CN108753280A - A kind of synthetic paper - Google Patents

A kind of synthetic paper Download PDF

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Publication number
CN108753280A
CN108753280A CN201810781100.0A CN201810781100A CN108753280A CN 108753280 A CN108753280 A CN 108753280A CN 201810781100 A CN201810781100 A CN 201810781100A CN 108753280 A CN108753280 A CN 108753280A
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China
Prior art keywords
acid
long
ester
afterglow
enumerate
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CN201810781100.0A
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Chinese (zh)
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杨道救
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Individual
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Individual
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Priority to CN201810781100.0A priority Critical patent/CN108753280A/en
Publication of CN108753280A publication Critical patent/CN108753280A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7783—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals one of which being europium
    • C09K11/7792—Aluminates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63G—MERRY-GO-ROUNDS; SWINGS; ROCKING-HORSES; CHUTES; SWITCHBACKS; SIMILAR DEVICES FOR PUBLIC AMUSEMENT
    • A63G1/00—Roundabouts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F13/00—Illuminated signs; Luminous advertising
    • G09F13/20—Illuminated signs; Luminous advertising with luminescent surfaces or parts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50—Wavelength conversion elements
    • H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
    • H01L33/502—Wavelength conversion materials

Abstract

The invention belongs to fluorescent powder application fields, more particularly to a kind of synthetic paper.Contain red long-afterglow phosphor inside the synthetic paper, the chemical composition general formula of red long-afterglow phosphor is Sr3‑x‑ ySiAlO5Cl3:xEu2+,yRe3+, wherein Re is Dy, and one or more of Gd and Nd are combined, and the value range of x and y are respectively：0.01≤x≤0.05,0.01≤y≤0.10.The centre of luminescence of the fluorescent powder is Eu2+Ion, by introducing Dy3+, Gd3+And Nd3+Equal rare earth impurities ion can effectively enhance its long afterglow effect.The long lad phosphor of the present invention has the characteristics that chemical stability is good, after-glow brightness is high, persistence is long.

Description

A kind of synthetic paper
The application is divisional application, the applying date of original application：2017-11-02, original applying number：2017110616047,
The denomination of invention of original application：A kind of red long-afterglow phosphor and preparation method thereof.
Technical field
The invention belongs to fluorescent powder application fields, more particularly to a kind of synthetic paper.
Background technology
Luminescent material can absorb various forms of energy from the external world and be converted into light radiation, and illumination mode is a variety of more Sample, emission type mainly have luminescence generated by light, cathode-ray luminescence, electroluminescent, thermoluminescence, radioluminescence etc..Long afterglow is sent out Luminescent material is otherwise known as light-storing material, energy-saving luminous material or Noctilucent material, has in solar energy conversion and use aspects only Special advantage, can store solar energy, evening slow release daytime, be a kind of important light-light conversion material and section Can material, academicly referred to as long phosphorescence fluorescent body or long time luminescent material.Long after glow luminous material industrial and agricultural production, military affairs, Many aspects of fire-fighting and people's life are used widely, and especially in terms of safety instruction, long after glow luminous material can be with Play the role of prodigious.So far, long after glow luminous material building decoration, communications and transportation, military installations, fire-fighting emergent with And the research of daily necessities etc. is very much, diversified long after glow luminous material occurs, from simple matrix It shines, the solid material of rare earth ion doped special matrix till now, luminous performance is also all improved constantly.To length Afterglow materials base Quality Research mainly experienced sulfide, aluminate, silicate, titanate, sulphur oxidation in chronological order Five stages such as object.In terms of largely all concentrating on blue-green luminous material for the research of long after glow luminous material at present, and It is less for the research and report of red long-afterglow phosphor, it is concentrated mainly on sulfide and oxysulfide series.
Sulfide series long after glow luminous material has very long history, is truly realized industrialized production early 20th century. Sulfide series long after glow luminous material includes mainly zinc sulphide, calcium sulfide, barium sulphide, strontium sulfide, cadmium sulfide etc., wherein vulcanizing Zinc material most study is applied also relatively wider.With Eu2+As in the sulfide systems of activator, red emission belongs to Eu2+4f65d1-4f7Between electron transition emit.Such as ZnS: Eu2+、SrS: Eu2+, Er3+、Ca1-xSrxS: Eu2+, Dy3+, Er3+Deng.In addition, rare earth ion Sm3+、Yb3+The calcium sulfide long-afterglow material of activation can also send out feux rouges.The disadvantage is that shining Brightness is low, persistence is short, easy deliquescence.Although radioactive element can be added to overcome these disadvantages, radioactive element Health and environment to people are all harmful, so receiving considerable degree of limitation in the application.
Oxysulfide series long after glow luminous material is a kind of novel long after glow luminous material, and matrix system is mainly Eu2+And Sm3+The Y of activation to glow2O2S rare-earth oxide sulfate materials.The Y prepared using high temperature solid-state method2O2S: Eu, Mg, Ti, Gd red long afterglow material, for heat treatment temperature at 600 DEG C or less, the luminescent properties of material are constant；Work as heat treatment temperature When reaching 800 DEG C, luminescent properties slowly decline；When heat treatment temperature reaches 1000 DEG C, principal crystalline phase Y2O2S becomes Y2O2SO4With Y2O3, luminescent properties drastically decline, compared with sulfide luminescent material, Y2O2S:Eu, Mg, Ti, Gd red long afterglow material With preferable thermal stability, but there are still the disadvantages that after-glow brightness is weaker and persistence is shorter.
Invention content
In order to overcome a systems such as the luminous intensity of above-mentioned red long afterglow material in the prior art is weaker, persistence is shorter Row problem, the present invention provides a kind of red long-afterglow phosphor and preparation method thereof, the fluorescent powder have chemical stability it is good, The advantages that after-glow brightness is high, persistence is long can be used for the fields such as decoration, emergent display.
Since the type of long after glow luminous material is more, different materials has different luminous mechanisms, and some materials Luminescence mechanism be also not clear at present, therefore, seek suitable matrix and active ions opening for new type long-persistence material Send out most important.Further, since the preparation method of long after glow luminous material is more, and there are respective advantage and disadvantage, thus it is right The optimum organization of the preparation method of various long after glow luminous material will also be played the popularization and application of long after glow luminous material and be closed very much The effect of key.
To solve above-mentioned the deficiencies in the prior art, the technical solution adopted in the present invention is as follows：
The chemical composition general formula of a kind of red long-afterglow phosphor, the fluorescent powder is Sr3-x-ySiAlO5Cl3: xEu2+, yRe3 +, wherein Re is Dy, and one or more of Gd and Nd are combined, and the value range of x and y are respectively：0.01≤x≤0.05,0.01 ≤y≤0.10.Preferably, the centre of luminescence of the fluorescent powder is Eu2+Ion, by introducing rare earth ion Dy3+、Gd3+With Nd3+One or more of combination provide trap level, effectively enhance long afterglow effect.
A kind of preparation method of red long-afterglow phosphor, it is characterised in that include the following steps：
（1）Dispensing：With the SrCO of high-purity3、SiO2、AlCl3、Eu2O3、Dy2O3、Gd2O3And Nd2O3As raw material, according to chemistry Form general formula Sr3-x-ySiAlO5Cl3: xEu2+, yRe3+The proportioning of middle each element accurately weighs each raw material；
（2）Batch mixing：Using agate ball as mill ball, using absolute ethyl alcohol as ball-milling medium, by agate ball, absolute ethyl alcohol and raw material It is put into ball grinder simultaneously, ball mill mixing 5 ~ 20 hours on planetary ball mill, forms pulp-like mixture, the anhydrous second The mass ratio of alcohol and raw material is 2:3；
（3）Drying：The pulp-like mixture of acquisition is placed in baking oven, heat preservation drying 4 ~ 8 hours under the conditions of 70 ~ 80 DEG C, then The raw material obtained after drying is crossed into 300 mesh sieve, obtains uniformly mixed raw material；
（4）Sintering：The uniformly mixed raw material is put into high temperature process furnances and is sintered, sintering temperature is 900 ~ 1200 DEG C, sintering time is 3 ~ 6 hours, and heating rate is 5-10 DEG C/min, sintering atmosphere 5%H2/95%N2Hydrogen nitrogen mixed gas, burn It cools to room temperature after the completion of knot with the furnace, obtains sintered body；
（5）Select powder：By step（4）The sintered body of acquisition carries out ball mill grinding, and using gas flow sizing machine to the powder after crushing It is classified to get the red long-afterglow phosphor according to particle size.
Compared with prior art, the beneficial effects of the invention are as follows：
（1）The present invention provides a kind of novel red long lad phosphor, matrix group becomes Sr3SiAlO5Cl3, pass through rare earth Ion Eu2+Doping obtains red emission, further through introducing rare earth ion Dy3+、Gd3+And Nd3+One or more of combination carry For trap level, after-glow brightness and the time of the fluorescent powder are effectively enhanced；
（2）Red long-afterglow phosphor provided by the invention have chemical stability is good, after-glow brightness is high, persistence length etc. it is excellent Point.
The invention also discloses a kind of red long-afterglow light-emitting components, made of above-mentioned red long-afterglow phosphor Substrate.
The invention also discloses a kind of red long-afterglow light-emitting components, including substrate to be sent out with the long afterglow being attached in substrate Optical thin film, the long-persistence luminous film are that above-mentioned red long-afterglow phosphor powder or red long-afterglow phosphor are thin Piece.
Include substrate and the long afterglow being attached in substrate hair the invention also discloses a kind of red long-afterglow light-emitting component Optical thin film, the long-persistence luminous film are red long-afterglow phosphor powder or red long-afterglow phosphor thin slice.
Preferably, the thickness of long-persistence luminous film is 1-10mm.
The substrate of the present invention, can be rigid basement, or flexible substrates.Preferably, the rigid basement can To be selected from glass, silicon, steel, ceramics, cement, timber and stone, the flexible substrates can be selected from PDMS (polydimethylsiloxanes Alkane) film, PET (polyethylene terephthalate) film, PS (polystyrene) film, PU (polyurethane) film, PI (polyimides) film With PVA (polyvinyl alcohol) film.
Above-mentioned red long-afterglow light-emitting component preparation method, including：By red long-afterglow phosphor powder as described above The suspension of last particle is coated in substrate as described above.
Although by suspension is prepared into red long-afterglow phosphor powder particle suspension solvent as described above, then Coated on can be prepared in the substrate meet the present invention claims light-emitting component, but also contain high score in the suspension When sub- substance, the sensitivity of final prepared light-emitting component and precision can be promoted further.
The content of the red long-afterglow phosphor powder particle can also change in a wider scope, preferable case Under, the content of the suspension based on 100 parts by weight, the red long-afterglow phosphor powder particle is 0.5-10 weight Part, preferably 1-5 parts by weight.
Preferably, the polymer substance is selected from PVA, EVA (ethene-vinyl acetate copolymer), PDMS, PU, PMMA (gather Methyl methacrylate), PAM (polyacrylamide), PVP (polyvinylpyrrolidone), starch, cellulose, natural plant gum, animal It is one or more in glue, carboxymethyl starch, acetic starch, hydroxymethyl cellulose and carboxymethyl cellulose.
According to the present invention, the content of the polymer substance can also change in a wider scope, under preferable case, base In the suspension of 100 parts by weight, the high molecular content is 1-10 parts by weight, preferably 3-8 parts by weight.
According to the present invention, the solvent can be various solvents commonly used in the art, be preferably selected from water, methanol, second Alcohol, acetone, ethylene glycol, isopropanol, diethylene glycol (DEG), ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, ethylene glycol phenyl ether, second two Alcohol benzyl oxide, health alcohol, diethylene glycol methyl ether, diethylene glycol ether, butyl carbitol, triethylene glycol methyl ether, diacetone alcohol, tridecanol, 14 Alcohol, dioctyl phthalate, ethyl acetate, butyl acetate, cyclohexanone, dimethylbenzene, bicyclohexyl, hexamethylene, n-butanol, It is one or more in butanone, repefral and D-sorbite.
According to the present invention, the suspension of the red long-afterglow phosphor powder particle is coated on the substrate surface Method can be the selection of this field routine can also use and print for example, the painting methods such as spraying, spin coating may be used Technology.The suspension of red long-afterglow phosphor powder particle is imprinted on the surface of substrate to the present invention by preferred printing technique herein On, so that the sensitivity for the sensor being prepared and precision are further promoted.Wherein, the printing technique can With one kind in dispensing, inkjet printing, water transfer, silk-screen printing and roll-to-roll printing.When use printing technique will be described When the suspension of red long-afterglow phosphor powder particle is printed on the surface of the substrate, the suspension is preferably prepared into ink The preparation method of water, the ink is by obtaining the suspension blending and stirring or blending ultrasonic disperse.
The invention also discloses a kind of red long-afterglow light-emitting component, which includes macromolecule material Material and the red long-afterglow phosphor powder, red long-afterglow phosphor powder is evenly distributed in high molecular material, red The addition of color long lad phosphor powder is 1 ~ 90%；Preferably 10 ~ 80%.High molecular material can be selected from PDMS (poly- diformazans Radical siloxane), PET (polyethylene terephthalate), PS (polystyrene), PU (polyurethane), PI (polyimides) and PVA (polyvinyl alcohol) is thin.Appropriateness in order to improve the performance of processing, which can also be added coupling agent, lubricant, plasticising Agent etc..
The invention also discloses a kind of ink, which includes ink conventional ingredient and the red long-afterglow phosphor Powder, red long-afterglow phosphor powder are evenly distributed in ink conventional ingredient, the addition of red long-afterglow phosphor powder Amount is 1 ~ 30%；Preferably 5 ~ 10%.Ink resin system can be polyamide, chlorination polypropylene, polyurethane or acrylic acid.Both may be used Can also be water-based ink to be oil-based ink.
The invention also discloses a kind of coating, which includes coating conventional ingredient and the red long-afterglow phosphor Powder, red long-afterglow phosphor powder are evenly distributed in coating conventional ingredient, the addition of red long-afterglow phosphor powder Amount is 1 ~ 30%；Preferably 5 ~ 10%.Coating resin system can be polyamide, chlorination polypropylene, polyurethane or acrylic acid.Both may be used Can also be water paint to be oil paint.
In addition, by that will include that red long-afterglow phosphor is formed in common paper, synthetic paper or epoxy resin, poly- second The macromolecules such as alkene, polyethylene terephthalate, polyester, polypropylene, polyvinyl chloride raw material, natural rubber or synthesis rubber Glue, glass, ceramics, metal, wood, artificial fiber or natural fiber, concrete or combination thereof and their fabricated product Deng exterior trim surface, or by containing red long-afterglow phosphor in inside.
Red long-afterglow light-emitting component of the present invention can as illumination, for safety display utilization.For example,：Device Vibrate the luminaires such as lamp, wind power lamp；Promptly, abnormal notification, very apparatus, dangerous display, very lamp, non-common mark, rescue Mark, signboard, the display device of life tool；Safety guard hangs on nervous rope, animal protective fence around shop building； Use filament to the pedal of ladder, handrail and the mesh that is arranged in the state ofs being partly embedded in road etc.；Health promoting appliance, walking are auxiliary Help utensil (walking auxiliary walking stick, the notification that shines antenna etc.)；The jewellery such as earrings, necklace；Support cutting for pillar, railway of flag etc. The exterior trim component or build-in components of the road roads Ji Jie stick, bicycle, automobile, electric car, ship, aircraft etc., fishing tackle (simulation Bait, fishing rod, fishing net etc.；Photism fiber construct, photism fishing gear, fishing line, fishing net etc.), buoy (float, buoy)； The position of the domestic animals such as the pets such as people, dog, cat, ox, pig, sheep, chicken etc. is shown；Fan (blade etc. of wind-power electricity generation, ventilating fan etc.), Clothes (shoes, gym suit, manually shine cloth, artificial luminous filament, artificial luminescent fibre etc.)；Pack (case, holder, device, letter Envelope, ground paper, crust packaging, external overlay film), medical products (breathing assistance utensil, experimental study equipment) robot it is (artificial to shine Hair structure body, artificial shiny skin, manually shine body) etc..It is covered as coating composition, ink composition, cement, surface Utilization example containing red long-afterglow phosphor in lid agent, can enumerate：Financial institution, community organization, credit card company, circulation The mail pieces such as crimping postcard sheet material containing red long-afterglow phosphor in bonding agent used in industry etc., stickup； The furniture such as chair, bed；Flooring material, ceramic tile, wall material, prefabricated board material, paveio(u)r, timber steel concrete etc. Building materials；It is equipped on the automated navigation system device of vehicle；Operating device for operating audio devices and air-conditioning etc.；Household electrical appliances system The input units such as product, portable machine, electronic computer；The images such as digital camera, CCD camera, film, photo, image store Means etc..
New appearance is generated by so that red long-afterglow phosphor is shone, therefore is also contemplated for toy, movable quotient Product etc. entertain the expansion of commodity, daily necessities.For example,：It is the wind long narrow flags such as dynamic toy, kite, carp shape flag, swing, fast Ski-running driving, carrousel, bow and arrow etc.；Pass through wind-force while the Powerless type light-emitting device (windbell etc.) of generation sound and light.Hair The windmill of the photosphere ball etc. of the ball of baseball, table tennis ball, billiard ball (golf), luminous mechanism；Balloon；Laminated structure object For paper, batch flute, paper folding, paper balloon, folding fan, New Year card, paint this；(jumping pole, fencing, bow and arrow are isometric for sporting goods Size objects etc.)；The score confirmation pressure sensitive sealant part of golf club, dynamic ornamentation body, moves tennis court line tester State engraving, dynamic souvenir；Dynamic Display device；Luminous decorative device；The audio device such as loud speaker, musical instrument (violin, guitar The diaphragms such as wind instruments, the glass such as percussion instruments, trumpet, the flutes such as equal stringed musical instruments, xylophone, drum), tuning fork etc.；The joys such as lipuid goods Happy commodity；The water plant of the ornamental sink in aquarium etc., container；Luminous wrist watch, luminous sand timer or sand timer type shine Device；Light emitting-type simulates candle device；The artificial plant that can be shone；Artificial eye；Cosmetics group containing adhesion polymer Conjunction object, the printed article and marketable securities, the printer's ink containing long-persistence luminous particle, ticket that forgery can be distinguished under visual state According to, the admission of check, stock, bond, various security, exchange ticket, books certificate, the ticket of traffic organization, toll facility, project Middle lottery ticket of ballot certificate that certificate, lottery ticket, Public Physical Education are competed etc., bank note, identity card, ticket, the pass etc., passport, writing are organic The printed article of ciphertext book seals sealing element etc..
Using shining along with long lad phosphor, the photochemical catalyst for being attached to red long-afterglow phosphor surface is made to live Obtained from change, long-lasting phosphor-photochemical catalyst complex can be used for：Antibacterial, sterilization, the treatment to non-human animal, vehicle The dirt purifications of the antibacterial articles such as handrail, handle, the fluid using internal wall surfaces such as pipings positioned at dark place The purification of energy of flow.Long-lag phosphor makes the photocrosslinking agent in macromolecule resin activate, can also promote by shining Crosslinking.
By the way that the red long-afterglow phosphor of the present invention with being mixed in resin, can be formed the resin combination of the present invention Object.
In addition, being formed again by the way that other inorganic material or organic material are further added in the resin combination of the present invention Condensation material can also form the long-lasting phosphor of the present invention.
For example, in the case that resin is epoxy resin, acrylic resin etc., relative in the compounding of 100 mass parts of resin 1~200 part of red long-afterglow phosphor is stated, in the case that resin is polyvinyl resin, flexible vinyl chloride resin etc., relative to tree 100 mass parts of fat are compounded above-mentioned 30~300 mass parts of red long-afterglow phosphor.Blend can be by using tapered mixing The mixing machines such as machine, V-Mixer, ribbon mixer, Henschel mixer, banbury mixers, triple-roller mill make resin Composition.
In addition, in the case of forming long-lasting phosphor by the resin combination, such as obtain the long-persistence luminous of sheet When body, such as relative to 100 parts by weight of Corvic, be compounded 50~200 mass parts of above-mentioned red long-afterglow phosphor, Calcium -3~5 mass parts of zinc system stabilizer, 30~100 mass parts of dioctyl phthalate as plasticizer, are existed with two-roller mill It is kneaded at 150~200 DEG C, so as to obtain the long-lasting phosphor with flexible sheet.
When obtaining the long-lasting phosphor of film-form, such as relative to 100 mass of pet resin Part, 20~50 mass parts of above-mentioned red long-afterglow phosphor are compounded, with double screw extruder, inflation processing machine at 250~300 DEG C Under be kneaded, be molded, so as to obtain the long-lasting phosphor of film-form.
When obtaining the long-lasting phosphor of other shapes, such as relative to 100 mass parts of acrylic resin, it is compounded red long 5~100 mass parts of persistence phosphor are kneaded at 170~200 DEG C with double screw extruder, are molded, so as to obtain Band-like, plate, rodlike, partical long-lasting phosphor.In addition, by using injection (mo(u)lding) machine to grain at 170~200 DEG C The long-lasting phosphor of material shape is processed molding, can obtain the long-lasting phosphor of three-dimensional shape.
As above-mentioned resin or other organic materials, can enumerate：Resin as thermoplastic resin, thermosetting resin. As thermoplastic resin, for example,：Low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE), linear, low density The polyethylene such as polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyvinyl fluoride, polyvinylidene chloride, acrylonitrile-butadiene- The polyamide such as the styrene polymers such as styrol copolymer (ABS resin) or copolymer, 6- nylon, 66- nylon, 12- nylon gather The acrylic resins such as amide imide, polyimides, polyetherimide, polyurethane, polymethyl methacrylate, poly- acetic acid second The fluororesin such as enester, vinyl-vinyl acetate copolymer, polyvinylidene fluoride, polytetrafluoroethylene (PTFE), gather alkenyl aroma hydroxy-aromatic resin The polyester such as ethylene glycol terephthalate, polybutylene terephthalate (PBT), polyethylene naphthalate, polylactic acid, bisphenol-A Be the makrolon such as makrolon, polyacetals, polyphenylene sulfide, polymethylpentene, cellulose, polyvinyl alcohol, polyvinyl acetate, The polyacrylic acid such as polyacrylonitrile, polyphenylene oxide (PPE), MODIFIED PP E, polyarylate, gather at styrene-acrylonitrile copolymer (AS resins) Copolymer, ethylene or the propylene of diphenyl sulfide, polysulfones, polyether sulfone, polyethers nitrile, polyether-ketone, polyketone, liquid crystal polymer ethylene and propylene With copolymer, ethylene and other olefinic insatiable hungers of other alpha-olefins (1- butylene, 1- amylenes, 1- hexenes, 4-methyl-1-pentene etc.) With the copolymer of monomer (vinyl acetate, acrylic acid, acrylate, methacrylic acid, methacrylate, vinyl alcohol etc.) Deng.
Thermoplastic resin can be used alone or in combination of two or more kinds.It should be noted that thermoplastic resin is copolymerization Can be the copolymer of any forms such as random copolymer, block copolymer when object.As thermosetting resin, can enumerate：Phenol Urea formaldehyde, urea resin, melmac, unsaturated polyester resin, diallyl phthalate resin, epoxy resin, Organic siliconresin, alkyd resin, polyimides, polyaminobismaleimide, casein resin, furane resins, polyurethane resin Deng.It can additionally enumerate：Utilize ultraviolet light, the resin of radiation curing.
In turn, it can enumerate：Natural rubber, polyisoprene rubber, butadiene-styrene rubber, polybutadiene rubber, ethylene-the third The rubber-based materials such as alkene-diene rubber, butyl rubber, neoprene, acrylonitrile butadiene rubber, silicon rubber.
It in addition to this, can be by pigment, dyestuff, lubricant, antioxidant, ultra-violet absorber, light stabilizer, antistatic The red long-afterglow phosphor of agent, fire retardant, fungicide, antiseptic, solidification catalyst, Photoepolymerizationinitiater initiater etc. and the present invention It is mixed together, is shaped to rodlike, plate, film-form, threadiness, membranaceous, needle-shaped, spherical, foil-like, graininess, sand shape, scale The arbitrary shapes such as shape, sheet, liquid, gel, sol form, suspension, aggregation, capsule-type.
As pigment, inorganic pigment, organic pigment can be enumerated.
As inorganic pigment, can enumerate：Titanium oxide, barium sulfate, calcium carbonate, zinc oxide, lead sulfate, yellow lead, zinc yellow, Kermes (red iron oxide (III)), cadmium red, ultramarine, dark blue, chrome oxide green, cobalt green, chocolate, titanium is black, synthesis is iron black, carbon black, Mica, the aluminium oxide covered by titanium oxide, iron oxide, mica, glass flake, the holographic pigment covered by titanium oxide, iron oxide Deng.In addition to this, it as metallic powdery pigment, can enumerate：Aluminium powder, copper powders, powder of stainless steel, metallic colloid, conduct There are transparent emerylite, coloring mica, interference mica, interference aluminium oxide, the interference silica (interference glass) of interference effect Deng.
As organic pigment, can enumerate：Azo pigment (monoazo yellow, condensation azophosphine, azomethine Huang etc.), Huang Color iron oxide, titan yellow, pucherite, benzimidazolone, isoindolinone, isoindoline, quinophthalone, benzidine yellow, permanent Huang etc. Yellow uitramarine；The orange pigments such as permanent orange；Red iron oxide, naphthols AS systems azophloxine, anthanthrone, anthraquinone is red, pyrene is reddish brown, quinoline The red pigments such as acridone is red, diketopyrrolopyrrolecocrystals are red, permanent red；The purples face such as cobalt violet, quinacridone violet, dioxazine violets Material；The blue pigments such as cobalt blue, phthualocyanine pigment (phthalocyanine blue etc.), anthracene indigo plant；The viridine greens such as phthalocyanine green, azo system disperse dyes, Organic dyestuff such as anthraquinone system disperse dyes etc..
As dyestuff, can enumerate：Azo dyes, anthraquinone dye, bipseudoindoxyl dye, sulfur dye, triphenhlmethane dye, Pyrazolone dye, Stilbene dyestuff, diphenylmethane dye, Xanthene dyes, alizarin dyes, acridine dye, quinoneimine dye (piperazine Dyestuff, oxazine dyes, thiazine dye), thiazole dye, first alkynes dyestuff, nitro dye and nitroso-dyes etc..
As antioxidant, can enumerate：Hindered phenolic compound, phosphite ester based compound, phosphinate system chemical combination Object and thioether based compound etc..
As hindered phenolic compound, can enumerate：Alpha-tocopherol, butylated hydroxytoluene, sinapinic alcohol, vitamin E, positive ten Eight alkyl-β-(4 '-hydroxyls -3 ', 5 '-di-tert-butyl-phenyls) propionic ester, 2- tertiary butyls -6- (3 '-tertiary butyls -5 '-methyl -2 ' - Hydroxybenzyl) -4- aminomethyl phenyls acrylate, 2,6- di-t-butyls -4- (N, N- dimethylaminomethyl) phenol, bis- uncles of 3,5- Butyl -4- benzylphosphonic acids diethyl ester, 2,2 '-di-2-ethylhexylphosphine oxides (4- methyl-6-tert-butylphenols), 2,2 '-di-2-ethylhexylphosphine oxides (4- ethyl -6- tert-butyl phenols), 4,4 '-methylene-bis(2,6-di-t-butyl phenol)s, 2,2 '-di-2-ethylhexylphosphine oxides (4- methyl -6- Cyclohexylphenol), 2,2 '-dimethylenes-bis- (6- Alpha-Methyls-benzyl-paracresol) 2,2 '-ethidines-bis- (4,6- di-t-butyls Phenol), 2,2 '-butanes-bis- (4- methyl-6-tert-butylphenols), 4,4 '-butanes bis- (3 methy 6 tert butyl phenols), Triethylene glycol-N- double -3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, bis- [3- (the bis- tertiary fourths of 3,5- of 1,6-HD Base -4- hydroxy phenyls) propionic ester], bis- [2- tertiary butyl -4- methyl 6- (3- tertiary butyl -5- methyl -2- hydroxybenzyls) phenyl] it is right Bis- { 2- [3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propiono the oxygroup] -1,1- dimethyl second of phthalic acid ester, 3,9- Base } -2,4,8,10- four oxaspiro [5,5] hendecane, 4,4 '-thiobis (6- tertiary butyls-metacresol), 4,4 '-thiobis (3- Methyl-6-tert-butylphenol), 2,2 '-thiobis (4- methyl-6-tert-butylphenols), bis- (3,5- di-t-butyl -4- hydroxyl benzyls Base) thioether, 4,4 '-two thio bis(2,6-di-butyl phenol)s, 4,4 '-three thio bis(2,6-di-butyl phenol)s, 2,2- Thiodiethylene pair-[3- (3,5- di-tert-butyl-hydroxy phenyls) propionic ester], bis- (just pungent sulfenyl) -6- (4- hydroxyls of 2,4- Base -3 ', 5 '-di-tert-butyl amidos) -1,3,5- triazines, N, N '-hexamethylene bis-(3,5- di-t-butyl -4- hydroxy groups Cinnamamide), N, bis- [3- (3,5- di-tert-butyl-hydroxy phenyls) propiono] hydrazines of N ' -, (2- methyl -4- hydroxyls of 1,1,3- tri- Base -5- tert-butyl-phenyls) butane, 1,3,5- trimethyls -2,4,6- three (3,5- di-tert-butyl-4-hydroxyl benzyls) benzene, three (3,5- Di-tert-butyl-hydroxy phenyl) isocyanuric acid ester, three (3,5- di-tert-butyl-4-hydroxyl benzyls) isocyanuric acid esters, 1,3,5- tri- (4- tertiary butyl -3- hydroxyl -2,6- dimethyl benzyls) isocyanuric acid ester, the [3- (3,5- di-t-butyl -4- hydroxy benzenes of 1,3,5- 32 Base) propiono oxygroup] ethyl isocyanurate and four [methylene -3- (3 ', 5 '-di-tert-butyl-hydroxy phenyl) propionic esters] Methane etc..
As phosphite ester based compound, triphenyl phosphite, phosphorous acid three (nonyl phenyl) ester, phosphorous acid can be enumerated Three decyl esters, phosphorous acid trioctylphosphine ester, phosphorous acid three (octadecyl) ester, phosphorous acid didecyl list phenylester, phosphorous acid two are pungent Base mono-phemyol ester, phosphorous acid diisopropyl list phenylester, phosphorous acid monobutyl diphenyl, phosphorous acid list decyl diphenyl, Phosphorous acid list octyl diphenyl, phosphorous acid three (diethyl phenyl) ester, phosphorous acid three (diisopropyl phenyl) ester, phosphorous acid three (di-n-butyl phenyl) ester, phosphorous acid three (2,4- di-tert-butyl-phenyls) ester, phosphorous acid three (2,6- di-tert-butyl-phenyls) ester, two Stearyl pentaerythritol diphosphites, bis- (2,4- di-tert-butyl-phenyls) pentaerythritol diphosphites, bis- (bis- tertiary fourths of 2,6- Base -4- aminomethyl phenyls) pentaerythritol diphosphites, bis- (2,6- di-t-butyl -4- ethylphenyls) pentaerythrite diphosphorous acids Ester, bis- { bis- (1- methyl-1s-phenylethyl) phenyl of 2,4- } pentaerythritol diphosphites, phenyl bisphenol-A pentaerythrite two are sub- Phosphate, bis- (nonyl phenyl) pentaerythritol diphosphites and dicyclohexyl pentaerythritol diphosphites etc..As other Phosphite ester based compound can be enumerated and be reacted with dihydric phenol class to the phosphite ester based compound with cyclic structure.
As phosphinate based compound, can enumerate：Four (2,4- di-tert-butyl-phenyls) -4,4 '-biphenylene two is sub- Phosphonate ester, four (2,4- di-tert-butyl-phenyls) -4,3 '-biphenylens, four (2,4- di-tert-butyl-phenyls) -3, 3 '-biphenylens, four (2,6- di-tert-butyl-phenyls) -4,4 '-biphenylens, four (2,6- bis- Tert-butyl-phenyl) -4,3 '-biphenylens, the sub- phosphine of four (2,6- di-tert-butyl-phenyls) -3,3 '-biphenylene two Acid esters, bis- (2,4- di-tert-butyl-phenyls) -4- phenyl-phenyls phosphinates, bis- (2,4- di-tert-butyl-phenyls) -3- phenyl-benzene Base phosphinate, bis- (2,6- di-n-butyls phenyl) -3- phenyl-phenyls phosphinates, bis- (2,6- di-tert-butyl-phenyls) -4- benzene Base-phenylphosphite ester and bis- (2,6- di-tert-butyl-phenyls) -3- phenyl-phenyl phosphinates etc..
As thioether based compound, can enumerate：Thiodipropionate dilauryl, thio-2 acid two (tridecyl) Ester, thio-2 acid myristyl ester, thio-2 acid distearyl base ester, (the 3- lauryl propane thioic acids of pentaerythrite-four Ester), pentaerythrite-four (3- laurylthiopropionates), pentaerythrite-four (3- octadecyls thiopropionate), season penta Tetrol four (3- myristyls thiopropionate) and pentaerythrite-four (3- stearyl-thios propionic ester) etc..As comprising ultraviolet The light stabilizer of light absorbers can be enumerated：Benzophenone based compound, benzotriazole based compound, aromatic series benzoic ether Based compound, oxanilide based compound, cyanoacrylate based compound and the amine compound that is obstructed etc..
As benzophenone based compound, can enumerate：Benzophenone, 2,4 dihydroxyl benzophenone, 2,2 '-dihydroxy Benzophenone, 2,2 ', 4,4 '-tetrahydroxybenzophenones, ESCALOL 567,2,2 '-dihydroxy -4,4 '-two Methoxy benzophenone, 2,2 '-dihydroxy -4,4 '-dimethoxy -5- sulfonyls benzophenone, 2- hydroxyl -4- octyloxy hexichol Ketone, 2- hydroxyl -4- dodecyloxy benzophenones, 2- hydroxyl -4- octyloxybenzophenones, 2- hydroxyl -4- methoxyl group -5- sulphurs Acyl group benzophenone, 5- chlorine-2-hydroxyls benzophenone, 2- hydroxyl -4- octyloxybenzophenones, 2- hydroxyl -4- methoxyl groups -2 ' - Carboxyl benzophenone and 2- hydroxyls -4- (2- hydroxy-3-methyls-acryloxy isopropoxy) benzophenone etc..
As benzotriazole based compound, can enumerate：2- (5- methyl -2- hydroxy phenyls) benzotriazole, 2- (3,5- bis- Tertiary butyl -2- hydroxy phenyls) benzotriazole, 2- (bis- tertiary pentyl -2- hydroxy phenyls of 3,5-) benzotriazole, 2- (3 ', 5 '-two uncles Butyl -4 '-methyl -2 '-hydroxy phenyl) benzotriazole, 2- (bis- tertiary pentyl -2- hydroxy phenyls of 3,5-) -5- chlorobenzotriazoles, 2- (5- tertiary butyl -2- hydroxy phenyls) benzotriazole, 2- [2 '-hydroxyls -3 ', 5 '-bis- (bis (alpha, alpha-dimethylbenzyl) base) phenyl] benzo three Azoles, 2- [2 '-hydroxyls -3 ', 5 '-bis- (bis (alpha, alpha-dimethylbenzyl) base) phenyl] -2H- benzotriazole and 2- (4 '-octyloxies -2 '-hydroxyl Phenyl) benzotriazole etc..
As aromatic series benzoic ether based compound, can enumerate：Salicylic acid is to tert-butyl benzene base ester, salicylic acid to octyl Salicylic acids alkyl phenyl esters such as phenylester etc..
As oxanilide based compound, can enumerate：2- ethyoxyls -2 '-ethyloxanilide, 2- ethyoxyls -5- Tertiary butyl -2 '-ethyloxanilide and 2- ethyoxyls -3 '-dodecyl butoxanilide etc..
As cyanoacrylate based compound, can enumerate：Ethyl -2- cyano -3,3 '-diphenylacrylate ester, 2- Ethylhexyl-cyano -3,3 '-diphenylacrylate ester etc..
As the amine compound that is obstructed, can enumerate：4- acetoxyl group -2,2,6,6- tetramethyl piperidines, 4- stearoyl ketos Base -2,2,6,6- tetramethyl piperidines, 4- acryloxy -2,2,6,6- tetramethyl piperidines, 4- (phenylacetyl oxygroup) -2,2,6, 6- tetramethyl piperidines, 4 benzoyloxy 2,2,6,6 tetramethyl piperidine, 4- methoxyl group -2,2,6,6- tetramethyl piperidines, 4- ten Eight alkyl oxy -2,2,6,6- tetramethyl piperidines, 4- cyclohexyl oxygroup -2,2,6,6- tetramethyl piperidines, 4- benzyls oxygroup -2,2, 6,6- tetramethyl piperidines, 4- phenoxy group -2,2,6,6- tetramethyl piperidines, 4- (ethylcarbamoyl oxygroup) -2,2,6,6- tetramethyls Phenylpiperidines, 4- (cyclohexyl carboxyamide oxygroup) -2,2,6,6- tetramethyl piperidines, 4- (phenylcarbamoyl oxygroup) -2,2,6, 6- tetramethyl piperidines, bis- (2,2,6,6- tetramethyl -4- piperidyls) carbonic esters, bis- (2,2,6,6- tetramethyl -4- piperidyls) grass Acid esters, bis- (2,2,6,6- tetramethyl -4- piperidyls) malonates, bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, Bis- (2,2,6,6- tetramethyl -4- piperidyls) adipate esters, bis- (2,2,6,6- tetramethyl -4- piperidyls) terephthalates, Bis- (2,2,6,6- tetramethyl -4- piperidyls the oxygroup)-ethane of 1,2-, α, the bis- (2,2,6,6- tetramethyl -4- piperidyl oxygen of α ' - Base)-paraxylene, bis- (2,2,6,6- tetramethyl -4- piperidyls)-toluylene -2,4- diurethanes, it is bis- (2,2, 6,6- tetramethyl -4- piperidyls)-hexa-methylene -1,6- diurethanes, three (2,2,6,6- tetramethyl -4- piperidyls) - Benzene -1,3,5- tricarboxylic esters, three (2,2,6,6- tetramethyl -4- piperidyls)-benzene -1,3,4- tricarboxylic esters, 1,2- { 3- (3,5- Di-tert-butyl-hydroxy phenyl) propiono oxygroup } -2,2,6,6- tetramethyl piperidines and 1,2,3,4- butane tetracarboxylic acid and 1, 2,2,6,6- pentamethyl -4- hydroxy piperidines and β, β, β ', β '-tetramethyls -3,9- [tetra- oxaspiros (5,5) of 2,4,8,10- 11 Alkane] dimethanol condensation product etc..
As antistatic agent, can enumerate：The toner bodies such as carbon black, graphite, tin antimony composite oxides, antimony indium tin are multiple Close the metal oxygens such as oxide, indium tin composite oxides, the electric conductivity indium oxide for being doped with Sn, F, Cl etc., tin oxide, zinc oxide Inorganic system's antistatic agent such as the various metallic particles such as compound, copper, nickel, silver, gold, aluminium (powder) or metallic fiber and (β-bay Amide propiono) quaternary ammonium salts system, sulfonate based compound, the alkyl phosphate such as trimethyl ammonium sulfate, neopelex The antistatic agent etc. of the organic systems such as based compound.
As fire retardant, can enumerate：Bromide fire retardant, phosphorus flame retardant, chlorine-based flame retardant, triazine flame retardant, with And other inorganic flame retardants such as salt of phosphoric acid and piperazine etc..
As bromide fire retardant, can enumerate：Brominated Polystyrene, brominated polyacrylate, brominated polyphenylether, bromination are double Phenol A types epoxy resin, brominated bisphenol a type epoxy resin molecule chain end glycidyl part or all by envelope The modifier at end, using brominated bisphenol A as the polycarbonate oligomer of Material synthesis, two phthalimide chemical combination of bromination The compounds such as the brominated diphenyls base alkane such as object, bromination Biphenyl Ether and 1,2- bis- (penta-bromophenyl) ethane.Wherein it is possible to enumerate：Poly- three The brominated Polystyrenes such as bromstyrol, poly- (dibromobenzene aether), decabrominated dipheny base ether, bis- (tribromophenoxy) ethane, 1,2- bis- (five Bromophenyl) ethane, ethylene-is bis--(tetrabromo phthalimide), tetrabromobisphenol A, brominated polycarbonate oligomer, poly- tribromo The brominated Polystyrenes such as styrene, 1,2- bis- (penta-bromophenyl) ethane etc..
As phosphorus flame retardant, can enumerate：Trimethyl phosphate, triethyl phosphate, tributyl phosphate, tricresyl phosphate (2- second Base hexyl) ester, tributoxyethyl phosphate, triphenyl phosphate, lindol, tricresyl phosphate (xylyl) ester, phosphoric acid Three (isopropyl phenyl) esters, tricresyl phosphate (phenyl) ester, tricresyl phosphate naphthalene ester, tricresyl phosphate base diphenyl, phosphoric acid diformazan Phenyl diphenyl, diphenyl phosphate (2- ethylhexyls) ester, di(2-ethylhexyl)phosphate (isopropyl phenyl) phenylester, mono phosphoric acid ester isodecyl Ester, 2- acryloyl-oxyethyls phosphate ester acid, 2- methacryloxyethyls phosphate ester acid, diphenyl -2- acryloyls Oxygroup ethyl phosphonic acid ester, diphenyl -2- methacryloxyethyls phosphate, melamine phosphate, two (melamines) Phosphate, melamine pyrophosphoric ester, triphenylphosphine oxide, trimethylphenyl phosphine oxide, methanephosphonic acid diphenyl ester, phenyl-phosphonic acid two The phosphates such as ethyl ester, resorcinol Polyphenyl phosphate, 1,3- phenylenes bis- (2,6- dimethylphenylphosphates), resorcinol Poly- (two -2,6- xylyls) phosphate, polymer with bis phenol A tolyl phosphate, bisphenol-A Polyphenyl phosphate, the poly- (2,6- bis- of quinhydrones Tolyl) condensed phosphoric acid esters such as the aromatic condensations phosphate such as phosphate and their condensation product etc..
As chlorine-based flame retardant, can enumerate：Five cyclodecane of pentachloro-, hexachloro-benzene, toluene pentachloride, tetrachlorobisphenol A and polychlorostyrene Styrene etc..As triazine flame retardant, can enumerate：Melamine, methyl guanamines, benzoguanamine, acryloyl guanamines, 2,4- Diamino -6- nonyl -1,3,5- triazines, 2,4- diamino -6- hydroxyl -1,3,5- triazines, dihydroxy -1,3 2- amino -4,6-, 5- triazines, 2,4- diamino -6- methoxyl group -1,3,5- triazines, 2,4- diamino -6- ethyoxyl -1,3,5- triazines, 2,4- diaminos Base -6- propoxyl group -1,3,5- triazines, 2,4- diamino -6- isopropoxy -1,3,5- triazines, sulfydryl -1 2,4- diamino -6-, 3,5- triazines and 2- amino -4,6- dimercapto -1,3,5- triazines etc..
As the salt of phosphoric acid and piperazine, can enumerate：Orthophosphoric acid piperazine, piperazine pyrophosphate and polyphosphoric acid piperazine etc..
As inorganic flame retardant, can enumerate：The antimonials such as antimony trioxide, Antimony pentachloride, zinc borate, Boratex, Aluminium hydroxide, magnesium hydroxide and red phosphorus etc..
As fungicide, can enumerate：The copper fungicides such as copper 8-hydroxyquinolinate, zineb (Zineb), maneb (Maneb) etc. have The organochlorines such as machine thiophanate fungicide, captan, Bravo system fungicide, thiophanate-methyl, benomyl, carbendazim, thiabendazole etc. The acyls such as the dicarboximides system such as benzimidazole system fungicide, iprodione, vinclozolin, procymidone fungicide, furametpyr The morpholines system fungicide such as the phenylpyrroles such as amine system fungicide, fludioxonil system fungicide, dimethomorph, Fluoxastrobin, kresoxim-methyl, The anilino-pyrimidines system fungicide such as the methoxy acrylates such as ORIBRIGHT system fungicide, mepanipyrim, cyprodinil, pyrimethanil, The soil fungicides such as the ergosterol biosynthesis inhibitors such as triazolone, fluorine bacterium azoles, trichloronitromethane, PCNB and fluorine pyridine Bis- (acetyl bromide oxygroup) ethane of amine, o-phenyl phenol (OPP), diphenyl, chlorodiphenyl base, cresols, 1,2-, cinnamic acid, acetic acid benzene Ester, allyl isothiocyanate, Alpha-Methyl acetophenone, thymol, full-chloro-cyclopentadiene, bromoacetic acid, bis- bromo- 3- itrile groups propionyl of 2,2- Amine, ethyl chloroacetate, butyl chloroacetate, methyl chloroacetate, 5- chloro-2-methyl isothiazoline -3- ketone, glutaraldehyde and Hinokitiol Deng.
As antiseptic, can enumerate：Make silver, zinc, one kind of copper or antibiotic property Metal Supported of more than two kinds in inorganization Close inorganic system's powder obtained from object.As load, can enumerate：Zeolite, apatite, basic zirconium phosphate, titanium oxide, silica Gel, aluminum sulfate hydroxide, calcium phosphate, calcium silicates etc..In addition it can enumerate：With phosphate, boric acid system, silicic acid system Be respectively glass one kind or two or more glass as glass forming constituents in containing silver, zinc, copper one kind or two or more Antibiotic property metal obtained from antibacterial glass powder.
As lubricant, can enumerate：Aliphatic acid, fatty acid metal salts, oxo aliphatic acid, paraffin, low molecular weight it is poly- Alkene, fatty acid amide, alkylenebisfatty amide, aliphatic ketone, fatty acid part saponification ester, aliphatic acid low-carbon-ester, fat Acid polyol ester, fatty acid polyglycol ethyl alcohol ester and modified organic silicon etc..
As aliphatic acid, can enumerate：Oleic acid, stearic acid, lauric acid, hydroxy stearic acid, behenic acids, arachidonic acid, The aliphatic acid of the carbon numbers 6~40 such as linoleic acid, leukotrienes, ricinoleic acid, palmitic acid, montanic acid and their mixture.As fat Fat acid metal salt can be enumerated：It is sodium laurate, potassium laurate, Magnesium dilaurate, calcium laurate, zinc laurate, barium laurate, hard Resin acid sodium, potassium stearate, magnesium stearate, calcium stearate, zinc stearate, barium stearate, behenic acid sodium, behenic acid potassium, behenic acids Alkali (soil) gold of the aliphatic acid of carbon numbers 6~40 such as magnesium, behenic acid calcium, behenic acid zinc, behenic acids barium, montanic acid sodium and montanic acid calcium Belong to salt.
As oxo aliphatic acid, can enumerate：1,2- stearoxylic acids etc..
As paraffin, can enumerate：The paraffin of 18 or more the carbon numbers such as atoleine, natural paraffin wax, microwax and vaseline.
As the polyolefin of low molecular weight, can enumerate：Polyethylene wax, maleic acid modified polyethylene wax, the poly- second of oxidized form 5000 polyolefin below of alkene wax, haloflex wax and polypropylene wax equimolecular quantity.It, specifically can be with as fatty acid amide It enumerates：The fatty acid amide of 6 or more the carbon numbers such as oleamide, erucic amide, Shan Yu amides.
As alkylenebisfatty amide, can enumerate：Methylene bis stearamide, ethylenebisstearamide and N, N- The alkylenebisfatty amide of 6 or more the carbon numbers such as bis- (2- hydroxyethyls) stearmides.
As aliphatic ketone, can enumerate：The aliphatic ketone of 6 or more the carbon numbers such as higher aliphatic ketone.As fatty acid moieties Divide saponification ester, can enumerate：Partly-hydrolysed ester of montanic acid etc..
As aliphatic acid low-carbon-ester, can enumerate：Stearate, oleate, linoleate, linolenate, adipic acid Ester, behenic acids ester, arachidonate, montanate and isostearate etc..
As polyol esters of fatty acids, can enumerate：Glycerine tristearate, glycerine distearate, glycerine Monostearate, pentaerythritol tetrastearate, pentaerythrite tristearate, two myristinate of pentaerythrite, Ji Wusi Alcohol monostearate, pentaerythritol adipate stearate and anhydrous sorbitol Dan behenic acid esters etc..
As fatty acid polyglycol ethyl alcohol ester, can enumerate：Cithrol, polytrimethylene diol fatty acid ester and Polypropylene glycol fatty acid esters etc..
As modified organic silicon, can enumerate：The alkoxy-modified organosilicon of organic silicon modified by polyether, higher fatty acids contains There are organosilicon, high-grade aliphatic ester modified organic silicon, methacrylic modified organic silicon and the fluorine richness of higher fatty acids to have Machine silicon etc..
As solidification catalyst, can enumerate：(peroxidized t-butyl perbenzoate, benzoyl peroxide, peroxidating first and second Ketone etc.) and organic peroxides, octyl acid tin, the dibutyl such as azo-compound (azodiisobutyronitrile and azobisisovaleronitrile etc.) Tin two (2 ethyl hexanoic acid ester), dioctyl tin two (2 ethyl hexanoic acid ester), dioctyl tin diacetate esters, dibutyltindilaurylmercaptide cinnamic acid Ester, dioctyl tin dilaurate, Dibutyltin oxide, dioctyl tin oxide, dibutyl tin fatty acid salt, 2 ethyl hexanoic acid Lead, zinc octoate, zinc naphthenate, fatty acid zinc class, cobalt naphthenate, calcium octoate, copper naphthenate, 2 ethyl hexanoic acid lead lead octoate and four The inorganic acids such as Organometallic derivatives, hydrochloric acid, nitric acid, the sulfuric acid such as the metals such as n-butyl titanate and organic and inorganic acid salt, The sulfoacid compounds such as p-methyl benzenesulfonic acid, dodecyl benzene sulfonic acid, dinonylnaphthalene sulfonic acid, dinonylnaphthalene disulfonic acid, sulfoacid compound Amine corrective, organic amines, phosphoric acid, the pyrophosphoric acid such as triethylamine etc., phosphate monoester or di-phosphate ester etc..As phosphate monoester, For example,：Mono-octyl phosphate, mono phosphoric acid ester propyl ester and mono phosphoric acid ester lauryl etc..As di-phosphate ester, for example,： Dioctylphosphoric acid ester, phosphoric acid dipropyl and didodecyl phosphate etc..In turn, it can enumerate：Single (2- (methyl) acryloxy second Base) phosphate cpds, diazabicyclo endecatylene series catalysts, lewis acid and the acid anhydrides such as phosphate ester acid etc..
As Photoepolymerizationinitiater initiater, can enumerate：(2-hydroxybenzoyl) compound (2- hydroxy-2-methyl -1- phenyl-propanes - 1- ketone, 1- hydroxycyclohexylphenylketones, benzoin alkylether etc.), benzoyl formic acid ester compounds (methylbenzoyl formate Deng), thioxanthone compounds (isopropyl thioxanthone etc.), benzophenone cpd (benzophenone etc.), phosphate compound (1,3, 5- trimethylbenzoyl diphenyl phosphine oxides etc.) and benzil dimethyl ketal etc..
In turn, coating is mixed in which the length of the present invention can also be made by matching the red long-afterglow phosphor of the present invention Afterglow coating composition.
The long-persistence luminous property coating composition of the present invention can be coated with the surface of other materials.
In addition, the hair of the long-persistence luminous property coating composition of the present invention of the red long-afterglow phosphor containing the present invention Brightness is high, therefore can carry out visual high application.
As coating composition, the coating composition containing overlay film formative resin can be used.In coating composition, root It can also contain according to needs：Solvent, dispersant, filler, thickener, levelling agent, curing agent, crosslinking agent, pigment, antifoaming agent, The coating such as antioxidant, the light stabilizer comprising ultra-violet absorber, fire retardant, solidification catalyst, fungicide and antiseptic Use additive.
As the material used in coating composition, thermosetting resin, normal temperature cure resin, ultraviolet light can also be used The various resins such as curable resin, radiation curing resin, for example,：Acrylic resin, alkyd resin, poly- ammonia Ester resin, polyester resin, amino resins etc., organosilicon acid esters, organic titanate etc..
As ink film forming material, can enumerate：Polyurethane resin, acrylic resin, polyamide, vinyl chloride- Vinyl acetate resin and propylene dichloride resin etc..
As solvent, can enumerate：Aliphatic hydrocarbon, aromatic hydrocarbon (C7~10, such as toluene, dimethylbenzene and ethyl Benzene), ester or ether-ether (C4~10, such as methoxybutyl acetic acid esters), ether (C4~10, such as tetrahydrofuran, EG single ethyl Single ethylether of ether, the single-butyl ether of EG, the monomethyl ether of PG and DEG), (C3~10, such as methyl iso-butyl ketone (MIBK), two are just for ketone Butyl ketone), alcohol (C1~10, such as methanol, ethyl alcohol, normal propyl alcohol and isopropanol, n-butanol, isobutanol, sec-butyl alcohol and the tert-butyl alcohol, 2- ethylhexyl alcohols), amide (C3~6, such as dimethylformamide, dimethylacetylamide, N-Methyl pyrrolidone), sulfoxide (C2~4, such as dimethyl sulfoxide (DMSO)) and their mixed solvent of more than two kinds, water or aforementioned mixed solvent.As dispersion Agent can enumerate as long as being macromolecule dispersing agent：The formal of naphthalene sulfonate [alkali metal (Na and K etc.) salt, ammonium salt etc.] Woods condensation product, poly styrene sulfonate (same as described above), polyacrylate (same as described above), poly- (2~4) carboxylic acid (Malaysia Acid/glycerine/monoallyl ether copolymer etc.) salt (same as described above), carboxymethyl cellulose (Mn2000~10000) and polyethylene Alcohol (Mn2000~100000) etc..
As low molecule dispersant, following substances can be enumerated.
(1) poly (oxyalkylene) fundamental mode
Aliphatic alcohol (C4~30), [alkyl (C1~30)] phenol, aliphatic (C4~30) amine and aliphatic (C4~30) amide 1~30 mole of addition product of AO (C2~4).
As aliphatic alcohol, there are n-butanol, isobutanol, sec-butyl alcohol and the tert-butyl alcohol, octanol, dodecanol etc.；As (alkane Base) phenol, there are phenol, methylphenol and nonyl phenol etc.；As aliphatic amine, there are lauryl amine and methyl stearic amine etc.； With as aliphatic amide, there is stearmide etc..
(2) polyol type
The aliphatic acid (lauric acid, stearic acid etc.) of C4~30 and polynary (2~6 or its more than) alcohol (such as GR, PE, D-sorbite And anhydrous sorbitol) monoester compound.
(3) carboxylic acid type
Alkali metal (same as described above) salt of the aliphatic acid (same as described above) of C4~30.
(4) sulfuric acid ester type
The sulfuric ester of the aliphatic alcohol (same as described above) of C4~30 and AO (C2~4) 1~30 mole of addition product of aliphatic alcohol Alkali metal (same as described above) salt etc..
(5) sulfonate type
Sulfonate alkali metal (same as described above) salt of [alkyl (C1~30)] phenol (same as described above).
(6) phosphate type
The monophosphate of the aliphatic alcohol (same as described above) of C4~30 and AO (C2~4) 1~30 mole of addition product of aliphatic alcohol The salt [alkali metal (same as described above) salt, quaternary ammonium salt etc.] of ester or bisphosphate.
(7) primary~tertiary amine salt form
Aliphatic amine [primary amine (lauryl amine etc.), secondary amine (dibutylamine etc.) and the tertiary amine (dimethylstearamine of C4~30 Deng)] inorganic acid (hydrochloric acid, sulfuric acid, the nitric acid of the monoesters of hydrochloride, triethanolamine and the aliphatic acid of C4~30 (same as described above) With phosphoric acid etc.) salt.
(8) quaternary
The inorganic acid of the quaternary ammonium (butyl trimethyl ammonium, diethyl lauryl methyl ammonium, dimethyl distearyl ammonium etc.) of C4~30 (same as described above) salt etc..
As inorganic dispersant, can enumerate：Alkali metal (same as described above) salt and phosphate dispersant (phosphorus of polyphosphoric acid Acid, monoalkyl phosphoric acid esters and dialkyl phosphate etc.) etc..
As filler, can enumerate：It is inorganic as the oxide system of representative using silica, aluminium oxide, zirconium oxide, mica The organic compounds such as the micro mist or acrylic resin, fluororesin of the non-oxidized substances based inorganic material such as object, silicon carbide, silicon nitride.Separately Outside, the metal powders such as aluminium, zinc, copper can also be added according to purposes.In turn, it as the concrete example of filler, can enumerate：Dioxy SiClx colloidal sol, zirconia sol, alumina sol, TiO 2 sol isosol；Silica sand, quartz, close quartzy salt, diatomite Etc. silica-based substance；Synthesize amorphous silica；Kaolinite, mica, talcum, wollastonite, asbestos, calcium silicates, silicic acid The silicates such as aluminium；The vitreums such as glass powder, glass marble, hollow glass ball, glass flake, bulb glass ball；Boron nitride, carbonization The non-oxidized substances based inorganic material such as boron, aluminium nitride, aluminium carbide, silicon nitride, silicon carbide, titanium boride, titanium nitride, titanium carbide；Calcium carbonate； The metal oxides such as zinc oxide, aluminium oxide, magnesia, titanium oxide, beryllium oxide：Barium sulfate, molybdenum disulfide, tungsten disulfide, fluorination The inorganic matters such as carbon；The metal powders such as aluminium, bronze, lead, stainless steel, zinc；With carbon black, coke, graphite, thermally decomposed carbon, hollow carbon balls Equal carbon body etc..
As thickener, can enumerate：Montmorillonite system clay mineral, the bentonite comprising these mineral, colloidal oxidation The inorganic fillers such as aluminium system thickener, methylcellulose, carboxymethyl cellulose, hexyl methyl cellulose, hydroxyethyl cellulose, hydroxyl The cellulose-based thickeners such as propyl cellulose, polyurethane resin system thickener, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene The polyethers trees such as the polyethylene-based thickener such as benzyl ether copolymer, polyethers dialkyl ester, polyethers dialkyl ether, the epoxy-modified object of polyethers The association thickeners such as fat system thickener, urethane-modified polyether system, polyurethane resin system of polyether polyol system etc. are special The eggs such as the surfactants such as macromolecule nonionic thickener, nonionic system system thickener, casein, casein acid sodium, casein acid ammonium Acrylic thickeners such as white matter system thickener and mosanom etc..
As levelling agent, can enumerate：PEG types nonionic surfactant (nonyl phenol EO1~40 mole addition product, Stearic acid EO1~40 mole addition product etc.), polyol-based non-ionic surfactant (anhydrous sorbitol palm acid monoester, dehydration Sorbierite stearate monoesters, three ester of anhydrous sorbitol stearic acid etc.), fluorine-containing surfactant (perfluoroalkyl EO1~50 mole plus At object, perfluoroalkyl carboxylate, perfluoroalkyl betain etc.) and modified silicon oil [polyether modified silicon oil, (methyl) acrylate Modified silicon oil etc.] etc..
Curing agent can be enumerated as the curing agent of polyalcohols：Hexamethylene diisocyanate, trimethyl six Methylene diisocyanate, isophorone diisocyanate, hydrogenated diphenyl methane diisocyanate, two isocyanide of diphenyl methane Acid esters, xylylene diisocyanate, hydrogenation xylylene diisocyanate, toluylene diisocya-nate, hydrogenation first generation Phenylene vulcabond, lysine diisocyanate, the nurate bodies of polyisocyanate compound, buret bodies, polyisocyanic acid The addition body of polyalcohol as ester compounds and ethylene glycol, propylene glycol, trimethylolpropane, by blocked polyisocyanic acid The monomers such as ester curing agent or mixture of more than two kinds, their polyalcohol addition product, their copolymer, block polymer etc. It like that at normal temperatures being capable of cured isocyanates.As the curing agent of epoxy resin, can enumerate：Acid anhydrides, phenolic aldehyde tree Fat, polyamide, amine additives, urea resin, melmac and isocyanates etc..
As crosslinking agent, can enumerate：Melmac, urea resin, polyisocyanate compound, block polyisocyanate cyanogen Ester compound, epoxide or resin, carboxylated compound or resin, acid anhydrides, based compound containing alkoxy silane or tree Fat and hexamethoxy methylated melamine, N, N, N ', N '-tetrakis hydroxymethyl phosphoniums succinamide, tetramethoxymethylization urine Element, 2,4,6- tetrakis hydroxymethyl phosphonium phenol etc. have the compound of hydroxymethyl and methoxy or ethoxyl methyl etc..
As pigment, other than aforesaid pigments, can also enumerate：Vanadium pentoxide, calcium vanadate, vanadic acid magnesium and ammonium metavanadate Equal vfanadium compound；Magnesium phosphate, ammonium magnesium phosphate eutectoid object, one hydrogen magnesium of phosphoric acid, magnesium dihydrogen phosphate, magnesium phosphate calcium eutectoid object, phosphorus Sour magnesium cobalt eutectoid object, magnesium phosphate nickel eutectoid object, phosphorous acid magnesium, phosphorous acid magnesium calcium eutectoid object, three polyphosphoric acid aluminum dihydrogens, three The phosphate metals such as polyphosphoric acid magnesium, the magnesia processed material of three polyphosphoric acid aluminum dihydrogens, the magnesia processed material of three polyphosphoric acid dihydro zinc The silica modified chemical combination of magnesium phosphate as the processed material of the magnesium-containing compound of salt and then silica modified magnesium phosphate etc. The phosphate-based rust resisting pigment such as object；The rust resisting pigment containing zinc ingredient such as trbasic zinc phosphate, magnesium handle three polyphosphoric acid aluminum dihydrogens, Calcium treatment Calcium phosphate etc. is without zinc rust resisting pigment；Including the calcium silicates such as composite calcium silicate of calcium orthosilicate ingredient or calcium metasilicate ingredient；Calcium from Son exchanges silica, magnesium ion exchanges the metal ion exchangeds silica such as silica；With preventing comprising Cr VI, lead etc. Become rusty pigment etc..
As antifoaming agent, for example,：Silicone oil, dimethyl polysiloxane, organic modified polyorganosiloxane, fluorine richness are poly- The silicon-types such as siloxanes antifoaming agent, mineral oil system antifoaming agent, non-organic silicon polymer system antifoaming agent, comprising changing selected from organic At least one kind of antifoaming agent in property fluorine compounds and poly (oxyalkylene) based compound and the aliphatic alcohol for including 18 or more carbon number Antifoaming agent etc..
Light stabilizer, fire retardant, solidification catalyst, fungicide for antioxidant, comprising ultra-violet absorber and Antiseptic etc. can enumerate aforementioned substances.
Description of the drawings
Fig. 1 is the excitation spectrum of 1 sample of embodiment provided by the invention；
Fig. 2 is the emission spectrum of 1 sample of embodiment provided by the invention；
Fig. 3 is the afterglow intensity test result of 1 ~ 3 sample of embodiment provided by the invention；
Fig. 4 is the afterglow intensity test result of 4 ~ 6 sample of embodiment provided by the invention.
Specific implementation mode
Invention is further described in detail for 1-4 and specific embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of red long-afterglow phosphor, chemical composition Sr2.96SiAlO5Cl3: 0.02Eu2+, 0.02Dy3+。
A kind of preparation method of red long-afterglow phosphor, with the SrCO of high-purity3、SiO2、AlCl3、Eu2O3And Dy2O3 As raw material, according to chemical composition Sr2.96SiAlO5Cl3: 0.02Eu2+, 0.02Dy3+The proportioning of middle each element, accurately weighs Each raw material；Using agate ball as mill ball, using absolute ethyl alcohol as ball-milling medium, simultaneously by agate ball, absolute ethyl alcohol and raw material It is put into ball grinder, ball mill mixing 5 hours on planetary ball mill, forms pulp-like mixture, absolute ethyl alcohol and raw material Mass ratio is 2:3；The pulp-like mixture of acquisition is placed in baking oven, heat preservation drying 8 hours under the conditions of 70 DEG C, then will dried The raw material obtained afterwards crosses 300 mesh sieve, obtains uniformly mixed raw material；By uniformly mixed raw material be put into high temperature process furnances into Row sintering, sintering temperature are 1200 DEG C, and sintering time is 4 hours, and heating rate is 5 DEG C/min, sintering atmosphere 5%H2/95%N2 Hydrogen nitrogen mixed gas, cool to room temperature with the furnace after the completion of sintering, obtain sintered body；Finally, the sintered body of acquisition is subjected to ball milling It crushes, and using gas flow sizing machine the powder after crushing is classified according to particle size glimmering to get a kind of red long-afterglow Light powder.
Embodiment 2
A kind of red long-afterglow phosphor, chemical composition Sr2.98SiAlO5Cl3: 0.01Eu2+, 0.01Gd3+。
A kind of preparation method of red long-afterglow phosphor, with the SrCO of high-purity3、SiO2、AlCl3、Eu2O3And Gd2O3 As raw material, according to chemical composition Sr2.98SiAlO5Cl3: 0.01Eu2+, 0.01Gd3+The proportioning of middle each element, accurately weighs Each raw material；Using agate ball as mill ball, using absolute ethyl alcohol as ball-milling medium, simultaneously by agate ball, absolute ethyl alcohol and raw material It is put into ball grinder, ball mill mixing 15 hours on planetary ball mill, forms pulp-like mixture, absolute ethyl alcohol and raw material Mass ratio is 2:3；The pulp-like mixture of acquisition is placed in baking oven, heat preservation drying 6 hours under the conditions of 80 DEG C, then will dried The raw material obtained afterwards crosses 300 mesh sieve, obtains uniformly mixed raw material；By uniformly mixed raw material be put into high temperature process furnances into Row sintering, sintering temperature are 900 DEG C, and sintering time is 3 hours, and heating rate is 7.5 DEG C/min, sintering atmosphere 5%H2/95% N2Hydrogen nitrogen mixed gas, cool to room temperature with the furnace after the completion of sintering, obtain sintered body；Finally, the sintered body of acquisition is subjected to ball It is milled broken, and the powder after crushing is classified according to particle size to get a kind of red long-afterglow using gas flow sizing machine Fluorescent powder.
Embodiment 3
A kind of red long-afterglow phosphor, chemical composition Sr2.94SiAlO5Cl3: 0.03Eu2+, 0.03Nd3+。
A kind of preparation method of red long-afterglow phosphor, with the SrCO of high-purity3、SiO2、AlCl3、Eu2O3And Nd2O3 As raw material, according to chemical composition Sr2.94SiAlO5Cl3: 0.03Eu2+, 0.03Nd3+The proportioning of middle each element, accurately weighs Each raw material；Using agate ball as mill ball, using absolute ethyl alcohol as ball-milling medium, simultaneously by agate ball, absolute ethyl alcohol and raw material It is put into ball grinder, ball mill mixing 10 hours on planetary ball mill, forms pulp-like mixture, absolute ethyl alcohol and raw material Mass ratio is 2:3；The pulp-like mixture of acquisition is placed in baking oven, heat preservation drying 7 hours under the conditions of 75 DEG C, then will dried The raw material obtained afterwards crosses 300 mesh sieve, obtains uniformly mixed raw material；By uniformly mixed raw material be put into high temperature process furnances into Row sintering, sintering temperature are 1100 DEG C, and sintering time is 5 hours, and heating rate is 10 DEG C/min, sintering atmosphere 5%H2/95% N2Hydrogen nitrogen mixed gas, cool to room temperature with the furnace after the completion of sintering, obtain sintered body；Finally, the sintered body of acquisition is subjected to ball It is milled broken, and the powder after crushing is classified according to particle size to get a kind of red long-afterglow using gas flow sizing machine Fluorescent powder.
Embodiment 4
A kind of red long-afterglow phosphor, chemical composition Sr2.92SiAlO5Cl3: 0.04Eu2+, 0.02Dy3+, 0.02Gd3+。
A kind of preparation method of red long-afterglow phosphor, with the SrCO of high-purity3、SiO2、AlCl3、Eu2O3、Dy2O3、 And Gd2O3As raw material, according to chemical composition Sr2.92SiAlO5Cl3: 0.04Eu2+, 0.02Dy3+, 0.02Gd3+Middle each element Proportioning, accurately weigh each raw material；Using agate ball as mill ball, using absolute ethyl alcohol as ball-milling medium, by agate ball, anhydrous Ethyl alcohol and raw material are put into ball grinder simultaneously, and ball mill mixing 20 hours on planetary ball mill form pulp-like mixture, nothing The mass ratio of water-ethanol and raw material is 2:3；The pulp-like mixture of acquisition is placed in baking oven, drying is kept the temperature under the conditions of 75 DEG C 4 hours, then the raw material obtained after drying is crossed into 300 mesh sieve, obtain uniformly mixed raw material；Uniformly mixed raw material is put into It is sintered in high temperature process furnances, sintering temperature is 1200 DEG C, and sintering time is 6 hours, and heating rate is 7.5 DEG C/min, is burnt Knot atmosphere is 5%H2/95%N2Hydrogen nitrogen mixed gas, cool to room temperature with the furnace after the completion of sintering, obtain sintered body；Finally, it will obtain Sintered body carry out ball mill grinding, and using gas flow sizing machine to the powder after crushing according to particle size be classified to get A kind of red long-afterglow phosphor.
Embodiment 5
A kind of red long-afterglow phosphor, chemical composition Sr2.9SiAlO5Cl3: 0.04Eu2+, 0.03Gd3+, 0.03Nd3+。
A kind of preparation method of red long-afterglow phosphor, with the SrCO of high-purity3、SiO2、AlCl3、Eu2O3、Gd2O3With Nd2O3As raw material, according to chemical composition Sr2.9SiAlO5Cl3: 0.04Eu2+, 0.03Gd3+, 0.03Nd3+Middle each element Proportioning, accurately weighs each raw material；Using agate ball as mill ball, using absolute ethyl alcohol as ball-milling medium, by agate ball, anhydrous second Alcohol and raw material are put into ball grinder simultaneously, ball mill mixing 15 hours on planetary ball mill, form pulp-like mixture, anhydrous The mass ratio of ethyl alcohol and raw material is 2:3；The pulp-like mixture of acquisition is placed in baking oven, the heat preservation drying 5 under the conditions of 80 DEG C Hour, then the raw material obtained after drying is crossed into 300 mesh sieve, obtain uniformly mixed raw material；Uniformly mixed raw material is put into It is sintered in high temperature process furnances, sintering temperature is 1000 DEG C, and sintering time is 4 hours, and heating rate is 10 DEG C/min, sintering Atmosphere is 5%H2/95%N2Hydrogen nitrogen mixed gas, cool to room temperature with the furnace after the completion of sintering, obtain sintered body；Finally, by acquisition Sintered body carries out ball mill grinding, and is classified to get one according to particle size to the powder after crushing using gas flow sizing machine Kind red long-afterglow phosphor.
Embodiment 6
A kind of red long-afterglow phosphor, chemical composition Sr2.85SiAlO5Cl3: 0.05Eu2+, 0.03Dy3+, 0.03Gd3+, 0.04Nd3+。
A kind of preparation method of red long-afterglow phosphor, with the SrCO of high-purity3、SiO2、AlCl3、Eu2O3、Dy2O3、 Gd2O3And Nd2O3As raw material, according to chemical composition Sr2.85SiAlO5Cl3: 0.05Eu2+, 0.03Dy3+, 0.03Gd3+, 0.04Nd3+The proportioning of middle each element accurately weighs each raw material；Using agate ball as mill ball, it is situated between using absolute ethyl alcohol as ball milling Agate ball, absolute ethyl alcohol and raw material are put into ball grinder, ball mill mixing 10 hours, shape on planetary ball mill by matter simultaneously At pulp-like mixture, the mass ratio of absolute ethyl alcohol and raw material is 2:3；The pulp-like mixture of acquisition is placed in baking oven, Heat preservation drying 6 hours under the conditions of 70 DEG C, then the raw material obtained after drying is crossed into 300 mesh sieve, obtain uniformly mixed raw material；It will Uniformly mixed raw material, which is put into high temperature process furnances, to be sintered, and sintering temperature is 1100 DEG C, and sintering time is 5 hours, heating Rate is 10 DEG C/min, sintering atmosphere 5%H2/95%N2Hydrogen nitrogen mixed gas, sintering after the completion of cool to room temperature with the furnace, obtain Sintered body；Finally, the sintered body of acquisition is subjected to ball mill grinding, and utilizes gas flow sizing machine to the powder after crushing according to grain size Size is classified to get a kind of red long-afterglow phosphor.
Fig. 1 is 1 excitation spectrum of embodiment provided by the invention, supervisory wavelength 640nm, it can be seen from the figure that the sample Product can effectively be excited by the purple light of 200 ~ 400nm and black light；Fig. 2 is 1 launching light spectrogram of embodiment provided by the invention, Excitation wavelength is 340nm, it can be seen from the figure that the fluorescence emission peak of the sample is located at the red light region of 640nm.Fig. 3 and Fig. 4 The respectively afterglow intensity test result of embodiment 1 ~ 3 and embodiment 4 ~ 6, it can be seen from the figure that active ions Eu2+And impurity Energy level ion Dy3+、Gd3+And Nd3+Doping concentration to the initial fluorescent intensity and afterglow intensity of sample and persistence by weight It influences, by introducing rare earth ion Dy3+、Gd3+And Nd3+One or more of combination provide trap level, can effectively increase Strong after-glow brightness extends persistence.

Claims (1)

1. a kind of synthetic paper, which is characterized in that contain red long-afterglow phosphor, red long-afterglow phosphor inside the synthetic paper Chemical composition general formula be Sr3-x-ySiAlO5Cl3: xEu2+, yRe3+, wherein Re is Dy, one or more of Gd and Nd group It closes, the value range of x and y are respectively：0.01≤x≤0.05,0.01≤y≤0.10.
CN201810781100.0A 2017-11-02 2017-11-02 A kind of synthetic paper Withdrawn CN108753280A (en)

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Application publication date: 20181106