CN108707215A - A kind of ventilation wear-resistance polyurethane loomage coating adhesive - Google Patents
A kind of ventilation wear-resistance polyurethane loomage coating adhesive Download PDFInfo
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- CN108707215A CN108707215A CN201810378892.7A CN201810378892A CN108707215A CN 108707215 A CN108707215 A CN 108707215A CN 201810378892 A CN201810378892 A CN 201810378892A CN 108707215 A CN108707215 A CN 108707215A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4081—Mixtures of compounds of group C08G18/64 with other macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/83—Chemically modified polymers
- C08G18/837—Chemically modified polymers by silicon containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses a kind of ventilation wear-resistance polyurethane loomage coating adhesive, raw material includes：Modified polyurethane resin, thickener, antifoaming agent, curing agent, coalescents.Modified polyurethane resin is prepared using following technique：Polyoxypropyleneglycol, stannous octoate, isoflurane chalcone diisocyanate, carborane glycol are added in acetone and are uniformly mixed, prefabricated material A is made in heating stirring reaction；After aliphatic poly ketone resin is dissolved, the stirring that heats up is added in prefabricated material A with aminopropyl trimethoxysilane, modified polyurethane resin is made.The polyurethane loomage coating adhesive of the present invention, wear-resisting and permeability are excellent.
Description
Technical field
The present invention relates to fabric coating technical fields more particularly to a kind of ventilation wear-resistance to split polyurethane loomage coating adhesive.
Background technology
The coated technique of coating material is uniformly bonded in fabric surface, to increase the spies such as fabrics flame resistance, waterproof, windproof
Distinguished service energy improves appearance of fabrics and feel, improves fabric quality.Coating adhesive includes mainly by classification of chemical structure：Acrylate
Class, polyurethanes, polyvinyl chloride, organic silicon and synthetic rubber class, wherein urethane type coatings glue have nontoxic, safety collar
The characteristics of guarantor, fabric feeling is plentiful after coating, and elasticity is strong, and skin covering of the surface sense is good, is the emphasis direction studied at present.But polyurethane
The intensity of coating adhesive is low, not wear-resisting, and permeability is poor, cannot meet the needs of high quality fabric coating adhesive, limit polyurethane
The further development of coating adhesive industry.Therefore, how to prepare a kind of polyurethane coating glue that ventilation wear-resistance performance is good is at present urgently
Technical problem to be solved.
Invention content
Technical problems based on background technology, the present invention propose a kind of ventilation wear-resistance polyurethane loomage coating adhesive,
Intensity is high, and wear-resisting and permeability is excellent.
The present invention proposes that a kind of ventilation wear-resistance aqueous polyurethane fabric coating adhesive, raw material include by weight：It is modified poly-
80-120 parts of urethane resin, 1-3 parts of thickener, 0.2-1.0 parts of antifoaming agent, 1-4 parts of curing agent, 2-6 parts of coalescents.
Preferably, modified polyurethane resin is prepared using following technique：By polyoxypropyleneglycol, stannous octoate, different fluorine
It is uniformly mixed in your ketone diisocyanate, carborane glycol addition acetone, prefabricated material A is made in heating stirring reaction；By aliphatic
After polyketone resin dissolving, the stirring that heats up is added in prefabricated material A with aminopropyl trimethoxysilane, modified polyurethane resin is made.
Preferably, modified polyurethane resin is prepared using following technique：By polyoxypropyleneglycol, stannous octoate, different fluorine
Your ketone diisocyanate, carborane glycol are added in acetone after mixing, are heated to 72-78 DEG C and are stirred to react 1.5-2h being made
Prefabricated material A；After aliphatic poly ketone resin is dissolved, aminopropyl trimethoxysilane is added in prefabricated material A and is warming up to 90-100 DEG C
0.5-1.5h is stirred, modified polyurethane resin is made.
Preferably, modified polyurethane resin is prepared using following technique：By weight by 50-80 parts of two isocyanides of isophorone
Acid esters, 0.4-0.8 part stannous octoate, 25-35 parts of polyoxypropyleneglycols, 1-3 parts of carborane glycol are added in acetone and mix
After even, it is heated to 72-78 DEG C and is stirred to react 1.5-2h prefabricated material A is made；After 2-4 parts of aliphatic poly ketone resins are dissolved, same to 1-2
Part aminopropyl trimethoxysilane is added in prefabricated material A, is warming up to 90-100 DEG C of stirring 0.5-1.5h, modified polyurethane tree is made
Fat.
Preferably, curing agent is vinyl trimethylsilane and/or di-2-ethylhexylphosphine oxide hexamethylene alkanamine.
Preferably, thickener is agent for polyacrylic acid thickening and/or polyurethanes thickener.
Preferably, antifoaming agent is polyoxyethylene polyoxypropylene glycerin ether and/or dimethyl silicone polymer.
Preferably, coalescents are lauryl alcohol ester and/or propylene glycol methyl ether acetate.
Preferably, raw material includes by weight：90-110 parts of modified polyurethane resin, 1.5-2.5 parts of thickener, defoaming
0.4-0.8 parts of agent, 2-3 parts of curing agent, 3-5 parts of coalescents.
The present invention is using modified polyurethane resin as the base-material of polyurethane loomage coating adhesive, wherein with carborane glycol, ammonia third
Base trimethoxy silane and aliphatic poly ketone resin are that modified polyurethane resin is made in raw material, and carborane is introduced to point of polyurethane
In subchain, polyurethane resin film-strength and toughness can be significantly improved, aminopropyl trimethoxysilane activity is high, can increase fat
The intermolecular interaction of fat adoption ketone resin and polyurethane resin, improves adhesive force, and aliphatic poly ketone resin can form intensity
High, microporous membrane, can improve the wearability and permeability of polyurethane resin.Curing agent in the present invention can promote to be modified
Polyurethane resin and its crosslinked action between fabric fibre improve the wear-resisting property of polyurethane loomage coating adhesive；Coalescents
Modified polyurethane resin can be promoted in fabric surface fast filming, improve polyurethane loomage coating glued membrane compactness, further
Improve wear-resisting property；Thickener and antifoaming agent can adjust the viscosity of modified polyurethane coating glue, reduce bubble, improve polyurethane
The physicochemical property of coating adhesive.The present invention using modified polyurethane resin, thickener, antifoaming agent, curing agent, coalescents as raw material,
Cooperate composition polyurethane loomage coating adhesive, and intensity is high, and wearability and permeability are excellent, and performance is stablized.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of ventilation wear-resistance polyurethane loomage coating adhesive, raw material include by weight：80 parts of modified polyurethane resin gathers
1 part of acrylic thickener, 0.2 part of polyoxyethylene polyoxypropylene glycerin ether, 1 part of vinyl trimethylsilane, lauryl alcohol ester 2
Part.
Modified polyurethane resin is prepared using following technique：By weight by 50 parts of isoflurane chalcone diisocyanates, 0.4 part
Stannous octoate, 25 parts of polyoxypropyleneglycols, 1 part of carborane glycol are added in acetone after mixing, are heated to 72 DEG C of stirrings
Prefabricated material A is made in reaction 1.5h；After 2 parts of aliphatic poly ketone resins are dissolved, it is added with 1 part of aminopropyl trimethoxysilane prefabricated
Expect in A, is warming up to 90 DEG C of stirring 0.5h, modified polyurethane resin is made.
Embodiment 2
A kind of ventilation wear-resistance polyurethane loomage coating adhesive, raw material include by weight：120 parts of modified polyurethane resin,
3 parts of polyurethanes thickener, 1.0 parts of dimethyl silicone polymer, 4 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, propylene glycol methyl ether acetate 6
Part.
Modified polyurethane resin is prepared using following technique：By weight by 80 parts of isoflurane chalcone diisocyanates, 0.8 part
Stannous octoate, 35 parts of polyoxypropyleneglycols, 3 parts of carborane glycol are added in acetone after mixing, are heated to 78 DEG C of stirrings
Prefabricated material A is made in reaction 2h；After 4 parts of aliphatic poly ketone resins are dissolved, prefabricated material is added with 2 parts of aminopropyl trimethoxysilanes
In A, 100 DEG C of stirring 1.5h are warming up to, modified polyurethane resin is made.
Embodiment 3
A kind of ventilation wear-resistance polyurethane loomage coating adhesive, raw material include by weight：90 parts of modified polyurethane resin gathers
1.5 parts of acrylic thickener, 0.4 part of polyoxyethylene polyoxypropylene glycerin ether, 2 parts of vinyl trimethylsilane, lauryl alcohol ester 3
Part.
Modified polyurethane resin is prepared using following technique：By weight by 60 parts of isoflurane chalcone diisocyanates, 0.6 part
Stannous octoate, 28 parts of polyoxypropyleneglycols, 1.5 parts of carborane glycol are added in acetone after mixing, are heated to 74 DEG C and stir
It mixes reaction 1.6h and prefabricated material A is made；After 2.5 parts of aliphatic poly ketone resins are dissolved, add with 1.4 parts of aminopropyl trimethoxysilanes
Enter in prefabricated material A, is warming up to 94 DEG C of stirring 0.8h, modified polyurethane resin is made.
Embodiment 4
A kind of ventilation wear-resistance polyurethane loomage coating adhesive, raw material include by weight：110 parts of modified polyurethane resin,
2.5 parts of polyurethanes thickener, 0.8 part of dimethyl silicone polymer, 3 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, propylene glycol methyl ether acetate 5
Part.
Modified polyurethane resin is prepared using following technique：By weight by 70 parts of isoflurane chalcone diisocyanates, 0.7 part
Stannous octoate, 32 parts of polyoxypropyleneglycols, 2.5 parts of carborane glycol are added in acetone after mixing, are heated to 76 DEG C and stir
It mixes reaction 1.8h and prefabricated material A is made；After 3.5 parts of aliphatic poly ketone resins are dissolved, add with 1.8 parts of aminopropyl trimethoxysilanes
Enter in prefabricated material A, is warming up to 97 DEG C of stirring 1.2h, modified polyurethane resin is made.
The ventilation wear-resistance polyurethane loomage coating adhesive of embodiment 1-4 is coated on fabric surface, according to standard GB/T1768-
79 and GB/T5453-1997 tests wear-resisting and permeability, test data such as the following table 1.
Table 1
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Wear-resisting (750g/500r, weightless, g) | ≤0.015 | ≤0.015 | ≤0.015 | ≤0.015 |
| Air penetrability (cm3/cm2/s) | 0.54 | 0.52 | 0.53 | 0.55 |
Wear-resisting property and the permeability that can be seen that the polyurethane coating glue of the present invention by upper table data are excellent.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of ventilation wear-resistance polyurethane loomage coating adhesive, which is characterized in that its raw material includes by weight：Modified polyurethane tree
80-120 parts of fat, 1-3 parts of thickener, 0.2-1.0 parts of antifoaming agent, 1-4 parts of curing agent, 2-6 parts of coalescents.
2. ventilation wear-resistance polyurethane loomage coating adhesive according to claim 1, which is characterized in that modified polyurethane resin uses
It is prepared by following technique：Acetone is added in polyoxypropyleneglycol, stannous octoate, isoflurane chalcone diisocyanate, carborane glycol
In be uniformly mixed, heating stirring reaction be made prefabricated material A；After aliphatic poly ketone resin is dissolved, with aminopropyl trimethoxy silicon
The stirring that heats up is added in prefabricated material A in alkane, and modified polyurethane resin is made.
3. ventilation wear-resistance polyurethane loomage coating adhesive according to claim 2, which is characterized in that modified polyurethane resin uses
It is prepared by following technique：Acetone is added by polyoxypropyleneglycol, stannous octoate, isoflurane chalcone diisocyanate, carborane glycol
In after mixing, be heated to 72-78 DEG C and be stirred to react 1.5-2h prefabricated material A is made；After aliphatic poly ketone resin is dissolved, ammonia
Propyl trimethoxy silicane, which is added in prefabricated material A, is warming up to 90-100 DEG C of stirring 0.5-1.5h, and modified polyurethane resin is made.
4. according to ventilation wear-resistance polyurethane loomage coating adhesive described in Claims 2 or 3, which is characterized in that modified polyurethane resin
It is prepared using following technique：By weight by 50-80 parts of isoflurane chalcone diisocyanates, 0.4-0.8 parts of stannous octoates, 25-35
Part polyoxypropyleneglycol, 1-3 parts of carborane glycol are added in acetone after mixing, are heated to 72-78 DEG C and are stirred to react
Prefabricated material A is made in 1.5-2h；After 2-4 parts of aliphatic poly ketone resins are dissolved, it is added with 1-2 parts of aminopropyl trimethoxysilanes pre-
In system material A, it is warming up to 90-100 DEG C of stirring 0.5-1.5h, modified polyurethane resin is made.
5. according to any one of the claim 1-4 ventilation wear-resistance polyurethane loomage coating adhesives, which is characterized in that curing agent is second
Alkenyl trimethyl silane and/or di-2-ethylhexylphosphine oxide hexamethylene alkanamine.
6. according to any one of the claim 1-5 ventilation wear-resistance polyurethane loomage coating adhesives, which is characterized in that thickener is poly-
Acrylic thickener and/or polyurethanes thickener.
7. according to any one of the claim 1-6 ventilation wear-resistance polyurethane loomage coating adhesives, which is characterized in that antifoaming agent is poly-
Oxypropylene polyoxyethylene glycerol ether and/or dimethyl silicone polymer.
8. according to any one of the claim 1-7 ventilation wear-resistance polyurethane loomage coating adhesives, which is characterized in that coalescents are
Lauryl alcohol ester and/or propylene glycol methyl ether acetate.
9. according to any one of the claim 1-8 ventilation wear-resistance polyurethane loomage coating adhesives, which is characterized in that its raw material is by weight
Measuring part includes：90-110 parts of modified polyurethane resin, 1.5-2.5 parts of thickener, 0.4-0.8 parts of antifoaming agent, 2-3 parts of curing agent,
3-5 parts of coalescents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810378892.7A CN108707215A (en) | 2018-04-25 | 2018-04-25 | A kind of ventilation wear-resistance polyurethane loomage coating adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810378892.7A CN108707215A (en) | 2018-04-25 | 2018-04-25 | A kind of ventilation wear-resistance polyurethane loomage coating adhesive |
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|---|---|
| CN108707215A true CN108707215A (en) | 2018-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810378892.7A Withdrawn CN108707215A (en) | 2018-04-25 | 2018-04-25 | A kind of ventilation wear-resistance polyurethane loomage coating adhesive |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500244A (en) * | 2019-11-26 | 2020-08-07 | 华东理工大学 | High and low temperature resistant adhesive resin containing carborane and preparation method thereof |
| CN117447909A (en) * | 2023-12-26 | 2024-01-26 | 成都虹润制漆有限公司 | Moisture curing type anti-corrosion coating for wind and rain roof and preparation method thereof |
-
2018
- 2018-04-25 CN CN201810378892.7A patent/CN108707215A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500244A (en) * | 2019-11-26 | 2020-08-07 | 华东理工大学 | High and low temperature resistant adhesive resin containing carborane and preparation method thereof |
| CN117447909A (en) * | 2023-12-26 | 2024-01-26 | 成都虹润制漆有限公司 | Moisture curing type anti-corrosion coating for wind and rain roof and preparation method thereof |
| CN117447909B (en) * | 2023-12-26 | 2024-03-12 | 成都虹润制漆有限公司 | Moisture curing type anti-corrosion coating for wind and rain roof and preparation method thereof |
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Application publication date: 20181026 |