CN108690391A - A kind of water proof coating in PVC board - Google Patents

A kind of water proof coating in PVC board Download PDF

Info

Publication number
CN108690391A
CN108690391A CN201810555166.8A CN201810555166A CN108690391A CN 108690391 A CN108690391 A CN 108690391A CN 201810555166 A CN201810555166 A CN 201810555166A CN 108690391 A CN108690391 A CN 108690391A
Authority
CN
China
Prior art keywords
parts
water proof
pvc board
proof coating
polyvinyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810555166.8A
Other languages
Chinese (zh)
Inventor
段满礼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jieshou Yaxin Plastic Industry Co Ltd
Original Assignee
Jieshou Yaxin Plastic Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jieshou Yaxin Plastic Industry Co Ltd filed Critical Jieshou Yaxin Plastic Industry Co Ltd
Priority to CN201810555166.8A priority Critical patent/CN108690391A/en
Publication of CN108690391A publication Critical patent/CN108690391A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09D179/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C09D179/085Unsaturated polyimide precursors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds

Abstract

A kind of water proof coating in PVC board is related to PVC product processing technical field, it is characterised in that:Material including following parts by weight is made, 14-20 parts of resin, 1-4 parts of lithium metasilicate, 9-13 parts of modified wollastonite powder, 2-5 parts of Isooctyl acrylate monomer, 4-8 parts of ethylene glycol, 2-5 parts of butyl glycol ether, 5-9 parts of polyvinyl alcohol carboxylic butyraldehyde, 1-4 parts of 2-ethyl-4-methylimidazole, 5-10 parts of polyvinyl alcohol carboxylic butyraldehyde, 7-12 parts of anti-aging agent, 9-14 parts of biological agent, 30-35 parts of deionized water.The method of the present invention is reasonable, easy to implement, water proof, heat-resisting.

Description

A kind of water proof coating in PVC board
Technical field
The present invention relates to PVC products to process technical field, and in particular to the water proof coating in a kind of PVC board.
Background technology
PVC board is using PVC as plank that section made of raw material is honeycomb eyed structure.Also known as decorating film, attached glue Film is a kind of vacuum forming film, and the surface layer for all kinds of panels is packed, and all conglomeraties such as building materials, packaging, medicine are applied to.
PVC board is maximum in the proportion that building material industry accounts for, and is 60%, followed by packaging industry, also other several small ranges The industry of application.It can be divided into soft pvc and hard PVC according to soft or hard degree.It can be divided into PVC foams plate and PVC by manufacture craft Free Foaming Panel.By transparent and opaque be divided into PVC transparent plate and pvc plates.
And present PVC board all performances with certain waterproof, but performance is not high, often appears in for a long time It impregnates or meets after water and the generation of the problems such as softening, fracture occur, be easy for bringing great fiber crops to using, install etc. in this way It is tired.
Invention content
Technical problem to be solved by the present invention lies in overcome existing technological deficiency provide a kind of method rationally, embodiment party Just, water proof, the water proof coating in a kind of heat-resisting PVC board.
The technical problems to be solved by the invention are realized using technical solution below:
A kind of water proof coating in PVC board, it is characterised in that:Material including following parts by weight is made,
14-20 parts of resin, 1-4 parts of lithium metasilicate, 9-13 parts of modified wollastonite powder, 2-5 parts of Isooctyl acrylate monomer, ethylene glycol 4- 8 parts, 2-5 parts of butyl glycol ether, 5-9 parts of polyvinyl alcohol carboxylic butyraldehyde, 1-4 parts of 2-ethyl-4-methylimidazole, polyvinyl alcohol carboxylic butyraldehyde 5-10 parts, 7-12 parts of anti-aging agent, 9-14 parts of biological agent, 30-35 parts of deionized water;
The resin is E-12 epoxy resin, amino resins, polyamide, vinyl ester resin, bismaleimide One kind in resin;
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W;
The preparation method of the modified wollastonite powder is:Wollastonite is ground to and crossed 300-400 mesh sieve, is then added Methyl tributanoximo silane is stirred 10min at normal temperatures, then heats to 80-85 DEG C of heat preservation grinding 30min, adds water The solution that solid content reaches 25-35% is made in stirring, and gained mixed liquor is sent into dry in spray dryer, obtained 20-40 purposes Spheric granules, and dried at 100-110 DEG C;
The weight part ratio of the methyl tributanoximo silane and wollastonite is 1:3.2;
The biological agent includes that the material of following parts by weight is made,
1 part of oyster, 2 parts of Radix Polygalae, 3 parts of magnetite, 4 parts of psoralea corylifolia, 5 parts of grass-leaved sweetflag, 6 parts of alum, 7 parts of sulphur, calamine 1 Part, 2 parts of mantis egg-case, 3 parts of the fleece-flower root, 4 parts of raspberry, 5 parts of red halloysite;
Preparation method is:Above-mentioned material is placed in 85-95 DEG C of drying equipment and is tiled, 4-5 hour is then dried, It is then placed in milling apparatus and is ground into powder;
The preparation method of water proof coating in a kind of PVC board includes:Above-mentioned material is sequentially placed into reaction kettle In be uniformly mixed, be warming up to 150-200 DEG C, insulated and stirred 3-5h obtains mixture, then cools to 100-150 DEG C, mixing is stirred It mixes to the formation preferable slurry of mobility.
Beneficial effects of the present invention are:The coating used can apply multilayer, and can mix and make with other japannings, coating etc. With, thus enhanced convenience, and the wear-resisting, heat-resisting of product, corrosion-resistant performance are all very good, and with good anti- The performance of water, it will be able to guarantee be not in due to bubble, vapor and occur fold, cracking, fracture the problems such as, and And bond properties, the wear-resisting property of product are very good, and the biological assistant used can play the role of neutralizing a toxin, in this way Just human body is not just injured, and contain a large amount of mineral in biological assistant all without toxin when production, use Matter etc. can increase the hardness and strength of product, increase the service life of product.Product can be used on a variety of basic materials, Coating is with a wide range of features, and few, at low cost, the nontoxic no side reaction of material consumption, and processability is good, molding is easy.
Specific implementation mode
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, below into One step illustrates the present invention.
Embodiment 1
A kind of water proof coating in PVC board, it is characterised in that:Material including following parts by weight is made,
14 parts of resin, 1 part of lithium metasilicate, 9 parts of modified wollastonite powder, 2 parts of Isooctyl acrylate monomer, 4 parts of ethylene glycol, ethylene glycol fourth 2 parts of ether, 5 parts of polyvinyl alcohol carboxylic butyraldehyde, 1 part of 2-ethyl-4-methylimidazole, 5 parts of polyvinyl alcohol carboxylic butyraldehyde, 7 parts of anti-aging agent, biology 9 parts of agent, 30 parts of deionized water;
The resin is E-12 epoxy resin, amino resins, polyamide, vinyl ester resin, bismaleimide One kind in resin;
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W;
The preparation method of the modified wollastonite powder is:Wollastonite is ground to and crossed 300-400 mesh sieve, is then added Methyl tributanoximo silane is stirred 10min at normal temperatures, then heats to 80-85 DEG C of heat preservation grinding 30min, adds water The solution that solid content reaches 25-35% is made in stirring, and gained mixed liquor is sent into dry in spray dryer, obtained 20-40 purposes Spheric granules, and dried at 100-110 DEG C;
The weight part ratio of the methyl tributanoximo silane and wollastonite is 1:3.2;
The biological agent includes that the material of following parts by weight is made,
1 part of oyster, 2 parts of Radix Polygalae, 3 parts of magnetite, 4 parts of psoralea corylifolia, 5 parts of grass-leaved sweetflag, 6 parts of alum, 7 parts of sulphur, calamine 1 Part, 2 parts of mantis egg-case, 3 parts of the fleece-flower root, 4 parts of raspberry, 5 parts of red halloysite;
Preparation method is:Above-mentioned material is placed in 85-95 DEG C of drying equipment and is tiled, 4-5 hour is then dried, It is then placed in milling apparatus and is ground into powder;
The preparation method of water proof coating in a kind of PVC board includes:Above-mentioned material is sequentially placed into reaction kettle In be uniformly mixed, be warming up to 150-200 DEG C, insulated and stirred 3-5h obtains mixture, then cools to 100-150 DEG C, mixing is stirred It mixes to the formation preferable slurry of mobility.
Embodiment 2
A kind of water proof coating in PVC board, it is characterised in that:Material including following parts by weight is made,
20 parts of resin, 4 parts of lithium metasilicate, 13 parts of modified wollastonite powder, 5 parts of Isooctyl acrylate monomer, 8 parts of ethylene glycol, ethylene glycol 5 parts of butyl ether, 9 parts of polyvinyl alcohol carboxylic butyraldehyde, 4 parts of 2-ethyl-4-methylimidazole, 10 parts of polyvinyl alcohol carboxylic butyraldehyde, 12 parts of anti-aging agent, 14 parts of biological agent, 35 parts of deionized water;
The resin is E-12 epoxy resin, amino resins, polyamide, vinyl ester resin, bismaleimide One kind in resin;
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W;
The preparation method of the modified wollastonite powder is:Wollastonite is ground to and crossed 300-400 mesh sieve, is then added Methyl tributanoximo silane is stirred 10min at normal temperatures, then heats to 80-85 DEG C of heat preservation grinding 30min, adds water The solution that solid content reaches 25-35% is made in stirring, and gained mixed liquor is sent into dry in spray dryer, obtained 20-40 purposes Spheric granules, and dried at 100-110 DEG C;
The weight part ratio of the methyl tributanoximo silane and wollastonite is 1:3.2;
The biological agent includes that the material of following parts by weight is made,
1 part of oyster, 2 parts of Radix Polygalae, 3 parts of magnetite, 4 parts of psoralea corylifolia, 5 parts of grass-leaved sweetflag, 6 parts of alum, 7 parts of sulphur, calamine 1 Part, 2 parts of mantis egg-case, 3 parts of the fleece-flower root, 4 parts of raspberry, 5 parts of red halloysite;
Preparation method is:Above-mentioned material is placed in 85-95 DEG C of drying equipment and is tiled, 4-5 hour is then dried, It is then placed in milling apparatus and is ground into powder;
The preparation method of water proof coating in a kind of PVC board includes:Above-mentioned material is sequentially placed into reaction kettle In be uniformly mixed, be warming up to 150-200 DEG C, insulated and stirred 3-5h obtains mixture, then cools to 100-150 DEG C, mixing is stirred It mixes to the formation preferable slurry of mobility.
Embodiment 3
A kind of water proof coating in PVC board, it is characterised in that:Material including following parts by weight is made,
17 parts of resin, 2 parts of lithium metasilicate, 11 parts of modified wollastonite powder, 4 parts of Isooctyl acrylate monomer, 6 parts of ethylene glycol, ethylene glycol 4 parts of butyl ether, 8 parts of polyvinyl alcohol carboxylic butyraldehyde, 2 parts of 2-ethyl-4-methylimidazole, 7 parts of polyvinyl alcohol carboxylic butyraldehyde, 11 parts of anti-aging agent, 11 parts of biological agent, 33 parts of deionized water;
The resin is E-12 epoxy resin, amino resins, polyamide, vinyl ester resin, bismaleimide One kind in resin;
The anti-aging agent includes one kind in anti-aging agent RD, antioxidant A, antioxidant D, anti-aging agent CPPD, antioxidant A W;
The preparation method of the modified wollastonite powder is:Wollastonite is ground to and crossed 300-400 mesh sieve, is then added Methyl tributanoximo silane is stirred 10min at normal temperatures, then heats to 80-85 DEG C of heat preservation grinding 30min, adds water The solution that solid content reaches 25-35% is made in stirring, and gained mixed liquor is sent into dry in spray dryer, obtained 20-40 purposes Spheric granules, and dried at 100-110 DEG C;
The weight part ratio of the methyl tributanoximo silane and wollastonite is 1:3.2;
The biological agent includes that the material of following parts by weight is made,
1 part of oyster, 2 parts of Radix Polygalae, 3 parts of magnetite, 4 parts of psoralea corylifolia, 5 parts of grass-leaved sweetflag, 6 parts of alum, 7 parts of sulphur, calamine 1 Part, 2 parts of mantis egg-case, 3 parts of the fleece-flower root, 4 parts of raspberry, 5 parts of red halloysite;
Preparation method is:Above-mentioned material is placed in 85-95 DEG C of drying equipment and is tiled, 4-5 hour is then dried, It is then placed in milling apparatus and is ground into powder;
The preparation method of water proof coating in a kind of PVC board includes:Above-mentioned material is sequentially placed into reaction kettle In be uniformly mixed, be warming up to 150-200 DEG C, insulated and stirred 3-5h obtains mixture, then cools to 100-150 DEG C, mixing is stirred It mixes to the formation preferable slurry of mobility.
A kind of coating in PVC board, including following material,
17 parts of amino resins, 2 parts of lithium metasilicate, 11 parts of wollastonite in powder, 6 parts of ethylene glycol, 4 parts of butyl glycol ether, polyvinyl alcohol 8 parts of carboxylic butyraldehyde, 7 parts of polyvinyl alcohol carboxylic butyraldehyde, 11 parts of antioxidant A, 33 parts of water;
Preparation method:Above-mentioned material is put into reaction kettle, 40-50 points are stirred in 110-120 DEG C of temperature Clock is then pressed into three-roller, is ground into powder.
By experiment, the performance and effect of 1-3 of the embodiment of the present invention and comparative example, such as following table are measured:
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (2)

1. the water proof coating in a kind of PVC board, it is characterised in that:Material including following parts by weight is made,
14-20 parts of resin, 1-4 parts of lithium metasilicate, 9-13 parts of modified wollastonite powder, 2-5 parts of Isooctyl acrylate monomer, 4-8 parts of ethylene glycol, 2-5 parts of butyl glycol ether, 5-9 parts of polyvinyl alcohol carboxylic butyraldehyde, 1-4 parts of 2-ethyl-4-methylimidazole, polyvinyl alcohol carboxylic butyraldehyde 5-10 Part, 7-12 parts of anti-aging agent, 9-14 parts of biological agent, 30-35 parts of deionized water.
2. the water proof coating in a kind of PVC board according to claim 1, it is characterised in that:It is used in a kind of PVC board The preparation method of water proof coating include:Above-mentioned material is sequentially placed into reaction kettle and is uniformly mixed, 150-200 is warming up to DEG C, insulated and stirred 3-5h obtains mixture, then cools to 100-150 DEG C, mixes to form mobility and preferably starch Body.
CN201810555166.8A 2018-06-01 2018-06-01 A kind of water proof coating in PVC board Pending CN108690391A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810555166.8A CN108690391A (en) 2018-06-01 2018-06-01 A kind of water proof coating in PVC board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810555166.8A CN108690391A (en) 2018-06-01 2018-06-01 A kind of water proof coating in PVC board

Publications (1)

Publication Number Publication Date
CN108690391A true CN108690391A (en) 2018-10-23

Family

ID=63849250

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810555166.8A Pending CN108690391A (en) 2018-06-01 2018-06-01 A kind of water proof coating in PVC board

Country Status (1)

Country Link
CN (1) CN108690391A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505060A (en) * 2015-12-31 2016-04-20 长沙民德消防工程涂料有限公司 Water-based nano reflection and heat insulation transparent coating and preparation method thereof
CN107556888A (en) * 2017-09-27 2018-01-09 阜南县邰氏宇崴运动器材有限公司 A kind of protective coating of roller skate brake disk

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505060A (en) * 2015-12-31 2016-04-20 长沙民德消防工程涂料有限公司 Water-based nano reflection and heat insulation transparent coating and preparation method thereof
CN107556888A (en) * 2017-09-27 2018-01-09 阜南县邰氏宇崴运动器材有限公司 A kind of protective coating of roller skate brake disk

Similar Documents

Publication Publication Date Title
CN105694739A (en) Silicone acrylic emulsion modified magnesium-containing inorganic adhesive for straws and preparation method of silicone acrylic emulsion modified magnesium-containing inorganic adhesive
CN102702707A (en) Surface-modified hemp fiber enhanced unsaturated polyester composite material
CN107266853A (en) Phenolic foam heat insulation plate and preparation method thereof
CN108546482A (en) A kind of polymer cement waterproof paint and preparation method thereof using modified sericite in powder
CN104059574A (en) Preparation method of polyvinyl formal adhesive
CN107540769A (en) A kind of polymer overmold type building thermal insulation material and preparation method thereof
CN108690391A (en) A kind of water proof coating in PVC board
CN106495554B (en) A kind of preparation method of stable type alkali-free quick-coagulant
CN106065301A (en) A kind of anti-gaping of joints hot pressing veneer overlay glue stick and preparation method
CN103319930B (en) High-performance cooked adhesive powder for wall rendering and preparation method thereof
CN107880818A (en) A kind of mineral wool abatvoix formaldehydeless bio-based backboard glue and preparation method
CN106366844A (en) High-adhesion epoxy paint with excellent mechanical properties
WO2020211188A1 (en) Method for making nano shell powder plastic ingot
CN106892639B (en) The production method on composite glass magnesium floor and composite glass magnesium floor
CN102276906A (en) Modified ethane-vinyl alcohol copolymer composite material and preparation technology thereof
CN111849415B (en) Environment-friendly waterproof adhesive and preparation method thereof
CN107674339A (en) New-energy automobile is modified diaphragm and preparation method thereof with anti-radiation insulation stalk
CN103936993A (en) Method for preparing methyl silicone oil by utilizing sulfuric acid
CN107903009A (en) A kind of anti-cracking high-strength degree aerated-block
CN103627073A (en) Polyethylene-polystyrene foam
CN110257005B (en) Formaldehyde-free flour-based adhesive and preparation method thereof
CN106244097A (en) A kind of high-temperature resistant electronic wire road special adhesive of backing plate adding organic modification montmonrillonite
CN110437766B (en) Aldehyde-free low-cost polysaccharide adhesive and preparation method thereof
CN108707387A (en) A kind of refractory coating of sheet material for roofs for kitchen use
CN107986686B (en) Wet-mixed mortar interface agent and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181023

RJ01 Rejection of invention patent application after publication