CN108728181A - A kind of high-clean gasoline component and its application - Google Patents
A kind of high-clean gasoline component and its application Download PDFInfo
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- CN108728181A CN108728181A CN201810620053.1A CN201810620053A CN108728181A CN 108728181 A CN108728181 A CN 108728181A CN 201810620053 A CN201810620053 A CN 201810620053A CN 108728181 A CN108728181 A CN 108728181A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
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Abstract
The present invention provides a kind of high-clean gasoline components, belong to clean energy technology, include the ingredient of following mass percentage:Detergent-dispersant additive 0.2~0.5%;Preservative 0.1~0.3%;Power agent 0.1~0.4%;Cosolvent 0.5~0.8%;Extraction raffinate is methanol and methyl tertiary butyl ether(MTBE), and the mass ratio of the methanol tertbutyl ether is 80:19.For the content of methanol up to 70%, the volume of the high-clean gasoline component in automobile-used high-clean gasoline is big in high-clean gasoline component provided by the invention, and without being modified to engine.The problem of experimental data in the embodiment of the present invention shows in automobile-used high-clean gasoline, and the component of the high-clean gasoline can be added to 80%, and there is no being short of power, cold start-up difficulty and corrosion swelling.
Description
Technical field
The present invention relates to clean energy technology field, more particularly to a kind of high-clean gasoline component and its application.
Background technology
It is growing day by day for the demand of fuel with the development of world economy, the moneys such as traditional diesel oil, gasoline, natural gas
Source is all the more deficient.According to world oil summit statistical data, world oil can commercial use exploit 32 years, so exploitation novel high-definition
Clean alternative energy source becomes the Main way of future source of energy field development;The utilization of the renewable sources of energy are had been increased to
Unprecedented height, rubbish, agricultural residue, coal, timber, straw etc. may pass through gasification and be synthetically produced methanol, so
Methanol fuel worldwide promotes the use of a large area.
Automobile-used high-clean gasoline is by normal benzine, methanol and a series of cosolvents, made of being allocated using advanced technologies
Novel clean-fuel.Methanol is a kind of physicochemical properties and the approximate organic-fuel of gasoline.It can be by natural gas, coal, biology
The productions such as raw material are made.Methanol is colourless, easy flowing, volatile, soluble easily in water, but the solubility in aliphatic hydrocarbon is smaller.
The methanol fuel thermal efficiency is high, adaptability is good, clean and safe, can meet the power and requirement of existing engine, convenient for defeated
Match and promotes and applies.
Substitute of the automobile-used high-clean gasoline as gasoline, it is desirable to it to be equally directly used in automobile internal to gasoline
Machine.Automobile-used high-clean gasoline is prepared the most common are simple mixing method, countries in the world are all widely being studied.But
Currently common automobile-used high-clean gasoline methanol volume is few, must be no to engine modification if methanol volume is more than 70%
Then can go out to be short of power, cold start-up difficulty and corrosion swelling the problems such as.
Invention content
In view of this, present invention aims at provide a kind of high-clean gasoline component, high-clean gasoline provided by the invention
Volume of the component in automobile-used high-clean gasoline is big, and without being modified to engine.
The present invention provides a kind of high-clean gasoline components, include the ingredient of following mass percentage:
Extraction raffinate is methanol and methyl tertiary butyl ether(MTBE), and the mass ratio of the methanol tertbutyl ether is 80:19.
Preferably, the detergent-dispersant additive includes polyisobutylene amine, BL100 polyetheramines or PEA polyetheramines.
Preferably, the preservative includes triethanolamine, ring amine or imidazoline.
Preferably, the power agent includes uprising dose of MMT, dimethyl carbonate or compound isooctyl acid lithium.
Preferably, the cosolvent includes the alcohol or n-octyl alcohol of isopropanol, C12~C18.
Preferably, the alcohol of the C12~C18 includes carbon lauryl alcohol, carbon tetradecyl alchohol or carbon hexadecanol.
Preferably, the mass ratio of the methanol and methyl tertiary butyl ether(MTBE) is 80:19.
The present invention also provides application of the above-mentioned high-clean gasoline component in automobile-used high-clean gasoline, the high cleaning vapour
The addition content of oil ingredient is 15-80.
Advantageous effects:The present invention provides a kind of high-clean gasoline component, including following mass percentage at
Point:Detergent-dispersant additive 0.2~0.5%;Preservative 0.1~0.3%;Power agent 0.1~0.4%;Cosolvent 0.5~0.8%;It is remaining
Liquid is methanol and methyl tertiary butyl ether(MTBE), and the mass ratio of methanol and methyl tertiary butyl ether(MTBE) is 80:19.Due to methanol calorific value deficiency gasoline
One of three, become smaller dynamic property can be caused poor as the additive amount of methanol increases gasoline additive amount, the present invention, which passes through, adds power
Agent make its laminar flame propagation velocity accelerate, on high compression ratio vehicle improve engine power, make up methanol calorific value it is low lack
It falls into, the latent calorific value of methanol is 3.7 times of gasoline, as the increase of methanol additive amount can cause cold rear difficulty in starting, the present invention
Methyl tertiary butyl ether(MTBE) by adding low latent calorific value, which increases volatility, makes it smoothly start, and methyl tertiary butyl ether(MTBE) also has one
Fixed hydrotropy;Metalwork and plastic part protective film after the present invention can make clean gasoline component enter fuel tank by addition preservative
Inhibit the corrosion and swelling of methanol.The content of methanol is up to 70% in high-clean gasoline component provided by the invention, the high cleaning vapour
Volume of the oil ingredient in automobile-used high-clean gasoline is big, and without being modified to engine.Experimental data shows in automobile-used height
In clean gasoline, the component of the high-clean gasoline can be added to 80%, and there is no being short of power, cold start-up is difficult and corrodes
The problem of swelling.
Description of the drawings:
Fig. 1 is the platinum resistance of the model 678201 of Ruian Chuan Chi motor vehicle fittings factory production;
Fig. 2 is the 678201 platinum sensor wiring diagram of model for travelling the production of 10000 kilometers of Hou Fu factories;
Fig. 3 is platinum resistance pictorial diagram after travelling 10000 kilometers in embodiment 4;
Fig. 4 is the platinum resistance pictorial diagram after being powered in usual methanol clean gasoline in embodiment 4;
Fig. 5 is the platinum resistance pictorial diagram after being powered in usual methanol clean gasoline in embodiment 4;
Fig. 6 is the pictorial diagram of the platinum resistance after the automobile-used high-clean gasolines of M80 are powered in embodiment 4;
Fig. 7 is the pictorial diagram of the platinum resistance after the automobile-used high-clean gasolines of M80 are powered in embodiment 4;
Fig. 8 is the comparison diagram of the platinum resistance after platinum resistance is not used in embodiment 4 and is powered in different medium;
Fig. 9 is the pictorial diagram of fuel oil filter screen after 50000 kilometers of traveling in embodiment 5;
Figure 10 is the pictorial diagram of fuel oil filter screen after 50000 kilometers of traveling in embodiment 5;
Figure 11 is the pictorial diagram of electric pump inserted sheet after 50000 kilometers of traveling in embodiment 5;
Figure 12 is the pictorial diagram of electric pump inserted sheet after 50000 kilometers of traveling in embodiment 5;
Figure 13 is the nonmetallic materials pictorial diagram of electric pump after 50000 kilometers of traveling in embodiment 6;
Figure 14 is the nonmetallic materials pictorial diagram of electric pump after 50000 kilometers of traveling in embodiment 6;
Figure 15 is engine cylinder cover pictorial diagram after travelling 50000 kilometers in example 7
Figure 16 is engine crankcase pictorial diagram after travelling 50000 kilometers in example 7
Figure 17 is engine piston pictorial diagram after travelling 50000 kilometers in example 7
Figure 18 is engine cylinder body pictorial diagram after travelling 50000 kilometers in example 7
Specific implementation mode
The present invention provides a kind of high-clean gasoline components, include the ingredient of following mass percentage:
Extraction raffinate is methanol and methyl tertiary butyl ether(MTBE), and the mass ratio of the methanol tertbutyl ether is 80:19.
In the present invention, the mass ratio of the methanol and methyl tertiary butyl ether is preferably 80:19, more preferably 74:25.
In the present invention, the methanol is preferably the smart alcohol of national standard 99.9.
The present invention is not particularly limited the source of methanol and methyl tertiary butyl ether, selects well known to those skilled in the art
Commercial goods.
Invention makes it smoothly start by adding the methyl tertiary butyl ether(MTBE) increase volatility of low latent calorific value, and methyl- tert
Butyl ether also has certain hydrotropy.
In the present invention, the detergent-dispersant additive is preferably polyisobutylene amine, BL100 polyetheramines or PEA polyetheramines, more
Preferably polyisobutylene amine or PEA polyetheramines.
In the present invention, the detergent-dispersant additive can effectively remove the unsaturated hydrocarbons in gasoline and occur cracking generation in high temperature
Carbon deposit is heavy, inhibits fuel injector, the carbon deposit in inlet valve and cylinder.
In the present invention, the preservative is preferably triethanolamine, ring amine or imidazoline.
Metalwork and plastic part protective film press down after the present invention can make clean gasoline component enter fuel tank by addition preservative
The corrosion and swelling of methanol processed.
In the present invention, the power agent is preferably uprising dose of MMT, dimethyl carbonate or compound isooctyl acid lithium, more preferably
For uprising dose of MMT or compound isooctyl acid lithiums.
The present invention makes its laminar flame propagation velocity accelerate by adding power agent, and engine is improved on high compression ratio vehicle
Power, make up the low defect of methanol calorific value.
In the present invention, the cosolvent is preferably the alcohol or n-octyl alcohol of isopropanol, C12~C18.
In the present invention, the alcohol of the C12~C18 is preferably carbon lauryl alcohol, carbon tetradecyl alchohol or carbon hexadecanol.
The present invention is preferably by detergent-dispersant additive, preservative, power agent, cosolvent, methanol and methyl tertiary butyl ether(MTBE) by described
Mass fraction mixing, obtain high-clean gasoline component.
The present invention is not particularly limited mixed method, selects mixed method well known to those skilled in the art.
The present invention also provides application of the above-mentioned high-clean gasoline component in automobile-used high-clean gasoline, the high cleaning vapour
The addition content of oil ingredient is 15-80.
In the present invention, the addition content of the high-clean gasoline component is preferably 30, and more preferably 25.
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention
Content is not limited solely to the following examples.
Embodiment 1
A kind of clean gasoline component, composition includes detersive, preservative, cosolvent and methanol, methyl tertiary butyl ether(MTBE).
By mass fraction by 90 parts of methanol, 9 parts of methyl tertiary butyl ether(MTBE), 0.5 part of cosolvent isopropanol, 0.1 part of preservative triethanolamine, dynamic
Uprising dose 0.1 part of power agent MMT, 0.3 part of detersive polyamine ether are mixed to get high-clean gasoline component.
It takes 20 parts to be mixed 20 minutes with 80 parts of cycles of 93# national standards gasoline high-clean gasoline component obtained above and vehicle is made
With clean gasoline, have oil consumption low with former national standard 93# steam oil ratio (SOR)s, the strong feature of dynamic property.It is tested on the 4G15S engines of Dongan
It is 7.04kg/h that engine 2000r/min, which uses national standard 93# gasoline, per hour oil consumption, uses the high-clean gasoline in embodiment 1
Engine 2000r/min, oil consumption 6.55kg/h.Engine output was that 2000r/min power is 20.3kw originally, used vehicle
It is 20.8kw with 2000r/min power after high-clean gasoline.
Embodiment 2
A kind of high-clean gasoline component, composition includes detersive, preservative, cosolvent and methanol, methyl tertbutyl
Ether.By methanol by 80 parts of mass fraction, 18 parts of methyl tertiary butyl ether(MTBE), 0.8 part of cosolvent n-octyl alcohol, preservative triethanolamine 0.3
100 parts of high-clean gasoline components are obtained after 0.5 part of part, 0.4 part of the compound isooctyl acid lithium of power agent, detersive PEA polyetheramines mixing.
Above the prepared high-clean gasoline component is taken into 30 parts and 15 parts of hydrocracked naphtha of oil refining, 89# base gasolines
Clean gasoline is made in 20 minutes in 65 parts of cycle mixing.
Embodiment 3
A kind of high-clean gasoline component, composition includes detersive, preservative, cosolvent and methanol, methyl tertbutyl
Ether.By methanol by 80 parts of mass fraction, 18 parts of methyl tertiary butyl ether(MTBE), 0.8 part of cosolvent isopropanol, 0.3 part of preservative imidazoline,
Uprising dose 0.4 part of power agent MMT, 0.5 part of detersive polyetheramine are uniformly mixed and obtain high-clean gasoline component.
High-clean gasoline component is mixed with 93# national standard gasoline, makes the mass fraction of high-clean gasoline component be respectively
15%, 30%, 50%, 70%, 80% and 85%, respectively obtain automobile-used high-clean gasoline M15, M30, M50, M70, M80 and
M85。
1~table of table 3 is that 93# national standard gasoline adds 80% high-clean gasoline component and is not added with the 93# national standards of high cleaning component
Gasoline is in 7 load points, mean power, average torque, average consumprion and the average fuel of 8 load points and 6 load points
The Engine Load Characteristics Experimental Comparison result of consumption rate:
Full engine load speed characteristic test refers to engine in different rotating speeds, and peak load (all beats by air throttle
Open-throttle is maximum) extreme condition under power, torque, fuel consumption and fuel consumption rate contrast test.
Performance test of the M80 and 93# national standards gasoline in 7 load points in 1 embodiment 3 of table
Performance test of the M80 and 93# national standards gasoline in 8 load points in 2 embodiment 3 of table
Performance test of the M80 and 93# national standards gasoline in 8 load points in 3 embodiment 3 of table
As shown in Table 1, the mean power of M80 Vehicular methanol petrols ratio 93# gasoline has lost under normal driving condition
3%, average torque has lost 3%, and average consumprion reduces 3.5%, and average fuel consumption rate reduces 5.2%.Illustrate reality
The automobile-used high-clean gasoline in example 3 is applied with 93# national standards gasoline in the mean power of 7 load points, average torque, average consumprion
It is very close with the Engine Load Characteristics data such as average fuel consumption rate, illustrate, the automobile-used high cleaning vapour obtained in embodiment 3
The problem of being short of power is not present when high-clean gasoline component additive amount is 80% for oil.Solves methanol volume in the prior art
More than 70%, then must otherwise engine modification then can be gone out to be short of power.
It can be obtained by 1~table of table 3 to draw a conclusion:
1) under conditions of the normal driving of 2000r/min, mean power has lost 3%, and average torque has lost 3%,
But average consumprion has saved 3.5%.
2) under the extreme condition of 1000~4500r/min peak loads (air throttle is fully open --- throttle maximum),
Average maximum power has lost 10.3%, and average peak torque has lost 9.1%, and average maximum fuel consumption increases 27%.
3) under the extreme condition of 1000~3500r/min peak loads (air throttle is fully open --- throttle maximum),
Average maximum power has lost 6.7%, and average peak torque has lost 5.6%, and average maximum fuel consumption increases 27%.
The automobile-used high-clean gasolines of M80 are obtained in embodiment 3 to be negated in the world about the first for often increasing by 10% in the oil
Alcohol, power dropping 5% and oil consumption increase by 5% so-called authentic theory.Automobile uses the automobile-used high-clean gasolines of M80 in embodiment 3,
Engine is not required to be transformed, and dynamic property is basically unchanged, especially in high compression engine, under normal driving condition, and M80
Oil consumption also than gasoline save 3-5%.
The automobile-used high-clean gasoline that is obtained in 4 embodiment 3 of table is cold to open performance test
Product | Cold start-up ignition times | Cold start-up firing temperature |
M15 | 1 time | -30℃ |
M30 | 1 time | -30℃ |
M50 | 1 time | -20℃ |
M70 | 1 time | -10℃ |
M80 | 1 time | -5℃ |
As shown in Table 4, the automobile-used high high-clean gasoline obtained in embodiment 1 opens difficult problem there is no cold.
Automobile-used high-clean gasoline and 93# ethanol petrol engine idling and high idle speed operating mode lower stage pair in 5 embodiment 3 of table
Brake specific exhaust emission test result
As shown in Table 5, the automobile-used high-clean gasoline rule discharge obtained in embodiment 3 is lower than 93# ethanol petrol.
Embodiment 4
In the fuel tank of automobile and motorcycle, equipped with the fuel level sensor for detecting level height, form mainly has two
Kind:One is electromagnetism tongue cast fuel level sensor, another kind is thick-film resistor template fuel level sensor, and thick-film resistor template
According to the structure and material of thick-film resistor board, there are many types, wherein model in PCB types fuel level sensor again for fuel level sensor
For 678201 Ruian Chuan Chi motor vehicle fittings factory produce platinum resistance be that quality is worst in all fuel level sensors, be easiest to by
The platinum resistance of methanol gasoline corrosion, after fuel level sensor is corroded by methanol, will lead to oil meter pointer failure or inaccuracy.
Fig. 1 is not used platinum resistance, and model 678201, generation producer is * * * *.
Thick-film resistor fuel level sensor substrate material:96%Al2O3, conductor material:Ag/Pd, silver-cadmium contact is in electrode surface
Sliding, external cord are 0.5 square millimeter thin skin oil resistant conducting wire or QVR primary cables, and general plug-in jacket is nylon, and inserted sheet is
Phosphor bronze or brass.
The operating current of thick-film resistor fuel level sensor is generally the mA of several mA~hundreds of, and operating voltage is 0~12V, work
It is equivalent to a variable potentiometer as principle, when thick-film resistor is high resistance, operating voltage just increases, on the contrary then reduce.
Fig. 2 and Fig. 3 is to breathe out the Song Hua River minicar for flying to produce to travel using the automobile-used high-clean gasolines of M80 in embodiment 3
After 10000 kilometers, the platinum resistance of the 678201 thick-film resistor fuel level sensor of model of Ruian Chuan Chi motor vehicle fittings factory production
Situation of change.As can be seen from the figure:The anode plate face and anode contact of thick-film resistor are passivated by methanol gasoline preservative,
Its metalwork, rubber parts and plastic part do not change, are detected with multimeter:Circuit each point is logical.
Fig. 4 and Fig. 5 is that figure is the methanol and 93# national standards that the thick mould resistance of model 678201 is 80% in usual methanol content
Gasoline configuration usual methanol clean gasoline laboratory lead to 12V DC electricity 6 hours after situation of change.Fig. 4 platinum resistance is
Blackening corrosion is bad, and the contact of Fig. 5 resistance is corroded, and supply lines falls off.The anode plate face of platinum resistance is burnt, and is detected with multimeter:
Circuit is obstructed.
It is the automobile-used high-clean gasolines of M80 of 678201 thick mould resistance in embodiment 3 in reality that Fig. 6 and Fig. 7, which is the upper figure number of being,
It tests room and leads to situation of change of the 12V DC electricity after 120 hours.Fig. 6 can be seen that the platinum resistance still bright blackening that is not corroded, figure
7 it can be seen that wiring electric shock still falls off with connected be not corroded of wiring.Platinum resistance anode plate face and anode contact are by methanol
Gasoline preservative is passivated;It is detected with multimeter:Circuit each point is logical.
Fig. 8 is the 678201 platinum resistance original paper of model of Ruian Chuan Chi motor vehicle fittings factory production, in embodiment 3 M80
Lead to methanol and 93# national standard vapour of the 12V DC electricity after 120 hours and in usual methanol additive amount for 80% in automobile-used high-clean gasoline
Lead to situation of change comparison diagram of the 12V DC electricity after 6 hours in oily blend gasoline.
Embodiment 5
There are various metals component, the antiseptic properties such as pump case, armature laminate patch and electrical plug bad in electric fuel punp
The substances such as the formic acid that methanol gasoline is generated due to oxidation have corrosivity to metals such as copper, aluminium, magnesium and zinc, lead to methanol vapor
It on the one hand can accelerate the abrasion of pump body portion containing the corrosion products such as a large amount of positive metal ions, corrosion product in oil, separately
On the one hand it is readily adsorbed in the negative terminal surface of carbon brush, makes carbon brush and commutator poor contact, leads to the decline of pump speed, the pump housing
Abrasion and the lower general who has surrendered of pump revolution reduce the working efficiency of pump and shorten the service life of pump, while corrosivity product will
Cause fuel oil filter to block, makes vehicle can not normally travel.
Fig. 9 and Figure 10 is to breathe out the Song Hua River minicar for flying to produce to travel using the automobile-used high-clean gasolines of M80 in embodiment 3
After 50000 kilometers, the situation of change of fuel filter net, Fig. 9 fuel screens surface is totally miscellaneous without adsorbing the metal of any corrosion
Matter, Figure 10 illustrate that the fixed plastics part of oil pump is intact without there is corrosion swelling set, illustrate that M80 Vehicular methanol petrols are using
In without generate corrosion product.
Figure 11 and Figure 12 is to breathe out the Song Hua River minicar for flying to produce to use the automobile-used high-clean gasoline rows of M80 in embodiment 3
After sailing 50000 kilometers, the situation of change of electric pump inserted sheet.It can be seen that from figure:Electric pump anode tab is by methanol gasoline preservative
Passivation, does not occur corrosion phenomenon.
Methanol molecules amount is small, and molecular structure is simple, is easier to penetrate into the non-metal workpieces such as plastics, rubber than gasoline,
Plastics and rubber part are made to be swollen.When the methanol ratio in methanol gasoline is less than 15%, negligible methanol gasoline is to oil pump
In influenced for the swelling of the resinous material and adhesive material for sealing of insulation;When the methanol ratio in methanol gasoline is big
When 15%, after the resinous material of the insulation used in oil pump armature and the adhesive material for sealing are swollen by methanol gasoline
Being easy to fall off causes to block fuel system, influences the normal work of electric pump.
Embodiment 6
Figure 13 and Figure 14 is to breathe out the Song Hua River minicar for flying to produce to use the automobile-used high-clean gasoline rows of M80 in embodiment 3
After sailing 50000 kilometers, the nonmetallic materials situation of change of electric pump.It can be seen that from figure:The nonmetallic materials of electric pump are not sent out
Raw Swelling.
Embodiment 7
Figure 15, Figure 16, Figure 17 and Figure 18 are that upper figure is to breathe out to fly the M80 that the Song Hua River minicar of production uses embodiment 1 total
After Vehicular methanol petrol travels 50000 kilometers, the cylinder cap of engine, the situation of change of cylinder body, crankshaft and piston.It can be with from figure
Find out:Corrosion phenomenon does not occur for engine.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as the protection model of the present invention.
Claims (8)
1. a kind of high-clean gasoline component, includes the ingredient of following mass percentage:
Extraction raffinate is methanol and methyl tertiary butyl ether(MTBE), and the mass ratio of the methanol and methyl tertiary butyl ether(MTBE) is 80:19.
2. high-clean gasoline component according to claim 1, which is characterized in that the detergent-dispersant additive includes polyisobutene
Amine, bl100 polyetheramines or PEA polyetheramines.
3. high-clean gasoline component according to claim 1, which is characterized in that the preservative includes triethanolamine, ring
Amine or imidazoline.
4. high-clean gasoline component according to claim 1, which is characterized in that the power agent includes uprising dose of MMT, carbon
Dimethyl phthalate or compound isooctyl acid lithium.
5. high-clean gasoline component according to claim 1, which is characterized in that the cosolvent include isopropanol, C12~
The alcohol or n-octyl alcohol of C18.
6. high-clean gasoline component according to claim 5, which is characterized in that the alcohol of the C12~C18 includes carbon 12
Alcohol, carbon tetradecyl alchohol or carbon hexadecanol.
7. high-clean gasoline component according to claim 1, which is characterized in that the matter of the methanol and methyl tertiary butyl ether(MTBE)
Amount is than being 80:19.
8. application of the high-clean gasoline component in automobile-used high-clean gasoline described in claim 1~8 any one, feature
It is, the addition content of the high-clean gasoline component is 15-80%.
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