CN108753414A - A kind of closed operation oil additive and preparation method thereof - Google Patents
A kind of closed operation oil additive and preparation method thereof Download PDFInfo
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- CN108753414A CN108753414A CN201810707794.3A CN201810707794A CN108753414A CN 108753414 A CN108753414 A CN 108753414A CN 201810707794 A CN201810707794 A CN 201810707794A CN 108753414 A CN108753414 A CN 108753414A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
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Abstract
The present invention relates to a kind of closed operation oil additives and preparation method thereof, and raw material includes needed for the additive：Combustion adjuvant, detersive, lubricant, preservative, fungicide, antirust agent and antioxidant, wherein the raw material of combustion adjuvant includes one or more in isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, ethylo benzene class.Combustion adjuvant increases catalytic activity by rare earth element, acts synergistically together with other types combustion adjuvant, effectively reduces the discharge of smog and pernicious gas, provides safeguard for the working environment of enclosure space operating personnel；Simultaneously can decarbonizing and deposit, protect engine, play a very good protection to implement；Importantly, can also reduce operation oil mass, economy is improved, is tackled the problem at its root.
Description
Technical field
The present invention relates to fuel oil additives, and in particular to a kind of closed operation oil additive.
Background technology
With the progress of the development and science and technology of society, the closed operations such as underground, tunnel increase therewith, modernization underground, tunnel
Road large scale equipment also rapidly develops, and the required diesel oil amount of operation is continuously increased, while problem encountered is also to emerge one after another.
The enclosure spaces such as underground, tunnel, oxygen content in air is low, causes engine oxygen feeding amount few, and diesel combustion is incomplete, combustion
Burning slows, and engine power declines, oil consumption sharply increases, and exhaust emissions deteriorates, and generates a large amount of smog and pernicious gas,
Aggravate the generation of carbon distribution and deposit, underground, tunnel are a closed spaces in addition, this is directly related to the work of operating personnel
Make environment and physical and mental health；The carbon distribution and deposit that diesel oil generates in use, badly damaged equipment influence to use, together
When, mordant component is contained in diesel oil, can etching apparatus oil piping system, damage engine；Underground, tunneling operation oil mass
It is larger, how it is fuel-efficient more allow bosses' headache endlessly.
Invention content
In order to solve the above technical problem, the present invention provides a kind of closed operation oil additives.
According to an aspect of the invention, there is provided a kind of closed operation oil additive, raw material needed for the additive
Including：
Combustion adjuvant, detersive, lubricant, preservative, fungicide, antirust agent and antioxidant,
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, second
It is one or more in base benzene class.
Further, in parts by weight, combustion adjuvant 58.4-70.7 parts, 1.2-3.0 parts of detersive, 12-19.5 parts of lubricant,
1.5-4 parts of 7-11 parts of preservative, 1.5-3 parts of fungicide, 1.5-4 parts of antirust agent and antioxidant.
The raw material selection of combustion adjuvant, detersive, lubricant, preservative, fungicide, antirust agent and antioxidant at least meets
Following one,
The raw material of detersive include methyl amine, naphthalenes it is one or more；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid
Class, ethyl hexyl esters it is one or more；
The raw material of preservative include phenoxy propionic acid, decene class, hexanol class, hydrogen indene it is one or more；
The raw material of fungicide include phenol, ketone (thiosemicarbazone) it is one or more；
The raw material of antirust agent include fatty acid ester, succinic acid class it is one or more；
The raw material of antioxidant include dicyclohexyl amine class, azanol class it is one or more.
Further, in parts by weight,
The raw material of combustion adjuvant includes 46.7-52 parts of butyl peroxy class, 0.3-0.9 parts of aliphatic ketone, methylbenzene class 2.4-
4.3 parts, 1.0-1.5 parts of ethylo benzene class, 8-12 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.05-0.25 parts of methyl amine, 1.15-2.75 parts of naphthalenes,
The raw material of lubricant includes 0.03-0.08 parts of binary acid esters, 0.03-0.09 parts of sulfurous esters, hexene esters
0.04-0.13 parts, 8-14 parts of diene acids, 3-3.9 parts of hexanol class, 0.3-0.5 parts of alkanoic acid class, 0.6-0.8 parts of ethyl hexyl esters,
The raw material of preservative includes 0.06-0.2 parts of phenoxy propionic acid, 0.75-1.6 parts of decene class, 4.37-6.2 parts of hexanol class, hydrogen
1.82-3.0 parts of indene,
The raw material of fungicide includes 0.05-0.2 parts of phenol, 1.45-2.8 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 0.5-1.5 parts of fatty acid ester, 1-2.5 parts of succinic acid class,
The raw material of antioxidant includes 1-2.5 parts of dicyclohexyl amine class, 0.5-1.5 parts of azanol class.
Further, in parts by weight,
The raw material of combustion adjuvant includes 46.7-50 parts of butyl peroxy class, 0.5-0.8 parts of aliphatic ketone, methylbenzene class 2.8-
3.3 parts, 1.0-1.5 parts of ethylo benzene class, 9-11 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.07-0.15 parts of methyl amine, 1.4-2.2 parts of naphthalenes,
The raw material of lubricant includes 0.03-0.08 parts of binary acid esters, 0.04-0.08 parts of sulfurous esters, hexene esters
0.05-0.10 parts, 10-13 parts of diene acids, 3-3.9 parts of hexanol class, 0.3-0.45 parts of alkanoic acid class, ethyl hexyl esters 0.6-0.8
Part,
The raw material of preservative includes 0.08-0.15 parts of phenoxy propionic acid, 1.0-1.6 parts of decene class, 5.0-6.0 parts of hexanol class, hydrogen
2.0-2.6 parts of indene,
The raw material of fungicide includes 0.08-0.16 parts of phenol, 1.5-2.4 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 0.5-1.5 parts of fatty acid ester, 1-2.0 parts of succinic acid class,
The raw material of antioxidant includes 1.5-2.0 parts of dicyclohexyl amine class, 0.5-1.5 parts of azanol class.
Further,
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, methylbenzene
Class combustion adjuvant includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, and ethylo benzene class combustion adjuvant includes 1,2- diethyl-
Benzene, isooctoate of rare earth metal class combustion adjuvant includes isocaprylic acid lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, naphthalenes detersive include naphthalene,
2- methyl naphthalenes,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes Asia
Sulfuric acid-two (cyclohexyl methyl) ester, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids
Lubricant includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid
Series lubricant agent includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2, the 4- dimethyl -1- last of the ten Heavenly stems
Alkene, hexanol class preservative include 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,
6,7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4-
(p- methoxyphenyls) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes laurylene base fourth two
Acid, dicyclohexyl amine class antioxidant include N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
Further, trimethylbenzene class combustion adjuvant includes 1, and 2,3- trimethyls-benzene, durol class combustion adjuvant includes benzene, and 1,
2,3,5- tetramethyls-benzene, 1.3-2.3 parts of trimethylbenzene class combustion adjuvant, 1.1-2.0 parts of durol class combustion adjuvant.
Further, naphthalene 1-2.0 parts, 0.15-0.75 parts of 2- methyl naphthalenes.
The closed operation is diesel oil with oil.
The closed operation is underground or tunneling operation.
According to another aspect of the present invention, the preparation method for providing the closed operation oil additive, will add
Add raw material needed for agent to be uniformly mixed to obtain the final product.
Compared with prior art, the invention has the advantages that：
1, the exemplary closed operation oil additive of the present invention, combustion adjuvant include isooctoate of rare earth metal class and butyl peroxy class,
One or more in aliphatic ketone, methylbenzene class, ethylo benzene class, combustion adjuvant increases catalytic activity by rare earth element, with
Other types combustion adjuvant acts synergistically together, is adsorbed to the activation of fuel molecule and oxygen, realizes the abundant mist of closed operation oil
Change, improve the after-flame degree of closed operation oil firing, reduces the chemistry not exclusively combustion of enclosure space inner sealing operation oil
The discharge capacity of flue dust and pernicious gas, slows down carbon distribution and deposit in heat loss and exhaust gas that burning and mechanical incomplete combustion are taken away
Generation, detersive pierces in the hole of carbon distribution and destroys its structure, and encirclement is split to it, make carbon distribution out of engine its
Depended on position falls off, and is started by lubricant raising to realize that carbon distribution is removed with closed operation oil together high-temp combustion
The lubricity of machine, the in addition addition of preservative, fungicide, antirust agent and antioxidant, effectively reduces smog and pernicious gas
Discharge, provide safeguard for the working environment of enclosure space operating personnel, harmful substance and PM2.5 discharges 95% can be reduced；Together
When can decarbonizing and deposit, reduce carbon-deposits the cylinder deposit 92%, protect engine, good guarantor is played to implement
Shield acts on；Importantly, can also reduce operation oil mass, fuel oil 12% is saved, economy is improved, tackles the problem at its root.
2, the preparation method of the exemplary closed operation oil additive of the present invention, preparation method simple possible are convenient for the production
The preparation and popularization of product.
Specific implementation mode
In order to be better understood by technical scheme of the present invention, the present invention is made furtherly with reference to specific embodiment
It is bright.
Embodiment one：
The closed operation oil additive of the present embodiment, raw material needed for the additive include：
In parts by weight, 58.4 parts of combustion adjuvant, 1.2 parts of detersive, 12 parts of lubricant, 7 parts of preservative, 1.5 parts of fungicide,
1.5 parts of 1.5 parts of antirust agent and antioxidant.
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, second
Base benzene class.
The raw material of detersive includes methyl amine, naphthalenes；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid
Class, ethyl hexyl esters；
The raw material of preservative includes phenoxy propionic acid, decene class, hexanol class, hydrogen indene；
The raw material of fungicide includes phenol, ketone (thiosemicarbazone)；
The raw material of antirust agent includes fatty acid ester, succinic acid class；
The raw material of antioxidant includes dicyclohexyl amine class, azanol class.
In parts by weight,
The raw material of combustion adjuvant includes 46.7 parts of butyl peroxy class, 0.3 part of aliphatic ketone, 2.4 parts of methylbenzene class, ethylo benzene
1.0 parts of class, 8 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.05 part of methyl amine, 1.15 parts of naphthalenes,
The raw material of lubricant includes 0.03 part of binary acid esters, 0.03 part of sulfurous esters, 0.04 part of hexene esters, diene
8 parts of acids, 3 parts of hexanol class, 0.3 part of alkanoic acid class, 0.6 part of ethyl hexyl esters,
The raw material of preservative includes 0.06 part of phenoxy propionic acid, 0.75 part of decene class, 4.37 parts of hexanol class, 1.82 parts of hydrogen indene,
The raw material of fungicide includes 0.05 part of phenol, 1.45 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 0.5 part of fatty acid ester, 1 part of succinic acid class,
The raw material of antioxidant includes 1 part of dicyclohexyl amine class, 0.5 part of azanol class.
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, methylbenzene
Class combustion adjuvant includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, wherein trimethylbenzene class combustion adjuvant includes 1,2,3-
Trimethyl-benzene, durol class combustion adjuvant include benzene, 1,2,3,5- tetramethyl-benzene, 1.3 parts of trimethylbenzene class combustion adjuvant, tetramethyl
1.1 parts of base benzene class combustion adjuvant, ethylo benzene class combustion adjuvant include 1,2- diethyl-benzene, and isooctoate of rare earth metal class combustion adjuvant includes different pungent
Sour lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, naphthalenes detersive include naphthalene,
2- methyl naphthalenes, wherein 1 part of naphthalene, 0.15 part of 2- methyl naphthalenes,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes Asia
Sulfuric acid-two (cyclohexyl methyl) ester, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids
Lubricant includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid
Series lubricant agent includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2, the 4- dimethyl -1- last of the ten Heavenly stems
Alkene, hexanol class preservative include 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,
6,7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4-
(p- methoxyphenyls) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes laurylene base fourth two
Acid, dicyclohexyl amine class antioxidant include N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
The closed operation is diesel oil with oil.
Raw material needed for additive is uniformly mixed to obtain the final product by the preparation process of the closed operation oil additive.
Embodiment two：
The closed operation oil additive of the present embodiment, raw material needed for the additive include：
In parts by weight, 70.7 parts of combustion adjuvant, 3.0 parts of detersive, 19.5 parts of lubricant, 11 parts of preservative, fungicide 3
4 parts of part, 4 parts of antirust agent and antioxidant.
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, second
Base benzene class.
The raw material of detersive includes methyl amine, naphthalenes；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid
Class, ethyl hexyl esters；
The raw material of preservative includes phenoxy propionic acid, decene class, hexanol class, hydrogen indene；
The raw material of fungicide includes phenol, ketone (thiosemicarbazone)；
The raw material of antirust agent includes fatty acid ester, succinic acid class；
The raw material of antioxidant includes dicyclohexyl amine class, azanol class.
In parts by weight,
The raw material of combustion adjuvant includes 52 parts of butyl peroxy class, 0.9 part of aliphatic ketone, 4.3 parts of methylbenzene class, ethylo benzene class
1.5 parts, 12 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.25 part of methyl amine, 2.75 parts of naphthalenes,
The raw material of lubricant includes 0.08 part of binary acid esters, 0.09 part of sulfurous esters, 0.13 part of hexene esters, diene
14 parts of acids, 3.9 parts of hexanol class, 0.5 part of alkanoic acid class, 0.8 part of ethyl hexyl esters,
The raw material of preservative includes 0.2 part of phenoxy propionic acid, 1.6 parts of decene class, 6.2 parts of hexanol class, 3.0 parts of hydrogen indene,
The raw material of fungicide includes 0.2 part of phenol, 2.8 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 1.5 parts of fatty acid ester, 2.5 parts of succinic acid class,
The raw material of antioxidant includes 2.5 parts of dicyclohexyl amine class, 1.5 parts of azanol class.
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, methylbenzene
Class combustion adjuvant includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, wherein trimethylbenzene class combustion adjuvant includes 1,2,3-
Trimethyl-benzene, durol class combustion adjuvant include benzene, 1,2,3,5- tetramethyl-benzene, 2.3 parts of trimethylbenzene class combustion adjuvant, tetramethyl
2.0 parts of base benzene class combustion adjuvant, ethylo benzene class combustion adjuvant include 1,2- diethyl-benzene, and isooctoate of rare earth metal class combustion adjuvant includes different pungent
Sour lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, naphthalenes detersive include naphthalene,
2- methyl naphthalenes, wherein 2.0 parts of naphthalene, 0.75 part of 2- methyl naphthalenes,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes Asia
Sulfuric acid-two (cyclohexyl methyl) ester, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids
Lubricant includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid
Series lubricant agent includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2, the 4- dimethyl -1- last of the ten Heavenly stems
Alkene, hexanol class preservative include 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,
6,7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4-
(p- methoxyphenyls) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes laurylene base fourth two
Acid, dicyclohexyl amine class antioxidant include N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
The closed operation is diesel oil with oil.
Raw material needed for additive is uniformly mixed to obtain the final product by the preparation process of the closed operation oil additive.
Embodiment three：
The closed operation oil additive of the present embodiment, raw material needed for the additive include：
In parts by weight, 60 parts of combustion adjuvant, 1.47 parts of detersive, 14.02 parts of lubricant, 8.08 parts of preservative, fungicide
2 parts of 1.58 parts, 1.5 parts of antirust agent and antioxidant.
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, second
Base benzene class.
The raw material of detersive includes methyl amine, naphthalenes；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid
Class, ethyl hexyl esters；
The raw material of preservative includes phenoxy propionic acid, decene class, hexanol class, hydrogen indene；
The raw material of fungicide includes phenol, ketone (thiosemicarbazone)；
The raw material of antirust agent includes fatty acid ester, succinic acid class；
The raw material of antioxidant includes dicyclohexyl amine class, azanol class.
In parts by weight,
The raw material of combustion adjuvant includes 46.7 parts of butyl peroxy class, 0.5 part of aliphatic ketone, 2.8 parts of methylbenzene class, ethylo benzene
1.0 parts of class, 9 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.07 part of methyl amine, 1.4 parts of naphthalenes,
The raw material of lubricant includes 0.03 part of binary acid esters, 0.04 part of sulfurous esters, 0.05 part of hexene esters, diene
10 parts of acids, 3 parts of hexanol class, 0.3 part of alkanoic acid class, 0.6 part of ethyl hexyl esters,
The raw material of preservative includes 0.08 part of phenoxy propionic acid, 1.0 parts of decene class, 5.0 parts of hexanol class, 2.0 parts of hydrogen indene,
The raw material of fungicide includes 0.08 part of phenol, 1.5 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 0.5 part of fatty acid ester, 1 part of succinic acid class,
The raw material of antioxidant includes 1.5 parts of dicyclohexyl amine class, 0.5 part of azanol class.
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, methylbenzene
Class combustion adjuvant includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, wherein trimethylbenzene class combustion adjuvant includes 1,2,3-
Trimethyl-benzene, durol class combustion adjuvant include benzene, 1,2,3,5- tetramethyl-benzene, 1.6 parts of trimethylbenzene class combustion adjuvant, tetramethyl
1.2 parts of base benzene class combustion adjuvant, ethylo benzene class combustion adjuvant include 1,2- diethyl-benzene, and isooctoate of rare earth metal class combustion adjuvant includes different pungent
Sour lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, naphthalenes detersive include naphthalene,
2- methyl naphthalenes, wherein 1.2 parts of naphthalene, 0.2 part of 2- methyl naphthalenes,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes Asia
Sulfuric acid-two (cyclohexyl methyl) ester, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids
Lubricant includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid
Series lubricant agent includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2, the 4- dimethyl -1- last of the ten Heavenly stems
Alkene, hexanol class preservative include 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,
6,7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4-
(p- methoxyphenyls) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes laurylene base fourth two
Acid, dicyclohexyl amine class antioxidant include N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
The closed operation is diesel oil with oil.
Raw material needed for additive is uniformly mixed to obtain the final product by the preparation process of the closed operation oil additive.
Example IV：
The closed operation oil additive of the present embodiment, raw material needed for the additive include：
In parts by weight, 66.6 parts of combustion adjuvant, 2.35 parts of detersive, 18.41 parts of lubricant, 10.35 parts of preservative, sterilization
3.5 parts of 2.56 parts of agent, 3.5 parts of antirust agent and antioxidant.
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, second
Base benzene class.
The raw material of detersive includes methyl amine, naphthalenes；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid
Class, ethyl hexyl esters；
The raw material of preservative includes phenoxy propionic acid, decene class, hexanol class, hydrogen indene；
The raw material of fungicide includes phenol, ketone (thiosemicarbazone)；
The raw material of antirust agent includes fatty acid ester, succinic acid class；
The raw material of antioxidant includes dicyclohexyl amine class, azanol class.
In parts by weight,
The raw material of combustion adjuvant includes 50 parts of butyl peroxy class, 0.8 part of aliphatic ketone, 3.3 parts of methylbenzene class, ethylo benzene class
1.5 parts, 11 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.15 part of methyl amine, 2.2 parts of naphthalenes,
The raw material of lubricant includes 0.08 part of binary acid esters, 0.08 part of sulfurous esters, 0.10 part of hexene esters, diene
13 parts of acids, 3.9 parts of hexanol class, 0.45 part of alkanoic acid class, 0.8 part of ethyl hexyl esters,
The raw material of preservative includes 0.15 part of phenoxy propionic acid, 1.6 parts of decene class, 6.0 parts of hexanol class, 2.6 parts of hydrogen indene,
The raw material of fungicide includes 0.16 part of phenol, 2.4 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 1.5 parts of fatty acid ester, 2.0 parts of succinic acid class,
The raw material of antioxidant includes 2.0 parts of dicyclohexyl amine class, 1.5 parts of azanol class.
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, methylbenzene
Class combustion adjuvant includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, wherein trimethylbenzene class combustion adjuvant includes 1,2,3-
Trimethyl-benzene, durol class combustion adjuvant include benzene, 1,2,3,5- tetramethyl-benzene, trimethylbenzene class combustion adjuvant 1.8, tetramethyl
Benzene class combustion adjuvant 1.5, ethylo benzene class combustion adjuvant include 1,2- diethyl-benzene, and isooctoate of rare earth metal class combustion adjuvant includes isocaprylic acid lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, naphthalenes detersive include naphthalene,
2- methyl naphthalenes, wherein 1.65 parts of naphthalene, 0.55 part of 2- methyl naphthalenes,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes Asia
Sulfuric acid-two (cyclohexyl methyl) ester, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids
Lubricant includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid
Series lubricant agent includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2, the 4- dimethyl -1- last of the ten Heavenly stems
Alkene, hexanol class preservative include 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,
6,7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4-
(p- methoxyphenyls) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes laurylene base fourth two
Acid, dicyclohexyl amine class antioxidant include N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
The closed operation is diesel oil with oil.
Raw material needed for additive is uniformly mixed to obtain the final product by the preparation process of the closed operation oil additive.
Embodiment five：
The closed operation oil additive of the present embodiment, raw material needed for the additive include：
In parts by weight, 65.117 parts of combustion adjuvant, 1.986 parts of detersive, 16.018 parts of lubricant, 9.343 parts of preservative,
2.7 parts of 2.336 parts of fungicide, 2.5 parts of antirust agent and antioxidant.
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, second
Base benzene class；
The raw material of detersive includes methyl amine, naphthalenes；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid
Class, ethyl hexyl esters；
The raw material of preservative includes phenoxy propionic acid, decene class, hexanol class, hydrogen indene；
The raw material of fungicide includes phenol, ketone (thiosemicarbazone)；
The raw material of antirust agent includes fatty acid ester, succinic acid class；
The raw material of antioxidant includes dicyclohexyl amine class, azanol class.
In parts by weight,
The raw material of combustion adjuvant includes 50 parts of butyl peroxy class, 0.689 part of aliphatic ketone, 3.135 parts of methylbenzene class, ethyl
1.293 parts of benzene class, 10 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.103 part of methyl amine, 1.883 parts of naphthalenes,
The raw material of lubricant include 0.048 part of binary acid esters, 0.064 part of sulfurous esters, 0.077 part of hexene esters,
11.173 parts of diene acids, 3.574 parts of hexanol class, 0.39 part of alkanoic acid class, 0.692 part of ethyl hexyl esters,
The raw material of preservative includes 0.128 part of phenoxy propionic acid, 1.378 parts of decene class, 5.439 parts of hexanol class, hydrogen indene 2.398
Part,
The raw material of fungicide includes 0.139 part of phenol, 2.197 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 1 part of fatty acid ester, 1.5 parts of succinic acid class,
The raw material of antioxidant includes 1.7 parts of dicyclohexyl amine class, 1 part of azanol class.
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, methylbenzene
Class combustion adjuvant includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, wherein trimethylbenzene class combustion adjuvant includes 1,2,3-
Trimethyl-benzene, durol class combustion adjuvant include benzene, 1,2,3,5- tetramethyl-benzene, trimethylbenzene class combustion adjuvant 1.661, tetramethyl
Base benzene class combustion adjuvant 1.474, ethylo benzene class combustion adjuvant include 1,2- diethyl-benzene, and isooctoate of rare earth metal class combustion adjuvant includes different pungent
Sour lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, naphthalenes detersive include naphthalene,
2- methyl naphthalenes, wherein 1.608 parts of naphthalene, 0.275 part of 2- methyl naphthalenes,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes Asia
Sulfuric acid-two (cyclohexyl methyl) ester, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids
Lubricant includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid
Series lubricant agent includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2, the 4- dimethyl -1- last of the ten Heavenly stems
Alkene, hexanol class preservative include 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,
6,7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4-
(p- methoxyphenyls) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes laurylene base fourth two
Acid, dicyclohexyl amine class antioxidant include N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
The closed operation is diesel oil with oil.
Raw material needed for additive is uniformly mixed to obtain the final product by the preparation process of the closed operation oil additive.
Embodiment six：
The present embodiment feature identical with embodiment one repeats no more, and the present embodiment feature different from embodiment one exists
In：
The raw material of combustion adjuvant includes butyl peroxy class, isooctoate of rare earth metal class, both butyl peroxy class, isooctoate of rare earth metal class
Amount ratio is 5.5:1,
The raw material of detersive includes naphthalenes,
The raw material of lubricant includes diene acids,
The raw material of preservative includes hexanol class,
The raw material of fungicide includes ketone (thiosemicarbazone),
The raw material of antirust agent includes succinic acid class,
The raw material of antioxidant includes dicyclohexyl amine class.
Above description is only the preferred embodiment of the application and the explanation to institute's application technology principle.People in the art
Member should be appreciated that invention scope involved in the application, however it is not limited to technology made of the specific combination of above-mentioned technical characteristic
Scheme, while should also cover in the case where not departing from the inventive concept, it is carried out by above-mentioned technical characteristic or its equivalent feature
Other technical solutions of arbitrary combination and formation.Such as features described above has similar work(with (but not limited to) disclosed herein
Can technical characteristic replaced mutually and the technical solution that is formed.
Claims (10)
1. a kind of closed operation oil additive, characterized in that raw material includes needed for the additive：
Combustion adjuvant, detersive, lubricant, preservative, fungicide, antirust agent and antioxidant,
Wherein, the raw material of combustion adjuvant includes isooctoate of rare earth metal class and butyl peroxy class, aliphatic ketone, methylbenzene class, ethylo benzene
It is one or more in class.
2. closed operation oil additive according to claim 1, characterized in that in parts by weight, combustion adjuvant 58.4-
70.7 parts, 1.2-3.0 parts of detersive, 12-19.5 parts of lubricant, 7-11 parts of preservative, 1.5-3 parts of fungicide, antirust agent 1.5-4
1.5-4 parts of part and antioxidant.
3. closed operation oil additive according to claim 1 or 2, characterized in that detersive, lubricant, preservative,
The raw material selection of fungicide, antirust agent and antioxidant at least meets following one,
The raw material of detersive include methyl amine, naphthalenes it is one or more；
The raw material of lubricant includes binary acid esters, sulfurous esters, hexene esters, diene acids, hexanol class, alkanoic acid class, second
The own esters of base it is one or more；
The raw material of preservative include phenoxy propionic acid, decene class, hexanol class, hydrogen indene it is one or more；
The raw material of fungicide include phenol, ketone (thiosemicarbazone) it is one or more；
The raw material of antirust agent include fatty acid ester, succinic acid class it is one or more；
The raw material of antioxidant include dicyclohexyl amine class, azanol class it is one or more.
4. closed operation oil additive according to claim 3, characterized in that in parts by weight,
The raw material of combustion adjuvant includes 46.7-52 parts of butyl peroxy class, 0.3-0.9 parts of aliphatic ketone, methylbenzene class 2.4-4.3
Part, 1.0-1.5 parts of ethylo benzene class, 8-12 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.05-0.25 parts of methyl amine, 1.15-2.75 parts of naphthalenes,
The raw material of lubricant includes 0.03-0.08 parts of binary acid esters, 0.03-0.09 parts of sulfurous esters, hexene esters 0.04-
0.13 part, 8-14 parts of diene acids, 3-3.9 parts of hexanol class, 0.3-0.5 parts of alkanoic acid class, 0.6-0.8 parts of ethyl hexyl esters,
The raw material of preservative includes 0.06-0.2 parts of phenoxy propionic acid, 0.75-1.6 parts of decene class, 4.37-6.2 parts of hexanol class, hydrogen indene
1.82-3.0 part,
The raw material of fungicide includes 0.05-0.2 parts of phenol, 1.45-2.8 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 0.5-1.5 parts of fatty acid ester, 1-2.5 parts of succinic acid class,
The raw material of antioxidant includes 1-2.5 parts of dicyclohexyl amine class, 0.5-1.5 parts of azanol class.
5. closed operation oil additive according to claim 4, characterized in that in parts by weight,
The raw material of combustion adjuvant includes 46.7-50 parts of butyl peroxy class, 0.5-0.8 parts of aliphatic ketone, methylbenzene class 2.8-3.3
Part, 1.0-1.5 parts of ethylo benzene class, 9-11 parts of isooctoate of rare earth metal class,
The raw material of detersive includes 0.07-0.15 parts of methyl amine, 1.4-2.2 parts of naphthalenes,
The raw material of lubricant includes 0.03-0.08 parts of binary acid esters, 0.04-0.08 parts of sulfurous esters, hexene esters 0.05-
0.10 part, 10-13 parts of diene acids, 3-3.9 parts of hexanol class, 0.3-0.45 parts of alkanoic acid class, 0.6-0.8 parts of ethyl hexyl esters,
The raw material of preservative includes 0.08-0.15 parts of phenoxy propionic acid, 1.0-1.6 parts of decene class, 5.0-6.0 parts of hexanol class, hydrogen indene
2.0-2.6 parts,
The raw material of fungicide includes 0.08-0.16 parts of phenol, 1.5-2.4 parts of ketone (thiosemicarbazone),
The raw material of antirust agent includes 0.5-1.5 parts of fatty acid ester, 1-2.0 parts of succinic acid class,
The raw material of antioxidant includes 1.5-2.0 parts of dicyclohexyl amine class, 0.5-1.5 parts of azanol class.
6. closed operation oil additive according to claim 4, characterized in that
Butyl peroxy class combustion adjuvant includes di-tert-butyl hydrogen peroxide, and aliphatic ketone combustion adjuvant includes acetone, and methylbenzene class helps
Combustion agent includes trimethylbenzene class combustion adjuvant, durol class combustion adjuvant, and ethylo benzene class combustion adjuvant includes 1,2- diethyl-benzene, different
Sad terres rares combustion adjuvant includes isocaprylic acid lanthanum,
Methyl amine detersive includes N- (2- difluorophenyls)-thiophenol -2- methyl amines, and naphthalenes detersive includes naphthalene, 2- first
Base naphthalene,
Dibasic acid ester series lubricant agent includes 2- acrylic-propane diacid dimethyl esters, and sulfite series lubricant agent includes sulfurous acid-
Two (cyclohexyl methyl) esters, hexene ester lubricant include (2E) -2- hexenoic acids (E, E)-hexene -1- esters, diene acids lubrication
Agent includes (Z, Z) -9,12- octadecadienoic acids (linoleic acid), and hexanol series lubricant agent includes 2- ethyls-n-hexyl alcohol, alkanoic acid class profit
Lubrication prescription includes n-hexadecanoic, and ethylhexyl series lubricant agent includes 2-ethyl hexyl ethanoate,
Phenoxy propionic acid preservative includes 1,2- benzisothiazole -3- propionic acid, and decene class preservative includes 2,4- dimethyl -1- decene,
Hexanol class preservative includes 2- ethyls-n-hexyl alcohol, and hydrogen indene preservative includes 3a, 6-Methano-3aH- indenes, and 2,3,4,5,6,
7- hexahydros,
Phenol series bactericidal agent includes phenol (1,1- dimethyl propyl)-phenol, and ketone thiosemicarbazones series bactericidal agent includes 4- (p- first
Phenyl) -3- butene-2s -one-thiosemicarbazones,
Fatty acid ester antirust agent includes sorbitol aliphatic ester, and succinic acid class antirust agent includes dodecenylsuccinic acid, and two
Hexamethylene amine antioxidant includes N.N dicyclohexyl amines, and hydroxyl amine antioxidants includes azanol.
7. closed operation oil additive according to claim 6, characterized in that
Trimethylbenzene class combustion adjuvant includes 1, and 2,3- trimethyls-benzene, durol class combustion adjuvant includes benzene, 1,2,3,5- tetramethyl
Base-benzene, 1.3-2.3 parts of trimethylbenzene class combustion adjuvant, 1.1-2.0 parts of durol class combustion adjuvant.
8. closed operation oil additive according to claim 6, characterized in that
1-2.0 parts of naphthalene, 0.15-0.75 parts of 2- methyl naphthalenes.
9. closed operation oil additive according to claim 1, characterized in that the closed operation is diesel oil with oil.
10. according to the preparation method of any closed operation oil additives of claim 1-9, characterized in that will add
Raw material needed for agent is uniformly mixed to obtain the final product.
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| CN101070501A (en) * | 2006-05-08 | 2007-11-14 | 马征坤 | Energy-saving environment-protective fuel-oil compounding agent |
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| CN101070501A (en) * | 2006-05-08 | 2007-11-14 | 马征坤 | Energy-saving environment-protective fuel-oil compounding agent |
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Application publication date: 20181106 |