CN108708787A - A method of removing automobile combustion chamber carbon distribution - Google Patents

A method of removing automobile combustion chamber carbon distribution Download PDF

Info

Publication number
CN108708787A
CN108708787A CN201810543301.7A CN201810543301A CN108708787A CN 108708787 A CN108708787 A CN 108708787A CN 201810543301 A CN201810543301 A CN 201810543301A CN 108708787 A CN108708787 A CN 108708787A
Authority
CN
China
Prior art keywords
combustion chamber
parts
carbon
carbon distribution
cleaning agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810543301.7A
Other languages
Chinese (zh)
Inventor
胡丽春
何伟仁
张建初
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Mausoleum Environmental Protection Technology Co Ltd
Original Assignee
Foshan Mausoleum Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Mausoleum Environmental Protection Technology Co Ltd filed Critical Foshan Mausoleum Environmental Protection Technology Co Ltd
Priority to CN201810543301.7A priority Critical patent/CN108708787A/en
Publication of CN108708787A publication Critical patent/CN108708787A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00Component parts, details or accessories, not otherwise provided for
    • F02B77/04Cleaning of, preventing corrosion or erosion in, or preventing unwanted deposits in, combustion engines

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to pretreatment of metal surface technical fields, and in particular to a method of removing automobile combustion chamber carbon distribution.The present invention is first passed through the mixed gas of oxygen and nitrogen into combustion chamber, preliminary clear carbon is completed to combustion chamber, cleaning agent is prepared again, and hydro-peening processing is carried out to combustion chamber, finally by isopropanol, methanol, magnesium powder, the mixing such as polyphosphate sodium, spraying treatment is carried out to combustion chamber, the present invention, which first passes through, makes thicker carbon be oxidized by oxygen into gas discharge combustion chamber the thermal oxidation of combustion chamber, the oily matter of combustor surface is set to dissolve dispersion by cleaning agent surface reactive material again, with methanol and isopropanol etc. for liquid dispersion, catalytic combustion-supporting powder promotes the oxidizing fire of gasoline, reduce the generation of carbon monoxide, carbon-coating is set to aoxidize, improve the efficiency of combustion of gasoline, and magnesium powder is oxidized to magnesia again, it constantly so recycles and reacts with carbon-coating, reduce the deposition of carbon-coating, it has a extensive future.

Description

A method of removing automobile combustion chamber carbon distribution
Technical field
The present invention relates to pretreatment of metal surface technical fields, and in particular to a kind of side removing automobile combustion chamber carbon distribution Method.
Background technology
In recent years, as the fast development of China's economy, living standards of the people are gradually increased, the family for possessing automobile is more next It is more.With the increase of the mileage and the time limit of vehicle traveling, just will appear after petrol engine runs 30,000 kilometers or after 2 years A kind of substance of the dirt and resin-like of viscosity.These substances can gradually increase, deposit, and then lead to the fuel combustions such as gasoline not Completely, the generation of carbon distribution is further aggravated.
Carbon distribution be automobile engine during the work time, unsaturated olefin and colloid generate at high operating temperatures in fuel oil A kind of substance of deeply worried shape.The maggot of automobile carbon deposition such as shank annoyings always every car owner, it constantly corrodes the heart of automobile It is dirty --- engine allows automobile fuel consumption to increase, power weakens, ignition difficulties and Idling wobble.Automobile carbon deposition is all the time all Generating, at the same also at every moment automobile is lost.Carbon distribution can be gathered in each position of engine, such as intake and exhaust system System, combustion chamber, atomizer etc..When combustion-chamber deposit is serious, combustion knock, slow-speed of revolution acceleration can also be caused to have sound, right Piston and bent axle damage, or even may finally lead to engine burn oil and be damaged.
Currently, the sweep-out method of carbon distribution mainly has:Physical removal method strikes off the carbon distribution on engine, and such method is very Difficulty is clean by carbon cleaning, and easily forms cut in metal surface, and efficiency is low, and cleaning is complicated;Chemical cleaning method, Mainly engine is impregnated by chemical agent, that is, utilizes 1%~10% 741 detergent, it is prolonged to impregnate, generally It controls more than for 24 hours.But some stubbornness carbon distributions can not be thoroughly removed in this way, can only be polished by local mechanical, if adopted It is operated with this, and is easy to damage matrix, cause scrapping for part.Metal watch of the majority chemical to engine itself at present There is certain corrosivity in face, and such cleaning agent is poisonous and harmful irritant, inflammable and explosive, can seriously endanger the strong of operating personnel Health, and serious pollution can be caused;Gasoline adds agent:Addition promotes the additive of burning in the oil, and gasoline is made fully to burn, This method can effectively pre- anti-carbon deposition generation, but for have carbon distribution eradicating efficacy unobvious.
Invention content
Present invention mainly solves the technical issues of, for the carbon distribution on combustion chamber is struck off by physical cleaning method at present, Easily form cut in metal surface, efficiency is low, and cleaning is complicated, and chemical cleaning method scavenging period is long, obstinate carbon distribution without Method thoroughly removes, and can only polish by local mechanical, be easy to damage matrix, causes scrapping for part, in addition, chemical is to combustion There is certain corrosivity in the metal surface for burning room itself, and residual component does not have combustion-supporting effect to lack in gasoline after cleaning agent cleaning It falls into, provides a kind of preparation method for removing automobile combustion chamber carbon distribution.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of preparation method for removing automobile combustion chamber carbon distribution, it is characterised in that specifically preparation process is:
(1)It is passed through oxygen and nitrogen into automobile burning room, starts engine, is continually fed into gas, first stops after being passed through oxygen Stop being passed through nitrogen again, while flame-out to the preliminary clear carbon of combustion chamber completion;
(2)It counts in parts by weight, takes 10~15 parts of deionized waters to be put into stirred autoclave, then sequentially add 30~40 part three Polyethanol and 4~5 parts of ethylene glycol monobutyl ethers are stirred with the rotating speed of 400~500r/min, mixed liquor are obtained, by alkylamide third Base dimethyl amine alkali solution of beet mixes in equal volume with mixed liquor, then adds 4~5 parts of chitosans and 10~15 parts of acetic acid solutions, It is placed in supercentrifuge and centrifuges, remove upper liquid, obtain sediment, put the precipitate in baking oven, heat temperature raising is done It is dry, obtain surface-active compound;
(3)It counts in parts by weight, 20~30 parts of surface-active compounds, 15~20 parts of Solid hydrogen peroxides, 100~120 parts is gone Ionized water, 10~15 parts of corrosion inhibiter benzotriazole mixing, are placed in the dispersion of high speed dispersor high speed, obtain cleaning agent;
(4)Cleaning agent is circulated into inhalator jar at normal temperatures and pressures with filling machine, is sealed with valve, by potassium permanganate when use Solution is packed at aerosol nozzle mouth, is sprayed cleaning agent to the combustion chamber after preliminary clear carbon by jet pipe, is completed hydro-peening;
(5)4~5g vanadic anhydrides, 15~20mL isobutanols, 8~10mL benzyl alcohols are placed in three with condensation reflux unit In mouthful flask, heat temperature raising after condensing reflux, 10~12mL phosphoric acid solutions is added into three-necked flask, continues condensing reflux, obtains To light green product, light green product is put into Muffle furnace, heat temperature raising, calcines, obtain catalytic combustion-supporting powder;
(6)It counts in parts by weight, by 10~15 parts of isopropanols, 30~35 parts of methanol, 8~10 parts of magnesium powders, 10~12 parts of polyphosphoric acids Sodium, 20~25 parts of triethanolamines, 4~5 parts of catalytic combustion-supporting powder mixing, are filled in spraying machine, to the combustion chamber after cleaning agent hydro-peening Spraying post-processing is carried out, starting engine makes combustion chamber heat up, and heat preservation a period of time, completes the removing to carbon distribution in combustion chamber.
Step(1)The described mixed volume ratio for being passed through oxygen and nitrogen is 3 ︰ 2, control burning indoor temperature is 100~ 120 DEG C, gas is continually fed into until aeration resistance≤0.4kPa in combustion chamber, first stops being passed through 4~5min of oxygen.
Step(2)The mass fraction of the alkylamide propyl dimethyl amine alkali solution of beet is 20%, acetic acid solution Mass fraction is 20%, and high speed centrifugation rotating speed is 4000~4200r/min, and centrifugation time is 15~20min, temperature after heat temperature raising Degree is 100~120 DEG C, and drying time is 2~3h.
Step(3)The high speed dispersor rotating speed is 3000~3300r/min, and the high speed dispersion time is 13~15min. Step(4)The liquor potassic permanganate mass fraction is 20%, and flow is 200~220mL/min when controlling hydro-peening, and hydro-peening is held Continuous 20~25min.
Step(5)Temperature is 80~90 DEG C after the heat temperature raising, and the condensing reflux time is 12~13h, phosphoric acid solution Mass fraction is 80%, and the condensing reflux time is 6~7h, and temperature is 400~450 DEG C after heat temperature raising in Muffle furnace, when calcining Between be 4~5h.
Step(6)The magnesium powder grain size is 50~80 μm, and spray amount is 200~250mL, and combustion chamber temperature is controlled when heat preservation Degree is 70~80 DEG C, and soaking time is 30~35min.
The beneficial effects of the invention are as follows:
(1)The present invention is first passed through the mixed gas of oxygen and nitrogen into combustion chamber, is tentatively preheated to carbon distribution in combustion chamber Oxidation processes complete preliminary clear carbon to combustion chamber, then prepare cleaning agent and carry out hydro-peening processing to combustion chamber, with vanadic anhydride, Isobutanol, benzyl alcohol are that raw material heats reaction in phosphoric acid solution, and catalytic combustion-supporting is prepared in obtained product after calcining Powder is filled with finally by mixing such as isopropanol, methanol, magnesium powder, polyphosphate sodium, triethanolamine, catalytic combustion-supporting powder in spraying machine, right Combustion chamber carries out spraying post-processing, completes the removing to carbon distribution in combustion chamber, and the present invention first passes through at the thermal oxide to combustion chamber Reason makes thicker carbon be oxidized by oxygen into gas discharge combustion chamber, then makes combustion chamber table by cleaning agent surface reactive material The oily matter dissolving dispersion in face forms organic dispersions, and cleaning agent can be with potassium permanganate play during hydro-peening in the present invention Strong heat release, and discharge oxygen, in cleaning process the aerosolization of cleaning agent can reach the position for being difficult to clear up of combustion chamber, together When cleaning agent in the inhibition substance that contains can form corrosion inhibition film after cleaning, avoid cleaning agent from generating the metal surface of combustion chamber Corrosion;
(2)The present invention, for liquid dispersion, preheats combustion chamber by starting engine, makes magnesium powder oxygen with methanol and isopropanol etc. Change complexing in polyphosphate sodium, triethanolamine, forms the protective layer of oleophobic and sink when can reduce gasoline combustion within a certain period of time Carbon, afterwards in combustion chamber when burns gasoline, catalytic combustion-supporting powder promotes gasoline as catalyst using its high-specific surface area Oxidizing fire, reduce the generation of carbon monoxide, and the magnesium elements being complexed can be reacted with the carbon-coating for being deposited on surface, make carbon-coating Magnesium elements are reduced into magnesium powder, magnesium powder has combustion-supporting effect in combustion, improves the efficiency of combustion of gasoline, magnesium powder by oxidation It is oxidized to magnesia again, constantly so recycles and reacts with carbon-coating, reduce the deposition of carbon-coating, have a extensive future.
Specific implementation mode
It is that 3 ︰ 2 are passed through oxygen and nitrogen by volume into automobile burning room, starts engine, control burning indoor temperature It is 100~120 DEG C, is continually fed into gas until aeration resistance≤0.4kPa in combustion chamber, first stops after being passed through 4~5min of oxygen Stop being passed through nitrogen again, while flame-out to the preliminary clear carbon of combustion chamber completion;It counts in parts by weight, 10~15 parts of deionized waters is taken to put Enter in stirred autoclave, 30~40 part of three polyethanol and 4~5 parts of ethylene glycol monobutyl ethers is then sequentially added, with 400~500r/ The rotating speed of min stirs, and obtains mixed liquor, by mass fraction be 20% alkylamide propyl dimethyl amine alkali solution of beet with it is mixed It closes liquid to mix in equal volume, then adds the acetic acid solution that 4~5 parts of chitosans and 10~15 parts of mass fractions are 20%, be placed in high speed 15~20min is centrifuged with the rotating speed of 4000~4200r/min in centrifuge, upper liquid is removed, obtains sediment, sediment is set In baking oven, 100~120 DEG C are heated to, dry 2~3h obtains surface-active compound;It counts in parts by weight, by 20 ~30 parts of surface-active compounds, 15~20 parts of Solid hydrogen peroxides, 100~120 parts of deionized waters, 10~15 parts of corrosion inhibiter benzos Triazole mixes, and is placed in rotating speed 13~15min of high speed dispersion with 3000~3300r/min in high speed dispersor, is cleaned Agent;Cleaning agent is circulated into inhalator jar at normal temperatures and pressures with filling machine, is sealed with valve, is by mass fraction when use 20% liquor potassic permanganate is packed at aerosol nozzle mouth, sprays cleaning agent, control to the combustion chamber after preliminary clear carbon by jet pipe Flow is 200~220mL/min when hydro-peening processed, and hydro-peening continues 20~25min;By 4~5g vanadic anhydrides, 15~20mL isobutyls Alcohol, 8~10mL benzyl alcohols are placed in the three-necked flask with condensation reflux unit, are heated to 80~90 DEG C, condensing reflux After 12~13h, the phosphoric acid solution that 10~12mL mass fractions are 80% is added into three-necked flask, continues 6~7h of condensing reflux, Light green product is obtained, light green product is put into Muffle furnace, is heated to 400~450 DEG C, 4~5h is calcined, is urged Change combustion supporting powder;It counts in parts by weight, the magnesium for being 50~80 μm by 10~15 parts of isopropanols, 30~35 parts of methanol, 8~10 parts of grain sizes Powder, 10~12 parts of polyphosphate sodiums, 20~25 parts of triethanolamines, 4~5 parts of catalytic combustion-supporting powder mixing, are filled in spraying machine, to cleaning Combustion chamber after agent hydro-peening carries out spraying post-processing, and spray amount is 200~250mL, starts engine, and control chamber temperature is 70~80 DEG C, 30~35min is kept the temperature, completes the removing to carbon distribution in combustion chamber.
It is that 3 ︰ 2 are passed through oxygen and nitrogen by volume into automobile burning room, starts engine, control burning indoor temperature It is 100 DEG C, is continually fed into gas until aeration resistance≤0.4kPa in combustion chamber, first stops being passed through after oxygen 4min stopping leading to again Enter nitrogen, while flame-out to the preliminary clear carbon of combustion chamber completion;It counts in parts by weight, 10 parts of deionized waters is taken to be put into stirred autoclave It is interior, 30 part of three polyethanol and 4 parts of ethylene glycol monobutyl ethers are then sequentially added, is stirred with the rotating speed of 400r/min, obtains mixed liquor, The alkylamide propyl dimethyl amine alkali solution of beet that mass fraction is 20% is mixed in equal volume with mixed liquor, then adds 4 parts of shells The acetic acid solution that glycan and 10 parts of mass fractions are 20% is placed in supercentrifuge the rotating speed centrifugation with 4000r/min 15min removes upper liquid, obtains sediment, put the precipitate in baking oven, is heated to 100 DEG C, and dry 2h obtains table Face active compound;Count in parts by weight, by 20 parts of surface-active compounds, 15 parts of Solid hydrogen peroxides, 100 parts of deionized waters, 10 parts of corrosion inhibiter benzotriazole mixing, are placed in the rotating speed high speed dispersion 13min with 3000r/min in high speed dispersor, obtain Cleaning agent;Cleaning agent is circulated into inhalator jar at normal temperatures and pressures with filling machine, is sealed with valve, by mass fraction when use It is packed at aerosol nozzle mouth for 20% liquor potassic permanganate, cleaning agent is sprayed to the combustion chamber after preliminary clear carbon by jet pipe, Flow is 200mL/min when controlling hydro-peening, and hydro-peening continues 20min;4g vanadic anhydrides, 15mL isobutanols, 8mL benzyl alcohols are set In the three-necked flask with condensation reflux unit, it is heated to 80 DEG C, after condensing reflux 12h, is added into three-necked flask The phosphoric acid solution that 10mL mass fractions are 80% continues condensing reflux 6h, obtains light green product, light green product is put into horse Not in stove, 400 DEG C are heated to, 4h is calcined, obtains catalytic combustion-supporting powder;It counts in parts by weight, by 10 parts of isopropanols, 30 parts of first Alcohol, the magnesium powder that 8 parts of grain sizes are 50 μm, 10 parts of polyphosphate sodiums, 20 parts of triethanolamines, 4 parts of catalytic combustion-supporting powder mixing, are filled with spraying machine In, spraying post-processing is carried out to the combustion chamber after cleaning agent hydro-peening, spray amount 200mL starts engine, control burning room temperature Degree is 70 DEG C, keeps the temperature 30min, completes the removing to carbon distribution in combustion chamber.
It is that 3 ︰ 2 are passed through oxygen and nitrogen by volume into automobile burning room, starts engine, control burning indoor temperature It is 110 DEG C, is continually fed into gas until aeration resistance≤0.4kPa in combustion chamber, first stops being passed through after oxygen 4min stopping leading to again Enter nitrogen, while flame-out to the preliminary clear carbon of combustion chamber completion;It counts in parts by weight, 13 parts of deionized waters is taken to be put into stirred autoclave It is interior, 35 part of three polyethanol and 4 parts of ethylene glycol monobutyl ethers are then sequentially added, is stirred with the rotating speed of 450r/min, obtains mixed liquor, The alkylamide propyl dimethyl amine alkali solution of beet that mass fraction is 20% is mixed in equal volume with mixed liquor, then adds 4 parts of shells The acetic acid solution that glycan and 13 parts of mass fractions are 20% is placed in supercentrifuge the rotating speed centrifugation with 4100r/min 17min removes upper liquid, obtains sediment, put the precipitate in baking oven, is heated to 110 DEG C, and dry 2h obtains table Face active compound;Count in parts by weight, by 25 parts of surface-active compounds, 17 parts of Solid hydrogen peroxides, 110 parts of deionized waters, 13 parts of corrosion inhibiter benzotriazole mixing, are placed in the rotating speed high speed dispersion 14min with 3150r/min in high speed dispersor, obtain Cleaning agent;Cleaning agent is circulated into inhalator jar at normal temperatures and pressures with filling machine, is sealed with valve, by mass fraction when use It is packed at aerosol nozzle mouth for 20% liquor potassic permanganate, cleaning agent is sprayed to the combustion chamber after preliminary clear carbon by jet pipe, Flow is 210mL/min when controlling hydro-peening, and hydro-peening continues 23min;4g vanadic anhydrides, 17mL isobutanols, 9mL benzyl alcohols are set In the three-necked flask with condensation reflux unit, it is heated to 85 DEG C, after condensing reflux 12h, is added into three-necked flask The phosphoric acid solution that 11mL mass fractions are 80% continues condensing reflux 6h, obtains light green product, light green product is put into horse Not in stove, 425 DEG C are heated to, 4h is calcined, obtains catalytic combustion-supporting powder;It counts in parts by weight, by 14 parts of isopropanols, 33 parts of first Alcohol, the magnesium powder that 9 parts of grain sizes are 65 μm, 11 parts of polyphosphate sodiums, 22 parts of triethanolamines, 4 parts of catalytic combustion-supporting powder mixing, are filled with spraying machine In, spraying post-processing is carried out to the combustion chamber after cleaning agent hydro-peening, spray amount 225mL starts engine, control burning room temperature Degree is 75 DEG C, keeps the temperature 33min, completes the removing to carbon distribution in combustion chamber.
It is that 3 ︰ 2 are passed through oxygen and nitrogen by volume into automobile burning room, starts engine, control burning indoor temperature It is 120 DEG C, is continually fed into gas until aeration resistance≤0.4kPa in combustion chamber, first stops being passed through after oxygen 5min stopping leading to again Enter nitrogen, while flame-out to the preliminary clear carbon of combustion chamber completion;It counts in parts by weight, 15 parts of deionized waters is taken to be put into stirred autoclave It is interior, 40 part of three polyethanol and 5 parts of ethylene glycol monobutyl ethers are then sequentially added, is stirred with the rotating speed of 500r/min, obtains mixed liquor, The alkylamide propyl dimethyl amine alkali solution of beet that mass fraction is 20% is mixed in equal volume with mixed liquor, then adds 5 parts of shells The acetic acid solution that glycan and 15 parts of mass fractions are 20% is placed in supercentrifuge the rotating speed centrifugation with 4200r/min 20min removes upper liquid, obtains sediment, put the precipitate in baking oven, is heated to 120 DEG C, and dry 3h obtains table Face active compound;Count in parts by weight, by 30 parts of surface-active compounds, 20 parts of Solid hydrogen peroxides, 120 parts of deionized waters, 15 parts of corrosion inhibiter benzotriazole mixing, are placed in the rotating speed high speed dispersion 15min with 3300r/min in high speed dispersor, obtain Cleaning agent;Cleaning agent is circulated into inhalator jar at normal temperatures and pressures with filling machine, is sealed with valve, by mass fraction when use It is packed at aerosol nozzle mouth for 20% liquor potassic permanganate, cleaning agent is sprayed to the combustion chamber after preliminary clear carbon by jet pipe, Flow is 220mL/min when controlling hydro-peening, and hydro-peening continues 25min;By 5g vanadic anhydrides, 20mL isobutanols, 10mL benzyl alcohols Be placed in the three-necked flask with condensation reflux unit, be heated to 90 DEG C, after condensing reflux 13h, into three-necked flask plus Enter the phosphoric acid solution that 12mL mass fractions are 80%, continues condensing reflux 7h, obtain light green product, light green product is put into In Muffle furnace, 450 DEG C are heated to, 5h is calcined, obtains catalytic combustion-supporting powder;Count in parts by weight, by 15 parts of isopropanols, 35 parts Methanol, the magnesium powder that 10 parts of grain sizes are 80 μm, 12 parts of polyphosphate sodiums, 25 parts of triethanolamines, 5 parts of catalytic combustion-supporting powder mixing, are filled with spray In mist machine, spraying post-processing is carried out to the combustion chamber after cleaning agent hydro-peening, spray amount 250mL starts engine, control burning Room temperature is 80 DEG C, keeps the temperature 35min, completes the removing to carbon distribution in combustion chamber.
Comparative example is as a comparison case made the present invention with the automobile combustion chamber carbon deposit cleaning agent that company of Beijing produces Automobile combustion chamber carbon deposit cleaning agent and comparative example in automobile combustion chamber carbon deposit cleaning agent be detected, testing result such as table 1 It is shown:
1, under the same conditions, the cleaning agent that Examples 1 to 3 and comparative example provide is respectively adopted, to automobile in cleanliness factor detection The carbon distribution of combustion chamber is cleaned, and is then detected to the cleanliness factor of automobile combustion chamber using cleanliness factor detecting instrument.
Copper corrosion is tested according to GB/T5096-2017《Oil product copper strip test method》Regulation, using copper sheet Corrosion measurement instrument tests the cleaning agent of Examples 1 to 3 and comparative example.It is corroded by style to be measured according to copper sheet surface Degree, copper corrosion grade are divided into 1,2,3,4 level Four.Wherein, 1 represent that extent of corrosion is slighter, almost with new copper sheet one Sample, 4 to represent extent of corrosion the most serious.
Flash-point is tested according to GB/T261-2008《The measurement of Flash Point for Petroleum Products》Regulation, sample is poured into test glass In, it is continuously stirred under given pace, and sample is heated with constant rate of speed.With defined temperature interval, in the feelings for interrupting stirring Under condition, burning things which may cause a fire disaster is introduced into test glass opening, makes sample vapors that moment scintillation occur, and spread to the lowest temperature of liquid surface Degree, this temperature are the flash-point of ambient air pressure, then are adapted to the flash-point of normal atmosphere pressure.
Water-soluble acid and alkali is measured according to GB/T259《Oil product water soluble acid and alkalimetry》Regulation, with distillation Water soluble acid or alkali in water or ethanol solution extracting sample, use methyl orange or phenolphthalein indicator to check the color of Extract respectively Situation of change, or with acidometer measure extract pH value, to determine whether the presence of water soluble acid or alkali.
1 performance measurement result of table
From the data in table 1, it can be seen that when removing Inner Wall of Combustion Chamber carbon distribution using automobile combustion chamber carbon deposit cleaning agent produced by the present invention, go It is corrosion-free to engine base material and auto parts and components except rate is high, dosage is few, dissolving is complete, noresidue.It is substantially better than comparative example sample Product have important market value and social value.

Claims (7)

1. a kind of method for removing automobile combustion chamber carbon distribution, it is characterised in that specifically preparation process is:
(1)It is passed through oxygen and nitrogen into automobile burning room, starts engine, is continually fed into gas, first stops after being passed through oxygen Stop being passed through nitrogen again, while flame-out to the preliminary clear carbon of combustion chamber completion;
(2)It counts in parts by weight, takes 10~15 parts of deionized waters to be put into stirred autoclave, then sequentially add 30~40 part three Polyethanol and 4~5 parts of ethylene glycol monobutyl ethers are stirred with the rotating speed of 400~500r/min, mixed liquor are obtained, by alkylamide third Base dimethyl amine alkali solution of beet mixes in equal volume with mixed liquor, then adds 4~5 parts of chitosans and 10~15 parts of acetic acid solutions, It is placed in supercentrifuge and centrifuges, remove upper liquid, obtain sediment, put the precipitate in baking oven, heat temperature raising is done It is dry, obtain surface-active compound;
(3)It counts in parts by weight, 20~30 parts of surface-active compounds, 15~20 parts of Solid hydrogen peroxides, 100~120 parts is gone Ionized water, 10~15 parts of corrosion inhibiter benzotriazole mixing, are placed in the dispersion of high speed dispersor high speed, obtain cleaning agent;
(4)Cleaning agent is circulated into inhalator jar at normal temperatures and pressures with filling machine, is sealed with valve, by potassium permanganate when use Solution is packed at aerosol nozzle mouth, is sprayed cleaning agent to the combustion chamber after preliminary clear carbon by jet pipe, is completed hydro-peening;
(5)4~5g vanadic anhydrides, 15~20mL isobutanols, 8~10mL benzyl alcohols are placed in three with condensation reflux unit In mouthful flask, heat temperature raising after condensing reflux, 10~12mL phosphoric acid solutions is added into three-necked flask, continues condensing reflux, obtains To light green product, light green product is put into Muffle furnace, heat temperature raising, calcines, obtain catalytic combustion-supporting powder;
(6)It counts in parts by weight, by 10~15 parts of isopropanols, 30~35 parts of methanol, 8~10 parts of magnesium powders, 10~12 parts of polyphosphoric acids Sodium, 20~25 parts of triethanolamines, 4~5 parts of catalytic combustion-supporting powder mixing, are filled in spraying machine, to the combustion chamber after cleaning agent hydro-peening Spraying post-processing is carried out, starting engine makes combustion chamber heat up, and heat preservation a period of time, completes the removing to carbon distribution in combustion chamber.
2. a kind of method for removing automobile combustion chamber carbon distribution according to claim 1, it is characterised in that:Step(1)It is described The mixed volume ratio for being passed through oxygen and nitrogen be 3 ︰ 2, control burning indoor temperature is 100~120 DEG C, and it is straight to be continually fed into gas Aeration resistance≤0.4kPa in combustion chamber first stops being passed through 4~5min of oxygen.
3. a kind of method for removing automobile combustion chamber carbon distribution according to claim 1, it is characterised in that:Step(2)It is described The mass fraction of alkylamide propyl dimethyl amine alkali solution of beet be 20%, the mass fraction of acetic acid solution is 20%, high speed Centrifugal rotational speed is 4000~4200r/min, and centrifugation time is 15~20min, and temperature is 100~120 DEG C after heat temperature raising, dry Time is 2~3h.
4. a kind of method for removing automobile combustion chamber carbon distribution according to claim 1, it is characterised in that:Step(3)It is described High speed dispersor rotating speed be 3000~3300r/min, the high speed dispersion time be 13~15min.
5. a kind of method for removing automobile combustion chamber carbon distribution according to claim 1, it is characterised in that:Step(4)It is described Liquor potassic permanganate mass fraction be 20%, flow is 200~220mL/min when controlling hydro-peening, and hydro-peening continues 20~25min.
6. a kind of method for removing automobile combustion chamber carbon distribution according to claim 1, it is characterised in that:Step(5)It is described Heat temperature raising after temperature be 80~90 DEG C, the condensing reflux time is 12~13h, and phosphoric acid solution mass fraction is 80%, condensation Return time is 6~7h, and temperature is 400~450 DEG C after heat temperature raising in Muffle furnace, and calcination time is 4~5h.
7. a kind of method for removing automobile combustion chamber carbon distribution according to claim 1, it is characterised in that:Step(6)It is described Magnesium powder grain size be 50~80 μm, spray amount is 200~250mL, and control chamber temperature is 70~80 DEG C when heat preservation, when heat preservation Between be 30~35min.
CN201810543301.7A 2018-05-31 2018-05-31 A method of removing automobile combustion chamber carbon distribution Withdrawn CN108708787A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810543301.7A CN108708787A (en) 2018-05-31 2018-05-31 A method of removing automobile combustion chamber carbon distribution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810543301.7A CN108708787A (en) 2018-05-31 2018-05-31 A method of removing automobile combustion chamber carbon distribution

Publications (1)

Publication Number Publication Date
CN108708787A true CN108708787A (en) 2018-10-26

Family

ID=63869951

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810543301.7A Withdrawn CN108708787A (en) 2018-05-31 2018-05-31 A method of removing automobile combustion chamber carbon distribution

Country Status (1)

Country Link
CN (1) CN108708787A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109234743A (en) * 2018-11-28 2019-01-18 杨迪忠 A kind of automobile engine cleaning solution and preparation method thereof
CN113430071A (en) * 2021-05-27 2021-09-24 厦门筚路新材料科技有限公司 Carbon deposit cleaning composition for engine of fuel engine and use method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109234743A (en) * 2018-11-28 2019-01-18 杨迪忠 A kind of automobile engine cleaning solution and preparation method thereof
CN109234743B (en) * 2018-11-28 2020-12-08 博兴融智科技创新发展有限公司 Cleaning fluid for automobile engine and preparation method thereof
CN113430071A (en) * 2021-05-27 2021-09-24 厦门筚路新材料科技有限公司 Carbon deposit cleaning composition for engine of fuel engine and use method

Similar Documents

Publication Publication Date Title
CN108708787A (en) A method of removing automobile combustion chamber carbon distribution
CN102643688B (en) Nanometre fuel additive and preparation method for same
US5522905A (en) Diesel fuel containing an additive which improves the combustion of soot
CN108359504A (en) Low-carbon alcohols cleaning new energy fuel additive
CN111925844B (en) Efficient organic carbon removal repairing agent for piston ring
CN108841457A (en) A kind of carbon deposit cleaning agent for gasoline in-cylinder direct fuel-injection engine gas handling system
CN104745252B (en) The high activity composite modified additive of automotive methanol gasoline and preparation technology thereof
CN109735861B (en) Engine carbon deposition cleaning agent and preparation method thereof
CN1124885C (en) Method for treating gases to reduce nitrogen oxide emissions using catalytic composition based on silica and titanium oxide
CN101445751A (en) Non-shear-form environment-friendly and energy-saving watered procetane
CN102174701A (en) Carbon removing liquid avoiding trouble of dismounting automobile engine
CN106336925B (en) A kind of preparation method of fuel oil additive
CN110283670B (en) Special carbon deposition cleaning agent for three-way catalyst for direct injection engine
CN108659900A (en) Fuel system carbon distribution detersive, production technology and application
JPH07246365A (en) Formation of coating film on inside of combustion chamber of internal-combustion engine
CN103289762A (en) Gasoline cleaning agent
CN103758664B (en) A kind of front emission reduction system
Celik Examining combustion and emission characteristics of cotton methyl ester to which manganese additive material was added
CN103087791B (en) Bio-fuel oil energy saver and preparation method thereof
CN113005463A (en) Water-based carbon deposition cleaning agent for automobile three-way catalyst and preparation method thereof
CN106995733B (en) It is a kind of for improving the biomass-based additive preparation and application of diesel fuel characteristics
CN101255349A (en) Highly effective production technique of waste oil regenerative fuel oil
CN101864330B (en) Environment-friendly low-temperature starting agent
CN101333468A (en) Thermal value energizer of emulsified diesel oil
JP2005133720A (en) Method for reducing combustion chamber deposit peel-off

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20181026

WW01 Invention patent application withdrawn after publication