CN108727880A - A kind of formula of refractory ceramics coating - Google Patents

A kind of formula of refractory ceramics coating Download PDF

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Publication number
CN108727880A
CN108727880A CN201810675498.XA CN201810675498A CN108727880A CN 108727880 A CN108727880 A CN 108727880A CN 201810675498 A CN201810675498 A CN 201810675498A CN 108727880 A CN108727880 A CN 108727880A
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parts
nano
formula
refractory ceramics
ceramics coating
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梁小红
唐丽华
陆磊
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2244Oxides; Hydroxides of metals of zirconium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of formulas of refractory ceramics coating, become according to parts by weight group:10~30 parts of silicon nitride, 20~40 parts of Ludox, 10~20 parts of silicone acrylic emulsion, 5~10 parts of absolute ethyl alcohol, 5~20 parts of aluminium oxide, 5~10 parts of phosphate dihydrogen aluminum solution, 15~40 parts of carbon fiber, 0.5~5 part of nano material, 5~15 parts of color stuffing, 5~15 parts of silane coupling agent.Ceramic coating in the present invention has good high temperature resistant and wear-resisting property, has broad application prospects.

Description

A kind of formula of refractory ceramics coating
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of formula of refractory ceramics coating.
Background technology
Currently, sold high-temperature resistant coating is mostly organic high temperature-resistant coating in the market, also there is small part refractory inorganic paint, All in all, organic high temperature-resistant coating occupies the market of industry 85%.But high-temperature resistant coating in the prior art is generally deposited In heatproof insufficient strength, dope layer is easy to fall off under the high temperature conditions, and corrosion resistance is poor, and wear-resisting property is not ideal enough, service life The shortcomings of short.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of formula of refractory ceramics coating, existing skill can be solved The problem of art.
Invention content
The purpose of the present invention is to provide a kind of formulas of refractory ceramics coating, to overcome deficiency in the prior art.
To achieve the above object, the present invention provides the following technical solutions:
A kind of formula of refractory ceramics coating, becomes according to parts by weight group:10~30 parts of silicon nitride, Ludox 20~40 Part, 10~20 parts of silicone acrylic emulsion, 5~10 parts of absolute ethyl alcohol, 5~20 parts of aluminium oxide, 5~10 parts of phosphate dihydrogen aluminum solution, carbon fiber 15~40 parts of dimension, 0.5~5 part of nano material, 5~15 parts of color stuffing, 5~15 parts of silane coupling agent.
Preferably, become according to parts by weight group:15~30 parts of silicon nitride, 27.5~40 parts of Ludox, silicone acrylic emulsion 12.5 ~20 parts, 7.5~10 parts of absolute ethyl alcohol, 8~20 parts of aluminium oxide, 6~10 parts of phosphate dihydrogen aluminum solution, 20~40 parts of carbon fiber, 1.75~5 parts of nano material, 7.5~15 parts of color stuffing, 10~15 parts of silane coupling agent.
Preferably, become according to parts by weight group:22.5~30 parts of silicon nitride, 35~40 parts of Ludox, silicone acrylic emulsion 15~ 20 parts, 9~10 parts of absolute ethyl alcohol, 12~20 parts of aluminium oxide, 7.5~10 parts of phosphate dihydrogen aluminum solution, 27.5~40 parts of carbon fiber, 2.5~5 parts of nano material, 10~15 parts of color stuffing, 12.5~15 parts of silane coupling agent.
Preferably, the color stuffing be selected from wollastonite, perlite, zinc oxide, glass microsphere, ceramic microsphere, glass flakes, The combination of one or more of aluminium silicate wool or land plaster.
Preferably, the nano material is selected from nano silicon dioxide, nano-aluminium oxide, nano-titanium dioxide, nanometer One kind in zirconium oxide, nanometer silicon carbide, nano-silicon nitride, nano calcium oxide or nano-calcium carbonate.
Preferably, the nano material is nano-calcium carbonate.
Preferably, the silane coupling agent is selected from methyltriethoxysilane, amido diethoxy silane, dimethylformamide dimethyl It is one or more in oxysilane.
Compared with the prior art, the advantages of the present invention are as follows:Ceramic coating in the present invention has good high temperature resistant and resistance to Performance is ground, is had broad application prospects.
Specific implementation mode
The present invention is described further by the following example:According to following embodiments, the present invention may be better understood. However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of formula of refractory ceramics coating, becomes according to parts by weight group:10~30 parts of silicon nitride, silicon 20~40 parts of colloidal sol, 10~20 parts of silicone acrylic emulsion, 5~10 parts of absolute ethyl alcohol, 5~20 parts of aluminium oxide, phosphate dihydrogen aluminum solution 5~ 10 parts, 15~40 parts of carbon fiber, 0.5~5 part of nano material, 5~15 parts of color stuffing, 5~15 parts of silane coupling agent.
Wherein, the color stuffing is selected from wollastonite, perlite, zinc oxide, glass microsphere, ceramic microsphere, glass flakes, silicon The combination of one or more of sour aluminum wool or land plaster.
Further, the nano material is selected from nano silicon dioxide, nano-aluminium oxide, nano-titanium dioxide, receives One kind in rice zirconium oxide, nanometer silicon carbide, nano-silicon nitride, nano calcium oxide or nano-calcium carbonate.
Further, the nano material is nano-calcium carbonate.
Further, the silane coupling agent is selected from methyltriethoxysilane, amido diethoxy silane, dimethyl two It is one or more in methoxy silane.
Following formulas that the refractory ceramics coating in the present invention is illustrated with specifically embodiment.
Embodiment 1
Become according to parts by weight group:10 parts of silicon nitride, 20 parts of Ludox, 10 parts of silicone acrylic emulsion, 5 parts of absolute ethyl alcohol, oxidation 5 parts of aluminium, 5 parts of phosphate dihydrogen aluminum solution, 15 parts of carbon fiber, 0.5 part of nano material, 5 parts of color stuffing, 5 parts of silane coupling agent.
Embodiment 2
Become according to parts by weight group:15 parts of silicon nitride, 27.5 parts of Ludox, 12.5 parts of silicone acrylic emulsion, absolute ethyl alcohol 7.5 Part, 8 parts of aluminium oxide, 6 parts of phosphate dihydrogen aluminum solution, 20 parts of carbon fiber, 1.75 parts of nano material, 7.5 parts of color stuffing are silane coupled 10 parts of agent.
Embodiment 3
Become according to parts by weight group:22.5 parts of silicon nitride, 35 parts of Ludox, 15 parts of silicone acrylic emulsion, 9 parts of absolute ethyl alcohol, oxygen Change 12 parts of aluminium, 7.5 parts of phosphate dihydrogen aluminum solution, 27.5 parts of carbon fiber, 2.5 parts of nano material, 10 parts of color stuffing, silane coupling agent 12.5 parts.
Embodiment 4
Become according to parts by weight group:30 parts of silicon nitride, 40 parts of Ludox, 20 parts of silicone acrylic emulsion, 10 parts of absolute ethyl alcohol, oxidation 20 parts of aluminium, 10 parts of phosphate dihydrogen aluminum solution, 40 parts of carbon fiber, 5 parts of nano material, 15 parts of color stuffing, 15 parts of silane coupling agent.
Ceramic coating in the present invention has good high temperature resistant and therefore wear-resisting property has broad application prospects.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that including a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (7)

1. a kind of formula of refractory ceramics coating, which is characterized in that become according to parts by weight group:10~30 parts of silicon nitride, silicon 20~40 parts of colloidal sol, 10~20 parts of silicone acrylic emulsion, 5~10 parts of absolute ethyl alcohol, 5~20 parts of aluminium oxide, phosphate dihydrogen aluminum solution 5~ 10 parts, 15~40 parts of carbon fiber, 0.5~5 part of nano material, 5~15 parts of color stuffing, 5~15 parts of silane coupling agent.
2. the formula of refractory ceramics coating according to claim 1, which is characterized in that become according to parts by weight group:Nitrogen 15~30 parts of SiClx, 27.5~40 parts of Ludox, 12.5~20 parts of silicone acrylic emulsion, 7.5~10 parts of absolute ethyl alcohol, aluminium oxide 8~ 20 parts, 6~10 parts of phosphate dihydrogen aluminum solution, 20~40 parts of carbon fiber, 1.75~5 parts of nano material, 7.5~15 parts of color stuffing, 10~15 parts of silane coupling agent.
3. the formula of refractory ceramics coating according to claim 2, which is characterized in that become according to parts by weight group:Nitrogen 22.5~30 parts of SiClx, 35~40 parts of Ludox, 15~20 parts of silicone acrylic emulsion, 9~10 parts of absolute ethyl alcohol, aluminium oxide 12~20 Part, 7.5~10 parts of phosphate dihydrogen aluminum solution, 27.5~40 parts of carbon fiber, 2.5~5 parts of nano material, 10~15 parts of color stuffing, 12.5~15 parts of silane coupling agent.
4. the formula of refractory ceramics coating according to claim 1, which is characterized in that the color stuffing is selected from silicon ash One or more of stone, perlite, zinc oxide, glass microsphere, ceramic microsphere, glass flakes, aluminium silicate wool or land plaster Combination.
5. the formula of refractory ceramics coating according to claim 1, which is characterized in that the nano material is selected from nanometer Silica, nano-aluminium oxide, nano-titanium dioxide, nano zircite, nanometer silicon carbide, nano-silicon nitride, nano oxygen Change one kind in calcium or nano-calcium carbonate.
6. the formula of refractory ceramics coating according to claim 5, which is characterized in that the nano material is nano-sized carbon Sour calcium.
7. the formula of refractory ceramics coating according to claim 1, which is characterized in that the silane coupling agent is selected from first It is one or more in ethyl triethoxy silicane alkane, amido diethoxy silane, dimethyldimethoxysil,ne.
CN201810675498.XA 2018-06-27 2018-06-27 A kind of formula of refractory ceramics coating Withdrawn CN108727880A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109439059A (en) * 2018-11-09 2019-03-08 刘景典 A kind of high tenacity ceramic coating and preparation method thereof
CN112094511A (en) * 2019-06-18 2020-12-18 佛山市南海区沙头才华化工有限公司 Preparation method of nano composite ceramic coating
CN114133133A (en) * 2021-11-26 2022-03-04 洛阳耐研陶瓷纤维有限公司 Fire-resistant fiber composite board for working lining of glass tempering furnace
CN114315393A (en) * 2022-01-28 2022-04-12 淄博硅华陶瓷科技有限公司 Carbon fiber high-temperature-resistant coating and coating process thereof
CN115537047A (en) * 2022-10-09 2022-12-30 中华制漆(深圳)有限公司 Inorganic interior wall heat-insulating flame-retardant coating and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109439059A (en) * 2018-11-09 2019-03-08 刘景典 A kind of high tenacity ceramic coating and preparation method thereof
CN112094511A (en) * 2019-06-18 2020-12-18 佛山市南海区沙头才华化工有限公司 Preparation method of nano composite ceramic coating
CN114133133A (en) * 2021-11-26 2022-03-04 洛阳耐研陶瓷纤维有限公司 Fire-resistant fiber composite board for working lining of glass tempering furnace
CN114133133B (en) * 2021-11-26 2023-09-19 洛阳耐研陶瓷纤维有限公司 Refractory fiber composite board for working lining of glass tempering furnace
CN114315393A (en) * 2022-01-28 2022-04-12 淄博硅华陶瓷科技有限公司 Carbon fiber high-temperature-resistant coating and coating process thereof
CN114315393B (en) * 2022-01-28 2023-03-10 淄博硅华陶瓷科技有限公司 Carbon fiber high-temperature-resistant coating and coating process thereof
CN115537047A (en) * 2022-10-09 2022-12-30 中华制漆(深圳)有限公司 Inorganic interior wall heat-insulating flame-retardant coating and preparation method thereof

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