CN108684701A - A kind of composition and product of mosquito - Google Patents

A kind of composition and product of mosquito Download PDF

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Publication number
CN108684701A
CN108684701A CN201810824607.XA CN201810824607A CN108684701A CN 108684701 A CN108684701 A CN 108684701A CN 201810824607 A CN201810824607 A CN 201810824607A CN 108684701 A CN108684701 A CN 108684701A
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China
Prior art keywords
mosquito
composition
active ingredient
vaporized
repellent
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CN201810824607.XA
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Chinese (zh)
Inventor
柏坤
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CHENGDU RAINBOW ELECTRICAL APPLIANCE (GROUP) SHARERS Co Ltd
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CHENGDU RAINBOW ELECTRICAL APPLIANCE (GROUP) SHARERS Co Ltd
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Priority to CN201810824607.XA priority Critical patent/CN108684701A/en
Publication of CN108684701A publication Critical patent/CN108684701A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/32Cyclic imides of polybasic carboxylic acids or thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46N-acyl derivatives
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/46Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom rings with more than six members

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)

Abstract

The invention discloses a kind of composition of mosquito and products, are related to daily use chemicals consumer goods industries.The composition of the mosquito of the present invention includes active ingredient 0.005-20.0% by mass, it is vaporized conditioning agent 75.0-99.8%, stabilizer 0.05-1.0%, synergist 0.1-5.0%, the composition, which is equipped with acceptable auxiliary material, can prepare the product of a variety of mosquitos, such as electric mosquito repellent liquid, coiled mosquito-repellent incense, line spices, insect aerosol.The mosquito-repellent incense liquid of the composition manufacture is vaporized speed using be vaporized that conditioning agent flexibly controls active ingredient, to adjust the usage time of mosquito-repellent incense liquid so that active ingredient does not have an impact while air reaches effective mosquito repellent concentration, to health;Stablize active ingredient using stabilizer, delays its speed that fails under ultraviolet light and high temperature;Effectively enhance pharmacological action of the active ingredient to mosquito using synergist, reaches stronger repelling effect, product practicability higher obtained.

Description

A kind of composition and product of mosquito
Technical field
The present invention relates to daily use chemicals consumer goods industries, the composition and product of especially a kind of mosquito.
Background technology
Mosquito is one of communication media of infectious disease.It was found that the disease of mosquitoes spread is up to as many as more than 80 kinds.In the whole world, There are about 1,200,000 people to infect filariasis.The disease of the mosquito meeting infectious disease toxicity of most of kind, including yellow fever, dengue fever, day This encephalitis, St. Louis encephalitis, polyarthirtis, Rift Valley fever (Rift Valley fever), contract elder brother Gen Yare and West Nile Heat etc..It can be seen that mosquito has seriously threatened human health.Expelling mosquito can control epidemic infectious diseases, be to ensure that the mankind are strong Health improves the important research direction of people's lives quality.
For many years, people develop and have used a large amount of hygienic insecticide product, for driving killing mosquitoes.Mosquito-repellent incense is most Ancient natural drug mosquito repellent method.Just there is culicifuge incense stick made of Chinese medicine early in Southern Song Dynasty's period.Modern mosquito-repellent incense has rich Rich product form, such as Mosquito-repellant spray, electric mosquito repellent liquid can effectively be driven and kill mosquito, but there is also some to lack It falls into:(1) active ingredient is vaporized speed and cannot flexibly control, and is vaporized that speed is fast, and repelling effect is good, but insecticidal constituent exists early period Concentration is excessive in air, influences health;(2) light case of thermal instability is met, product failure is too fast.
Invention content
The first invention purpose of the present invention is:In view of the above problems, a kind of composition of mosquito is provided, It is added in the composition and is vaporized conditioning agent and is vaporized speed to adjust active ingredient, adjust the aerial concentration of active ingredient, The influence to human body is reduced while effective desinsection;Being added to stabilizer delays the failure of active ingredient in harsh environment simultaneously Speed increases the practicability of product.
The second goal of the invention of the present invention is that provide a kind of product of mosquito, which contains above-mentioned kill The composition of mosquito.
The technical solution adopted by the present invention is as follows:
A kind of composition of mosquito comprising active ingredient 0.005-20.0% by mass is vaporized conditioning agent 75.0-99.8%, stabilizer 0.05-1.0%, synergist 0.1-5.0%.
In above-mentioned technical proposal, be vaporized that conditioning agent can flexibly control active ingredient is vaporized speed, and mosquito is killed to adjust The usage time of the product of worm, and make active ingredient while air reaches effective mosquito repellent concentration, not to health It has an impact.Stabilizer plays the role of stable active ingredient, delays its speed that fails.Synergist can effectively enhance effectively at Divide the pharmacological action to mosquito, reaches stronger repelling effect.
A kind of composition of mosquito of the present invention, the conditioning agent that is vaporized are selected from fatty linear paraffin, aliphatic side chains It is one or more in alkane, alcohol compound, ketone compounds, ester type compound, deionized water.
A kind of composition of mosquito of the present invention, the alkane and/or isomery for being vaporized conditioning agent and being selected from C9 to C20 Any one or a few in alkane.
A kind of composition of mosquito of the present invention, the stabilizer are selected from organophosphorus compounds, alkyl phosphite And one or more of derivative, alkyl polyoxyethylene ether phosphite ester and derivative.
By adopting the above-described technical solution, can effectively stablize active ingredient under conditions of meeting ultraviolet light and high temperature, protect It protects it not to be degraded, extends usage time.
A kind of composition of mosquito of the present invention, the synergist are Azone.
By adopting the above-described technical solution, the wax coat of synergist energy dissolved destruction mosquito surface hydrophobicity, make effectively at Divide and be easier to enter mosquito horny layer of epidermis, improves the useful effect concentration of active ingredient, hence it is evident that synergy.
The present invention a kind of mosquito composition, the active ingredient be selected from etrafluorine ethofenprox, dimefluthrin, Transfluthrin, seven fluorine methothrins, fluorine chlorine ether pyrethroids, metofluthrin, prallethrin, d_allethrin, chlorine cyanogen chrysanthemum Ester, effective cypermethrin, Imiprothrin, tetramethrin, dtetramethrin, d-phenothrin, d-phenothrin, dimethyl phthalate In any one or a few.
In above-mentioned technical proposal, 2,2,3,3- Tetramethylcycloprop-ne -ne carboxylic acid -2,3 of etrafluorine ethofenprox, 5,6- tetra- fluoro- 4- Methoxyl methyl benzyl ester;Dimefluthrin is 2,3,5,6- tetrafluoro-4-methoxymethyl benzyls base (1RS, 3RS, 3SR) -2,2- two Methyl -3- (2- methyl-1s-allyl) cyclopropanecarboxylcompound;Transfluthrin is the trans- -3- of 1R- (2,2- dichloroethylene) - 2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6- tetrafluoro phenyl) methyl ester;Seven fluorine methothrins are 2,3,5,6- tetra- fluoro- 4- first Oxygen methylbenzyl -3- (3,3,3- tri- fluoro- 1- acrylic) -2,2- dimethyl cyclopropane carboxylic acid's esters;Fluorine chlorine ether pyrethroids is 2,3,5, 6- tetrafluoro-4-methoxymethyl benzyls base (1R, 3S) -3- (2,2- dichloroethylenes) -2,2- dimethyl cyclopropane carboxylic acid's esters;Methoxy benzyl Flumethrin is tetra- fluoro- 4- methoxies benzyls (EZ) of 2,3,5,6--(1RS, 3RS;1RS, 3SR) -2,2- dimethyl -3- (propyl-s 1- alkenyls) cyclopropanecarboxylcompound;Prallethrin be the amyl- 2- alkenyls of (S) -2- methyl -4- oxos -3- (2- propargyls)-rings (1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropanecarboxylcompound;D_allethrin is (1R)-trans- -2,2- two Methyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid-(R, the S) -2- methyl -3- allyls -4- oxos-amyl- 2- alkenyls of ring Ester;Cypermethrin is 2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane-carboxylic acid-alpha-cyano-(3- phenoxy groups)-benzyl ester; Effective cypermethrin is α -2,2- dimethyl -3- (2,2- dichloroethylenes) cyclopropane-carboxylic acid-alpha-cyano-(3- phenoxy groups)-benzyl Ester;Imiprothrin is (2- methyl-1-propylenes base) cyclopropane-carboxylic acid-(R, the S) -2,5- dioxos -3- of 2,2- dimethyl -3 (2- third Alkynyl) -1- imidazole-methyl esters;Tetramethrin is 2,2- dimethyl -3- (2- methyl-1s-allyl) cyclopropane-carboxylic acid -3,4,5,6- Tetrahydrophthalimide ylmethyl ester;Dtetramethrin is that dextrorotation-is suitable, trans- -2,2- dimethyl -3- (2- methyl-1s-allyl) Cyclopropane-carboxylic acid -3,4,5,6- tetrahydrophthalimide ylmethyl esters;D-phenothrin is that dextrorotation-is suitable, trans- -2,2- diformazans Base -3- (2- methyl-1s-allyl) cyclopropane-carboxylic acid-(±) а-cyano -3- phenoxy benzyl esters;D-phenothrin is 3- benzene Oxy-benzyl (1R, 3R;1R, 3S) -2,2 dimethyl -3- (2- methyl propyl- 1- alkenyls) cyclopropanecarboxylcompound;Dimethyl phthalate is 3- (N- Butyl-acetamido) ethyl propionate.
A kind of product of mosquito comprising the composition of acceptable auxiliary material and above-mentioned mosquito.
Acceptable auxiliary material include water, solvent, preservative, interference by insects agent, emulsifier and colorant etc. in the prior art Typical additives.
A kind of product of mosquito of the present invention, specific product form include electric mosquito repellent liquid, the mosquito-repellent incense liquid that volatilizees certainly, kill Worm aerosol, pesticide spray, coiled mosquito-repellent incense, line spices.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
The present invention provides a kind of composition of mosquito, in the composition using be vaporized conditioning agent flexibly control effectively at Point be vaporized speed, to adjust mosquito product usage time, and make active ingredient reach effective in air While mosquito repellent concentration, health is not had an impact;Stablize active ingredient using stabilizer, delays it in ultraviolet light and height The lower speed that fails of temperature;Effectively enhance pharmacological action of the active ingredient to mosquito using synergist, reaches stronger repelling effect.It should Composition can be applicable in mosquito liquid, also applicable to be suitble to incense coil, line spices spary liquid from volatilization mosquito-repellent incense liquid, be applicable in and kill The built-in liquid of worm aerosol, spray.
Specific implementation mode
All features disclosed in this specification or disclosed all methods or in the process the step of, in addition to mutually exclusive Feature and/or step other than, can combine in any way.
Any feature disclosed in this specification (including any accessory claim, abstract), unless specifically stated, It is replaced by other equivalent or with similar purpose alternative features.That is, unless specifically stated, each feature is a series of An example in equivalent or similar characteristics.
Embodiment 1
The present embodiment provides a kind of compositions of mosquito, have using the product of the mosquito made by the composition It is effective more preferably, active ingredient be vaporized that speed is easy to control, meets the characteristics of not degradable light heat, long-term placement stable system.The group It includes active ingredient 0.005g by mass to close object, is vaporized conditioning agent 98.895g, stabilizer 1.0g, synergist 0.1g.
Embodiment 2
The present embodiment provides a kind of compositions of mosquito, have using the product of the mosquito made by the composition It is effective more preferably, active ingredient be vaporized that speed is easy to control, meets the characteristics of not degradable light heat, long-term placement stable system.The group It includes active ingredient 1.0g by mass to close object, is vaporized conditioning agent 93.95g, stabilizer 0.05g, synergist 5.0g.
Embodiment 3
The present embodiment provides a kind of compositions of mosquito, have using the product of the mosquito made by the composition It is effective more preferably, active ingredient be vaporized that speed is easy to control, meets the characteristics of not degradable light heat, long-term placement stable system.The group It includes etrafluorine ethofenprox 2.0g by mass, pentadecane isoparaffin 93.0g, organophosphorus ester 1.0g, N- lauryl to close object Azacycloheptan-2-one 4.0g.
Embodiment 4
The present embodiment provides a kind of compositions of mosquito, have using the product of the mosquito made by the composition It is effective more preferably, active ingredient be vaporized that speed is easy to control, meets the characteristics of not degradable light heat, long-term placement stable system.The group It includes fluorine chlorine ether pyrethroids 0.05g by mass, hexadecane isoparaffin 99.8g, alkyl phosphite 0.05g, the N- month to close object Osmanthus base azacycloheptan-2-one 0.1g.
Embodiment 5
The present embodiment provides a kind of compositions of mosquito, have using the product of the mosquito made by the composition It is effective more preferably, active ingredient be vaporized that speed is easy to control, meets the characteristics of not degradable light heat, long-term placement stable system.The group It includes dimethyl phthalate 10.0g by mass, isopropyl myristate 87.0g, alkyl phosphite 0.5g, N- lauryl nitrogen to close object Trioxepane -2- ketone 2.5g.
Embodiment 6
The present embodiment provides a series of electric mosquito repellent liquids, which includes the composition of mosquito and is subjected to Auxiliary material, include specifically:0.6g transfluthrins, 0.1gN- lauryl azacycloheptan-2-ones, 0.05g alkyl phosphorous acid Ester, 39.0 are vaporized conditioning agent, and it is as shown in table 1 to be vaporized conditioning agent ingredient.Each ingredient is mixed evenly to clear, it is filling In 45mL Packaging Bottles, mosquito-repellent incense liquid special core rod is loaded onto, electric mosquito repellent liquid product identification obtained is 1-17.
Conditioning agent composition is vaporized in 1 1-17 electric mosquito repellent liquids of table
Note:IP2028:213 DEG C of initial boiling point does isoparaffin (the Japanese light extraction based on 262 DEG C of pentadecane isoparaffins Petro Chemicals Co., Ltd.);
ISOPAR M:223 DEG C of initial boiling point does the isoparaffin (Exxon Mobil based on 254 DEG C of hexadecane isoparaffins Company);
SMD95:218 DEG C of initial boiling point does the isoparaffin (Sinopec Group based on 254 DEG C of pentadecane isoparaffins Qingjian River petrochemical industry Co., Ltd);
SMD110:248 DEG C of initial boiling point does the isoparaffin (Sinopec Group based on 266 DEG C of hexadecane isoparaffins Qingjian River petrochemical industry Co., Ltd);
G232H:237 DEG C of initial boiling point does isoparaffin (the Dao Daer lubricating oil based on 263 DEG C of hexadecane isoparaffins (China) Co., Ltd)
G240H:247 DEG C of initial boiling point does isoparaffin (the Dao Daer lubricating oil based on 281 DEG C of octadecane isoparaffins (China) Co., Ltd);
G250H:255 DEG C of initial boiling point does isoparaffin (the Dao Daer lubricating oil based on 326 DEG C of eicosane isoparaffins (China) Co., Ltd);
G3H:278 DEG C of initial boiling point, do based on 321 DEG C of eicosane isoparaffins isoparaffin (Dao Daer lubricating oil (in State) Co., Ltd)
SMD130:281 DEG C of initial boiling point does the isoparaffin (Sinopec Group based on 307 DEG C of eicosane isoparaffins Qingjian River petrochemical industry Co., Ltd);Similarly hereinafter.
Embodiment 7
The present embodiment provides a kind of electric mosquito repellent liquid, which includes the composition of mosquito and acceptable auxiliary Expect, includes specifically:0.6g etrafluorine ethofenproxes, 0.1gN- lauryl azacycloheptan-2-ones, 0.05g alkyl phosphites, 37.9g is vaporized conditioning agent, wherein 33.7 grams of SMD110,4.2 grams of SMD130.Each ingredient is mixed evenly to clear, Filling to load onto mosquito-repellent incense liquid special core rod in 45mL Packaging Bottles, electric mosquito repellent liquid product identification obtained is 18.
Embodiment 8
The present embodiment provides a kind of electric mosquito repellent liquid, which includes the composition of mosquito and acceptable auxiliary Expect, includes specifically:0.48g fluorine chlorine ether pyrethroids, 1.0g tributyl 2-acetylcitrates, 0.05gN- lauryl azepans -2- Ketone, 0.02g alkyl phosphites, 37.5g are vaporized conditioning agent, wherein 34.0gSMD110,3.5gSMD130.Each ingredient is mixed It is evenly stirred until clear, it is filling in 45mL Packaging Bottles, mosquito-repellent incense liquid special core rod is loaded onto, electric mosquito repellent liquid product obtained is compiled Number be 19.
Embodiment 9
The present embodiment provides a kind of electric mosquito repellent liquid, which includes the composition of mosquito and acceptable auxiliary Expect, includes specifically:0.25g dimefluthrins, 0.05gN- lauryl azacycloheptan-2-ones, 0.02g alkyl phosphorous acid Ester, 38g are vaporized conditioning agent, wherein 34.0 grams of SMD110,4.0 grams of SMD130.Each ingredient is mixed evenly saturating to clarification It is bright, it is filling in 45mL Packaging Bottles, mosquito-repellent incense liquid special core rod is loaded onto, electric mosquito repellent liquid product identification obtained is 20.
Embodiment 10
The performance of product 1-20 of the present embodiment to being obtained in embodiment 6-9 is tested, and foundation is provided for its application.It presses Quasi- 18418/T -2009 GB of sighting target"Domestic sanitary desinsection articles for use mosquito liquid"Specified in qualified electric heater it is mating It uses, " the minimum lasting period " of product 1-20 is detected, and test data is shown in Table 2.
The 2 mosquito-repellent incense liquid product 1-20 minimum lasting periods of table
As shown in Table 2:By be vaporized conditioning agent using boiling range it is relatively low be vaporized conditioning agent and boiling range it is higher be vaporized conditioning agent by Certain proportion mixes, and can modulate the usage time of the mosquito liquid of makers-up's needs, reaches mosquito-repellent incense liquid and uses 30h to 1200h.
Mosquito-repellent incense liquid product 1-20 is carried out (hereinafter referred to as to mosquito-repellent incense liquid) with other mosquito-repellent incense liquid in the market selling pair Than experiment:The above mosquito-repellent incense liquid is placed on by the window of sunlight for each two bottles, solar ray energy is allowed to irradiate mosquito-repellent incense liquid, is tested one month, The mosquito-repellent incense liquid discoloration of timing observation daily, experimental result such as the following table 3.
3 mosquito-repellent incense liquid 1-20 of table and comparison mosquito-repellent incense liquid lighting color variation
Note:0-clear, color are unchanged;1-simple yellow;2-is light yellow;3-yellow;4-buffs;5— Deep yellow.
As shown in Table 3:Colour stability is better than other mosquito-repellent incenses sold in the market in mosquito-repellent incense liquid provided by the invention Liquid.
Embodiment 11
The present embodiment provides a kind of from volatilization mosquito-repellent incense liquid comprising the composition of mosquito and acceptable auxiliary material, tool Include body:0.3g metofluthrins, 0.1gN- lauryl azacycloheptan-2-ones, 0.02g alkyl phosphites, 39.0 Gram nonane.Each ingredient is mixed evenly to clear, it is filling in 45mL Packaging Bottles, load onto mosquito-repellent incense liquid special core rod i.e. .It should be used 45 days from volatilization mosquito-repellent incense liquid energy, and meet the HJ2533-2013 of Environmental Protection Department publication in 2013"Environmental mark produces Product technology requires mosquito-repellent incense".
Embodiment 12
The present embodiment provides a kind of spary liquids of incense coil comprising the composition of mosquito and acceptable auxiliary material, Include specifically:1.75g dimefluthrins, 0.1gN- lauryl azacycloheptan-2-ones, 0.01g alkyl phosphites, Each ingredient is mixed evenly to clear for 0.2g essence, 34.0g tasteless kerosenes to obtain the final product.By the above spary liquid medicine jet On 0.8g to 35g mosquito-repellent incense sky bases, the stronger mosquito-repellent incense of effect is made.
Embodiment 13
The present embodiment provides a kind of mosquito repellent aerosol, which includes the composition of mosquito and acceptable auxiliary Expect, includes specifically:2.2g dtetramethrins, 0.5g d_allethrins, 0.5g effective cypermethrins, 1.2gN- lauryl nitrogen Trioxepane -2- ketone, 0.02g alkyl phosphites, 2g essence, 235gSMD110,160LPG propellants.Propellant will be gone out first Except each ingredient be mixed evenly to clear, be made aerosol liquid preparation, the liquid preparation is filling in gas In mist tank, it is filled into propellant to obtain the final product.The aerosol insecticidal synergistic is more powerful, meets the HJ/ of Environmental Protection Department publication T423—2008"Environmental labelling product technology requires insect aerosol"It is required that.
Embodiment 14
The present embodiment carries out performance detection to the mosquito repellent aerosol that embodiment 13 provides, and foundation is provided for its application.Wherein, Trial target is the mosquito repellent aerosol (hereinafter referred to as this aerosol) provided in embodiment 13, is removed in reference substance and does not contain N- lauryls Outside azacycloheptan-2-one, other compositions, that is, content is identical as trial target.
By two above sample according to GB/T 17322.2-2009"Agriculture chemical registration hygienic insecticide indoor pharmacodynamic test And evaluation part 2:Aerosol"It is tested, experimental result is shown in Table 4.
4 aerosols of table are compared with reference substance repelling effect
As shown in Table 4, it is added to desinsection of the Azone as this mosquito repellent aerosol of synergist It is with obvious effects to be better than reference substance.
The invention is not limited in specific implementation modes above-mentioned.The present invention, which expands to, any in the present specification to be disclosed New feature or any new combination, and disclose any new method or process the step of or any new combination.

Claims (8)

1. a kind of composition of mosquito, which is characterized in that it includes active ingredient 0.005-20.0% by mass, is waved Dissipate conditioning agent 75.0-99.8%, stabilizer 0.05-1.0%, synergist 0.1-5.0%.
2. the composition of mosquito according to claim 1, which is characterized in that the conditioning agent that is vaporized is selected from fat directly It is one or more in alkane, aliphatic side chains alkane, alcohol compound, ketone compounds, ester type compound, deionized water.
3. the composition of mosquito according to claim 2, which is characterized in that the conditioning agent that is vaporized is arrived selected from C9 The alkane of C20 and/or any one or a few in isoparaffin.
4. the composition of mosquito according to claim 1, which is characterized in that the stabilizer is selected from organophosphorus ester One or more of class, alkyl phosphite and derivative, alkyl polyoxyethylene ether phosphite ester and derivative.
5. the composition of mosquito according to claim 1, which is characterized in that the synergist is N- lauryl azepines Cycloheptane -2- ketone.
6. the composition of mosquito according to any one of claims 1-5, which is characterized in that the active ingredient choosing From etrafluorine ethofenprox, dimefluthrin, transfluthrin, seven fluorine methothrins, fluorine chlorine ether pyrethroids, metofluthrin, alkynes Third pyrethroids, d_allethrin, cypermethrin, effective cypermethrin, Imiprothrin, tetramethrin, dtetramethrin, dextrorotation phenylate Any one or a few in Cyano chrysanthemate, d-phenothrin, dimethyl phthalate.
7. a kind of product of mosquito, which is characterized in that it includes any one of acceptable auxiliary material and claim 1-7 institute The composition for the mosquito stated.
8. the product of mosquito according to claim 7, which is characterized in that its specific product form includes electric mosquito repellent Liquid, certainly volatilization mosquito-repellent incense liquid, insect aerosol, pesticide spray, coiled mosquito-repellent incense, line spices.
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