CN108719742A - A kind of food preservative freshness retaining agent - Google Patents

A kind of food preservative freshness retaining agent Download PDF

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Publication number
CN108719742A
CN108719742A CN201710285989.9A CN201710285989A CN108719742A CN 108719742 A CN108719742 A CN 108719742A CN 201710285989 A CN201710285989 A CN 201710285989A CN 108719742 A CN108719742 A CN 108719742A
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CN
China
Prior art keywords
food
retaining agent
freshness retaining
sodium selenite
food preservative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710285989.9A
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Chinese (zh)
Inventor
秦才东
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710285989.9A priority Critical patent/CN108719742A/en
Priority to EP18787606.5A priority patent/EP3613417A4/en
Priority to CN201880026533.3A priority patent/CN110545805A/en
Priority to AU2018253749A priority patent/AU2018253749A1/en
Priority to SG11201909854U priority patent/SG11201909854UA/en
Priority to JP2019558658A priority patent/JP2020517726A/en
Priority to CA3060606A priority patent/CA3060606A1/en
Priority to US16/607,353 priority patent/US20200121716A1/en
Priority to PCT/CN2018/083952 priority patent/WO2018192573A1/en
Priority to KR1020197034390A priority patent/KR20190137909A/en
Publication of CN108719742A publication Critical patent/CN108719742A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/14Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
    • A23B4/18Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
    • A23B4/24Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/157Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/358Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

The food preservative freshness retaining agent of the present invention, it is that micro sodium selenite or selenite are added in food, purpose be to provide a kind of low cost, efficiently and can be beneficial to human body food preservative freshness retaining agent, achieve the purpose that substitute harmful or of high cost existing food preservative freshness retaining agent.Selenium element is the necessary trace element of human body, using sodium selenite, not only necessary trace element can be supplemented to human body, but also can achieve the purpose that food antiseptic is fresh-keeping, avoid that harmless preservative is of high cost, inexpensive preservative often harmful problem.

Description

A kind of food preservative freshness retaining agent
Technical field
The present invention relates to a kind of food preservative freshness retaining agents.
Background technology
It is well known that the selenium (sodium selenite etc.) of reproducibility has preventive and therapeutic action to tumour, but its mechanism is always Without explicitly analysis and explanation.It is by glycolytic cycle in view of tumour cell obtains energy, and normal cell is then logical Aerobic oxidation is crossed, and in view of the reproducibility of selenium, from redox reaction angle analysis, it should it is concluded that and obtaining It is widely applied effect.
It is pyruvic acid, the process of ATP and NADH+H+ that glycolysis, which refers to by glucose or decomposition of glycogen,.Under anoxic conditions Pyruvic acid can then receive the hydrogen that triose phosphate is taken off, be reduced to lactic acid under the catalysis of lactic dehydrogenase.And under aerobic conditions Sugar oxygenolysis, referred to as sugared aerobic oxidation, pyruvic acid further oxygenolysis can generate acetyl-CoA and enter tricarboxylic acids and follow Ring generates CO2 and H2O.Many steps of the aerobic oxidation and glycolysis of sugar in the incipient stage are duplicate, are only decomposed After pyruvic acid, due to the different just disagreement of oxygen supply condition.
Glycolysis includes in total 10 consecutive steps, by corresponding enzymatic.Overall reaction is:
2 pyruvic acid+4ATP+2NADH+2H+ of glucose+2ATP+2ADP+2Pi+2NAD+ --- >
Reversible-> lactic acid (the CH3CHOHCOOH)+NAD+ of pyruvic acid (CH3COCOOH)+NADH+H+-
Specifically, two important redox reactions involved during tumour cell glycometabolism to lactic acid are:
(1) glyceraldehyde 3-phosphate+phosphoric acid+NAD+ → 1,3- diphosphoglyceric acids+NADH+H+
And
(2) pyruvic acid+NADH+H+ → lactic acid+NAD+
Wherein, NAD+ and NADH can be recycled and be generated as catalyst, ensure that the sustainability of metabolism.
In the presence of sodium selenite, the available following chemical formula of reproducibility reaction of sodium selenite indicates:
Na2SeO3 (strong reducing property)+H2O--- > Na2SeO4 (stable compound)+2H (atom state hydrogen)
For reaction (1), sodium selenite is as reducing agent (antioxidant), with the same substrate 3- phosphoric acid as reducing agent Glyceraldehyde competes, and following redox reaction may occur respectively:
A, sodium selenite+H2O+NAD+ → NADH+H++ sodium selenates
B, glyceraldehyde 3-phosphate+phosphoric acid+NAD+ → 1,3- diphosphoglyceric acids+NADH+H+
Chemically free energy of reaction variation judges that reaction (b) should be much larger than reaction from aldehyde to the driving energy of the reaction of acid (a), therefore, reaction (1) is smaller by being influenced existing for sodium selenite, avoid or reduces sodium selenite to normal cell metabolism Interference effect;Or sodium selenite is competed as reducing agent and the same substrate glyceraldehyde 3-phosphate as reducing agent, is urged in enzyme In the specific reaction of change, sodium selenite is not engaged in the advantage of reaction.
For reaction (2), sodium selenite as reducing agent directly be equally that the NADH coenzyme of reducing agent competes, without It is to be competed with substrate pyruvate.If pyruvic acid receives the hydrogen provided from sodium selenite reduction reaction, then NADH can not be converted into NAD+ or pyruvic acid still can receive the hydrogen from NADH, and NADH is made to be converted into NAD+, but NAD+ can immediately with sub- selenium The atom state hydrogen that sour sodium reduction reaction provides, which combines, forms NADH, it is therefore intended that because being unable to get reaction (1) in glycolysis chain Required NAD+ and the failure for leading to tumour cell glycometabolism are played and inhibit growth of tumour cell, promote apoptosis of tumor cells Effect.
In view of causing the common microbiological of food spoilage to be the mushrooms such as bacterium, saccharomycete and mould, and the energy of mushroom Metabolism is also via sugared aerobic oxidation or glycolytic cycle.The corruption of the anti-corrosive fresh-keeping of food in sealed states, food is main It is growth and breeding process of the microorganisms such as anaerobic fermentation process, that is, mushroom under anaerobic condition.Third involved by the process Ketone acid is consistent to the metabolic process of lactic acid and the metabolic process of tumour cell, and therefore, sodium selenite makees the inhibition of tumour cell With can equally inhibit the growth and breeding of the microorganisms such as putrefactivebacteria in food, to gram have the function that food is anti-corruption fresh-keeping And purpose.
Invention content
The present invention food preservative freshness retaining agent purpose be to provide it is a kind of low cost, efficiently and can be beneficial to human body food Antisepsis antistaling agent achievees the purpose that substitute harmful or of high cost existing food preservative freshness retaining agent.Selenium element is human body Must trace element can not only human body have been given to supplement necessary trace element, but also food antiseptic can be reached using sodium selenite Fresh-keeping purpose, avoids that harmless preservative is of high cost, inexpensive preservative often harmful problem.
The food preservative freshness retaining agent of the present invention, is to add micro sodium selenite or selenite in food, especially exists It is more effective in the case of isolation air.Because the corruption of food also has the corruption that oxidation effect of food itself is incurred, it is based on The inoxidizability of sodium selenite or selenite, the aerial food of exposure is in the presence of sodium selenite, oxidation Corrupt speed can also lower, to achieve the purpose that extend the food shelf-life.Likewise, the food preservative freshness retaining agent of the present invention is suitable It closes applied in the marinated of food, sauced, molding, canned, packed, bottled production.
Specific implementation mode
Embodiment 1
In order to verify effect of the sodium selenite to food antiseptic, it will be symmetrically cut into two panels with a piece of leaf lettuce, size is big Small is 2x2 centimetres, is respectively put into the beaker for the tap water for filling 80g, it is micro- that in terms of selenium 180 are additionally incorporated in one of beaker Gram sodium selenite, selenium concentration about 2.3ppm.Experiment finds that room temperature is about at 15 DEG C, in the solution containing sodium selenite In leaf lettuce until the 5th day, just there is the brown corruption spot of diameter about 1mm in surface, but does not add the lettuce in sodium selenite solution The strip brown plaque of a diameter about 6mm round spot and an about 1x4mm is formd on lettuce leaf.Thus sodium selenite is illustrated To the effect of food antiseptic, also inhibition of the indirect proof sodium selenite to microorganism and tumour cell pyruvic acid to lactic acid metabolism Effect.
During production application, the characteristics of according to different foods, seasonal characteristic can also be increased or decreased suitably The dosage of sodium selenite.Because the reproducibility of sodium selenite or other selenites (ammonium salt, sylvite etc.) is lacked for microorganism Inhibiting effect occurs for the metabolic process under oxygen condition, and therefore, the corrosion-resistanting fresh-keeping effect of selenite should mainly salt down in food It is effective when system, sauced, molding (such as the rice dumpling, various meatballs, Tofu etc.), canned, packed, bottled production, i.e., substantially every It is more effective in the case of exhausted air.
The above is only presently preferred embodiments of the present invention, any those of ordinary skill in the art, not It is detached from the range of the carried technical characteristic of the present invention, using disclosed technology contents makes part change or modifies Equivalent embodiment, and without departing from the technical feature content of the present invention, in the range of still falling within the technology of the present invention feature.

Claims (3)

1. a kind of food preservative freshness retaining agent, which is characterized in that add micro sodium selenite or selenite in food.
2. food preservative freshness retaining agent as described in claim 1, which is characterized in that the fresh-keeping food antiseptic is empty in isolation It is carried out in the case of gas.
3. food preservative freshness retaining agent as described in claim 1, which is characterized in that the food antiseptic is fresh-keeping to be applied to food Marinated, sauced, molding, canned, packed, bottled production.
CN201710285989.9A 2017-04-22 2017-04-22 A kind of food preservative freshness retaining agent Pending CN108719742A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
CN201710285989.9A CN108719742A (en) 2017-04-22 2017-04-22 A kind of food preservative freshness retaining agent
EP18787606.5A EP3613417A4 (en) 2017-04-22 2018-04-20 Method for inhibiting cellular glycolysis process and application thereof
CN201880026533.3A CN110545805A (en) 2017-04-22 2018-04-20 Method for inhibiting cell glycolysis process and application
AU2018253749A AU2018253749A1 (en) 2017-04-22 2018-04-20 Method for inhibiting cellular glycolysis process and application thereof
SG11201909854U SG11201909854UA (en) 2017-04-22 2018-04-20 Method for Inhibiting Both Glycolysis and Glutamine Metabolism in Cells and Use Thereof
JP2019558658A JP2020517726A (en) 2017-04-22 2018-04-20 Method for inhibiting cell glycolysis and use thereof
CA3060606A CA3060606A1 (en) 2017-04-22 2018-04-20 Method for inhibiting glycolysis in cells and use thereof
US16/607,353 US20200121716A1 (en) 2017-04-22 2018-04-20 Method for Inhibiting Both Glycolysis and Glutamine Metabolism in Cells and Use Thereof
PCT/CN2018/083952 WO2018192573A1 (en) 2017-04-22 2018-04-20 Method for inhibiting cellular glycolysis process and application thereof
KR1020197034390A KR20190137909A (en) 2017-04-22 2018-04-20 Method and application of simultaneous inhibition of cell glycolysis and glutamine metabolism

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710285989.9A CN108719742A (en) 2017-04-22 2017-04-22 A kind of food preservative freshness retaining agent

Publications (1)

Publication Number Publication Date
CN108719742A true CN108719742A (en) 2018-11-02

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CN201710285989.9A Pending CN108719742A (en) 2017-04-22 2017-04-22 A kind of food preservative freshness retaining agent

Country Status (1)

Country Link
CN (1) CN108719742A (en)

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Application publication date: 20181102