CN108706947A - A kind of special antifreeze environment-friendly type water mud of roadbed stone - Google Patents

A kind of special antifreeze environment-friendly type water mud of roadbed stone Download PDF

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Publication number
CN108706947A
CN108706947A CN201810375906.XA CN201810375906A CN108706947A CN 108706947 A CN108706947 A CN 108706947A CN 201810375906 A CN201810375906 A CN 201810375906A CN 108706947 A CN108706947 A CN 108706947A
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China
Prior art keywords
parts
account
clay
stone
accounts
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CN201810375906.XA
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Chinese (zh)
Inventor
赵亮亮
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Linquan County Kai Sheng Construction Engineering Co Ltd
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Linquan County Kai Sheng Construction Engineering Co Ltd
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Priority to CN201810375906.XA priority Critical patent/CN108706947A/en
Publication of CN108706947A publication Critical patent/CN108706947A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of special antifreeze environment-friendly type water mud of roadbed stone, are made of following raw material according to parts by weight:Clay accounts for 10-20 parts,Activated carbon accounts for 10-15 parts,Discarded 20-30 parts of crushed stone concrete,1-4 parts of calcium formate,3-9 parts of vessel slag,1-5 parts of organic polymer,Swelling agent accounts for 5-9 parts,2-6 parts of sodium metasilicate,2-9 parts of antifoaming agent,3-8 parts of titanium dioxide,3-7 parts of shraff,3-8 parts of active carbon powder,Clay accounts for 2-6 parts,Maleic anhydride accounts for 1-6 parts,3-7 parts of mullite fiber,3-8 parts of stabilizer,8-15 parts of metakaolin,2-6 parts of superfine spherical extra material,2-7 parts of metasilicate pentahydrate sodium,7-12 parts of lime stone,3-8 parts of potassium dihydrogen phosphate,3-9 parts of glass fibre,7-10 parts of straw,3-7 parts of boron carbide fibre,3-8 parts of fluorgypsum,Triethanolamine accounts for 6-10 parts and 3-7 parts of tetra calcium aluminoferrite.The cement mortar of the present invention can significantly improve the cohesive force of cement mortar;With superfine impermeability, crack resistance, impact resistance;High-low temperature resistant, alkaline resistance properties are good;The advantages that nontoxic, harmless, pollution-free.

Description

A kind of special antifreeze environment-friendly type water mud of roadbed stone
Technical field
The present invention relates to road and bridges to build correlative technology field more particularly to a kind of special antifreeze environment-friendly type water of roadbed stone Mud.
Background technology
Cement mortar is the working solution used in well cementation, and the function of cement mortar is well cementation.Well cementing operation is from casing to the borehole wall Cement mortar is injected with the annular space of casing and is allowed on it and returns to certain altitude, and cement mortar subsequently becomes Behavior of Hardened Cement Paste and consolidates the borehole wall and casing Knot gets up.
In petroleum drilling engineering, with going deep into for exploration and development, drilling depth is deepened, and needs the stratum of sealing more multiple It is miscellaneous.Such as the development of its medium and deep limestone of Tarim Basin, dolomite stratum fracture hole, formation pore pressure is low, and drilling well and well cementation are easy It misses, dolomite fracture hole type interval reservoir protection requires height, leak stopping difficulty big, it is difficult to it is effectively blocked, it can not Meet conventional cementing execution conditions.In addition, casing tripping in is deep, bottom hole temperature (BHT) is high, and cement strength is easy to happen decaying.
Cement mortar used at present takes floating bead to be formulated plus micro- silicon mostly, uses floating bead as main lightening material, Micro- silicon has big density adjustable extent, with good stability, mobility and certain thixotroping as packing material, the system Property, the advantages that fluid loss is low and early strength is high, leakage and its protection to oil-gas Layer can be effectively prevented.But for well depth, Bottom pressure is high, has been not suitable with deep well pressure requirement.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of roadbed stone proposed is special antifreeze Environment-friendly type water mud.
To achieve the goals above, present invention employs following technical solutions:
A kind of special antifreeze environment-friendly type water mud of roadbed stone, is made of according to parts by weight following raw material:Clay accounts for 10-20 parts, lives Property charcoal account for 10-15 parts, discarded 20-30 parts of crushed stone concrete, 1-4 parts of calcium formate, 3-9 parts of vessel slag, 1-5 parts of organic polymer, Swelling agent account for 5-9 parts, 2-6 parts of sodium metasilicate, 2-9 parts of antifoaming agent, 3-8 parts of titanium dioxide, 3-7 parts of shraff, active carbon powder 3-8 parts, clay account for 2-6 parts, maleic anhydride account for 1-6 parts, 3-7 parts of mullite fiber, 3-8 parts of stabilizer, 8-15 parts of metakaolin, 2-6 parts of superfine spherical extra material, 2-7 parts of metasilicate pentahydrate sodium, 7-12 parts of lime stone, 3-8 parts of potassium dihydrogen phosphate, glass fibre 3- 9 parts, 7-10 parts of straw, 3-7 parts of boron carbide fibre, 3-8 parts of fluorgypsum, triethanolamine account for 6-10 parts and 3-7 parts of tetra calcium aluminoferrite.
A kind of special antifreeze environment-friendly type water mud of above-mentioned roadbed stone, is made of according to parts by weight following raw material:Clay accounts for 10-19 parts, activated carbon account for 10-14 parts, discarded 20-29 parts of crushed stone concrete, 1-3 parts of calcium formate, 3-8 parts of vessel slag, You Jiju Close 1-4 parts of object, swelling agent account for 5-8 parts, 2-5 parts of sodium metasilicate, 2-8 parts of antifoaming agent, 3-7 parts of titanium dioxide, 3-6 parts of shraff, 3-7 parts of active carbon powder, clay account for 2-5 parts, maleic anhydride account for 1-5 parts, it is 3-6 parts of mullite fiber, 3-7 parts of stabilizer, higher Soil 8-14 parts of ridge, 2-5 parts of superfine spherical extra material, 2-6 parts of metasilicate pentahydrate sodium, 7-11 parts of lime stone, potassium dihydrogen phosphate 3-7 Part, 3-8 parts of glass fibre, 7-9 parts of straw, 3-6 parts of boron carbide fibre, 3-7 parts of fluorgypsum, triethanolamine account for 6-9 parts and iron aluminium Sour 3-6 parts of four calcium.
A kind of special antifreeze environment-friendly type water mud of above-mentioned roadbed stone, is made of according to parts by weight following raw material:Clay accounts for 11-19 parts, activated carbon account for 11-14 parts, discarded 21-29 parts of crushed stone concrete, 2-3 parts of calcium formate, 4-8 parts of vessel slag, You Jiju Close 2-4 parts of object, swelling agent account for 6-8 parts, 3-5 parts of sodium metasilicate, 3-8 parts of antifoaming agent, 4-7 parts of titanium dioxide, 4-6 parts of shraff, 4-7 parts of active carbon powder, clay account for 3-5 parts, maleic anhydride account for 2-5 parts, it is 4-6 parts of mullite fiber, 4-7 parts of stabilizer, higher Soil 9-14 parts of ridge, 3-5 parts of superfine spherical extra material, 3-6 parts of metasilicate pentahydrate sodium, 8-11 parts of lime stone, potassium dihydrogen phosphate 4-7 Part, 4-8 parts of glass fibre, 8-9 parts of straw, 4-6 parts of boron carbide fibre, 4-7 parts of fluorgypsum, triethanolamine account for 7-9 parts and iron aluminium Sour 4-6 parts of four calcium.
A kind of special antifreeze environment-friendly type water mud of above-mentioned roadbed stone, is made of according to parts by weight following raw material:Clay accounts for 15 parts, activated carbon account for 12.5 parts, it is discarded 25 parts of crushed stone concrete, 2.5 parts of calcium formate, 6 parts of vessel slag, 3 parts of organic polymer, swollen Swollen dose accounts for 7 parts, 4 parts of sodium metasilicate, 5.5 parts of antifoaming agent, 5.5 parts of titanium dioxide, 5 parts of shraff, 5.5 parts of active carbon powder, glues Soil accounts for 4 parts, maleic anhydride accounts for 3.5 parts, 5 parts of mullite fiber, 5.5 parts of stabilizer, 11.5 parts of metakaolin, mixes outside superfine spherical 4 parts of material, 4.5 parts of metasilicate pentahydrate sodium, 9.5 parts of lime stone, 5.5 parts of potassium dihydrogen phosphate, 6 parts of glass fibre, 8.5 parts of straw, carbon Change 5 parts of boron fibre, 5.5 parts of fluorgypsum, triethanolamine and accounts for 8 parts and 5 parts of tetra calcium aluminoferrite.
Compared with prior art, beneficial effects of the present invention are:
A kind of special antifreeze environment-friendly type water mud of roadbed stone of the present invention can significantly improve the cohesive force of cement mortar;With extremely Excellent impermeability, crack resistance, impact resistance;High-low temperature resistant, alkaline resistance properties are good;The beneficial effect such as nontoxic, harmless, pollution-free Fruit.
Specific implementation mode
Embodiment 1
A kind of special antifreeze environment-friendly type water mud of roadbed stone, is made of according to parts by weight following raw material:Clay accounts for 10 parts, activated carbon Account for 10 parts, discarded 20 parts of crushed stone concrete, 1 part of calcium formate, 3 parts of vessel slag, 1 part of organic polymer, swelling agent account for 5 parts, silicic acid 2 parts of sodium, 2 parts of antifoaming agent, 3 parts of titanium dioxide, 3 parts of shraff, 3 parts of active carbon powder, clay account for 2 parts, maleic anhydride account for 1 Part, 3 parts of mullite fiber, 3 parts of stabilizer, 8 parts of metakaolin, 2 parts of superfine spherical extra material, 2 parts of metasilicate pentahydrate sodium, lime 7 parts of stone, 3 parts of potassium dihydrogen phosphate, 3 parts of glass fibre, 7 parts of straw, 3 parts of boron carbide fibre, 3 parts of fluorgypsum, triethanolamine account for 6 parts With 3 parts of tetra calcium aluminoferrite.
Embodiment 2
A kind of special antifreeze environment-friendly type water mud of above-mentioned roadbed stone, is made of according to parts by weight following raw material:Clay account for 20 parts, Activated carbon account for 15 parts, discarded 30 parts of crushed stone concrete, 4 parts of calcium formate, 9 parts of vessel slag, 5 parts of organic polymer, swelling agent account for 9 Part, 6 parts of sodium metasilicate, 9 parts of antifoaming agent, 8 parts of titanium dioxide, 7 parts of shraff, 8 parts of active carbon powder, clay account for 6 parts, Malaysia Acid anhydrides account for 6 parts, 7 parts of mullite fiber, 8 parts of stabilizer, 15 parts of metakaolin, 6 parts of superfine spherical extra material, metasilicate pentahydrate sodium 7 parts, 12 parts of lime stone, 8 parts of potassium dihydrogen phosphate, 9 parts of glass fibre, 10 parts of straw, 7 parts of boron carbide fibre, 8 parts of fluorgypsum, three Ethanol amine accounts for 10 parts and 7 parts of tetra calcium aluminoferrite.
Embodiment 3
A kind of special antifreeze environment-friendly type water mud of above-mentioned roadbed stone, is made of according to parts by weight following raw material:Clay account for 15 parts, Activated carbon accounts for 12.5 parts, discards 25 parts of crushed stone concrete, 2.5 parts of calcium formate, 6 parts of vessel slag, 3 parts of organic polymer, swelling agent Account for 7 parts, 4 parts of sodium metasilicate, 5.5 parts of antifoaming agent, 5.5 parts of titanium dioxide, 5 parts of shraff, 5.5 parts of active carbon powder, clay account for 4 parts, maleic anhydride account for 3.5 parts, 5 parts of mullite fiber, 5.5 parts of stabilizer, 11.5 parts of metakaolin, superfine spherical extra material 4 Part, 4.5 parts of metasilicate pentahydrate sodium, 9.5 parts of lime stone, 5.5 parts of potassium dihydrogen phosphate, 6 parts of glass fibre, 8.5 parts of straw, boron carbide 5 parts of fiber, 5.5 parts of fluorgypsum, triethanolamine account for 8 parts and 5 parts of tetra calcium aluminoferrite.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of special antifreeze environment-friendly type water mud of roadbed stone, which is characterized in that be made of following raw material according to parts by weight:Clay Account for 10-20 parts, activated carbon account for 10-15 parts, it is discarded 20-30 parts of crushed stone concrete, 1-4 parts of calcium formate, 3-9 parts of vessel slag, organic 1-5 parts of polymer, swelling agent account for 5-9 parts, 2-6 parts of sodium metasilicate, 2-9 parts of antifoaming agent, 3-8 parts of titanium dioxide, 3-7 parts of shraff , 3-8 parts of active carbon powder, clay account for 2-6 parts, maleic anhydride account for 1-6 parts, it is 3-7 parts of mullite fiber, 3-8 parts of stabilizer, higher Soil 8-15 parts of ridge, 2-6 parts of superfine spherical extra material, 2-7 parts of metasilicate pentahydrate sodium, 7-12 parts of lime stone, potassium dihydrogen phosphate 3-8 Part, 3-9 parts of glass fibre, 7-10 parts of straw, 3-7 parts of boron carbide fibre, 3-8 parts of fluorgypsum, triethanolamine account for 6-10 parts and iron 3-7 parts of four calcium of aluminic acid.
2. the special antifreeze environment-friendly type water mud of a kind of roadbed stone according to claim 1, which is characterized in that according to parts by weight It is made of following raw material:Clay account for 10-19 parts, activated carbon account for 10-14 parts, discarded 20-29 parts of crushed stone concrete, calcium formate 1-3 Part, 3-8 parts of vessel slag, 1-4 parts of organic polymer, swelling agent account for 5-8 parts, 2-5 parts of sodium metasilicate, 2-8 parts of antifoaming agent, titanium dioxide 3-7 parts, 3-6 parts of shraff, 3-7 parts of active carbon powder, clay account for 2-5 parts, maleic anhydride account for 1-5 parts, mullite fiber 3- 6 parts, 3-7 parts of stabilizer, 8-14 parts of metakaolin, 2-5 parts of superfine spherical extra material, 2-6 parts of metasilicate pentahydrate sodium, lime stone 7- 11 parts, 3-7 parts of potassium dihydrogen phosphate, 3-8 parts of glass fibre, 7-9 parts of straw, 3-6 parts of boron carbide fibre, 3-7 parts of fluorgypsum, three second Hydramine accounts for 6-9 parts and 3-6 parts of tetra calcium aluminoferrite.
3. the special antifreeze environment-friendly type water mud of a kind of roadbed stone according to claim 1, which is characterized in that according to parts by weight It is made of following raw material:Clay account for 11-19 parts, activated carbon account for 11-14 parts, discarded 21-29 parts of crushed stone concrete, calcium formate 2-3 Part, 4-8 parts of vessel slag, 2-4 parts of organic polymer, swelling agent account for 6-8 parts, 3-5 parts of sodium metasilicate, 3-8 parts of antifoaming agent, titanium dioxide 4-7 parts, 4-6 parts of shraff, 4-7 parts of active carbon powder, clay account for 3-5 parts, maleic anhydride account for 2-5 parts, mullite fiber 4- 6 parts, 4-7 parts of stabilizer, 9-14 parts of metakaolin, 3-5 parts of superfine spherical extra material, 3-6 parts of metasilicate pentahydrate sodium, lime stone 8- 11 parts, 4-7 parts of potassium dihydrogen phosphate, 4-8 parts of glass fibre, 8-9 parts of straw, 4-6 parts of boron carbide fibre, 4-7 parts of fluorgypsum, three second Hydramine accounts for 7-9 parts and 4-6 parts of tetra calcium aluminoferrite.
4. the special antifreeze environment-friendly type water mud of a kind of roadbed stone according to claim 1, which is characterized in that according to parts by weight It is made of following raw material:Clay account for 15 parts, activated carbon account for 12.5 parts, discarded 25 parts of crushed stone concrete, 2.5 parts of calcium formate, converter 6 parts of slag, 3 parts of organic polymer, swelling agent account for 7 parts, 4 parts of sodium metasilicate, 5.5 parts of antifoaming agent, 5.5 parts of titanium dioxide, shraff 5 Part, 5.5 parts of active carbon powder, clay account for 4 parts, maleic anhydride account for 3.5 parts, it is 5 parts of mullite fiber, 5.5 parts of stabilizer, higher 11.5 parts of ridge soil, 4 parts of superfine spherical extra material, 4.5 parts of metasilicate pentahydrate sodium, 9.5 parts of lime stone, 5.5 parts of potassium dihydrogen phosphate, glass 6 parts of glass fiber, 8.5 parts of straw, 5 parts of boron carbide fibre, 5.5 parts of fluorgypsum, triethanolamine account for 8 parts and 5 parts of tetra calcium aluminoferrite.
CN201810375906.XA 2018-04-25 2018-04-25 A kind of special antifreeze environment-friendly type water mud of roadbed stone Withdrawn CN108706947A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110482967A (en) * 2019-09-27 2019-11-22 安徽虹达道路桥梁工程有限公司 A kind of road and bridge cement

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Publication number Priority date Publication date Assignee Title
RU2169828C1 (en) * 1999-11-22 2001-06-27 Острягин Анатолий Иванович Aerated cement mortar composition
CN101182139A (en) * 2007-11-12 2008-05-21 华南理工大学 Masonry cement having higher strength and water retention
CN106278063A (en) * 2016-07-25 2017-01-04 秦文雄 Green environmental-protection building mortar and production method thereof
CN107903001A (en) * 2017-11-27 2018-04-13 廖强 A kind of fibre cement

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2169828C1 (en) * 1999-11-22 2001-06-27 Острягин Анатолий Иванович Aerated cement mortar composition
CN101182139A (en) * 2007-11-12 2008-05-21 华南理工大学 Masonry cement having higher strength and water retention
CN106278063A (en) * 2016-07-25 2017-01-04 秦文雄 Green environmental-protection building mortar and production method thereof
CN107903001A (en) * 2017-11-27 2018-04-13 廖强 A kind of fibre cement

Non-Patent Citations (2)

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Title
李业兰主编: "《建筑材料》", 30 September 2007, 中国建筑工业出版社 *
杨伯科主编: "《混凝土实用新技术手册(精编)》", 31 January 1998, 吉林科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110482967A (en) * 2019-09-27 2019-11-22 安徽虹达道路桥梁工程有限公司 A kind of road and bridge cement

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