy that
High, surface crystallization can be melted rapidly.The content of sodium chloride is preferably 0.601 mole, and the fusing point of fused salt is 650 DEG C.
The present invention also provides a kind of methods that the high-temperature molten salt heats Thin Strip Steel, and this method is to add above-mentioned high-temperature molten salt
Heat is sprayed onto from the strip outlet end of heating furnace on strip later to annealing temperature, and the heating fused salt and strip being then sprayed into are reverse
Movement, and strip is made to be submerged by fused salt, last fused salt exits into molten bath from the strip input end of heating furnace.
Preferably, pass through circulating-heating transport system between the fused salt import and molten bath of the strip outlet end setting of heating furnace
Heated and conveyed fused salt.As shown in Figure 1, circulating-heating transport system includes fused salt transfer pipeline, from fused salt transfer pipeline
Input end to the fused salt preheater 4 that sets gradually of outlet extreme direction and molten salt heater group, the inlet and outlet of fused salt transfer pipeline
It imports and exports and connects with the fused salt of heating furnace 2 respectively, filled high-temperature liquid fused salt in heating furnace, annealing electrical steel strip is by heating furnace
Fused salt be completely covered, since the thermal conductivity of fused salt is good, the electrical steel strip heated be heated evenly (plate describes easy to control), heating
Speed is very high.Fused salt after being preheated preheater by pump for liquid salts 5 imports molten salt heater group and heats, later from fused salt
The outlet of transfer pipeline imports the import of heating furnace.
Molten salt heater group include for after being preheated to preheater 4 the combustion heater 6 that is heated of fused salt and be used for
The electric heater 7 that fused salt after being heated to combustion heater 6 further heats.Preferably, pump for liquid salts is set to preheater and combustion gas
On conveyance conduit between heater.
The present invention coordinates above-mentioned heating process to carry out salt bath heating using above-mentioned fused salt, and heating speed is fast, temperature is uniform, anti-
Only steel band aoxidizes.The product iron loss by continuous annealing is set to reduce using the salt bath heating result of fused salt, magnetic strength is high, surface quality
It improves.Specifically, the fused salt in heating furnace 2, (using the exhaust gas of heating furnace discharge, passes through heat exchange by the preheating of preheater 4
Device heats the fused salt for flowing through heat exchanger for the first time, improves efficiency of energy utilization, and heating temperature is relatively low) after, by fused salt
Pump 5 is sent to the heating of combustion heater 6 and (coal gas, natural gas may be used as combustion medium, burn in heat exchanger, melt
Salt from heat exchanger external circuit by process by heat transfer carry out indirectly heat, the temperature that heating temperature is needed close to technique
Degree), temperature of molten salt, is accurately increased to the annealing process temperature of electrical sheet strip by directly heating by electric heater 7 again later
Degree is pipelined to nozzle 8, is ejected on strip and (ensures that steel band accurately reaches technological temperature when being exported from heating furnace, add
The reverse flow of fast Steel In Reheating Furnace band and fused salt promotes steel band preheating in heating furnace and heating effect).Fused salt is by inverse
To flowing to strip entrance.Strip is heated in the process of running, and fused salt is cooled.Cold fused salt is set from strip arrival end again
The fused salt outlet set is admitted to preheater, recycles above-mentioned heating process, completes the heat cycles of fused salt, realizes the company of continuous belt steel
Continuous quickly heating.
Using the above method, the thin electrician's strip 1 of cold rolling is by continuous annealing furnace, due to filled high-temperature fused salt in heating furnace,
Steel band is set 2 to be moved back in heating furnace then in 3 insulation annealing of soaking pit by fused salt rapidly pre-warming, the technological temperature for being heated to anneal
Steel band after fire leaves annealing furnace, completes subsequent technique.In continuous annealing furnace, heating furnace 2 and soaking pit 3 are to be isolated, two
It is connected by furnace throat between person, is High Temperature Gas privacy protection in furnace throat, and the fused salt of steel band can be blown off, ensure that steel band enters
Surface does not have fused salt when annealing furnace.In heating furnace, fused salt flow direction is with the steel band direction of motion on the contrary, annealing electrical steel strip quilt
The salt bath of heating furnace is completely covered, and steel band heating is to transfer heat to low-temperature steel band by high-temperature molten salt, makes the temperature of steel band
Rise rapidly to the technological temperature of annealing；Since the thermal conductivity of fused salt is good, the electrical steel strip heated is heated evenly that (plate describes easily
Control), heating speed it is very high.
As shown in Fig. 2, in order to remove the volatile substances such as the moisture in fused salt, the non-oxidizable of fused salt is kept, electrician is made
It when steel band is heated, does not aoxidize substantially, purifier, purifier container 10 is preferably provided in above-mentioned circulating-heating transport system
With for the vacuum plant 13 to being vacuumized inside container 10, the import of container 10 is by introducing the molten of pipe 9 and heating furnace 2
Salt export mouth connects, and the outlet 11 of container 10 heats piping connection by discharge pipe and fused salt.
Using above-mentioned purifier, the fused salt after steel band is heated in electrical steel continuous annealing stove, and appearance is discharged by introducing pipe 9
In device 10, under conditions of vacuum is kept, the readily volatilized substance such as moisture in fused salt is discharged, and keeps arranging from fused salt outlet
The degree of purity of the fused salt gone out.Vacuum interface tube on container 10 is connected to vacuum equipment by vacuum tube 12.Pass through vacuum purification
Fused salt afterwards is discharged from outlet.After being heated subsequently into fused salt heating circulation system, it is sent into heating stove heat steel band.Vacuum
Device may be used existing vacuum equipment and realize, such as vacuum filtration machine etc..It is preferably provided with filtering knot in the outlet of container
Structure avoids fused salt from being exported by vacuum tube.
Preferably, it introduces pipe 9 and chamber wall is tangent.It is connected alternatively, introducing pipe and being tilted with chamber wall, angle of inclination 0-
5°.So that the fused salt into container is rotated in chamber wall and then is slowly fallen, increases the time of fused salt exposure in a vacuum, carry
The degree of purity of high fused salt.
It is as follows using the specific preferred embodiment of above-mentioned fused salt：
It is to chemical composition：0.0025%C, 3.13%Si, 0.20%Mn, 0.0008%S, 1.05%Al, 0.0020%
N, 0.01%Sn, other are heated for the 0.50mm electrical steel strips of Fe and inevitable impurity, and then steel band is in soaking zone
Cooling, coating is carried out after heat preservation a period of time, obtains final products.
Embodiment 1
The group of the salt of the salt bath heating of fused salt becomes BaCl2And CaCl2, in 1 mole of fused salt, CaCl2Molar content is
0.60, BaCl2Molar content is 0.40.Mixed BaCl2And CaCl2It is heated to 1050 DEG C outside stove, obtains uniform salt
Solution.1050 DEG C of salting liquids are sprayed onto from the exit of electrical sheet continuous furnace on the electrical steel strip for requiring heating, make steel band quilt
1050 DEG C are heated to, then flows into molten bath, fused salt by flowing to electrical sheet continuous furnace bringing-up section again after outer pipeline heating
Entrance is dropped, the raising of low belt steel temperature by reverse flow temperature of molten salt, and then fused salt is discharged to outside stove to reheat to be formed and add
Heat, cooling cycle.
It it is 620 DEG C since the fusing point of fused salt is higher.Cold strip causes steel strip surface to have the knot of salt in into annealing furnace
Crystalline substance, but can be melted rapidly with the raising of steel strip surface temperature, surface crystallization.The fused salt of liquid can obtain high heating speed
Degree.
The equal temperature section temperature setting of product is consistent with temperature of molten salt, is 1050 DEG C, product P1.0/50For 2.25W/kg, magnetic strength B50
For 1.681T.
Embodiment 2
The group of the salt of the salt bath heating of fused salt becomes BaCl2And KCl, in 1 mole of fused salt, KCl molar contents are 0.70,
BaCl2Molar content is 0.30.Mixed BaCl21050 DEG C are heated to outside stove with KCl, obtains uniform salting liquid.
1050 DEG C of salting liquids, which are sprayed onto from the exit of electrical sheet continuous furnace bringing-up section on the electrical steel strip for requiring heating, makes steel band quilt
1050 DEG C are heated to, then flows into molten bath, fused salt by flowing to electrical sheet continuous furnace bringing-up section again after outer pipeline heating
Entrance is dropped, the raising of low belt steel temperature by reverse flow temperature of molten salt, and then fused salt is discharged to outside stove to reheat to be formed and add
Heat, cooling cycle.
It it is 660 DEG C since the fusing point of fused salt is higher.Cold strip causes steel strip surface to have the knot of salt in into annealing furnace
Crystalline substance, but can be melted rapidly with the raising of steel strip surface temperature, surface crystallization.The fused salt of liquid can obtain high heating speed
Degree.
The equal temperature section temperature setting of product is consistent with temperature of molten salt, is 1050 DEG C, product P1.0/50For 2.27W/kg, magnetic strength B50
For 1.683T.
Embodiment 3
The group of the salt of the salt bath heating of fused salt becomes BaCl2And NaCl, in 1 mole of fused salt, NaCl molar contents are
0.60、BaCl2Molar content is 0.40.Mixed BaCl21050 DEG C are heated to outside stove with NaCl, obtains uniform salt
Solution.1050 DEG C of salting liquids, which are sprayed onto from the exit of electrical sheet continuous furnace bringing-up section on the electrical steel strip for requiring heating, makes steel
Band is heated to 1050 DEG C, then flows into molten bath, fused salt by flowing to electrical sheet laser heating stove heat again after outer pipeline heating
The entrance of section is increased by reverse flow temperature of molten salt drop, low belt steel temperature, and then fused salt is discharged to outside stove and reheats to be formed
Heating, cooling cycle.
It it is 600 DEG C since the fusing point of fused salt is higher.Cold strip causes steel strip surface to have the knot of salt in into annealing furnace
Crystalline substance, but can be melted rapidly with the raising of steel strip surface temperature, surface crystallization.The fused salt of liquid can obtain high heating speed
Degree.
The equal temperature section temperature setting of product is consistent with temperature of molten salt, is 1050 DEG C, product P1.0/50For 2.23W/kg, magnetic strength B50
For 1.679T.
Comparative example 1
Strip is heated 1050 DEG C using radiant tube heating (RTF), subsequently into equal temperature section, equal temperature section temperature is set as
1050 DEG C, cooling, coating is carried out after keeping the temperature a period of time, obtains final products.
The equal temperature section temperature setting of product is consistent with temperature of molten salt, is 1050 DEG C, product P1.0/50For 2.36W/kg, magnetic strength B50
For 1.657T.
The present invention is exemplarily described above in association with attached drawing.Obviously, present invention specific implementation is not by above-mentioned side
The limitation of formula.As long as using the improvement of the various unsubstantialities of inventive concept and technical scheme of the present invention progress；Or not
It is improved, the above-mentioned design of the present invention and technical solution are directly applied into other occasions, in protection scope of the present invention
Within.
Claims (8)
1. a kind of quick laser heating high-temperature molten salt of Thin Strip Steel, which is characterized in that the fused salt is by barium chloride and calcium chloride, chlorine
Change any one or more composition in potassium or sodium chloride, the fusing point of the fused salt is 600-700 DEG C.
2. the quick laser heating high-temperature molten salt of Thin Strip Steel according to claim 1, which is characterized in that the fused salt is by chlorination
Barium is formed with calcium chloride, and in each mole of fused salt, the content of calcium chloride is 0.52-0.70 moles.
3. the quick laser heating high-temperature molten salt of Thin Strip Steel according to claim 2, which is characterized in that the calcium chloride contains
Amount is 0.64 mole, and the fusing point of fused salt is 608 DEG C.
4. the quick laser heating high-temperature molten salt of Thin Strip Steel according to claim 1, which is characterized in that the fused salt is by chlorination
Barium is formed with potassium chloride, and in each mole of fused salt, the content of potassium chloride is 0.55-0.73 moles.
5. the quick laser heating high-temperature molten salt of Thin Strip Steel according to claim 4, which is characterized in that the sodium chloride contains
Amount is 0.555 mole, and the fusing point of fused salt is 649 DEG C.
6. the quick laser heating high-temperature molten salt of Thin Strip Steel according to claim 1, which is characterized in that the fused salt is by chlorination
Barium is formed with sodium chloride, and in each mole of fused salt, the content of sodium chloride is 0.50-0.70 moles.
7. the quick laser heating high-temperature molten salt of Thin Strip Steel according to claim 6, which is characterized in that the sodium chloride contains
Amount is 0.601 mole, and the fusing point of fused salt is 650 DEG C.
8. a kind of method heating Thin Strip Steel using any one of the claim 1-7 high-temperature molten salts, which is characterized in that the side
Method is that high-temperature molten salt is heated to annealing temperature, is sprayed onto on strip from the strip outlet end of heating furnace later, and what is be then sprayed into adds
Salt and strip reverse movement are heated, and strip is made to be submerged by fused salt, last fused salt is exited into from the strip input end of heating furnace
Molten bath.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810611673.9A CN108754091B (en) | 2018-06-14 | 2018-06-14 | High-temperature molten salt for rapidly and continuously heating thin strip steel and heating method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810611673.9A CN108754091B (en) | 2018-06-14 | 2018-06-14 | High-temperature molten salt for rapidly and continuously heating thin strip steel and heating method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108754091A true CN108754091A (en) | 2018-11-06 |
| CN108754091B CN108754091B (en) | 2019-12-20 |
Family
ID=64022204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810611673.9A Active CN108754091B (en) | 2018-06-14 | 2018-06-14 | High-temperature molten salt for rapidly and continuously heating thin strip steel and heating method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108754091B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105899705A (en) * | 2014-03-20 | 2016-08-24 | 新日铁住金株式会社 | Favorably workable steel wire and method for producing same |
-
2018
- 2018-06-14 CN CN201810611673.9A patent/CN108754091B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105899705A (en) * | 2014-03-20 | 2016-08-24 | 新日铁住金株式会社 | Favorably workable steel wire and method for producing same |
Non-Patent Citations (3)
| Title |
|---|
| 中国机械工程学会热处理学会: "《热处理手册 第1卷工艺基础》", 31 October 2013, 机械工业出版社 * |
| 机械工业部上海材料研究所: "《机械工业材料科技成果选编 1979-1984》", 31 December 1985, 机械工业部科学技术司 * |
| 西北工业大学等二十三所高等院校《热处理化学》编写组: "《热处理化学》", 28 February 1982, 辽宁人民出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108754091B (en) | 2019-12-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104451372B (en) | A kind of preparation method of the high silicon non-oriented silicon steel plate of high magnetic strength | |
| CN108971224A (en) | A kind of checkered steel plate and its production method | |
| RU2013114861A (en) | METHOD FOR PRODUCING PRODUCTS FROM TEXTURED ELECTRICAL STEEL WITH HIGH DENSITY OF MAGNETIC FLOW | |
| CN104831037B (en) | The half craft type cold rolling non-oriented electrical steel and its manufacture method of a kind of low iron loss | |
| CN102658301B (en) | Control and modifying unit of scale of hot rolling strip steel | |
| CN209816207U (en) | Steel pipe non-oxidation normalizing device | |
| CN102179672B (en) | Technology for processing anti-bacterial stainless steel tube | |
| CN108754326A (en) | A kind of non-oriented electrical steel strip and its production method | |
| EP3164523B1 (en) | Multipurpose processing line for heat treating and hot dip coating a steel strip | |
| CN108754091A (en) | The quick laser heating high-temperature molten salt of Thin Strip Steel and its heating means | |
| CN108715925A (en) | Thin Strip Steel quick laser heating sodium chloride system fused salt and its heating means | |
| CN108456766A (en) | Thin Strip Steel quick laser heating aluminium chloride system fused salt and its heating means | |
| CN209010566U (en) | A kind of inert gas quenching continuous production impewdance matching system | |
| CN108588355A (en) | The quick heating means of electrical steel continuous annealing and its circulating-heating transport system | |
| CN208455025U (en) | A kind of fused salt electric installation | |
| CN104831039B (en) | A kind of electrical sheet annealing heating method | |
| CN105063301B (en) | The vertical laser heating quenching production equipment of aluminum alloy strip | |
| CN108660297A (en) | Electrical sheet annealed wire conducting type heating means and its heating circulation system | |
| JPS6344805B2 (en) | ||
| CN206512252U (en) | A kind of annealing furnace and annealing system | |
| CN108165876A (en) | A kind of method for improving low temperature nitriding orientation silicon steel surface quality | |
| CN107058705A (en) | A kind of production technology for the fastener applied in high ferro | |
| CN112226597A (en) | Cold rolling annealing method for cold-rolled strip steel | |
| CN109136490A (en) | A kind of orientation silicon steel environmental protection process equipment and environmental protection processing method | |
| CN208455024U (en) | Fused salt purification device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |