CN108715564A - A kind of carbon-based mineral member soil conditioner and preparation method thereof - Google Patents
A kind of carbon-based mineral member soil conditioner and preparation method thereof Download PDFInfo
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- CN108715564A CN108715564A CN201810640424.2A CN201810640424A CN108715564A CN 108715564 A CN108715564 A CN 108715564A CN 201810640424 A CN201810640424 A CN 201810640424A CN 108715564 A CN108715564 A CN 108715564A
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- vermiculite
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of carbon-based mineral member soil conditioners and preparation method thereof, and wherein conditioning agent is prepared by the raw material comprising following parts by weight, 30~50 parts of vermiculite, 45~60 parts of organic matter, 1~10 part of beneficial bacterium；Purification, the calcining of vermiculite are first taken when preparation；Then the vermiculite and organic matter for taking certain component are stirred together；The vermiculite mixed in step 2 and organic matter are granulated followed by granulating disc；It is wrapped with beneficial bacteria followed by the granulation spray for obtaining step 3；Final sizing obtains carbon-based mineral member soil conditioner finished product.The present invention is using vermiculite as primary raw material, it is aided with high activity organic matter, and with bacillusmusilaginosiengineering and bacillus amyloliquefaciens it is addition microorganism, a kind of conditioning agent rich in natural mineral matter and beneficial activity bacterium directly synthesized, contain various elements, absorption rate of the crop to moisture, nutrient is greatly improved, there is long-acting type.
Description
Technical field
The present invention relates to microorganisms technical field more particularly to a kind of carbon-based mineral member soil conditioners.
Background technology
Microbial manure production cost is low, good application effect, therefore microbial manure is in the gradual quilt of effect agriculturally
People are recognized.Have more than 70 country's productions, application in the world at present and promote microbial manure, China also has 250 at present
Enterprise of family produces about few hundred thousand tonnes of microbial manure per year and is applied to production.Though this with same period fertilizer production and dosage cannot compared with,
Indeed start to play a role in agricultural production, achieves certain economic benefit and social effect, preliminarily formed regular work
Industry production scale.
Vermiculite is agriculturally mainly used for seedling medium currently on the market, and there has been no commercial fertilizer appearances.
Invention content
Against the above deficiency, the technical problem to be solved by the present invention is to：A kind of carbon-based mineral member soil conditioner is provided
And preparation method thereof, conditioning agent prepared by the present invention is rich in natural mineral matter and beneficial activity bacterium, and containing Crop development, institute is necessary
Various elements, persistently can provide more complete nutrition to crop, have and take root, water storage, fertilizer conservation, ventilative, disease prevention, improve nitrogen
Phosphorus potassium utilization rate etc. integrates effect, can greatly improve absorption rate of the crop to moisture, nutrient, has certain long-acting type.
In order to solve the above technical problems, the technical scheme is that：
A kind of carbon-based mineral member soil conditioner, is prepared, 30~50 parts of vermiculite, 45 by the raw material comprising following parts by weight
~60 parts of organic matter, 1~10 part of beneficial bacterium.
Preferred embodiment is to be prepared by the raw material comprising following parts by weight, 30 parts of vermiculite, 45 parts of organic matter, beneficial bacterium 1
Part.
Preferred embodiment is to be prepared by the raw material comprising following parts by weight, 50 parts of vermiculite, 60 parts of organic matter, beneficial bacterium
10 parts.
Preferred embodiment is to be prepared by the raw material comprising following parts by weight, 40 parts of vermiculite, 49 parts of organic matter, beneficial bacterium 6
Part.
Preferred embodiment is that the organic matter is high activity organic matter, predominantly furfural dregs, bean cake powder and corn oil residue.
Preferred embodiment is that the beneficial bacterium is by 1~10 part of bacillusmusilaginosiengineering bacterium powder and 1~10 part of solution starch bud
Spore bacillus bacterium powder forms.
The preparation method of above-mentioned carbon-based mineral member soil conditioner, includes the following steps：
Step 1: the purification of vermiculite, calcining, the temperature of calcining is 200~300 DEG C;
Step 2: the vermiculite of certain component is taken to be stirred together with organic matter；
Step 3: the vermiculite mixed in step 2 and organic matter are granulated using granulating disc；
Step 4: the granulation spray that step 3 obtains is wrapped with beneficial bacteria.
Step 5: screening obtains carbon-based mineral member soil conditioner finished product.
Preferred embodiment is, the purification of the vermiculite, take exercise the specific steps are：Primary mineral of vermiculite is chosen, then by primary mineral of vermiculite
It crushes, then shakeout, followed by high-temperature calcination is carried out, finally obtains vermiculite.
Preferred embodiment is that the beneficial bacterium is bacillusmusilaginosiengineering bacterium powder and bacillus amyloliquefaciens bacterium powder.
Preferred embodiment is, in step 4, fertilizer turner, top is used to have spray hole, sprinkling to be dissolved in water in advance when spray is wrapped up in
Profitable strain, be carried out at the same time cold wind drying, ensure the activity of bacterium.
After adopting the above technical scheme, the beneficial effects of the invention are as follows：Since the carbon-based mineral member soil of the present invention is adjusted
Agent and preparation method thereof, wherein conditioning agent are prepared by the raw material comprising following parts by weight, 30~50 parts of vermiculite, 45~
60 parts of organic matter, 1~10 part of beneficial bacterium；Purification, the calcining of vermiculite are first taken when preparation；Then take the vermiculite of certain component with
Organic matter is stirred together；The vermiculite mixed in step 2 and organic matter are made followed by granulating disc
Grain；It is wrapped with beneficial bacteria followed by the granulation spray for obtaining step 3；Final sizing obtains carbon-based mineral member soil conditioner finished product.Cause
The present invention's is combined with vermiculite with high activity organic matter, and a conditioning agent of microbial bacteria is added.Using vermiculite as primary raw material, warp
Purification, calcining, screening are aided with high activity organic matter, and are to add micro- life with bacillusmusilaginosiengineering and bacillus amyloliquefaciens
Object, a kind of conditioning agent rich in natural mineral matter and beneficial activity bacterium directly synthesized, containing various necessary to Crop development
Element can persistently provide crop more full nutrition, have and take root, water storage, fertilizer conservation, ventilative, disease prevention, improve N P and K profit
Effect is integrated with rate etc., absorption rate of the crop to moisture, nutrient can be greatly improved, there is certain long-acting type.
The principle of the carbon-based mineral member soil conditioner synthesis of the present invention is as follows：
Vermiculite is a kind of natural, inorganic, nontoxic minerals, the dilatable mineral under high temperature action.It is a kind of fewer
The mineral seen, belong to silicate.Its crystal structure is monoclinic system, like mica in terms of its shape.Vermiculite is by certain
What granite generated when being hydrated.It is generally generated with asbestos simultaneously.Since vermiculite has the ability of ion exchange, its battalion to soil
Supporting has great effect.
Vermiculite is called vermiculite power, the entitled VERMICULITE of English, and density is 2.4~2.7g/cm3；
No. CAS：1318-00-9；
Molecular formula：(Mg,Fe,Al)3[(Si,Al)4O10(OH)2].4H2O
The chemical analysis (%) of vermiculite
| SiO2 | Al2 O3 | Fe2O3 | MgO | H2O |
| 37-43 | 9-17 | 5-24 | 11-23 | 0.5-9 |
Vermiculite can be used as soil conditioner, since it is with good cationic exchangeability and adsorptivity, can improve the knot of soil
Structure, water storage soil moisture conservation, improves the gas permeability and the property of water-bearing of soil, acid soil is made to become neutral soil；Vermiculite may also function as buffering
Effect, hinders the rapid variation of pH value, makes conditioning agent slow release in plant growth medium, and allows slightly excessively using tune
It saves agent and is safe from harm to plant；Vermiculite can also provide K, Mg, Ca, the Fe itself contained and micro Mn, Cu, Zn to crop
Equal elements.The water imbibition of vermiculite, cationic exchangeability and properties of chemical composition, make its play fertilizer conservation, water conservation, water storage, it is ventilative and
The multiple actions such as mineral conditioning agent.Experiments have shown that：By in the expanded vermiculite incorporation composite fertilizer of 0.5-1%, crop yield can be made to carry
High 15-20%.
The title of vermiculite mineral comes from Latin, the meaning with " vermiform ", " worm trail shape ".Vermiculite is heated to suddenly
It is peeled off as generating worm along the c-axis of its crystal after 200 to 300 DEG C, thus it also obtains its name.Vermiculite is a kind of
The secondary metamorphic mineral of water aluminosilicate containing magnesium of layer structure, raw ore is similar to mica outside, usually mainly by black（Gold）Mica passes through
Hydrothermal alteration effect or weathering form, and curved in scratching when being expanded because of its dehydration of being heated, form exactly likes leech, therefore claims vermiculite.
Vermiculite is a kind of clay mineral similar with montmorillonite, is the silicate of layer structure.Generally by biotite through heat
Liquid alteration or weathering are formed.It occurs with coarse biotite appearance sometimes（This is the biotite illusion of vermiculite）, sometimes then thin
It is so micro- that become soil shape.When vermiculite is heated to 300 DEG C, 20 times of its expansion simultaneously bends.At this moment vermiculite is somewhat like water
Leech（It is commonly called as leech）, therefore it has so name.Vermiculite is generally brown, yellow, dirty-green, has the gloss as oil, adds
Become grey after heat.Vermiculite can be used as construction material, adsorbent, fire-retardant insulating material, mechanical lubrication agent, soil conditioner etc.
Deng widely used.
Vermiculite can be divided into vermiculite in flake and expanded vermiculite by stage, by color classification can be divided into golden yellow vermiculite,
Silvery white vermiculite, milky vermiculite.
By high-temperature roasting, its volume can expand rapidly 6~20 times to vermiculite in flake, and the proportion after expansion is 60~180kg/m3,
With very strong thermal and insulating performance.
Bacillus amyloliquefaciens：
White, translucent, smooth moistening bacterium colony slightly swells, round neat bacterium colony；Gram's staining thalline purple is gram
Positive bacteria, can secrete a variety of extracellular antiseptic substances, have good inhibiting effect to plant pathogenetic bacteria, fungi, virus, nematode,
The disease resistance of plant is significantly improved, while plant growth can be promoted, improves the yield of plant, is a kind of good biological and ecological methods to prevent plant disease, pests, and erosion growth-promoting
Bacterium, especially to bacterial wilt, mosaic disease has fine inhibiting effect.
The mechanism of action of bacillus amyloliquefaciens includes mainly secretion antibacterial material, generates antagonism, nutrition and space
Competition, induction host generates resistance and promotes plant growth etc..1, antibacterial material is secreted：Generate low molecular weight antibiotic and
Antibacterial protein or polypeptide isoreactivity substance inhibit phytopathogen, and can be used as Spraying potassium and promote plant growth.By non-
The small thermal stability of ribosomes approach synthetic molecular weight is good, contains D- amino acid, tolerance protein enzyme hydrolysis and organic solvent effect
Lipopeptide antibiotic, biological control application in main work is played to the inhibition of plant pathogenetic bacteria, fungi, virus, nematode
With.
2, antagonism：Microorganism by assimilation generate antibacterial material inhibit be harmful to pathogen growth or development or
Directly kill pathogen.It is directly acted on pathogen.Other than generating the secondary metabolites such as antibiotic, also it will produce a series of
The extracellular hydrolase that pathogen is inhibited to play an important role.
3, the competition of nutrition and space：The Vegetation space growth survival that fruits and vegetables wound can promptly be seized is simultaneously a large amount of numerous
It grows, and consumes wound nutrition as quickly as possible so that pathogen cannot get suitable nutrition and steric requirements and irreproducible
To inhibit the generation of disease.
4, induction host generates resistance：Plant tissue, in vivo can be spontaneous when by mechanical damage or Pathogen Infection
A series of biochemical reactions are generated to resist injury of these factors to itself.Bacillus amyloliquefaciens can induce plant this
Kind nature defensive enginery.
5, promote plant growth：It is a variety of that bacillus amyloliquefaciens can generate gibberellin, heteroauxin, basic element of cell division etc.
Physiological activator and amino acids substance promote root system of plant and plant strain growth, enhance disease resistance of plant, to subtract indirectly
Lack disease.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following embodiment carries out the present invention
It is further described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit
The present invention.
Embodiment one：
A kind of carbon-based mineral member soil conditioner, is prepared by the raw material comprising following parts by weight, 30 parts of vermiculite, organic matter 45
Part, 1 part of beneficial bacterium, wherein beneficial bacterium are by 1 part of bacillusmusilaginosiengineering bacterium powder and 1 part of bacillus amyloliquefaciens bacterium powder group
At.Wherein organic matter is high activity organic matter, predominantly furfural dregs, bean cake powder and corn oil residue.
Embodiment two：
A kind of carbon-based mineral member soil conditioner, is prepared by the raw material comprising following parts by weight, 50 parts of vermiculite, organic matter 60
Part, 10 parts of beneficial bacterium, wherein beneficial bacterium are by 10 parts of bacillusmusilaginosiengineering bacterium powder and 10 parts of bacillus amyloliquefaciens bacterium
Powder forms.
Wherein organic matter is high activity organic matter, predominantly furfural dregs, bean cake powder and corn oil residue.
Embodiment three：
A kind of carbon-based mineral member soil conditioner, is prepared by the raw material comprising following parts by weight, 40 parts of vermiculite, organic matter 49
Part, 6 parts of beneficial bacterium, wherein beneficial bacterium are by 6 parts of bacillusmusilaginosiengineering bacterium powder and 6 parts of bacillus amyloliquefaciens bacterium powder group
At.
Wherein organic matter is high activity organic matter, predominantly furfural dregs, bean cake powder and corn oil residue.
Example IV：
The preparation method of carbon-based mineral member soil conditioner in embodiment one to embodiment three, includes the following steps：
Step 1: the purification of vermiculite, calcining, the temperature of calcining is 200~300 DEG C；The purification of vermiculite, take exercise the specific steps are：
Primary mineral of vermiculite is chosen, is then crushed primary mineral of vermiculite, then shakeout, followed by high-temperature calcination is carried out, finally obtains vermiculite.
Step 2: the vermiculite of certain component is taken to be stirred together with organic matter；
Step 3: the vermiculite mixed in step 2 and organic matter are granulated using granulating disc；
Step 4: the granulation spray that step 3 obtains is wrapped with beneficial bacteria；Beneficial bacterium is that bacillusmusilaginosiengineering bacterium powder conciliates starch bud
Spore bacillus bacterium powder.Microbial-bacterial fertilizer living bacteria count of the present invention is 2.0 hundred million CFU/ grams or more, organic matter >=45%, silica >=
40%, calcium >=5% of magnesium >=11%, potassium >=3%, iron >=5%, moisture≤6%, pH value 7.0-8.0 is nontoxic, tasteless, without side-effects.Spray is wrapped up in
When use fertilizer turner, top to have a spray hole, sprinkling is dissolved in the profitable strain of water in advance, is carried out at the same time cold wind drying, ensures
The activity of bacterium.
Step 5: screening obtains carbon-based mineral member soil conditioner finished product.
The preparation method that the present invention uses, processing step is simple, at low cost, it is easy to accomplish, it is suitble to produce in enormous quantities.
The preferred embodiment of present invention described above, is not intended to limit the invention, it is all the present invention spirit and
Any modification made by within principle, etc. same carbon-based mineral member soil conditioner and preparation method thereof structure improvement etc.,
It should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of carbon-based mineral member soil conditioner, which is characterized in that it is prepared by the raw material comprising following parts by weight, 30~
50 parts of vermiculite, 45~60 parts of organic matter, 1~10 part of beneficial bacterium.
2. carbon-based mineral member soil conditioner according to claim 1, which is characterized in that by the original for including following parts by weight
Material is prepared, 30 parts of vermiculite, 45 parts of organic matter, 1 part of beneficial bacterium.
3. carbon-based mineral member soil conditioner according to claim 1, which is characterized in that by the original for including following parts by weight
Material is prepared, 50 parts of vermiculite, 60 parts of organic matter, 10 parts of beneficial bacterium.
4. carbon-based mineral member soil conditioner according to claim 1, which is characterized in that by the original for including following parts by weight
Material is prepared, 40 parts of vermiculite, 49 parts of organic matter, 6 parts of beneficial bacterium.
5. the carbon-based mineral member soil conditioner of Claims 1-4 any one of them, which is characterized in that the organic matter is height
Active organic matter, predominantly furfural dregs, bean cake powder and corn oil residue.
6. the carbon-based mineral member soil conditioner of Claims 1-4 any one of them, which is characterized in that the beneficial bacterium by 1~
10 parts of bacillusmusilaginosiengineering bacterium powder and 1~10 part of bacillus amyloliquefaciens bacterium powder composition.
7. the preparation method of the carbon-based mineral member soil conditioner of claim 1 to 6 any one of them, which is characterized in that including
Following steps：
Step 1: the purification of vermiculite, calcining, the temperature of calcining is 200~300 DEG C;
Step 2: the vermiculite of certain component is taken to be stirred together with organic matter；
Step 3: the vermiculite mixed in step 2 and organic matter are granulated using granulating disc；
Step 4: the granulation spray that step 3 obtains is wrapped with beneficial bacteria；
Step 5: screening obtains carbon-based mineral member soil conditioner finished product.
8. the preparation method of carbon-based mineral member soil conditioner according to claim 7, which is characterized in that the vermiculite
Purification, take exercise the specific steps are：Primary mineral of vermiculite is chosen, is then crushed primary mineral of vermiculite, then shakeout, is forged followed by high temperature is carried out
It burns, finally obtains vermiculite.
9. the preparation method of carbon-based mineral member soil conditioner according to claim 7, which is characterized in that the beneficial bacterium
For bacillusmusilaginosiengineering bacterium powder and bacillus amyloliquefaciens bacterium powder.
10. the preparation method of carbon-based mineral member soil conditioner according to claim 7, which is characterized in that in step 4,
It uses fertilizer turner, top to there is spray hole, sprinkling to be dissolved in the profitable strain of water in advance when spray is wrapped up in, is carried out at the same time cold wind drying,
Ensure the activity of bacterium.
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Application publication date: 20181030 |