CN108690748A - A kind of novel combination agent that washes the dishes of concentrated type - Google Patents
A kind of novel combination agent that washes the dishes of concentrated type Download PDFInfo
- Publication number
- CN108690748A CN108690748A CN201810663037.0A CN201810663037A CN108690748A CN 108690748 A CN108690748 A CN 108690748A CN 201810663037 A CN201810663037 A CN 201810663037A CN 108690748 A CN108690748 A CN 108690748A
- Authority
- CN
- China
- Prior art keywords
- solid
- mass percent
- ether
- dishwasher detergent
- dishes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007787 solid Substances 0.000 claims abstract description 87
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000003599 detergent Substances 0.000 claims abstract description 56
- -1 polybutylenes Polymers 0.000 claims abstract description 44
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 26
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 19
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 17
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 150000002170 ethers Chemical class 0.000 claims abstract description 15
- 229920001748 polybutylene Polymers 0.000 claims abstract description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920001400 block copolymer Polymers 0.000 claims abstract description 12
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003513 alkali Substances 0.000 claims abstract description 10
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011256 inorganic filler Substances 0.000 claims abstract description 10
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 6
- 239000000417 fungicide Substances 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 229920001451 polypropylene glycol Polymers 0.000 claims description 12
- 229920002125 Sokalan® Polymers 0.000 claims description 11
- 239000004584 polyacrylic acid Substances 0.000 claims description 11
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- 239000012265 solid product Substances 0.000 claims description 6
- 229940051250 hexylene glycol Drugs 0.000 claims description 5
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 235000002639 sodium chloride Nutrition 0.000 claims description 4
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims description 4
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 3
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 3
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 3
- 229940086737 allyl sucrose Drugs 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 238000000280 densification Methods 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- 239000004220 glutamic acid Substances 0.000 claims description 3
- 235000013922 glutamic acid Nutrition 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- CFVZILWIXKITDD-UHFFFAOYSA-N 2-acetyloxyprop-2-enoic acid Chemical compound CC(=O)OC(=C)C(O)=O CFVZILWIXKITDD-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 238000004851 dishwashing Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 2
- 239000013066 combination product Substances 0.000 description 2
- 229940127555 combination product Drugs 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
- C11D3/048—Nitrates or nitrites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of novel combination agents that washes the dishes of concentrated type, including solid dishwasher detergent and solid drier, wherein, solid dishwasher detergent by include in alkali, aminocarboxylate, C8~C28 fatty alcohols, C8~C28 Fatty alcohol polyoxyethylene polyoxypropylene ethers, C8~C28 aliphatic alcohol polyethenoxy polybutylenes ether, aliphatic amine polyoxyethylene polyethenoxy ether, polyalcohol, inorganic filler and pure water plurality of raw materials hybrid reaction form;Solid drier by include in the Fatty alcohol polyoxyethylene polyoxypropylene ethers of C8~28, polyoxyethylene polyoxypropylene block copolymer, polyalcohol, polyacrylate, acrylic acid crosslinked resin, fungicide and pure water plurality of raw materials hybrid reaction form, it is a kind of with good cleaning and quick-drying performance, the novel combination agent that washes the dishes of economic, efficient and environmentally friendly concentrated type to propose.
Description
Technical field
The present invention relates to kitchen cleaning technique field more particularly to a kind of novel combination agents that washes the dishes of concentrated type.
Background technology
Dishwasher detergent and drier are that public sphere (such as hotel, restaurant, coffee bar, bar, restaurant chain) uses
Indispensable product when dishwasher sterilizing dinnerware.At present general dishwasher detergent have effective alkalinity 15%~30% powder,
Liquid, solid product, and general drier is the fluid product that effective active object is 5%~15%.It usual dishwasher detergent and urges
Dry agent needs dry to be urged wriggle addition dishwasher detergent and addition of wriggling according to conductivity by connecting the automatic distributor of dish-washing machine
Agent.According to easy to use and common formula using effect, solid dishwasher detergent is better than liquid dishwasher agent, then washes the dishes better than powder
Agent;And liquid drier and solid drier are form difference, effect is with using formula material related.Country's tableware is washed at present
" dish-washing machine+dishwasher detergent+drier " scheme of bowl is to use liquid dishwasher agent and liquid (usually to buy by oneself or lease in a manner of)
Based on body drier.It is that fluid product does not accomplish that (effective active matter is dissolved in pure water enrichment the shortcomings that industry at present
It is limited), in addition Chinese catering trade dirt type is various, grease is mostly wide with various culinary art food materials, simple price competition causes
Fluid product effective active is low, leads to that the effect of dish washing machine is poor, product consumption is high.And because effect is washed the dishes at present
Difference, expedited the emergence of also manually will wash and use liquid detergent instead even with automatic dish-washing machine, not only increase labor cost,
And virtually increase the burden of municipal sewage.The transportation and packing of liquid are of high cost simultaneously, are also unfavorable for transporting safely.
Invention content
It is an object of the invention to one kind having good cleaning and quick-drying performance, economic, efficient and environmentally friendly concentrated type
The novel combination agent that washes the dishes.
In order to achieve the above objectives, the present invention proposes a kind of novel combination agent that washes the dishes of concentrated type, including solid dishwasher detergent and solid
Body drier, wherein the solid dishwasher detergent is by including alkali, aminocarboxylate, C8~C28 fatty alcohols, C8~C28 fatty alcohols
Polyoxyethylene poly-oxygen propylene aether, C8~C28 aliphatic alcohol polyethenoxy polybutylenes ether, aliphatic amine polyoxyethylene polyethenoxy ether,
Plurality of raw materials hybrid reaction forms in polyalcohol, inorganic filler and pure water;The solid drier is by including the fat of C8~28
Alcohol polyoxyethylene poly-oxygen propylene aether, polyoxyethylene polyoxypropylene block copolymer, polyalcohol, polyacrylate, acrylic acid crosslinking
Plurality of raw materials hybrid reaction forms in resin, fungicide and pure water.
Preferably, in the component of the solid dishwasher detergent;The alkali is at least one of sodium hydroxide and potassium hydroxide
Or two kinds of mixture, the aminocarboxylate includes nitrilotriacetic acid trisodium, disodium ethylene diamine tetraacetate, ethylenediamine tetra-acetic acid
At least one of four sodium, methylglycine diacetic acid trisodium, four sodium of glutamic acid diacetic acid acrylic acid;C8~C28 fat
Alcohol includes synthol or natural alcohol;C8~C28 Fatty alcohol polyoxyethylene polyoxypropylene ethers include C12~C18 poly alkyl alcohols
Ethylene oxide (3EO~15EO) polyoxypropylene (3PO~10PO) ether;C8~C28 aliphatic alcohol polyethenoxies polybutylene ether packet
Include C12~C18 aliphatic alcohol polyethenoxies (3EO~15EO) polybutylene (1PO~5PO) ether;C8~C28 fatty amines polyoxy
Ethylene polyethenoxy ether includes C12~C18 aliphatic amine polyoxyethylenes (3EO~15EO) polyoxypropylene (6PO~30PO) ether;It is described
Polyalcohol includes at least one of glycerine, ethylene glycol, pentanediol, hexylene glycol;The inorganic filler be sodium chloride, potassium chloride,
At least one of sodium nitrate, potassium nitrate, sodium sulphate, potassium sulfate.
Preferably, the mass percent that the alkali accounts in the solid dishwasher detergent is 30~50%;The amino carboxylic acid
The mass percent that salt accounts in the solid dishwasher detergent is 5~40%;C8~C28 fatty alcohols are in the solid dishwasher detergent
In the mass percent that accounts for be 0~5%;C8~C28 Fatty alcohol polyoxyethylene polyoxypropylene ethers are in the solid dishwasher detergent
In the mass percent that accounts for be 0~5%;C8~C28 aliphatic alcohol polyethenoxies polybutylene ether is in the solid dishwasher detergent
In the mass percent that accounts for be 0~5%;C8~C28 aliphatic amine polyoxyethylenes polyethenoxy ether is in the solid dishwasher detergent
In the mass percent that accounts for be 0~5%;The mass percent that the polyalcohol accounts in the solid dishwasher detergent is 0~5%;
The mass percent that the inorganic filler accounts in the solid dishwasher detergent is 0~20%.
Preferably, in the component of the solid drier;The Fatty alcohol polyoxyethylene polyoxypropylene ether packets of the C8~28
Include C12~C18 aliphatic alcohol polyethenoxies (3EO~15EO) polyoxypropylene (3PO~10PO) ether;The polyoxyethylene polyoxypropylene
Block copolymer includes the copolymer of molecular weight 1000~5000;The polyalcohol include glycerine, ethylene glycol, pentanediol, oneself
At least one of glycol;The polyacrylate includes the Sodium Polyacrylate or polyacrylic acid potassium that molecular weight is 3000~8000;
The acrylic acid crosslinked resin includes the crosslinked resin or allyl sucrose and polypropylene of pentaerythrite allyl ether and polyacrylic acid
The crosslinked resin of acid.
Preferably, the quality hundred that the Fatty alcohol polyoxyethylene polyoxypropylene ethers of the C8~28 account in the solid drier
Divide than being 2~30%;The mass percent that the polyoxyethylene polyoxypropylene block copolymer accounts in the solid drier
It is 10~40%;The mass percent that the polyacrylate accounts in the solid drier is 0~5%;The polypropylene
The mass percent that hydrochlorate accounts in the solid drier is 0~5%;The acrylic acid crosslinked resin is urged dry in the solid
The mass percent accounted in agent is 0~5%;The mass percent that the fungicide accounts in the solid drier be 0~
0.5%.
Preferably, in the polyoxyethylene polyoxypropylene block copolymer polyoxyethylated mass percent be 10~
40%.
Preferably, in the molecular weight is 3000~8000 Sodium Polyacrylate and polyacrylic acid potassium, the quality of sodium or potassium
Percentage is 0~5%.
Preferably, the solid dishwasher detergent and solid drier are stirred evenly by dispensing in the range of 60~90 DEG C
Afterwards, it is made by being down to the solid product of 40 DEG C of room temperature densification formed below naturally.
Compared with prior art, of the invention to be advantageous in that:Present invention employs the solids of dishwasher detergent and drier
The scheme of enrichment can enable various effective raw material compositions be added in formulation product, solid dishwasher detergent and solid of the present invention
Drier makes the better of dishwashing detergent quick-drying and cleaning, solves the problems, such as the use for adapting to different regions condition of water quality.Together
When solid product leakage will not be easy as liquid or powder, and the product after solids-enriched reduces packaging material and fortune
Defeated cost.The solid dishwasher detergent and solid drier combination product that the present invention is created are dishwashing detergents economic, efficiently, environmentally friendly
Solution.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, technical scheme of the present invention will be made below into
Illustrate to one step.
The present invention proposes a kind of novel combination agent that washes the dishes of concentrated type, including solid dishwasher detergent and solid drier, wherein Gu
Body dishwasher detergent by include alkali, aminocarboxylate, C8~C28 fatty alcohols, C8~C28 Fatty alcohol polyoxyethylene polyoxypropylene ethers,
C8~C28 aliphatic alcohol polyethenoxy polybutylenes ether, aliphatic amine polyoxyethylene polyethenoxy ether, polyalcohol, inorganic filler and pure
Plurality of raw materials hybrid reaction forms in water;Solid drier is by including the Fatty alcohol polyoxyethylene polyoxypropylene ethers of C8~28, gathering
It is a variety of in ethylene oxide polyoxypropylene block copolymers, polyalcohol, polyacrylate, acrylic acid crosslinked resin, fungicide and pure water
Raw material hybrid reaction forms.
In the present embodiment, in the component of solid dishwasher detergent;Alkali be at least one of sodium hydroxide and potassium hydroxide or
Two kinds of mixture, aminocarboxylate include nitrilotriacetic acid trisodium, disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate,
At least one of methylglycine diacetic acid trisodium, four sodium of glutamic acid diacetic acid acrylic acid;C8~C28 fatty alcohols include synthesis
Alcohol or natural alcohol;C8~C28 Fatty alcohol polyoxyethylene polyoxypropylene ethers include C12~C18 aliphatic alcohol polyethenoxies (3EO~
15EO) polyoxypropylene (3PO~10PO) ether;C8~C28 aliphatic alcohol polyethenoxy polybutylene ethers include C12~C18 fatty alcohols
Polyoxyethylene (3EO~15EO) polybutylene (1PO~5PO) ether;C8~C28 aliphatic amine polyoxyethylene polyethenoxy ethers include
C12~C18 aliphatic amine polyoxyethylenes (3EO~15EO) polyoxypropylene (6PO~30PO) ether;Polyalcohol includes glycerine, second two
At least one of alcohol, pentanediol, hexylene glycol;Inorganic filler is sodium chloride, potassium chloride, sodium nitrate, potassium nitrate, sodium sulphate, sulfuric acid
At least one of potassium.
In the present embodiment, the mass percent that alkali accounts in solid dishwasher detergent is 30~50%;Aminocarboxylate is solid
The mass percent accounted in body dishwasher detergent is 5~40%;The mass percent that C8~C28 fatty alcohols account in solid dishwasher detergent is
0~5%;The mass percent that C8~C28 Fatty alcohol polyoxyethylene polyoxypropylene ethers account in solid dishwasher detergent is 0~5%;C8
The mass percent that~C28 aliphatic alcohol polyethenoxy polybutylene ethers account in solid dishwasher detergent is 0~5%;C8~C28 fat
The mass percent that amine polyoxyethylene poly-oxygen propylene aether accounts in solid dishwasher detergent is 0~5%;Polyalcohol is in solid dishwasher detergent
The mass percent accounted for is 0~5%;The mass percent that inorganic filler accounts in solid dishwasher detergent is 0~20%.
In the present embodiment, in the component of solid drier;The Fatty alcohol polyoxyethylene polyoxypropylene ethers of C8~28 include
C12~C18 aliphatic alcohol polyethenoxies (3EO~15EO) polyoxypropylene (3PO~10PO) ether;Polyoxyethylene polyoxypropylene block is total
Polymers includes the copolymer of molecular weight 1000~5000;Polyalcohol include in glycerine, ethylene glycol, pentanediol, hexylene glycol at least
It is a kind of;Polyacrylate includes the Sodium Polyacrylate or polyacrylic acid potassium that molecular weight is 3000~8000;Acrylic acid crosslinked resin
The crosslinked resin of crosslinked resin or allyl sucrose and polyacrylic acid including pentaerythrite allyl ether and polyacrylic acid.
In the present embodiment, the quality percentage that the Fatty alcohol polyoxyethylene polyoxypropylene ethers of C8~28 account in solid drier
Than being 2~30%;The mass percent that polyoxyethylene polyoxypropylene block copolymer accounts in solid drier is 10~40%;
The mass percent that polyacrylate accounts in solid drier is 0~5%;The matter that polyacrylate accounts in solid drier
It is 0~5% to measure percentage;The mass percent that acrylic acid crosslinked resin accounts in solid drier is 0~5%;Fungicide exists
The mass percent accounted in solid drier is 0~0.5%.
In the present embodiment, in polyoxyethylene polyoxypropylene block copolymer polyoxyethylated mass percent be 10~
40%.
In the present embodiment, in molecular weight is 3000~8000 Sodium Polyacrylate and polyacrylic acid potassium, the matter of sodium or potassium
It is 0~5% to measure percentage.
In the present embodiment, solid dishwasher detergent and solid drier are stirred by dispensing in the range of 60~90 DEG C
After even, it is made by being down to the solid product of 40 DEG C of room temperature densification formed below naturally.
In the present embodiment, EO is ethylene oxide, and PO is propylene oxide.
In the present embodiment, the present invention can be made various effective using the technology of the solids-enriched of dishwasher detergent and drier
Raw material composition can be added in formulation product, and solid dishwasher detergent and solid drier of the present invention make dishwashing detergent quick-drying and clear
That washes is better, solves the problems, such as the use for adapting to different regions condition of water quality.Solid product will not be as liquid or powder simultaneously
It is equally easy leakage, and the product after solids-enriched reduces packaging material and transportation cost.The solid that the present invention is created
Dishwasher detergent and solid drier combination product are dishwashing detergent solutions economic, efficiently, environmentally friendly.
It is the preferred embodiment of the present invention below:
Preferably solid dishwasher detergent and solid drier product formula and specific proportioning is as follows:
Solid dishwasher detergent:
Solid drier:
The preferred embodiment of the present invention is above are only, does not play the role of any restrictions to the present invention.Belonging to any
Those skilled in the art, in the range of not departing from technical scheme of the present invention, to the invention discloses technical solution and
Technology contents make the variations such as any type of equivalent replacement or modification, belong to the content without departing from technical scheme of the present invention, still
Within belonging to the scope of protection of the present invention.
Claims (8)
1. a kind of novel combination agent that washes the dishes of concentrated type, which is characterized in that including solid dishwasher detergent and solid drier, wherein institute
Solid dishwasher detergent is stated by including alkali, aminocarboxylate, C8~C28 fatty alcohols, C8~C28 aliphatic alcohol polyethenoxy polyoxypropylenes
Ether, C8~C28 aliphatic alcohol polyethenoxy polybutylenes ether, aliphatic amine polyoxyethylene polyethenoxy ether, polyalcohol, inorganic filler and
Plurality of raw materials hybrid reaction forms in pure water;The solid drier is by including the aliphatic alcohol polyethenoxy polyoxypropylenes of C8~28
In ether, polyoxyethylene polyoxypropylene block copolymer, polyalcohol, polyacrylate, acrylic acid crosslinked resin, fungicide and pure water
Plurality of raw materials hybrid reaction forms.
2. the novel combination agent that washes the dishes of concentrated type according to claim 1, which is characterized in that in the group of the solid dishwasher detergent
In point;The alkali is at least one of sodium hydroxide and potassium hydroxide or two kinds of mixture, and the aminocarboxylate includes nitrogen
River triacetic acid trisodium, disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, methylglycine diacetic acid trisodium, glutamic acid two
At least one of four sodium of acetoxyacrylic acid;C8~C28 fatty alcohols include synthol or natural alcohol;C8~C28 fat
Fat alcohol polyoxyethylene poly-oxygen propylene aether include C12~C18 aliphatic alcohol polyethenoxies (3EO~15EO) polyoxypropylene (3PO~
10PO) ether;C8~C28 aliphatic alcohol polyethenoxies polybutylene ether include C12~C18 aliphatic alcohol polyethenoxies (3EO~
15EO) polybutylene (1PO~5PO) ether;C8~C28 aliphatic amine polyoxyethylenes polyethenoxy ether includes C12~C18 fat
Amine polyoxyethylene (3EO~15EO) polyoxypropylene (6PO~30PO) ether;The polyalcohol includes glycerine, ethylene glycol, penta 2
At least one of alcohol, hexylene glycol;The inorganic filler is in sodium chloride, potassium chloride, sodium nitrate, potassium nitrate, sodium sulphate, potassium sulfate
It is at least one.
3. the novel combination agent that washes the dishes of concentrated type according to claim 2, which is characterized in that the alkali washes the dishes in the solid
The mass percent accounted in agent is 30~50%;The mass percent that the aminocarboxylate accounts in the solid dishwasher detergent is
5~40%;The mass percent that C8~C28 fatty alcohols account in the solid dishwasher detergent is 0~5%;C8~the C28
The mass percent that Fatty alcohol polyoxyethylene polyoxypropylene ether accounts in the solid dishwasher detergent is 0~5%;C8~the C28
The mass percent that aliphatic alcohol polyethenoxy polybutylene ether accounts in the solid dishwasher detergent is 0~5%;C8~the C28
The mass percent that aliphatic amine polyoxyethylene polyethenoxy ether accounts in the solid dishwasher detergent is 0~5%;The polyalcohol exists
The mass percent accounted in the solid dishwasher detergent is 0~5%;The quality that the inorganic filler accounts in the solid dishwasher detergent
Percentage is 0~20%.
4. the novel combination agent that washes the dishes of concentrated type according to claim 1, which is characterized in that in the group of the solid drier
In point;The Fatty alcohol polyoxyethylene polyoxypropylene ethers of the C8~28 include C12~C18 aliphatic alcohol polyethenoxies (3EO~15EO)
Polyoxypropylene (3PO~10PO) ether;The polyoxyethylene polyoxypropylene block copolymer includes being total to for molecular weight 1000~5000
Polymers;The polyalcohol includes at least one of glycerine, ethylene glycol, pentanediol, hexylene glycol;The polyacrylate includes point
The Sodium Polyacrylate or polyacrylic acid potassium that son amount is 3000~8000;The acrylic acid crosslinked resin includes pentaerythrite allyl ether
With the crosslinked resin or allyl sucrose of polyacrylic acid and the crosslinked resin of polyacrylic acid.
5. the novel combination agent that washes the dishes of concentrated type according to claim 4, which is characterized in that the fatty alcohol polyoxies of the C8~28
The mass percent that ethylene polyethenoxy ether accounts in the solid drier is 2~30%;The polyoxyethylene polyoxypropylene
The mass percent that block copolymer accounts in the solid drier is 10~40%;The polyacrylate is in the solid
The mass percent accounted in drier is 0~5%;The mass percent that the polyacrylate accounts in the solid drier
It is 0~5%;The mass percent that the acrylic acid crosslinked resin accounts in the solid drier is 0~5%;The sterilization
The mass percent that agent accounts in the solid drier is 0~0.5%.
6. the novel combination agent that washes the dishes of concentrated type according to claim 4, which is characterized in that the polyoxyethylene polyoxypropylene
Polyoxyethylated mass percent is 10~40% in block copolymer.
7. the novel combination agent that washes the dishes of concentrated type according to claim 4, which is characterized in that the molecular weight be 3000~
In 8000 Sodium Polyacrylate and polyacrylic acid potassium, the mass percent of sodium or potassium is 0~5%.
8. the novel combination agent that washes the dishes of concentrated type according to claim 1, which is characterized in that the solid dishwasher detergent and solid
After drier is stirred evenly by dispensing in the range of 60~90 DEG C, by being down to 40 DEG C of densifications formed below of room temperature naturally
Solid product and be made.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810663037.0A CN108690748A (en) | 2018-06-25 | 2018-06-25 | A kind of novel combination agent that washes the dishes of concentrated type |
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|---|---|---|---|
| CN201810663037.0A CN108690748A (en) | 2018-06-25 | 2018-06-25 | A kind of novel combination agent that washes the dishes of concentrated type |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110157336A (en) * | 2019-05-12 | 2019-08-23 | 合肥博朗德纳米技术有限公司 | One kind is based on amino-acid rare earth drier and preparation method thereof |
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| CN106479755A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of efficient dishware drier and preparation method thereof |
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| CN1354212A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Special-purpose tableware dryer for dish-washer |
| CN1421518A (en) * | 2000-11-22 | 2003-06-04 | 上海白猫有限公司 | Tableware detergent liquid specially for commercial dish washer |
| CN101508872A (en) * | 2009-03-11 | 2009-08-19 | 李汉辉 | Drier for bleaching of dish washing machine |
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| CN110157336A (en) * | 2019-05-12 | 2019-08-23 | 合肥博朗德纳米技术有限公司 | One kind is based on amino-acid rare earth drier and preparation method thereof |
| CN110157336B (en) * | 2019-05-12 | 2021-08-20 | 合肥博朗德纳米技术有限公司 | Amino acid rare earth-based drier and preparation method thereof |
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Application publication date: 20181023 |