CN108706981A - A kind of ceramic green body reinforcing agent increasing slurry mobility - Google Patents

A kind of ceramic green body reinforcing agent increasing slurry mobility Download PDF

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Publication number
CN108706981A
CN108706981A CN201810693482.1A CN201810693482A CN108706981A CN 108706981 A CN108706981 A CN 108706981A CN 201810693482 A CN201810693482 A CN 201810693482A CN 108706981 A CN108706981 A CN 108706981A
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green body
parts
reinforcing agent
water
ceramic green
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卢群海
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Jieshou Dongcheng Group Sea Painted Pottery Studio
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Jieshou Dongcheng Group Sea Painted Pottery Studio
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • C04B35/6306Binders based on phosphoric acids or phosphates
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • CCHEMISTRY; METALLURGY
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • C04B35/634Polymers
    • C04B35/63448Polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes

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  • Engineering & Computer Science (AREA)
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Abstract

The invention belongs to ceramic body technical fields, and in particular to a kind of ceramic green body reinforcing agent increasing slurry mobility, including following raw material:Polyethylene glycol-polycaprolactone, sodium acid pyrophosphate, onion essential oil, inorganic bond, conditioning agent, water.The present invention has the following advantages compared with prior art:Reinforcing agent can increase the mobility of slurry by rational proportion and processing in the present invention, enhance the binding performance of powder, and the addition of conditioning agent helps to improve rate of drying of the green body in kiln and firing speed, shortens the production time;Onion essential oil helps to make to crosslink in reinforcing agent and green body particle, form the three-dimensional crosslinked network structure of stable structure, and then improve the green strength of green body, sodium acid pyrophosphate can avoid viscosity from increasing considerably with conditioning agent mating reaction, the dispersibility for ensureing green body, avoids the occurrence of green body crackle, the delicate defect in corner;It also can help to combining closely for glaze layer and green body simultaneously, increase durability.

Description

A kind of ceramic green body reinforcing agent increasing slurry mobility
Technical field
The invention belongs to ceramic body technical fields, and in particular to a kind of ceramic body enhancing increasing slurry mobility Agent.
Background technology
With the growing tension of traditional energy, scientific and technical development and ceramic process is continuously improved, promotes to make pottery The production of porcelain develops to high-performance, low energy consumption, inexpensive direction, and ceramic primary raw material tonerde resource increasingly depleted is being made pottery In the production of porcelain, the dosage of tonerde is gradually decreased, poor material usage amount gradually increases, and it is strong to be susceptible to ceramic blank drying Degree declines, it may appear that crackle, lacks many defects such as side at the angle of rupture, and yield rate is relatively low, influences the large-scale production of ceramics, existing skill By the way that carboxymethyl cellulose, polyvinyl alcohol material enhancing ceramics strength is added in art, drawbacks described above is overcome, but reinforcing agent meeting is added Increase the viscosity of blank slurry, therefore, it is necessary to further Improvements.
Invention content
The purpose of the present invention is for existing problem, provide a kind of ceramic body enhancing increasing slurry mobility Agent.
The present invention is achieved by the following technical solutions:A kind of ceramic green body reinforcing agent increasing slurry mobility, packet Include the raw material of following parts by weight:12-16 parts of polyethylene glycol-polycaprolactone, 1.2-1.5 parts of sodium acid pyrophosphate, onion essential oil 3.4-4.6 parts, 2-3 parts of inorganic bond, 1-2 parts of conditioning agent, 100-120 parts of water;
The inorganic bond is the water glass solution that mass concentration is 16-20%;
The conditioning agent includes the raw material of following parts by weight:26-28 parts of Hyperbranched Polymer with Terminal Amido, 1-2 parts of cerous nitrate, boric acid 0.2-0.8 parts of copper, 1-3 parts of hexamethylphosphoramide.
As further improvement of these options, active constituent content is 96.5-100% in the sodium acid pyrophosphate, PH value is 3.8-4.2.
As further improvement of these options, the preparation method of the onion essential oil is:By the onion peeling of acquisition Shredded after removing root, be added with the water of its equivalent, be kept in dark place 2-3 hour after broken homogenate, then through filter, isolate filtrate and Residue;By gained filtrate and petroleum ether with weight ratio 1:2 mixing extract 3 hours, separation water outlet after the completion in 35 DEG C of water-bath Layer and oil reservoir distill under conditions of temperature is 55-65 DEG C, obtain onion essential oil.
As further improvement of these options, the modulus of the waterglass is 1.0-1.6.
As further improvement of these options, the preparation method of the Hyperbranched Polymer with Terminal Amido is, by N, N- Methylene-bisacrylamide is with diethylenetriamine with weight ratio 1:1.5 mixing, are heated to 65-75 DEG C, are stirred to react 30- in water 40 minutes to obtain the final product.
As further improvement of these options, the preparation method of the conditioning agent is, in temperature after each raw material is mixed Degree stirs 30 minutes to be 400-600 revs/min under 80 DEG C of water bath conditions with rotating speed, is then allowed to stand 10 minutes, dry to aqueous Amount is less than 10% to obtain the final product.
As further improvement of these options, the additive amount of the reinforcing agent is the 0.1- of ceramic body dry weight 0.3%;Addition opportunity is addition in 10 minutes before the complete ball to be gone out of ceramic body butt ball milling, continues ball milling 10 minutes.
The present invention has the following advantages compared with prior art:Reinforcing agent, can by rational proportion and processing in the present invention The mobility for increasing slurry, enhances the binding performance of powder, the addition of conditioning agent helps to improve drying of the green body in kiln Speed and firing speed, shorten the production time;Onion essential oil helps to make to crosslink in reinforcing agent and green body particle, forms knot The three-dimensional crosslinked network structure that structure is stablized, and then the green strength of green body is improved, sodium acid pyrophosphate and conditioning agent mating reaction Viscosity can be avoided to increase considerably, ensure the dispersibility of green body, avoid the occurrence of green body crackle, the delicate defect in corner;Simultaneously Combining closely for glaze layer and green body is also can help to, durability is increased.
Specific implementation mode
Embodiment 1
A kind of ceramic green body reinforcing agent increasing slurry mobility, includes the raw material of following parts by weight:Polyethylene glycol-polycaprolactone 14 parts, 1.3 parts of sodium acid pyrophosphate, 3.9 parts of onion essential oil, 2.5 parts of inorganic bond, 1.5 parts of conditioning agent, 110 parts of water;
The inorganic bond is the water glass solution that mass concentration is 18%;
The conditioning agent includes the raw material of following parts by weight:27 parts of Hyperbranched Polymer with Terminal Amido, 1.5 parts of cerous nitrate, copper borate 0.5 part, 2 parts of hexamethylphosphoramide.
Wherein, active constituent content is 96.5-100%, pH value 3.8-4.2 in the sodium acid pyrophosphate;The water glass The modulus of glass is 1.0-1.6.
Wherein, the preparation method of the onion essential oil is:It shreds, is added and its equivalent after root is removed in the onion peeling of acquisition Water, be kept in dark place 2.5 hours after broken homogenate, then through filtering, isolating filtrate and residue;By gained filtrate and petroleum ether With weight ratio 1:2 mixing extract 3 hours in 35 DEG C of water-bath, detach water-yielding stratum and oil reservoir after the completion, are 60 DEG C in temperature Under the conditions of distill, obtain onion essential oil.
Wherein, the preparation method of the Hyperbranched Polymer with Terminal Amido is, by N, N- methylene-bisacrylamides and diethyl Alkene triamine is with weight ratio 1:1.5 mixing, are heated to 70 DEG C, are stirred to react 35 minutes in water to obtain the final product.
Wherein, the preparation method of the conditioning agent is, in the case where temperature is 80 DEG C of water bath conditions to turn after each raw material is mixed Speed stirs 30 minutes for 500 revs/min, is then allowed to stand 10 minutes, and drying to water content is less than 10% to obtain the final product.
Wherein, the additive amount of the reinforcing agent is the 0.2% of ceramic body dry weight;Addition opportunity is ceramic blank soma It is added within 10 minutes before the complete ball to be gone out of base ball milling, continues ball milling 10 minutes.
Embodiment 2
A kind of ceramic green body reinforcing agent increasing slurry mobility, includes the raw material of following parts by weight:Polyethylene glycol-polycaprolactone 12 parts, 1.5 parts of sodium acid pyrophosphate, 3.4 parts of onion essential oil, 3 parts of inorganic bond, 1 part of conditioning agent, 120 parts of water;
The inorganic bond is the water glass solution that mass concentration is 16%;
The conditioning agent includes the raw material of following parts by weight:28 parts of Hyperbranched Polymer with Terminal Amido, 2 parts of cerous nitrate, copper borate 0.8 Part, 3 parts of hexamethylphosphoramide.
Wherein, active constituent content is 96.5-100%, pH value 3.8-4.2 in the sodium acid pyrophosphate;The water glass The modulus of glass is 1.0-1.6.
Wherein, the preparation method of the onion essential oil is:It shreds, is added and its equivalent after root is removed in the onion peeling of acquisition Water, be kept in dark place 2 hours after broken homogenate, then through filtering, isolating filtrate and residue;By gained filtrate and petroleum ether with Weight ratio 1:2 mixing extract 3 hours in 35 DEG C of water-bath, detach water-yielding stratum and oil reservoir after the completion, the item for being 65 DEG C in temperature It is distilled under part, obtains onion essential oil.
Wherein, the preparation method of the Hyperbranched Polymer with Terminal Amido is, by N, N- methylene-bisacrylamides and diethyl Alkene triamine is with weight ratio 1:1.5 mixing, are heated to 75 DEG C, are stirred to react 40 minutes in water to obtain the final product.
Wherein, the preparation method of the conditioning agent is, in the case where temperature is 80 DEG C of water bath conditions to turn after each raw material is mixed Speed stirs 30 minutes for 600 revs/min, is then allowed to stand 10 minutes, and drying to water content is less than 10% to obtain the final product.
Wherein, the additive amount of the reinforcing agent is the 0.3% of ceramic body dry weight;Addition opportunity is ceramic blank soma It is added within 10 minutes before the complete ball to be gone out of base ball milling, continues ball milling 10 minutes.
Embodiment 3
A kind of ceramic green body reinforcing agent increasing slurry mobility, includes the raw material of following parts by weight:Polyethylene glycol-polycaprolactone 16 parts, 1.2 parts of sodium acid pyrophosphate, 4.6 parts of onion essential oil, 2 parts of inorganic bond, 2 parts of conditioning agent, 100 parts of water;
The inorganic bond is the water glass solution that mass concentration is 20%;
The conditioning agent includes the raw material of following parts by weight:26 parts of Hyperbranched Polymer with Terminal Amido, 1 part of cerous nitrate, copper borate 0.2 Part, 1 part of hexamethylphosphoramide.
Wherein, active constituent content is 96.5-100%, pH value 3.8-4.2 in the sodium acid pyrophosphate;The water glass The modulus of glass is 1.0-1.6.
Wherein, the preparation method of the onion essential oil is:It shreds, is added and its equivalent after root is removed in the onion peeling of acquisition Water, be kept in dark place 3 hours after broken homogenate, then through filtering, isolating filtrate and residue;By gained filtrate and petroleum ether with Weight ratio 1:2 mixing extract 3 hours in 35 DEG C of water-bath, detach water-yielding stratum and oil reservoir after the completion, the item for being 55 DEG C in temperature It is distilled under part, obtains onion essential oil.
Wherein, the preparation method of the Hyperbranched Polymer with Terminal Amido is, by N, N- methylene-bisacrylamides and diethyl Alkene triamine is with weight ratio 1:1.5 mixing, are heated to 75 DEG C, are stirred to react 30 minutes in water to obtain the final product.
Wherein, the preparation method of the conditioning agent is, in the case where temperature is 80 DEG C of water bath conditions to turn after each raw material is mixed Speed stirs 30 minutes for 400 revs/min, is then allowed to stand 10 minutes, and drying to water content is less than 10% to obtain the final product.
Wherein, the additive amount of the reinforcing agent is the 0.1% of ceramic body dry weight;Addition opportunity is ceramic blank soma It is added within 10 minutes before the complete ball to be gone out of base ball milling, continues ball milling 10 minutes.
Control group 1 is set, onion essential oil in embodiment 1 is removed, remaining content is constant;Control group 2 is set, by embodiment Sodium acid pyrophosphate is substituted for sodium pyrophosphate in 1, remaining content is constant;Control group 3 is set, conditioning agent in embodiment 1 is removed, Remaining content is constant;Control group 4, reference are set《The preparation of composite body reinforcing agent and to Al2O3Slurry performance and green strength Influence》(The works such as Li Miao)(Hereafter use《It is multiple》Instead of)The composite fortifier CRA of middle offer, additive amount are green body weight 0.6%;
It utilizes《It is multiple》The preparation of middle 1.2.2 ceramic slurries and mobile performance test method detection and 1.2.3 in ceramic green try The preparation of sample and fracture resistance test method detect influence of each group reinforcing agent to green strength and the shadow to slurry mobility It rings, obtains following result:
Table 1
Group Green strength(MPa) Mobility(s)
Embodiment 1 1.92 8.2
Embodiment 2 1.96 7.9
Embodiment 3 1.93 8.2
Control group 1 1.47 12.4
Control group 2 1.79 9.3
Control group 3 1.62 9.7
Control group 4 1.84 8.5
As data in table 1 can be seen that in the present invention obtained by reinforcing agent additive amount it is 4 few compared to the control group, and reached and its Similar even preferably technique effect adjusts reinforcing agent composition of raw materials, can be had an impact to blank performance.

Claims (7)

1. a kind of ceramic green body reinforcing agent increasing slurry mobility, which is characterized in that include the raw material of following parts by weight:Poly- second Glycol -12-16 parts of polycaprolactone, 1.2-1.5 parts of sodium acid pyrophosphate, 3.4-4.6 parts of onion essential oil, 2-3 parts of inorganic bond, 1-2 parts of conditioning agent, 100-120 parts of water;
The inorganic bond is the water glass solution that mass concentration is 16-20%;
The conditioning agent includes the raw material of following parts by weight:26-28 parts of Hyperbranched Polymer with Terminal Amido, 1-2 parts of cerous nitrate, boric acid 0.2-0.8 parts of copper, 1-3 parts of hexamethylphosphoramide.
2. a kind of ceramic green body reinforcing agent increasing slurry mobility as described in claim 1, which is characterized in that the acid is burnt Active constituent content is 96.5-100%, pH value 3.8-4.2 in sodium phosphate.
3. a kind of ceramic green body reinforcing agent increasing slurry mobility as described in claim 1, which is characterized in that the onion precision Oil preparation method be:It is shredded after root is removed in the onion peeling of acquisition, the water with its equivalent is added, is kept in dark place after broken homogenate 2-3 hours, then through filtering, isolating filtrate and residue;By gained filtrate and petroleum ether with weight ratio 1:2 mixing, at 35 DEG C Water-bath in extract 3 hours, detach water-yielding stratum and oil reservoir after the completion, distilled under conditions of temperature is 55-65 DEG C, obtain onion Essential oil.
4. a kind of ceramic green body reinforcing agent increasing slurry mobility as described in claim 1, which is characterized in that the waterglass Modulus be 1.0-1.6.
5. a kind of ceramic green body reinforcing agent increasing slurry mobility as described in claim 1, which is characterized in that the Amino End Group The preparation method of dissaving polymer is that, by N, N- methylene-bisacrylamides are with diethylenetriamine with weight ratio 1:1.5 mixing, It is heated to 65-75 DEG C in water, is stirred to react 30-40 minutes to obtain the final product.
6. a kind of ceramic green body reinforcing agent increasing slurry mobility as described in claim 1, which is characterized in that the conditioning agent Preparation method be, by each raw material mix after in the case where temperature is 80 DEG C of water bath conditions with rotating speed be 400-600 revs/min stirring 30 Minute, it is then allowed to stand 10 minutes, drying to water content is less than 10% to obtain the final product.
7. a kind of ceramic green body reinforcing agent increasing slurry mobility as described in claim 1, which is characterized in that the reinforcing agent Additive amount be ceramic body dry weight 0.1-0.3%;Addition opportunity is 10 points before the complete ball to be gone out of ceramic body butt ball milling Clock is added, and continues ball milling 10 minutes.
CN201810693482.1A 2018-06-29 2018-06-29 A kind of ceramic green body reinforcing agent increasing slurry mobility Pending CN108706981A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109400111A (en) * 2018-11-14 2019-03-01 王远川 A kind of sanitary ware cooling blender and its application method

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1213357A (en) * 1996-01-18 1999-04-07 东陶机器株式会社 Ceramic whiteware, ceramic body, processes for producing these, sanitary ware and process for producing the sanitary ware
CN1702160A (en) * 2004-05-24 2005-11-30 中国农业大学 Method for extracting onion essential oil
US20100212549A1 (en) * 2003-08-01 2010-08-26 Aalborg Universitet Method for preparing materials containing binder systems derived from amorphous silica and bases
CN102351518A (en) * 2011-06-17 2012-02-15 德化县顺尔美工艺品有限公司 Ceramic blank
CN102584253A (en) * 2012-02-15 2012-07-18 广东道氏技术股份有限公司 Ceramic green body reinforcing agent and application thereof
CN104529479A (en) * 2014-12-10 2015-04-22 景德镇陶瓷学院 Preparation method of novel high-efficiency ceramic blank reinforcer, product prepared by method and application of product
CN106046275A (en) * 2016-07-15 2016-10-26 李碧钗 Ceramic water reducer with blank strengthening effect and preparation method thereof
CN107382289A (en) * 2017-08-17 2017-11-24 徐欣怡 Ceramic body and its preparation method and application

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1213357A (en) * 1996-01-18 1999-04-07 东陶机器株式会社 Ceramic whiteware, ceramic body, processes for producing these, sanitary ware and process for producing the sanitary ware
US20100212549A1 (en) * 2003-08-01 2010-08-26 Aalborg Universitet Method for preparing materials containing binder systems derived from amorphous silica and bases
CN1702160A (en) * 2004-05-24 2005-11-30 中国农业大学 Method for extracting onion essential oil
CN102351518A (en) * 2011-06-17 2012-02-15 德化县顺尔美工艺品有限公司 Ceramic blank
CN102584253A (en) * 2012-02-15 2012-07-18 广东道氏技术股份有限公司 Ceramic green body reinforcing agent and application thereof
CN104529479A (en) * 2014-12-10 2015-04-22 景德镇陶瓷学院 Preparation method of novel high-efficiency ceramic blank reinforcer, product prepared by method and application of product
CN106046275A (en) * 2016-07-15 2016-10-26 李碧钗 Ceramic water reducer with blank strengthening effect and preparation method thereof
CN107382289A (en) * 2017-08-17 2017-11-24 徐欣怡 Ceramic body and its preparation method and application

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109400111A (en) * 2018-11-14 2019-03-01 王远川 A kind of sanitary ware cooling blender and its application method
CN109400111B (en) * 2018-11-14 2021-07-13 王远川 Sanitary ware cooling blender and using method thereof

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Application publication date: 20181026