CN108680024A - A kind of compound masonry construction of the full clay checker brick of coke oven regenerator - Google Patents

A kind of compound masonry construction of the full clay checker brick of coke oven regenerator Download PDF

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Publication number
CN108680024A
CN108680024A CN201810477735.1A CN201810477735A CN108680024A CN 108680024 A CN108680024 A CN 108680024A CN 201810477735 A CN201810477735 A CN 201810477735A CN 108680024 A CN108680024 A CN 108680024A
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brick
clay
coke oven
plies
checker brick
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CN108680024B (en
Inventor
徐国涛
盛军波
张洪雷
杨帆
王大春
张丙旭
崔会明
魏编
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Wuhan Iron and Steel Co Ltd
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Wuhan Iron and Steel Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/04Casings; Linings; Walls; Roofs characterised by the form, e.g. shape of the bricks or blocks used
    • F27D1/042Bricks shaped for use in regenerators
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/04Casings; Linings; Walls; Roofs characterised by the form, e.g. shape of the bricks or blocks used
    • F27D1/06Composite bricks or blocks, e.g. panels, modules
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, the clay grid brick masonry of the lower part of regenerative chamber by apparent porosity 17~20%, the number of plies, which accounts for regenerative chamber, builds the percentage of total number of plies by laying bricks or stones and is not less than 60%;Leck grid brick masonry of the top of regenerative chamber by apparent porosity 10~16%, the number of plies account for regenerative chamber and build the percentage of total number of plies by laying bricks or stones no more than 40%.The present invention can make the refractoriness under load of regenerator lattice brick improve 50 150 DEG C, the croop property of high temperature can increase substantially, the creep rate creep rate absolute value of 5 ~ 25 hour leck checker brick is kept to be not more than 0.4% at a temperature of 1350 DEG C, 50% or more is reduced than the creep rate of general coke oven clay checker brick compares, to solve coke oven regenerator top checker brick it is soft melt deformation and play good effect, reference function is provided with material to the checker brick structure of domestic other coke ovens.

Description

A kind of compound masonry construction of the full clay checker brick of coke oven regenerator
Technical field
The present invention relates to a kind of coking industry coke oven technical fields, definitely belong to a kind of answering for coke oven regenerator checker brick Close masonry construction.
Background technology
7.63m coke ovens are the especially big volumes of Recuperative heat type that the heat stepwise of German Wood Company exploitation is combined with waste gas circulation Coke oven produces 2130000 t/a of dry full coke per year, and technique is provided by Wood company, and Zhong Yejiaonai companies carry out transfer design.1 7.63m The various refractory materials of coke oven up to 30,000 t, up to more than 1100 plant by special form brick, according to the different operating modes at each position of coke oven, selects silicon respectively The refractory material laying of the types such as brick, semi-silica brick, clay brick, high-alumina insulated brick, sillimanite brick, common brick and castable.In Wood In the Basic Design of company, 7.63m coke oven Main Refractories use German Standard (DIN standards), the conversion of Zhong Yejiaonai companies If the index of silica brick, semi-silica brick is increased a bulk density by timing reference Chinese Industrial Standards (CIS).Refractory material is wide in variety, of large quantities And if each refractory material has many index controls bad, can influence service life and the normal operation of coke oven again.The use of coke oven Service life, some were up to 30 years or more, and regenerative chamber is mostly clay brick and semi-silica brick with refractory material, less with rear performance study.
Wuhan Iron and Steel Plant company possesses 7.63m large capacity coke ovens 2,7m coke ovens 2,6m coke ovens 5, coke annual production capacity 624 Ten thousand tons.Two 7.63 m capacity coke ovens technologies are introduced from Germany, are gone into operation respectively in March, 2008, June.Regenerative chamber uses lattice Formula designs, and air and coal gas are adjusted by regenerative chamber lower part jet tray.After going into operation 5 years, 7.63 m coke ovens part carbonization chambers Coke wilfully(It is generally called low temperature number), cause to generate a large amount of black flue dust when coke pushing, while finding basement portion Pan Chu Gas leakage severely exceeds.In 7.63m coke oven processs of construction, regenerative chamber uses the clay of Henan D refractory Companies production The semi-silica brick of checker brick and the production of Henan J refractory Companies, there are problem, regenerator lattice bricks deformation, melting loss occurs for quality. To find out its cause, the quality with refractory material is related, it is also related with technological parameter with the production technology characteristic of 7.63m coke ovens.
Coke oven regenerator checker brick generally use clay brick;Some producers are to reduce cost using waste material even three-level alumina The main material flint clay of quartz substitution clay brick is added.So that when coke oven BF gas heating, regenerative chamber top checker brick exist It is corroded by sour gas under reducing atmosphere, generates swell.Regenerative chamber top checker brick mostly use low aluminium clay checker brick;Lower part With the clay brick of AW-2, alumina content is close to 40%, but in Wuhan Iron and Steel Plant 10#、9#It is found in the investigation on the spot of coke oven:Top clay There is melting loss in checker brick and foaming deforms.Clay checker brick bulk density 2.32g/cm used in Wuhan Iron and Steel Plant3, alumina content 48.85%, it is desirable that bulk density is not less than 2.1g/cm3, alumina content is not less than 40%.
Semi-silica brick refers to SiO2Content be more than 65% alumina-silica refractory product, generally with containing quartz sand fire clay, Pyrophyllite and fire clay or the tailing of kaolin ore dressing make raw material.Dilatancy after semi-silica brick is heated is less big, this Micro expansion speciality is conducive to improve the globality of masonry.Semi-silica brick can weaken slag to masonry corrode, when high-temperature slag with Generates the larger enamel-like substance of one layer of viscosity on the surface of brick after the contact of brick surface, slag can be prevented to continue to permeate into brick, shape At layer protective layer, to improve the corrosion resistance of brick.Semi-silica brick is for coke oven regenerator middle and lower part using semi-silica brick Purpose is tightness in order to ensure masonry and prevents sour gas from corroding (when BF gas heating).The thermal expansion of semi-silica brick Between clay brick and silica brick, pyrophyllite dosage needs stringent control with firing temperature in dispensing, to ensure physical and chemical index Reach requirement.The country produces the lack of material of semi-silica brick since pyrophillite raw material resources are limited, and part of the manufacturer is quartzy using being added The ingredient of the raw material adjustment semi-silica brick of equal silicon oxide-containings, but its performance is affected, and is susceptible to the problem of deforming melting loss. Half silicon checker brick bulk density 2.05-2.15g/cm used in Wuhan Iron and Steel Plant3, alumina content 48.85%.
Coke oven regenerator checker brick using clay checker brick and semi-silica brick are compound build by laying bricks or stones by the way of, such as 4 layers of bottom clay Checker brick, 6 layer half of middle part silicon checker brick, 6 layers of top clay checker brick.Such structure has problems in that if top coal Gas is tempered or leakage, and temperature could possibly be higher than 1300 DEG C or even to 1400 DEG C, at this moment, the loading softening temperature of common clay checker brick Degree require be only deformation 0.6% when be not less than 1450 DEG C, 40 DEG C of error range, a coke oven maximum life span at 30 years or more, this The heat exchange for influencing air-flow at the top of sample after checker brick deformation, is finally easily deformed blocking stomata, and it is relatively low temperature occur, influences coke oven Coking time and coking temperature, wilfully, coke pushing over-emitting black exhaust produces impacted coke.
Through retrieval
Blast furnace leck brick (CN201510649925.3) patent of invention includes matrix, including the base at center and is set It is placed in the compacted zone of base upper surface, base lower surface is provided with heat insulating porous layer, and heat insulating porous layer thickness is the 1/3 of base, Dense layer thickness is the 1/5 of base, and substrate surface is evenly equipped with the blind hole that aperture is 10mm ~ 15mm, water has been poured in blind hole Material-mud.High pressure-temperature is molded, firm in structure, of low cost, high temperature resistant, and thermal stability is good.The document is only glutinous from effect The technical measures that the structure of cob brick is taken, but it prepares the complex process of brick, and the structure of brick is also relative complex.
A kind of low aluminium checker brick of coke oven and production technology (CN201610883974.8) patent of invention disclose a kind of coke The low aluminium checker brick of stove and production technology.The low aluminium checker brick of the coke oven are by mass percentage at being grouped as:Semisoft clay 30%, flint clay 55%, fire-clay grog 15%, additional organic bond lignosulfite 2%.The grid of the present invention Brick is low aluminum products, and low aluminum products are half acid refractory products, at high operating temperatures volume stability, and alkali resistance atmosphere capability is strong, And load softening point is high, improves applied at elevated temperature intensity, it is more suitable for coke furnace carbonization chamber bottom, regenerative chamber, double-edged fine-toothed comb brick;Using The New Type Material can extend the service life of checker brick, smoothly ensure the normal heat exchange of coke oven, be provided with for coking production stabilization Effect ground ensures support.The document is also the problem existing for the brick from solution, is asked from the solution of the structure of regenerative chamber Topic.
Invention content
The invention reside in the shortcomings of the prior art is overcome, a kind of used by coke oven regenerator checker brick is provided and shows gas The compound mode built by laying bricks or stones of the different clay checker brick of porosity improves the high-temperature behavior of coke oven regenerator superstructure, reduces coke oven The coke oven regenerator of coke oven regenerator service life can be improved in order to avoid influencing heat exchanger effectiveness in the deformation of regenerative chamber superstructure The compound masonry construction of the full clay brick of grid.
Realize the measure of above-mentioned purpose:
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 17~20% clay grid brick masonry, the number of plies account for regenerative chamber and build the percentage of total number of plies by laying bricks or stones not less than 60%;Regenerative chamber it is upper Leck grid brick masonry of the portion by apparent porosity 10~16%, the number of plies account for regenerative chamber and build the percentage of total number of plies by laying bricks or stones not More than 40%.
It is:The physical property of the leck checker brick:Its quality of alumina degree 39%~ 50%, apparent porosity is 10~16%;Refractoriness under load is not less than 1510 DEG C;The compacted of 5~25 hours is kept at 1350 DEG C The absolute value of variability is not more than 0.4%.
It is:The leck checker brick, the flint clay aggregate 50-70% containing 3-1mm in forming;Leaf is cured Stone fine powder 1-5%;Granularity is not more than 0.074mm flint clay fine powders 10-20%;Granularity is not more than 50 microns of kaolin fine powder 1- 8%;Granularity is not more than 50 microns of alumina powder 0.5-10%;Mild-clay 8-15%.
Preferably:Leck grid brick masonry of the top of regenerative chamber by apparent porosity 12~14%, the number of plies account for storage Build the 20 ~ 30% of total number of plies by laying bricks or stones in hot cell.
Preferably:The quality of alumina degree of the leck checker brick is 41%~46%.
The present invention why using apparent porosity 10~16% leck checker brick and lower part apparent porosity 17~ 20% clay checker brick progress is compound to build by laying bricks or stones, is the tempering due to facing coal gas at the top of coke oven regenerator, string fire, dust richness Collection, the destructive factors such as corrosion of the gas containing S exist in coal gas, general coke oven clay checker brick temperature in use at 1300-1350 DEG C, If facing tempering, string fire, dust enrichment, be easy for occurring deformation, it is soft melt, foam, if using fine and close clay checker brick, Its high temperature resistance improves, and the penetrating power enhancing of anti-gas, using effect can improve significantly.And its leck grid Brick is prepared using prior art.
Compared with prior art, the present invention the present invention can make the refractoriness under load of regenerator lattice brick improve 50-150 DEG C, the croop property of high temperature can increase substantially, and keep the absolute value of the creep rate of 5~25 hours to be not more than at 1350 DEG C 0.4%, 50% or more is reduced than the creep rate of general coke oven clay checker brick compares, to solving coke oven regenerator top checker brick It is soft melt deformation and play good effect, reference function is provided with material to the checker brick structure of domestic other coke ovens.
Specific implementation mode
The present invention is described in detail below:
Embodiment 1
For the present embodiment coke oven regenerator according to calculating, total number of plies is 16 layers;
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 19.2% 10 layers of clay grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 63%;The top of regenerative chamber is existed by apparent porosity 15.9% 6 layers of leck grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 37%.
The physical property of the leck checker brick:Its quality of alumina degree is 44.3%, apparent porosity 13.9%;1523 DEG C of refractoriness under load;The creep rate -0.29% of 5~25 hours is kept at 1350 DEG C of high temperature.
The leck checker brick, the flint clay aggregate 55% containing 3-1mm in forming;Pyrophillite fine powder 5%;Grain Degree is not more than 0.074mm flint clays fine powder 20%;Granularity is not more than 50 microns of kaolin fine powder 3%;Granularity is not more than 50 microns Alumina powder 7%;Mild-clay 10%.Its leck checker brick is prepared using prior art.
It has been tried out after building by laying bricks or stones 12 months, not it has been found that 6 layers of coke oven regenerator top checker brick melt metaboly there are soft. To improve coke oven regenerator checker brick service life, reduce maintenance cost.
Embodiment 2
For the present embodiment coke oven regenerator according to calculating, total number of plies is 24 layers;
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 18.7% 18 layers of clay grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 75%;The top of regenerative chamber is existed by apparent porosity 10.5% 6 layers of leck grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 25%.
The physical property of the leck checker brick:Its quality of alumina degree is 45.9%, apparent porosity 12.5%;1547 DEG C of refractoriness under load;The creep rate -0.22% of 5~25 hours is kept at 1350 DEG C of high temperature.
It is:The leck checker brick, the flint clay aggregate 64% containing 3-1mm in forming;Pyrophillite is thin Powder 1%;Granularity is not more than 0.074mm flint clays fine powder 19%;Granularity is not more than 50 microns of kaolin fine powder 1%;Granularity is not more than 50 microns of alumina powder 10%;Mild-clay 15%.Its leck checker brick is prepared using prior art.
It has been tried out after building by laying bricks or stones 12 months, not it has been found that 6 layers of coke oven regenerator top checker brick melt metaboly there are soft. To improve coke oven regenerator checker brick service life, reduce maintenance cost.
Embodiment 3
For the present embodiment coke oven regenerator according to calculating, total number of plies is 22 layers;
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 17.2% 14 layers of clay grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 64%;The top of regenerative chamber is existed by apparent porosity 13.7% 8 layers of leck grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 36%.
The physical property of the leck checker brick:Its quality of alumina degree is 47.5%, apparent porosity 15.7%;1519 DEG C of refractoriness under load;- the 0.31% of the creep rate of 5~25 hours is kept at 1350 DEG C of high temperature.
The leck checker brick, the flint clay aggregate 60% containing 3-1mm in forming;Pyrophillite fine powder 3%;Grain Degree is not more than 0.074mm flint clays fine powder 10%;Granularity is not more than 50 microns of kaolin fine powder 4%;Granularity is not more than 50 microns Alumina powder 8%;Mild-clay 15%.Its leck checker brick is prepared using prior art.
It has been tried out after building by laying bricks or stones 12 months, not it has been found that 8 layers of coke oven regenerator top checker brick melt metaboly there are soft. To improve coke oven regenerator checker brick service life, reduce maintenance cost.
Embodiment 4
For the present embodiment coke oven regenerator according to calculating, total number of plies is 24 layers;
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 17.6% 19 layers of clay grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 79%;The top of regenerative chamber is existed by apparent porosity 11.8% 5 layers of leck grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 21%.
The physical property of the leck checker brick:Its quality of alumina degree is 48.5%, apparent porosity 10.8%;1520 DEG C of refractoriness under load;The creep rate -0.35% of 5~25 hours is kept at 1350 DEG C of high temperature.
The leck checker brick, the flint clay aggregate 53% containing 3-1mm in forming;Pyrophillite fine powder 5%;Grain Degree is not more than 0.074mm flint clays fine powder 20%;Granularity is not more than 50 microns of kaolin fine powder 5%;Granularity is not more than 50 microns Alumina powder 9%;Mild-clay 8%.Its leck checker brick is prepared using prior art.
It has been tried out after building by laying bricks or stones 12 months, not it has been found that 5 layers of coke oven regenerator top checker brick melt metaboly there are soft. To improve coke oven regenerator checker brick service life, reduce maintenance cost.
Embodiment 5
For the present embodiment coke oven regenerator according to calculating, total number of plies is 26 layers;
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 19.1% 18 layers of clay grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 70%;The top of regenerative chamber is existed by apparent porosity 12.6% 8 layers of leck grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 30%.
The physical property of the leck checker brick:Its quality of alumina degree is 40.3%, apparent porosity 12.6%;1513 DEG C of refractoriness under load;The creep rate -0.32% of 5~25 hours is kept at 1350 DEG C of high temperature.
The leck checker brick, the flint clay aggregate 64.5% containing 3-1mm in forming;Pyrophillite fine powder 1%; Granularity is not more than 0.074mm flint clays fine powder 20%;Granularity is not more than 50 microns of kaolin fine powder 1%;Granularity is micro- no more than 50 The alumina powder 0.5% of rice;Mild-clay 13%.Its leck checker brick is prepared using prior art.
It has been tried out after building by laying bricks or stones 12 months, not it has been found that 6 layers of coke oven regenerator top checker brick melt metaboly there are soft. To improve coke oven regenerator checker brick service life, reduce maintenance cost.
Embodiment 6
For the present embodiment coke oven regenerator according to calculating, total number of plies is 24 layers;
A kind of compound masonry construction of the full clay checker brick of coke oven regenerator, is:The lower part of regenerative chamber is existed by apparent porosity 19.9% 19 layers of clay grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 79%;The top of regenerative chamber is existed by apparent porosity 15.2% 5 layers of leck grid brick masonry, accounts for regenerative chamber builds total number of plies by laying bricks or stones 21%.
The physical property of the leck checker brick:Its quality of alumina degree is 45.2%, apparent porosity 13.2%;1525 DEG C of refractoriness under load;The creep rate -0.19% of 5~25 hours is kept at 1350 DEG C of high temperature.
The leck checker brick, the flint clay aggregate 64% containing 3-1mm in forming;Pyrophillite fine powder 3%;Grain Degree is not more than 0.074mm flint clays fine powder 12%;Granularity is not more than 50 microns of kaolin fine powder 7%;Granularity is not more than 50 microns Alumina powder 6%;Mild-clay 8%.Its leck checker brick is prepared using prior art.
It has been tried out after building by laying bricks or stones 12 months, not it has been found that 6 layers of coke oven regenerator top checker brick melt metaboly there are soft. To improve coke oven regenerator checker brick service life, reduce maintenance cost.
Present embodiment is only the best example, not to the restricted implementation of technical solution of the present invention.

Claims (5)

1. a kind of compound masonry construction of the full clay checker brick of coke oven regenerator, it is characterised in that:In the lower part of regenerative chamber by showing Clay grid brick masonry of the porosity 17~20%, the number of plies account for regenerative chamber and build the percentage of total number of plies by laying bricks or stones not less than 60%;It stores Leck grid brick masonry of the top in hot cell by apparent porosity 10~16%, the number of plies account for regenerative chamber and build total number of plies by laying bricks or stones Percentage is no more than 40%.
2. a kind of compound masonry construction of the full clay brick of coke oven regenerator grid as described in claim 1, it is characterised in that:Institute The physical property for the leck checker brick stated:Its quality of alumina degree 39%~50%, apparent porosity 10~ 16%;Refractoriness under load is not less than 1510 DEG C;Keep the absolute value of the creep rate of 5~25 hours little at 1350 DEG C of high temperature In 0.4%.
3. a kind of compound masonry construction of the full clay brick of coke oven regenerator grid as described in claim 1, it is characterised in that:Institute The leck checker brick stated, the flint clay aggregate 50-70% containing 3-1mm in forming;Pyrophillite fine powder 1-5%;Granularity is not More than 0.074mm flint clay fine powders 10-20%;Granularity is not more than 50 microns of kaolin fine powder 1-8%;Granularity is not more than 50 microns Alumina powder 0.5-10%;Mild-clay 8-15%.
4. a kind of compound masonry construction of the full clay brick of coke oven regenerator grid as described in claim 1, it is characterised in that:It stores Leck grid brick masonry of the top in hot cell by apparent porosity 12~14%, the number of plies account for regenerative chamber and build total number of plies by laying bricks or stones 20~30%。
5. a kind of compound masonry construction of the full clay brick of coke oven regenerator grid as claimed in claim 2, it is characterised in that:Institute The quality of alumina degree for the leck checker brick stated is 41%~46%.
CN201810477735.1A 2018-05-18 2018-05-18 Composite masonry structure of all-clay checker bricks of coke oven regenerator Active CN108680024B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111574191A (en) * 2020-05-25 2020-08-25 郑州宏瑞耐火材料有限公司 Semi-silica brick for multi-electrode magnesium electrolytic cell and preparation process thereof
CN112341177A (en) * 2020-09-28 2021-02-09 山东耐材集团鲁耐窑业有限公司 Corrosion-resistant compact lattice brick for upper part of coke oven regenerator and preparation method thereof

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