CN108727672A - A kind of track cable jacket of high-wear resistance and preparation method thereof - Google Patents

A kind of track cable jacket of high-wear resistance and preparation method thereof Download PDF

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Publication number
CN108727672A
CN108727672A CN201810645126.2A CN201810645126A CN108727672A CN 108727672 A CN108727672 A CN 108727672A CN 201810645126 A CN201810645126 A CN 201810645126A CN 108727672 A CN108727672 A CN 108727672A
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CN
China
Prior art keywords
parts
wear resistance
cable jacket
track cable
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810645126.2A
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Chinese (zh)
Inventor
毕力
高敏
陈鹏
刘勇
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ANHUI YILI CABLE Co Ltd
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ANHUI YILI CABLE Co Ltd
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Priority to CN201810645126.2A priority Critical patent/CN108727672A/en
Publication of CN108727672A publication Critical patent/CN108727672A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2231Oxides; Hydroxides of metals of tin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses track cable jackets of a kind of high-wear resistance and preparation method thereof.The track cable jacket of one of which high-wear resistance, raw material are formed by following parts by weight:50~70 parts of high density polyethylene (HDPE), 30~40 parts of thermoplastic polyurethane, 15~25 parts of one acetate ethylene copolymer of ethylene, 20~30 parts of ethylene-propylene diene copolymer, 10~15 parts of calcium stearate, 5~10 parts of glass fibre, 8~12 parts of graphite, 5~8 parts of alumina silicate, 3~5 parts of magnesia, 8~10 parts of tin oxide, 3~5 parts of plasticizer, 4~6 parts of silane coupling agent, 2~5 parts of lubricant, 4~6 parts of stabilizer, 1~3 part of antioxidant.The present invention improves the wearability and intensity of sheath material, reduces the ageing time of sheath material, and high temperature and pressure effect can be kept lower non-degradable for a long time.

Description

A kind of track cable jacket of high-wear resistance and preparation method thereof
Technical field
The invention belongs to track field of cables, the track cable jacket more particularly to a kind of high-wear resistance and its preparation Method.
Background technology
It is exactly to be made of the conductor and external insulating protective layer of one or more mutually insulated for cable is popular, by electric power Or information is transferred to the conducting wire at another place from one.With the rapid development of economy, more and more places need cable to transmit Electric power or other information, therefore also have tightened up requirement to the manufacture of cable.Protective coverings of cable is the indispensable knot of cable Structure part plays a part of protecting cable, ensures the energization safety of cable, and cable core and water, the isolation of the media such as air is allowed to avoid There is leaky.
With scientific and technological progress, living-pattern preservation and progress, the rail traffics such as subway are also with rapid changepl. never-ending changes and improvements replace Change, the use of cable is also very universal in the construction of the infrastructure of the rail traffics such as subway and operational process, due to subway Etc. ground track setting build the wear-resisting property and ageing-resistant performance of cable can be required it is relatively high, it is desirable that the outer jacket of cable has Have good wearability energy and ageing-resistant performance.
Invention content
The present invention provides track cable jackets of a kind of high-wear resistance and preparation method thereof, to solve above-mentioned technology Problem.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:
A kind of track cable jacket of high-wear resistance, is made of by weight following raw material:High density polyethylene (HDPE) 50 ~70 parts, 30~40 parts of thermoplastic polyurethane, 15~25 parts of one acetate ethylene copolymer of ethylene, 20~30 parts of ethylene-propylene diene copolymer, 10~15 parts of calcium stearate, 5~10 parts of glass fibre, 8~12 parts of graphite, 5~8 parts of alumina silicate, 3~5 parts of magnesia, oxidation 8~10 parts of tin, 3~5 parts of plasticizer, 4~6 parts of silane coupling agent, 2~5 parts of lubricant, 4~6 parts of stabilizer, antioxidant 1~ 3 parts.
Preferably, the track cable jacket of a kind of high-wear resistance, is made of by weight following raw material:High density is poly- 50 parts of ethylene, 30 parts of thermoplastic polyurethane, 15 parts of one acetate ethylene copolymer of ethylene, 20 parts of ethylene-propylene diene copolymer, calcium stearate 10 Part, 5 parts of glass fibre, 8 parts of graphite, 5 parts of alumina silicate, 3 parts of magnesia, 8 parts of tin oxide, 3 parts of plasticizer, 4 parts of silane coupling agent, 2 parts of lubricant, 4 parts of stabilizer, 1 part of antioxidant.
Preferably, the track cable jacket of a kind of high-wear resistance, is made of by weight following raw material:High density is poly- 60 parts of ethylene, 35 parts of thermoplastic polyurethane, 20 parts of one acetate ethylene copolymer of ethylene, 25 parts of ethylene-propylene diene copolymer, calcium stearate 12.5 parts, 7.5 parts of glass fibre, 10 parts of graphite, 6.5 parts of alumina silicate, 4 parts of magnesia, 9 parts of tin oxide, 4 parts of plasticizer, silane 5 parts of coupling agent, 3.5 parts of lubricant, 5 parts of stabilizer, 2 parts of antioxidant.
Preferably, the track cable jacket of a kind of high-wear resistance, is made of by weight following raw material:High density is poly- 70 parts of ethylene, 40 parts of thermoplastic polyurethane, 25 parts of one acetate ethylene copolymer of ethylene, 30 parts of ethylene-propylene diene copolymer, calcium stearate 15 Part, 10 parts of glass fibre, 12 parts of graphite, 8 parts of alumina silicate, 5 parts of magnesia, 10 parts of tin oxide, 5 parts of plasticizer, silane coupling agent 6 Part, 5 parts of lubricant, 6 parts of stabilizer, 3 parts of antioxidant.
Preferably, the lubricant is microcrystalline wax.
Preferably, the plasticizer phthalic acid two (2- ethyl hexyls) ester.
Preferably, the antioxidant chooses hindered phenol antioxidant.
A kind of preparation method of the track cable jacket of high-wear resistance, which is characterized in that include the following steps:
(1) each component in above-mentioned raw materials is taken by weight, and is uniformly mixed;
(2) raw material of gained in step (1) is handled by kneader kneading;
(3) the raw material input double screw extruder of gained in step (2) is subjected to extruding pelletization;
(4) by the granulation of gained in step (3) through air-cooled, screening magnetic separation, metering, packaging to get required high-wearing feature The track cable jacket of energy.
Beneficial effects of the present invention:
The present invention improves the wearability and intensity of sheath material, reduces the ageing time of sheath material, can keep high Warm high pressure effect is lower non-degradable for a long time.
Specific implementation mode
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover Multitude of different ways is implemented.
Embodiment 1
A kind of track cable jacket of high-wear resistance, is made of by weight following raw material:
50 parts of high density polyethylene (HDPE), 30 parts of thermoplastic polyurethane, 15 parts of one acetate ethylene copolymer of ethylene, ethylene-propylene diene copolymer 20 parts, 10 parts of calcium stearate, 5 parts of glass fibre, 8 parts of graphite, 5 parts of alumina silicate, 3 parts of magnesia, 8 parts of tin oxide, plasticizer 3 Part, 4 parts of silane coupling agent, 2 parts of lubricant, 4 parts of stabilizer, 1 part of antioxidant.
Above-mentioned lubricant is microcrystalline wax.
Above-mentioned plasticizer phthalic acid two (2- ethyl hexyls) ester.
Above-mentioned antioxidant chooses hindered phenol antioxidant.
A kind of preparation method of the track cable jacket of high-wear resistance, includes the following steps:
(1) each component in above-mentioned raw materials is taken by weight, and is uniformly mixed;
(2) raw material of gained in step (1) is handled by kneader kneading;
(3) the raw material input double screw extruder of gained in step (2) is subjected to extruding pelletization;
(4) by the granulation of gained in step (3) through air-cooled, screening magnetic separation, metering, packaging to get required high-wearing feature The track cable jacket of energy.
Following embodiment is differed only in embodiment 1:
Embodiment 2
A kind of track cable jacket of high-wear resistance, is made of by weight following raw material:
60 parts of high density polyethylene (HDPE), 35 parts of thermoplastic polyurethane, 20 parts of one acetate ethylene copolymer of ethylene, ethylene-propylene diene copolymer 25 parts, 12.5 parts of calcium stearate, 7.5 parts of glass fibre, 10 parts of graphite, 6.5 parts of alumina silicate, 4 parts of magnesia, 9 parts of tin oxide, 4 parts of plasticizer, 5 parts of silane coupling agent, 3.5 parts of lubricant, 5 parts of stabilizer, 2 parts of antioxidant.
Embodiment 3
A kind of track cable jacket of high-wear resistance, is made of by weight following raw material:
70 parts of high density polyethylene (HDPE), 40 parts of thermoplastic polyurethane, 25 parts of one acetate ethylene copolymer of ethylene, ethylene-propylene diene copolymer 30 parts, 15 parts of calcium stearate, 10 parts of glass fibre, 12 parts of graphite, 8 parts of alumina silicate, 5 parts of magnesia, 10 parts of tin oxide, plasticising 5 parts of agent, 6 parts of silane coupling agent, 5 parts of lubricant, 6 parts of stabilizer, 3 parts of antioxidant.
The embodiments of the present invention described above are not intended to limit the scope of the present invention, any in the present invention Spirit and principle within made by modifications, equivalent substitutions and improvements etc., should be included in the claim protection model of the present invention Within enclosing.

Claims (8)

1. a kind of track cable jacket of high-wear resistance, which is characterized in that be made of by weight following raw material:High density 50~70 parts of polyethylene, 30~40 parts of thermoplastic polyurethane, 15~25 parts of one acetate ethylene copolymer of ethylene, ethylene-propylene diene copolymer 20 ~30 parts, 10~15 parts of calcium stearate, 5~10 parts of glass fibre, 8~12 parts of graphite, 5~8 parts of alumina silicate, magnesia 3~5 Part, 8~10 parts of tin oxide, 3~5 parts of plasticizer, 4~6 parts of silane coupling agent, 2~5 parts of lubricant, 4~6 parts of stabilizer, antioxygen 1~3 part of agent.
2. the track cable jacket of high-wear resistance according to claim 1, which is characterized in that by following raw material by weight Measure part composition:50 parts of high density polyethylene (HDPE), 30 parts of thermoplastic polyurethane, 15 parts of one acetate ethylene copolymer of ethylene, EPDM 20 parts of glue, 10 parts of calcium stearate, 5 parts of glass fibre, 8 parts of graphite, 5 parts of alumina silicate, 3 parts of magnesia, 8 parts of tin oxide, plasticizer 3 Part, 4 parts of silane coupling agent, 2 parts of lubricant, 4 parts of stabilizer, 1 part of antioxidant.
3. the track cable jacket of high-wear resistance according to claim 1, which is characterized in that by following raw material by weight Measure part composition:60 parts of high density polyethylene (HDPE), 35 parts of thermoplastic polyurethane, 20 parts of one acetate ethylene copolymer of ethylene, EPDM 25 parts of glue, 12.5 parts of calcium stearate, 7.5 parts of glass fibre, 10 parts of graphite, 6.5 parts of alumina silicate, 4 parts of magnesia, 9 parts of tin oxide, 4 parts of plasticizer, 5 parts of silane coupling agent, 3.5 parts of lubricant, 5 parts of stabilizer, 2 parts of antioxidant.
4. the track cable jacket of high-wear resistance according to claim 1, which is characterized in that by following raw material by weight Measure part composition:70 parts of high density polyethylene (HDPE), 40 parts of thermoplastic polyurethane, 25 parts of one acetate ethylene copolymer of ethylene, EPDM 30 parts of glue, 15 parts of calcium stearate, 10 parts of glass fibre, 12 parts of graphite, 8 parts of alumina silicate, 5 parts of magnesia, 10 parts of tin oxide, plasticising 5 parts of agent, 6 parts of silane coupling agent, 5 parts of lubricant, 6 parts of stabilizer, 3 parts of antioxidant.
5. the track cable jacket of high-wear resistance according to claim 1, which is characterized in that the lubricant is micro- Spar wax.
6. the track cable jacket of high-wear resistance according to claim 1, which is characterized in that the plasticizer is neighbour Phthalic acid two (2- ethyl hexyls) ester.
7. the track cable jacket of high-wear resistance according to claim 1, which is characterized in that the antioxidant choosing Take hindered phenol antioxidant.
8. the preparation method of the track cable jacket of the high-wear resistance as described in claim 1-4 any one, feature It is, includes the following steps:
(1) each component in above-mentioned raw materials is taken by weight, and is uniformly mixed;
(2) raw material of gained in step (1) is handled by kneader kneading;
(3) the raw material input double screw extruder of gained in step (2) is subjected to extruding pelletization;
(4) by the granulation of gained in step (3) through air-cooled, screening magnetic separation, metering, packaging to get required high-wear resistance Track cable jacket.
CN201810645126.2A 2018-06-21 2018-06-21 A kind of track cable jacket of high-wear resistance and preparation method thereof Withdrawn CN108727672A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810645126.2A CN108727672A (en) 2018-06-21 2018-06-21 A kind of track cable jacket of high-wear resistance and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810645126.2A CN108727672A (en) 2018-06-21 2018-06-21 A kind of track cable jacket of high-wear resistance and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128732A (en) * 2019-06-05 2019-08-16 中广核拓普(四川)新材料有限公司 A kind of wear-resisting toughened polyethylene protective cover material and preparation method thereof
CN110157107A (en) * 2019-06-24 2019-08-23 安徽华泰电缆有限公司 A kind of potent wear-resistant cable sheath material and preparation method thereof
CN110395032A (en) * 2019-07-20 2019-11-01 杨敏 A kind of lithium ion battery flexible package innermost layer polypropylene screen
CN111028988A (en) * 2019-11-18 2020-04-17 太仓市林源电线电缆有限公司 Electrical copper wire with ultra-strong tensile force and processing technology thereof
CN114573977A (en) * 2022-03-14 2022-06-03 乐庭电线工业(惠州)有限公司 High-temperature irradiation resistant crosslinked TPU (thermoplastic polyurethane) sheath material, preparation method thereof and cable

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104893087A (en) * 2015-05-29 2015-09-09 合肥得润电子器件有限公司 Halogen-free flame-retardant insulating material for durable household appliances and preparation method thereof
CN107286451A (en) * 2017-06-22 2017-10-24 芜湖航天特种电缆厂股份有限公司 Low orbit cable jacket of high-wear resistance and preparation method thereof
CN107556600A (en) * 2017-09-13 2018-01-09 安徽美腾特种电缆材料有限公司 Natural-crosslinked aerial insulating material of polyethylene of one-step method silanes and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104893087A (en) * 2015-05-29 2015-09-09 合肥得润电子器件有限公司 Halogen-free flame-retardant insulating material for durable household appliances and preparation method thereof
CN107286451A (en) * 2017-06-22 2017-10-24 芜湖航天特种电缆厂股份有限公司 Low orbit cable jacket of high-wear resistance and preparation method thereof
CN107556600A (en) * 2017-09-13 2018-01-09 安徽美腾特种电缆材料有限公司 Natural-crosslinked aerial insulating material of polyethylene of one-step method silanes and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128732A (en) * 2019-06-05 2019-08-16 中广核拓普(四川)新材料有限公司 A kind of wear-resisting toughened polyethylene protective cover material and preparation method thereof
CN110157107A (en) * 2019-06-24 2019-08-23 安徽华泰电缆有限公司 A kind of potent wear-resistant cable sheath material and preparation method thereof
CN110395032A (en) * 2019-07-20 2019-11-01 杨敏 A kind of lithium ion battery flexible package innermost layer polypropylene screen
CN111028988A (en) * 2019-11-18 2020-04-17 太仓市林源电线电缆有限公司 Electrical copper wire with ultra-strong tensile force and processing technology thereof
CN114573977A (en) * 2022-03-14 2022-06-03 乐庭电线工业(惠州)有限公司 High-temperature irradiation resistant crosslinked TPU (thermoplastic polyurethane) sheath material, preparation method thereof and cable
CN114573977B (en) * 2022-03-14 2024-02-09 乐庭电线工业(惠州)有限公司 High-temperature-radiation-resistant crosslinked TPU sheath material, preparation method thereof and cable

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Application publication date: 20181102

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