CN108724850A - A kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device - Google Patents

A kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device Download PDF

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Publication number
CN108724850A
CN108724850A CN201710253676.5A CN201710253676A CN108724850A CN 108724850 A CN108724850 A CN 108724850A CN 201710253676 A CN201710253676 A CN 201710253676A CN 108724850 A CN108724850 A CN 108724850A
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China
Prior art keywords
nanometer
thermal insulation
insulating
weight
nanometer micropore
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CN201710253676.5A
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Chinese (zh)
Inventor
向文艺
冯其庚
文海龙
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Weah Thermal Technology (shanghai) Co Ltd
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Weah Thermal Technology (shanghai) Co Ltd
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Priority to CN201710253676.5A priority Critical patent/CN108724850A/en
Publication of CN108724850A publication Critical patent/CN108724850A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/14Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/02Layer formed of wires, e.g. mesh
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00Compositions for artificial stone, not containing binders
    • C04B30/02Compositions for artificial stone, not containing binders containing fibrous materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/103Metal fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/302Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Insulation (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation devices comprising heat source, the nanometer micropore insulating being wrapped in successively outside heat source, environment-protection fiber insulating layer and enhancement layer, the outside of the enhancement layer are additionally provided with shell;The nanometer micropore insulating includes nanometer micropore thermal insulation board and the steel screen layer and aluminium foil scrim cloth that are covered in nanometer micropore thermal insulation board both sides successively;It the nanometer micropore thermal insulation board and is made of nano silicon dioxide, nanometer silicon carbide, high silica chopped strand and water;The environment-protection fiber insulating layer is made of silica, calcium oxide, magnesia and inorganic bonding agent.The present invention effectively reduces heat transfer, thermal convection current, heat radiation, has the characteristics that effectively insulating, energy saving, substantially reduces the volume and weight of equipment, and do not damage health, free from environmental pollution, and intensity is high, service life is long.

Description

A kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device
Technical field
The present invention relates to thermal insulation technology field more particularly to a kind of good heat-insulation effect, it is environment friendly and pollution-free, small, The nanometer micropore heat-insulating environment-protection composite thermal insulation device light-weight, intensity is high.
Background technology
The heat-insulated mode of tradition includes the various ways such as foam heat-insulating board, heat-preservation cotton and insulation fibre, but these methods are all More or less there is certain defect, is unable to meet production demand.The field high especially for insulation requirement, space is smaller It closes, traditional heat-insulated mode usually cannot be satisfied demand.
Currently, the defect of the heat-insulated mode of tradition is as follows:
A, equipment volume is big, and occupied ground is more, and increases the weight of integral device;
B, heatproof is low, and energy-saving effect is poor;
C, material therefor is not environmentally friendly enough, has injury to human body and environment;
D, the intensity of entire thermal insulation layer is insufficient, leads to its practical short life.
With the development of technology, there is new and effective super insulating material, refer to that thermal coefficient is extremely low, adiabatic effect The fabulous heat-insulating material of fruit, there are two types of types for it:Vacuum insulation product and nanometer micropore insulating product.In recent years due to nanometer skill The rapid development of art, nanometer micropore heat-insulating material are also more and more paid attention to, and the research dynamics of every country input is also got over Come bigger.
Invention content
In order to solve the problems in the prior art, the object of the present invention is to provide a kind of combinations of nanometer micropore heat-insulating environment-protection to protect Warm device effectively reduces heat transfer, thermal convection current, heat radiation, has the characteristics that effectively insulating, energy-efficient, to significantly The volume and weight of equipment is reduced, and does not damage health, it is free from environmental pollution.
To achieve the goals above, the technical solution adopted by the present invention is:
The present invention provides a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation devices comprising heat source is wrapped in outside heat source successively Nanometer micropore insulating, environment-protection fiber insulating layer and the enhancement layer in portion, the outside of the enhancement layer is additionally provided with shell;It is described Nanometer micropore insulating includes nanometer micropore thermal insulation board and is covered in the steel wire of nanometer micropore thermal insulation board both sides successively Stratum reticulare and aluminium foil scrim cloth;The nanometer micropore thermal insulation board and by nano silicon dioxide, nanometer silicon carbide, high silica be chopped fibre Peacekeeping water is made;The environment-protection fiber insulating layer is made of silica, calcium oxide, magnesia and inorganic bonding agent.
The parts by weight of preferred scheme, each component and each component that the nanometer micropore heat insulating board is included are:It receives Rice 60~70 parts by weight of silica, 20~30 parts by weight of nanometer silicon carbide, high 3~7 parts by weight of silica chopped strand, surplus are Water.
The parts by weight of further preferred scheme, each component and each component that the environment-protection fiber insulating layer is included are: 54~62 parts by weight of silica, 24~29 parts by weight of calcium oxide, 3~6 parts by weight of magnesia, surplus is inorganic bonding agent.
Scheme still more preferably, the weight for each component and each component that the nanometer micropore heat insulating board is included Part it is preferably:68 parts by weight of nano silicon dioxide, 25 parts by weight of nanometer silicon carbide, high 5 parts by weight of silica chopped strand, surplus are Water.
The particle size range of scheme still further preferably, the nano silicon dioxide is 6~18nm.
The particle size range of the nanometer silicon carbide is 3~10um.
The diameter range of the high silica chopped strand is 6~18um.
The enhancement layer is aluminium foil fiber cloth reinforced layer.
The average diameter of micropore is less than 50 nanometers on the nanometer micropore thermal insulation board.
In the present invention, the production method of the nanometer micropore insulating is:By nano silicon dioxide, nano silicon carbide Silicon, high silica chopped strand and water weigh up by weight, and each raw material weighed up are uniformly mixed, the raw material that then will be mixed Through production line extrusion forming, steel wire and patch aluminium foil fiber cloth are then sticked successively on its surface.
By using above technical scheme, a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device of the present invention and the prior art It compares, advantage is:
1, the present invention is effectively reduced using nanometer micropore thermal insulation layer and environment-protection fiber thermal insulation layer has been set gradually in the outside of heat source Heat transfer, thermal convection current, heat radiation, thermal coefficient(At 800 degree, thermal coefficient is about:0.035W/m.K)It substantially reduces, Product has the characteristics that effectively insulating, energy-efficient.
2, the granular superfine of the nano silicon dioxide and nanometer silicon carbide in the present invention is formed flat after tightly compacted Equal diameter is less than 50 nanometers of subtle emptying aperture, not only extends the path that heat conducts in solids, while the upper limit to a certain degree The convection current and radiation for having made heat, reduce heat loss, enhance heat insulation.
3, the present invention is due to having preferable heat insulation so that and the thickness of the thermal insulation layer of product can reduce 5 times or more, To make equipment volume be substantially reduced, weight mitigates significantly.
4, the environment-protection fiber layer formula in the present invention is unique, can enter natural environment, can be degraded, it is strong not damage human body Health, it is free from environmental pollution.
5, the both sides of nanometer micropore thermal insulation board are all covered with steel wire and aluminium foil fiber cloth, environment-protection fiber heat preservation in the present invention Layer is external to be equipped with enhancement layer, and contains high silica chopped strand in nanometer micropore thermal insulation layer, and the combination of these structures is greatly improved The intensity of thermal insulation layer.
Description of the drawings
Fig. 1 is a kind of overall structure diagram of nanometer micropore heat-insulating environment-protection composite thermal insulation device of the present invention;
Fig. 2 is a kind of structural representation of the nanometer micropore insulating of nanometer micropore heat-insulating environment-protection composite thermal insulation device of the present invention Figure.
Specific implementation mode
In order to make the objectives, technical solutions and advantages of the present invention clearer, with reference to specific example, to the present invention It is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the present invention.In addition, In illustrating below, descriptions of well-known structures and technologies are omitted, so as not to unnecessarily obscure the concept of the present invention.
A kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device of the present invention, as depicted in figs. 1 and 2 comprising heat source 1, according to The secondary nanometer micropore insulating 2 being wrapped in outside heat source 1, environment-protection fiber insulating layer 3 and enhancement layer 4, the enhancement layer 4 Outside is additionally provided with shell 5;The nanometer micropore insulating 2 is including nanometer micropore thermal insulation board 21 and is covered in described receive successively The steel screen layer 22 and aluminium foil scrim cloth 23 of 21 both sides of meter Wei Kong thermal insulation boards;The nanometer micropore thermal insulation board 21 and by nanometer two Silica, nanometer silicon carbide, high silica chopped strand and water are made;The environment-protection fiber insulating layer 3 is by silica, oxidation Calcium, magnesia and inorganic bonding agent are made.
The parts by weight for each component and each component that the nanometer micropore thermal insulation board 21 is included are:Nano silicon dioxide 60~ 70 parts by weight, 20~30 parts by weight of nanometer silicon carbide, high 3~7 parts by weight of silica chopped strand, surplus is water, wherein preferably 68 parts by weight of nano silicon dioxide, 25 parts by weight of nanometer silicon carbide, high 5 parts by weight of silica chopped strand;The nanometer titanium dioxide The particle size range of silicon is 6~18nm, and the particle size range of the nanometer silicon carbide is 3~10um, the high silica chopped strand Diameter range is 6~18um.The parts by weight for each component and each component that the environment-protection fiber insulating layer 3 is included are:Titanium dioxide 54~62 parts by weight of silicon, 24~29 parts by weight of calcium oxide, 3~6 parts by weight of magnesia, surplus is inorganic bonding agent.
The granular superfine of nano silicon dioxide and nanometer silicon carbide in inventive formulation is formed after tightly compacted Average diameter is less than 50 nanometers of subtle emptying aperture, not only extends the path that heat conducts in solids, while to a certain extent The convection current and radiation for limiting heat, reduce heat loss, enhance heat insulation.And contain high silica chopped strand, it can carry High raw material intensity, convenient for vacuumizing packaging in next step.
Environmentally friendly fibrous material uses and traditional heat insulation fiber in the present invention(Such as ceramic fibre, glass fibre, mineral wool)It is complete Complete different chemical formulation has biodegradability into human body and natural environment.
The above specific embodiments are only exemplary, is to preferably make skilled artisans appreciate that originally Patent, be not to be construed as include to this patent range limitation;As long as appointing according to made by spirit disclosed in this patent How with change or modification, the range that this patent includes is each fallen within.

Claims (9)

1. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device, which is characterized in that it includes heat source, is wrapped in outside heat source successively Nanometer micropore insulating, environment-protection fiber insulating layer and the enhancement layer in portion, the outside of the enhancement layer is additionally provided with shell;It is described Nanometer micropore insulating includes nanometer micropore thermal insulation board and is covered in the steel wire of nanometer micropore thermal insulation board both sides successively Stratum reticulare and aluminium foil scrim cloth;The nanometer micropore thermal insulation board and by nano silicon dioxide, nanometer silicon carbide, high silica be chopped fibre Peacekeeping water is made;The environment-protection fiber insulating layer is made of silica, calcium oxide, magnesia and inorganic bonding agent.
2. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 1, which is characterized in that the nanometer The parts by weight of each component and each component that micropore heat insulating board is included are:60~70 parts by weight of nano silicon dioxide, nanometer 20~30 parts by weight of silicon carbide, high 3~7 parts by weight of silica chopped strand, surplus is water.
3. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 2, which is characterized in that the environmental protection The parts by weight of each component and each component that fiber insulation layer is included are:54~62 parts by weight of silica, calcium oxide 24~29 Parts by weight, 3~6 parts by weight of magnesia, surplus is inorganic bonding agent.
4. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 2, which is characterized in that the nanometer The parts by weight of each component and each component that micropore heat insulating board is included are preferably:68 parts by weight of nano silicon dioxide, nanometer 25 parts by weight of silicon carbide, high 5 parts by weight of silica chopped strand, surplus is water.
5. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 3 or claim 4, feature exist In the particle size range of the nano silicon dioxide is 6~18nm.
6. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 5, which is characterized in that the nanometer The particle size range of silicon carbide is 3~10um.
7. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 6, which is characterized in that the high silicon The diameter range of oxygen chopped strand is 6~18um.
8. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 1, which is characterized in that described adds Strong layer is aluminium foil fiber cloth reinforced layer.
9. a kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device according to claim 1, which is characterized in that the nanometer The average diameter of micropore is less than 50 nanometers on micropore thermal insulation board.
CN201710253676.5A 2017-04-18 2017-04-18 A kind of nanometer micropore heat-insulating environment-protection composite thermal insulation device Pending CN108724850A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112339358A (en) * 2019-08-07 2021-02-09 恩若杰纳米技术(上海)有限公司 High-temperature-resistant nano micropore heat insulation material and preparation method thereof

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CN102964088A (en) * 2012-11-23 2013-03-13 山东鲁阳股份有限公司 Ultralow heat conductivity nano aerogel thermal insulation material and preparation method thereof
CN203348829U (en) * 2013-06-13 2013-12-18 江阴超越新材料有限公司 Composite reflective insulation board coiled material
CN203463871U (en) * 2013-08-09 2014-03-05 江阴超越新材料有限公司 Insulating pinch plate used for industrial device
CN103807568A (en) * 2013-12-20 2014-05-21 潍坊纳博欧化工科技有限公司 Nanometer micropore heat insulation board and manufacturing method thereof
CN104369480A (en) * 2013-08-14 2015-02-25 天津嘉源新型建材有限公司 Multilayer reflective heat-insulation composite plate
CN104476857A (en) * 2014-12-15 2015-04-01 山东鲁阳股份有限公司 Nano silicon thermal insulation material and preparation method thereof
CN205444807U (en) * 2016-03-10 2016-08-10 湖北格丽特建材有限公司 Sponge ground of installing resilient floor fast pastes and fills up

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102964088A (en) * 2012-11-23 2013-03-13 山东鲁阳股份有限公司 Ultralow heat conductivity nano aerogel thermal insulation material and preparation method thereof
CN203348829U (en) * 2013-06-13 2013-12-18 江阴超越新材料有限公司 Composite reflective insulation board coiled material
CN203463871U (en) * 2013-08-09 2014-03-05 江阴超越新材料有限公司 Insulating pinch plate used for industrial device
CN104369480A (en) * 2013-08-14 2015-02-25 天津嘉源新型建材有限公司 Multilayer reflective heat-insulation composite plate
CN103807568A (en) * 2013-12-20 2014-05-21 潍坊纳博欧化工科技有限公司 Nanometer micropore heat insulation board and manufacturing method thereof
CN104476857A (en) * 2014-12-15 2015-04-01 山东鲁阳股份有限公司 Nano silicon thermal insulation material and preparation method thereof
CN205444807U (en) * 2016-03-10 2016-08-10 湖北格丽特建材有限公司 Sponge ground of installing resilient floor fast pastes and fills up

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112339358A (en) * 2019-08-07 2021-02-09 恩若杰纳米技术(上海)有限公司 High-temperature-resistant nano micropore heat insulation material and preparation method thereof

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Application publication date: 20181102