CN108715753A - Hollow glass fluid sealant - Google Patents
Hollow glass fluid sealant Download PDFInfo
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- CN108715753A CN108715753A CN201810689739.6A CN201810689739A CN108715753A CN 108715753 A CN108715753 A CN 108715753A CN 201810689739 A CN201810689739 A CN 201810689739A CN 108715753 A CN108715753 A CN 108715753A
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- Prior art keywords
- parts
- fluid sealant
- hollow glass
- high temperature
- temperature resistant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2003/1034—Materials or components characterised by specific properties
- C09K2003/1078—Fire-resistant, heat-resistant materials
Abstract
The present invention proposes a kind of hollow glass fluid sealant, according to the number of parts by weight, including following components：0.2~0.6 part of 50~60 parts of organic hydroxylic silicone, 10~14 parts of organic methyl silicone, 6~12 parts of methyl-monosilane, 25~35 parts of inorganic filler, 10~16 parts of high temperature resistant auxiliary material, 1~3 part of nano zircite, 1~3 part of amino silane, 1~2 part of dibutyltin dilaurate, 12~16 parts of rubber, 1~2 part of adhesive aid, 8~10 parts of plasticizer, 1~3 part of antiseptic and ultraviolet absorber；The high temperature resistant auxiliary material is mainly matrix by nano magnalium hydrotalcite, and graphene oxide is as auxiliary agent, and hot pressed sintering forms under the conditions of 250 DEG C~350 DEG C.The fluid sealant has good flame-resistant high-temperature-resistant performance, service life long.
Description
Technical field
The invention belongs to sealing material technical fields, and in particular to a kind of hollow glass fluid sealant.
Background technology
Hollow glass is a kind of good heat-insulated, sound insulation, novel building material that is beautiful and applicable and can reducing building dead weight
Material.It is to use two panels or three sheet glass, using high intensity high-air-tightness compound binding agent, by sheet glass and the aluminium for including drier
Alloy framework bonds, manufactured high-effect sound-and heat-insulated glass.Hollow glass multiple performance is superior to ordinary double-layer glass, therefore
The approval of countries in the world is obtained, hollow glass is by two panels or divided glass effectively to support evenly spaced and perimeter bond close
Envelope, makes glass interlayer be formed with the glassware in dry gas space.Its main material be glass, warm side spacer bar, bent angle bolt,
Butyl rubber, TR sealant, drier.
Hollow glass is being exactly common silicone adhesive using glass cement at present, and the fire-proof high-temperature resistant ability of silicone adhesive is not
Foot, is not effective to ensure that the heat-resisting ability of hollow glass, so needing a kind of hollow glass special glass fluid sealant to solve
The certainly above problem.
Invention content
The present invention proposes that a kind of hollow glass fluid sealant, the fluid sealant have good flame-resistant high-temperature-resistant performance, uses
Long lifespan.
The technical proposal of the invention is realized in this way：
A kind of hollow glass fluid sealant, according to the number of parts by weight, including following components：
50~60 parts of organic hydroxylic silicone, 10~14 parts of organic methyl silicone, 6~12 parts of methyl-monosilane, inorganic filler 25
~35 parts, 10~16 parts of high temperature resistant auxiliary material, 1~3 part of nano zircite, 1~3 part of amino silane, dibutyltin dilaurate 1
~2 parts, 12~16 parts of rubber, 1~2 part of adhesive aid, 8~10 parts of plasticizer, 1~3 part of antiseptic and ultraviolet absorber 0.2~
0.6 part；The high temperature resistant auxiliary material is mainly matrix by nano magnalium hydrotalcite, graphene oxide as auxiliary agent, 250 DEG C~
Hot pressed sintering forms under the conditions of 350 DEG C.
Preferably, the preparation method of the high temperature resistant auxiliary material includes the following steps：
(1) nano magnalium hydrotalcite is put into ethanol solution and is carried out, stirred simultaneously ultrasonic disperse, obtain dispersion liquid A；
(2) graphene oxide is weighed in proportion, ultrasonic disperse in the acrylic emulsion of n,N-Dimethylformamide is added, obtain
To dispersion liquid B；
(3) organic binders solvent is added after mixing dispersion liquid A with dispersion liquid B, grinding is sufficiently mixed, then at 250 DEG C
~350 DEG C of condition pressure sintering sintering, you can obtain high temperature resistant auxiliary material.
Preferably, the mass ratio of the graphene oxide and the nano magnalium hydrotalcite is 5~15:100.
Preferably, the rubber is the composition of nitrile rubber and silicon rubber.
Preferably, the adhesive aid is selected from one or more of starch, Arabic gum and sodium alginate.
Preferably, the plasticizer is selected from dioctyl phthalate, di-n-octyl phthalate, phthalic acid two
One or more of cyclohexyl and diisononyl phthalate.
Preferably, the antiseptic is the mixture of chitin, mustard and copper oxide.
The preparation method of the hollow glass fluid sealant of the present invention：
Said components are weighed according to proportioning, are mediated after being mixed after vacuum drying.
Beneficial effects of the present invention：
1, as basic sizing material, methyl-monosilane can be used as crosslinking agent, dibutyl tin for organic hydroxylic silicone, organic methyl silicone
Dilaurate is used to accelerate the curingprocess rate of glazing compound as catalyst, catalyst；Aerosil can improve glass
Tensile strength, tear resistance and the wearability of glass fluid sealant, and make fluid sealant that there is definitely temperature resistant capability.
2, the present invention uses mainly by nano magnalium hydrotalcite for matrix, graphene oxide as auxiliary agent, 250 DEG C~
High temperature resistant auxiliary material made of hot pressed sintering under the conditions of 350 DEG C, can in the case where not influencing sealing joint strip tack and density,
The high temperature resistance for improving fluid sealant coordinates with components such as nano zircites, and high temperature resistance reaches 400~500 DEG C.In addition,
The flame retardant property of fluid sealant can be improved simultaneously.
Specific implementation mode
Embodiment 1
A kind of hollow glass fluid sealant, according to the number of parts by weight, including following components：
56 parts of organic hydroxylic silicone, 12 parts of organic methyl silicone, 9 parts of methyl-monosilane, 30 parts of inorganic filler, high temperature resistant auxiliary material
14 parts, 2 parts of nano zircite, 2 parts of amino silane, 1 part of dibutyltin dilaurate, 13 parts of rubber, 1 part of starch, adjacent benzene two
0.4 part of 8 parts of formic acid dioctyl ester, 2 parts of antiseptic and ultraviolet absorber.Rubber is the composition of nitrile rubber and silicon rubber.Antibacterial
Agent is the mixture of chitin, mustard and copper oxide.
The preparation method of high temperature resistant auxiliary material includes the following steps：
(1) nano magnalium hydrotalcite is put into ethanol solution and is carried out, stirred simultaneously ultrasonic disperse, obtain dispersion liquid A；
(2) graphene oxide is weighed in proportion, ultrasonic disperse in the acrylic emulsion of n,N-Dimethylformamide is added, obtain
To dispersion liquid B；The mass ratio of graphene oxide and nano magnalium hydrotalcite is 12:100.
(3) organic binders solvent is added after mixing dispersion liquid A with dispersion liquid B, grinding is sufficiently mixed, then at 250 DEG C
~350 DEG C of condition pressure sintering sintering, you can obtain high temperature resistant auxiliary material.
Embodiment 2
A kind of hollow glass fluid sealant, according to the number of parts by weight, including following components：
50 parts of organic hydroxylic silicone, 10 parts of organic methyl silicone, 6 parts of methyl-monosilane, 35 parts of inorganic filler, high temperature resistant auxiliary material
16 parts, it is 1 part of nano zircite, 1 part of amino silane, 1 part of dibutyltin dilaurate, 12 parts of rubber, 1 part of sodium alginate, adjacent
0.2 part of 8 parts of phthalic acid di-n-octyl, 1 part of antiseptic and ultraviolet absorber.Rubber is the combination of nitrile rubber and silicon rubber
Object.Antiseptic is the mixture of chitin, mustard and copper oxide.
The preparation method of high temperature resistant auxiliary material includes the following steps：
(1) nano magnalium hydrotalcite is put into ethanol solution and is carried out, stirred simultaneously ultrasonic disperse, obtain dispersion liquid A；
(2) graphene oxide is weighed in proportion, ultrasonic disperse in the acrylic emulsion of n,N-Dimethylformamide is added, obtain
To dispersion liquid B；The mass ratio of graphene oxide and nano magnalium hydrotalcite is 15:100.
(3) organic binders solvent is added after mixing dispersion liquid A with dispersion liquid B, grinding is sufficiently mixed, then at 350 DEG C
Condition pressure sintering is sintered, you can obtains high temperature resistant auxiliary material.
Embodiment 3
A kind of hollow glass fluid sealant, according to the number of parts by weight, including following components：
60 parts of organic hydroxylic silicone, 14 parts of organic methyl silicone, 12 parts of methyl-monosilane, 25 parts of inorganic filler, high temperature resistant are auxiliary
10 parts of material, 3 parts of nano zircite, 3 parts of amino silane, 2 parts of dibutyltin dilaurate, 16 parts of rubber, 2 parts of starch, adjacent benzene
0.6 part of 10 parts of diformazan dioctyl phthalate, 3 parts of antiseptic and ultraviolet absorber.Rubber is the composition of nitrile rubber and silicon rubber.It is anti-
Microbial inoculum is the mixture of chitin, mustard and copper oxide.
The preparation method of high temperature resistant auxiliary material includes the following steps：
(1) nano magnalium hydrotalcite is put into ethanol solution and is carried out, stirred simultaneously ultrasonic disperse, obtain dispersion liquid A；
(2) graphene oxide is weighed in proportion, ultrasonic disperse in the acrylic emulsion of n,N-Dimethylformamide is added, obtain
To dispersion liquid B；The mass ratio of graphene oxide and nano magnalium hydrotalcite is 5:100.
(3) organic binders solvent is added after mixing dispersion liquid A with dispersion liquid B, grinding is sufficiently mixed, then at 250 DEG C
Condition pressure sintering is sintered, you can obtains high temperature resistant auxiliary material.
Embodiment 4
A kind of hollow glass fluid sealant, according to the number of parts by weight, including following components：
53 parts of organic hydroxylic silicone, 11 parts of organic methyl silicone, 7 parts of methyl-monosilane, 28 parts of inorganic filler, high temperature resistant auxiliary material
12 parts, it is 2 parts of nano zircite, 2 parts of amino silane, 2 parts of dibutyltin dilaurate, 16 parts of rubber, 2 parts of sodium alginate, adjacent
0.6 part of 9 parts of phthalic acid dinonyl, 3 parts of antiseptic and ultraviolet absorber.Rubber is the combination of nitrile rubber and silicon rubber
Object.
The preparation method of high temperature resistant auxiliary material includes the following steps：
(1) nano magnalium hydrotalcite is put into ethanol solution and is carried out, stirred simultaneously ultrasonic disperse, obtain dispersion liquid A；
(2) graphene oxide is weighed in proportion, ultrasonic disperse in the acrylic emulsion of n,N-Dimethylformamide is added, obtain
To dispersion liquid B；The mass ratio of graphene oxide and nano magnalium hydrotalcite is 10:100.
(3) organic binders solvent is added after mixing dispersion liquid A with dispersion liquid B, grinding is sufficiently mixed, then at 300 DEG C
Condition pressure sintering is sintered, you can obtains high temperature resistant auxiliary material.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (7)
1. a kind of hollow glass fluid sealant, which is characterized in that according to the number of parts by weight, including following components：
50~60 parts of organic hydroxylic silicone, 10~14 parts of organic methyl silicone, 6~12 parts of methyl-monosilane, inorganic filler 25~35
Part, 10~16 parts of high temperature resistant auxiliary material, 1~3 part of nano zircite, 1~3 part of amino silane, dibutyltin dilaurate 1~2
Part, 12~16 parts of rubber, 1~2 part of adhesive aid, 8~10 parts of plasticizer, 1~3 part of antiseptic and ultraviolet absorber 0.2~0.6
Part；The high temperature resistant auxiliary material is mainly matrix by nano magnalium hydrotalcite, and graphene oxide is as auxiliary agent, at 250 DEG C~350 DEG C
Under the conditions of hot pressed sintering form.
2. hollow glass fluid sealant according to claim 1, which is characterized in that the preparation method of the high temperature resistant auxiliary material
Include the following steps：
(1) nano magnalium hydrotalcite is put into ethanol solution and is carried out, stirred simultaneously ultrasonic disperse, obtain dispersion liquid A；
(2) graphene oxide is weighed in proportion, ultrasonic disperse in the acrylic emulsion of n,N-Dimethylformamide is added, divided
Dispersion liquid B；
(3) organic binders solvent is added after mixing dispersion liquid A with dispersion liquid B, grinding is sufficiently mixed, then 250 DEG C~350
DEG C condition pressure sintering sintering, you can obtain high temperature resistant auxiliary material.
3. hollow glass fluid sealant according to claim 2, which is characterized in that the graphene oxide and the nanometer
The mass ratio of magnalium hydrotalcite is 5~15:100.
4. hollow glass fluid sealant according to claim 1, which is characterized in that the rubber is nitrile rubber and silicon rubber
The composition of glue.
5. hollow glass fluid sealant according to claim 1, which is characterized in that the adhesive aid is selected from starch, Ah
Draw one or more of primary glue and sodium alginate.
6. hollow glass fluid sealant according to claim 1, which is characterized in that the plasticizer is selected from phthalic acid
One kind in dioctyl ester, di-n-octyl phthalate, dicyclohexyl phthalate and diisononyl phthalate or
It is a variety of.
7. hollow glass fluid sealant according to claim 1, which is characterized in that the antiseptic is chitin, mustard
With the mixture of copper oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810689739.6A CN108715753A (en) | 2018-06-28 | 2018-06-28 | Hollow glass fluid sealant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810689739.6A CN108715753A (en) | 2018-06-28 | 2018-06-28 | Hollow glass fluid sealant |
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| Publication Number | Publication Date |
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| CN108715753A true CN108715753A (en) | 2018-10-30 |
Family
ID=63912404
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810689739.6A Pending CN108715753A (en) | 2018-06-28 | 2018-06-28 | Hollow glass fluid sealant |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927088A (en) * | 2015-06-11 | 2015-09-23 | 上海大学 | Graphene/layered double hydroxide halogen-free flame retardant masterbatch and preparation method thereof |
| CN106995643A (en) * | 2017-05-23 | 2017-08-01 | 上海工程技术大学 | A kind of water paint of graphene-containing/zinc-aluminum gavite nano-complex and preparation method thereof |
| CN107254291A (en) * | 2017-08-01 | 2017-10-17 | 合肥利裕泰玻璃制品有限公司 | A kind of antibacterial flame-retardant double glazing fluid sealant and preparation method thereof |
| CN107286661A (en) * | 2017-06-20 | 2017-10-24 | 东莞市佳乾新材料科技有限公司 | A kind of casting mold silicon rubber composite material and preparation method thereof |
-
2018
- 2018-06-28 CN CN201810689739.6A patent/CN108715753A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927088A (en) * | 2015-06-11 | 2015-09-23 | 上海大学 | Graphene/layered double hydroxide halogen-free flame retardant masterbatch and preparation method thereof |
| CN106995643A (en) * | 2017-05-23 | 2017-08-01 | 上海工程技术大学 | A kind of water paint of graphene-containing/zinc-aluminum gavite nano-complex and preparation method thereof |
| CN107286661A (en) * | 2017-06-20 | 2017-10-24 | 东莞市佳乾新材料科技有限公司 | A kind of casting mold silicon rubber composite material and preparation method thereof |
| CN107254291A (en) * | 2017-08-01 | 2017-10-17 | 合肥利裕泰玻璃制品有限公司 | A kind of antibacterial flame-retardant double glazing fluid sealant and preparation method thereof |
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Application publication date: 20181030 |
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