CN108676627A - Dry-cleaning and water-washing multifunctional detergent and preparation method thereof - Google Patents

Dry-cleaning and water-washing multifunctional detergent and preparation method thereof Download PDF

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Publication number
CN108676627A
CN108676627A CN201810677147.2A CN201810677147A CN108676627A CN 108676627 A CN108676627 A CN 108676627A CN 201810677147 A CN201810677147 A CN 201810677147A CN 108676627 A CN108676627 A CN 108676627A
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parts
content
agent
dry
oil
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CN108676627B (en
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张丹
武玉和
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Shandong Huanuo Daily Chemical Co ltd
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Jiangnan University
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2034Monohydric alcohols aromatic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a dry cleaning and washing multifunctional detergent and a preparation method and application thereof, and the detergent comprises a solvent, a detergent additive and a dispersing solubilizer, wherein the dispersing solubilizer comprises 3-12 parts by mass, the detergent additive comprises 20-35 parts by mass and the solvent comprises 800-895 parts by mass. The multifunctional detergent for dry cleaning and washing of the invention has the advantages that the adsorbent powder can not be agglomerated after being dried, can not be adhered to the fabric, and can be removed by applying external force slightly, so that white ring-shaped marks are not easy to form on the fabric, and secondary pollution is caused. On the contrary, after the product is used, the fabric is more flexible, is difficult to generate static electricity and has bright color due to the action of the effective substances.

Description

A kind of dry-cleaning washing Multifunctional decontaminating agent and preparation method thereof
Technical field
The invention belongs to detergent technology fields, and in particular to a kind of dry-cleaning washing Multifunctional decontaminating agent and its preparation side Method.
Background technology
In daily life, people always easily meet the spot of some bursts, and these spots are then in the majority with oiliness, and past It is adhered on the fabrics such as clothing shoes toward with concentrations such as small area, scatterplot shapes, brings inconvenience.In addition the fast section of the modern life Play, people feel more worried for cleaning this kind of clothes, and especially breadth is larger or is not easy clean fabric, as slip cover, western-style clothes, Bedding etc., if an only small pieces spot and go to clean entire fabric, not only take time and effort, effect is also got half the result with twice the effort, and makes one sunken Enter awkward condition.At this moment, a kind of light and handy and efficient Non-water washing spray dry washing agent, which just seems, particularly helps meet an urgent need and convenient.
Existing dry detergent uses chloralkane, alkene equal solvent mostly, has toxicity, therefore develop using pure natural Oil-based solvent, adsorbent moderate in grain size is nontoxic, and environmentally protective dry cleaning agent, which becomes this field, has technology to be solved to ask Topic.
Invention content
The purpose of this part is to summarize some aspects of the embodiment of the present invention and briefly introduce some preferably to implement Example.It may do a little simplified or be omitted to avoid our department is made in this section and the description of the application and the title of the invention Point, the purpose of abstract of description and denomination of invention it is fuzzy, and this simplification or omit and cannot be used for limiting the scope of the invention.
In view of above-mentioned technological deficiency, it is proposed that the present invention.
Therefore, as one aspect of the present invention, the present invention overcomes the deficiencies in the prior art, provides a kind of dry Wash water washes Multifunctional decontaminating agent.
In order to solve the above technical problems, the present invention provides following technical solutions:A kind of dry-cleaning washing Multifunctional decontaminating agent, It includes solvent, decontamination auxiliary agent, dispersion solubilizer, wherein in terms of mass fraction, the dispersion solubilizer level is 3~12 Part, the decontamination auxiliary agent content are 20~35 parts, the solvent content is 800~895 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:Further include adsorbent, anti-corrosion Agent, antistatic agent, wherein in terms of mass fraction, the absorption agent content is 70~130 parts, the antiseptic content is 2~3 Part, the antistatic agent content are 10~20 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:The solvent by orange oil, Turpentine oil, eucalyptus oil, ethyl alcohol composition, in terms of mass fraction, the sweet orange oil content is 450~470 parts, the Turpentine -content For 155~175 parts, the folium eucalypti oil content be 150~160 parts, the ethanol content is 50~52 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:The decontamination auxiliary agent is by vinegar Acid, ethyl acetate, butyl acetate, neopelex, sodium sulfate of polyethenoxy ether of fatty alcohol composition, with mass fraction Meter, the acetic acid content is 4 parts, the ethyl acetate content is 6 parts, the butyl acetate content is 5~6 parts, described 12 Alkyl benzene sulphonate sodium content is 8 parts, the sodium sulfate of polyethenoxy ether of fatty alcohol content is 7 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:The dispersion solubilizer is by gathering Ethylene glycol -200, dimethicone, paraffin oil, butyl glycol ether composition, in terms of mass fraction, -200 content of the polyethylene glycol For 3~3.5 parts, the dimethyl-silicon oil content be 3~3.5 parts, the paraffin oil content is 1.5~2 parts, butyl glycol ether contains Amount is 2.5~3 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:The preservative is by thyme Phenol, Sensiva SC50, Phenoxyethanol composition, in terms of mass fraction, the thymol content is 1 part, the ethylhexyl Glycerol content is 0.2 part, the Phenoxyethanol content is 1.8 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:The adsorbent be 800~ The silica gel of 1500 mesh, in terms of mass fraction, the content of the silica gel of 800~1500 mesh is 100~130 parts.
A kind of preferred embodiment as dry-cleaning washing Multifunctional decontaminating agent of the present invention:The antistatic agent is silica gel With antistatic agent, in terms of mass fraction, the content of the silica gel antistatic agent is 20 parts.
As another aspect of the present invention, the present invention overcomes the deficiencies in the prior art, provides the dry-cleaning water Wash the preparation method of Multifunctional decontaminating agent.
In order to solve the above technical problems, the present invention provides following technical solutions:Multifunctional decontaminating agent is washed in the dry-cleaning Preparation method comprising, 3~12 parts of dispersion solubilizer and 800 is added in the silica gel of 70~130 parts of 800~1500 mesh It is antistatic that 20~35 parts of decontamination auxiliary agent, 2~3 parts of preservative and 10~20 parts are added in~895 parts of solvent after mixing Agent seals and carries out canned packaging in the state of being stirred continuously immediately.
Beneficial effects of the present invention:Multifunctional decontaminating agent is washed in the dry-cleaning of the present invention, and oil-based solvent is different from common Halogenated alkane, alkene etc., and based on natural extract, it is green safe.Adsorbent size controlling is at 10 μm or so, at convenient point Dissipate while, will not because powder is meticulous reach nanoscale due to human body is caused potentially to injure, to be truly realized nontoxic nothing Evil, it is environmental-friendly.
Multifunctional decontaminating agent is washed in the dry-cleaning of the present invention, will not be lumpd after absorbent powder drying, will not be adhered to and knit On object, slightly external force can remove, therefore be not easy to form the white round marking on the fabric, cause secondary pollution.On the contrary, using this After product, due to the effect of active principle, fabric can more compliant, difficult electrostatic, bright in luster.
Description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Attached drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for this For the those of ordinary skill of field, without having to pay creative labor, it can also be obtained according to these attached drawings other Attached drawing.Wherein:
Fig. 1 is detergent-treatment thicker chemical & blended fabric compares figure before and after the processing prepared by the embodiment of the present invention 1.
Fig. 2 is the detergent-treatment thicker chemical & blended fabric compares figure before and after the processing of reference examples 1 of the present invention preparation.
Fig. 3 is the detergent-treatment thicker chemical & blended fabric compares figure before and after the processing of reference examples 4 of the present invention preparation.
Fig. 4 is the detergent-treatment thicker chemical & blended fabric compares figure before and after the processing of reference examples 5 of the present invention preparation.
Specific implementation mode
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, with reference to specific embodiment pair The specific implementation mode of the present invention is described in detail.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still the present invention can be with Implemented different from other manner described here using other, those skilled in the art can be without prejudice to intension of the present invention In the case of do similar popularization, therefore the present invention is not limited by following public specific embodiment.
Secondly, " one embodiment " or " embodiment " referred to herein refers to that may be included at least one realization side of the present invention A particular feature, structure, or characteristic in formula." in one embodiment " that different places occur in the present specification not refers both to The same embodiment, nor the individual or selective embodiment mutually exclusive with other embodiment.
Embodiment 1:
The silica gel of 100 parts of 800-1500 mesh is first added in a reservoir, adds 3 parts of polyethylene glycol -200,3 parts of dimethyl Silicone oil, 1.5 parts of paraffin oils, 2.5 parts of butyl glycol ethers disperse solubilizer, add 450 parts of orange oils, 175 parts of turpentine oil, 160 Part eucalyptus oil, 52 parts of alcohol solvents, stirring continue that 4 parts of acetic acid, 6 parts of ethyl acetates, 5 parts of acetic acid fourths are added wherein for several times afterwards Ester, 8 parts of neopelexes, 7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol decontamination auxiliary agents, add 1 part of thymol, 0.2 part of Sensiva SC50,1.8 parts of phenoxyethanol preservatives and 20 parts of silica gel antistatic agents seal and immediately continuous Canned packaging is carried out in the state of stirring.
Acquired solution is that troubled liquor of the milky to milk yellow is layered, after layering without apparent viscosity after standing 20min Upper layer is clarified, and solid absorbent sinks, but homogeneous phase can be returned after upper and lower shaken several times.
Test:On chemical fibre, hair, silk weaving object and slim cotton fabric, Fig. 1 is decontamination prepared by the embodiment of the present invention 1 Agent handles thicker chemical & blended fabric, and Fig. 1 a is before decontamination, Fig. 1 b is after decontamination, spot are from left to right followed successively by greasy dirt, coffee, iron Rust, dust, this formula is to most of oil-dirt (such as edible oil, chilli oil, machine oil, ballpoint pen oil, solid grease), part Beverage spot (such as coffee, milk, milk shake, ice cream, tea, fruit juice), iron rust, surface layer dust etc. have good decontamination to imitate Fruit, using soil removal efficiency after 1 time, powder easily removes after 98% or more, drying, and fabric is submissiveer.
Embodiment 2:
In a reservoir first be added 130 parts 800-1500 mesh silica gel, add 3.5 parts of polyethylene glycol -200,3.5 part two Methyl-silicone oil, 2 parts of paraffin oils, 3 parts of butyl glycol ethers disperse solubilizer, add 450 parts of orange oils, 155 parts of turpentine oil, 150 Part eucalyptus oil, 50 parts of alcohol solvents, stirring continue that 4 parts of acetic acid, 6 parts of ethyl acetates, 5 parts of acetic acid fourths are added wherein for several times afterwards Ester, 8 parts of neopelexes, 7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol decontamination auxiliary agents, add 1 part of thymol, 0.2 part of Sensiva SC50,1.8 parts of phenoxyethanol preservatives and 20 parts of silica gel antistatic agents seal and immediately continuous Canned packaging is carried out in the state of stirring can (cost be slightly higher but solution-stabilized, and clean effect is suitable with embodiment 1).
Acquired solution be milky to the troubled liquor of milk yellow, viscosity is higher, stand 1h be just layered, upper layer is clear after layering Clearly, solid absorbent sinks, but can return homogeneous phase after concussion for several times up and down.
Test:On chemical fibre, hair, silk weaving object and slim cotton fabric, this formula is to most of oil-dirt (as eaten Oil, chilli oil, machine oil, ballpoint pen oil, solid grease etc.), part beverage spot (such as coffee, milk, milk shake, ice cream, tea Water, fruit juice), iron rust, surface layer dust have a good clean effect (using soil removal efficiency after 1 time 98% or more), it is dry after powder Last easily removal, fabric are submissiveer.
Reference examples 1:
In a reservoir first be added 100 parts 800-1500 mesh silica gel, add 460 parts of orange oils, 175 parts of turpentine oil, 160 parts of eucalyptus oils, 52 parts of alcohol solvents, stirring continue that 4 parts of acetic acid, 6 parts of ethyl acetates, 5 parts of acetic acid are added wherein for several times afterwards Butyl ester, 8 parts of neopelexes, 7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol decontamination auxiliary agents, add 1 part of thymol, 0.2 part of Sensiva SC50,1.8 parts of phenoxyethanol preservatives and 20 parts of silica gel antistatic agents seal and immediately continuous Carried out in the state of stirring canned packaging can (compared with Example 1 non-bonus point dissipate solubilizer, and with solvent make-up surplus).
Acquired solution is troubled liquor of the milky to milk yellow, without apparent viscosity, stands 1min and is layered, after layering on Layer clarification, solid absorbent sinks, but homogeneous phase can be returned after upper and lower shaken several times.
Test:On chemical fibre, hair, silk weaving object and slim cotton fabric, Fig. 2 is decontamination prepared by reference examples 1 of the present invention Agent handles thicker chemical & blended fabric, and Fig. 2 a is before decontamination, Fig. 2 b is after decontamination, spot are from left to right followed successively by greasy dirt, coffee, ash Dirt, this formula is only to most of oil-dirt (such as edible oil, chilli oil, machine oil, ballpoint pen oil, solid grease), several beverages Spot (coffee, milk, milk shake), surface layer dust have preferable clean effect (using soil removal efficiency after 2-3 times 95% or more), Powder easily removes after drying, and fabric is submissiveer.
Reference examples 2:
The silica gel of 100 parts of 800-1500 mesh is first added in a reservoir, adds 3 parts of polyethylene glycol -200,3 parts of dimethyl Silicone oil, 1.5 parts of paraffin oils, 2.5 parts of butyl glycol ethers disperse solubilizer, add 470 parts of orange oils, 180 parts of turpentine oil, 165 Part eucalyptus oil, 52 parts of alcohol solvents, stirring continue to be added wherein for several times afterwards 1 part of thymol, 0.2 part of Sensiva SC50, 1.8 parts of phenoxyethanol preservatives and 20 parts of silica gel antistatic agents seal and carry out tank in the state of being stirred continuously immediately Packing (can not add decontamination auxiliary agent, and with solvent make-up surplus) compared with Example 1.
Acquired solution is that troubled liquor of the milky to milk yellow is layered, after layering without apparent viscosity after standing 20min Upper layer is clarified, and solid sinks, but homogeneous phase can be returned after upper and lower shaken several times.
Test:On chemical fibre, hair, silk weaving object and slim cotton fabric, this formula is only to most of oil-dirt (as eaten With oil, chilli oil, machine oil, ballpoint pen oil, solid grease) there is certain clean effect (to only have using soil removal efficiency after 2-3 times 80%), powder easily removes after drying, and fabric is submissiveer.
Reference examples 3:
The silica gel of 100 parts of 800-1500 mesh is first added in a reservoir, adds 3 parts of polyethylene glycol -200,3 parts of dimethyl Silicone oil, 1.5 parts of paraffin oils, 2.5 parts of butyl glycol ethers disperse solubilizer, add 450 parts of orange oils, 175 parts of turpentine oil, 160 Part eucalyptus oil, 55 parts of alcohol solvents, stirring continue that 4 parts of acetic acid, 6 parts of ethyl acetates, 5 parts of acetic acid fourths are added wherein for several times afterwards Ester, 8 parts of neopelexes, 7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol decontamination auxiliary agents and 20 parts of silica gel are with antistatic Agent, immediately seal and carried out in the state of being stirred continuously canned packaging can (non-adding preservative agent compared with Example 1, and with Solvent make-up surplus).
Acquired solution is that troubled liquor of the milky to milk yellow is layered, after layering without apparent viscosity after standing 20min Upper layer is clarified, and solid absorbent sinks, but homogeneous phase can be returned after upper and lower shaken several times.Test:In chemical fibre, hair, silk system On fabric and slim cotton fabric, this formula to most of oil-dirt, (chilli oil, machine oil, ballpoint pen oil, consolidate by such as edible oil State grease etc.), part beverage spot (such as coffee, milk, milk shake, ice cream, tea, fruit juice), iron rust, surface layer dust etc. all There is good clean effect (using soil removal efficiency after 1 time 98% or more), powder easily removes after drying, and fabric is submissiveer.But it opens It is honored as a queen perishable so that spray solution colour when reusing and deepen, be easily sticky on plain color fabric.
Reference examples 4:
The silica gel of 100 parts of 800-1500 mesh is first added in a reservoir, adds 3 parts of polyethylene glycol -200,3 parts of dimethyl Silicone oil, 1.5 parts of paraffin oils, 2.5 parts of butyl glycol ethers etc. disperse solubilizer, add 460 parts of orange oils, 180 parts of turpentine oil, 165 parts of eucalyptus oils, 52 parts of ethyl alcohol equal solvents, stirring continue that 4 parts of acetic acid, 6 parts of ethyl acetates, 5 portions of vinegar are added wherein for several times afterwards The decontaminations auxiliary agents such as acid butyl ester, 8 parts of neopelexes, 7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, add 1 part of Moschus The preservatives such as careless phenol, 0.2 part of Sensiva SC50,1.8 parts of Phenoxyethanols are sealed and are carried out in the state of being stirred continuously immediately Canned packaging (can not add antistatic agent, and with solvent make-up surplus) compared with Example 1.
Acquired solution is that troubled liquor of the milky to milk yellow is layered, after layering without apparent viscosity after standing 20min Upper layer is clarified, and solid sinks, but homogeneous phase can be returned after upper and lower shaken several times.
Test:On chemical fibre, hair, silk weaving object and slim cotton fabric, Fig. 3 is decontamination prepared by reference examples 4 of the present invention Agent handles thicker chemical & blended fabric, and Fig. 3 a is before decontamination, Fig. 3 b is after decontamination, spot are from left to right followed successively by greasy dirt, coffee, iron Rust, this formula is to most of oil-dirt (such as edible oil, chilli oil, machine oil, ballpoint pen oil, solid grease), part beverage Spot (such as coffee, milk, tea, fruit juice), iron rust etc. have good clean effect (using soil removal efficiency after 1 time 95% More than), but the more difficult removal of powder after drying, fabric are also easy to produce wrinkle knot.
Reference examples 5:
The silica gel of 50 parts of 800-1500 mesh is first added in a reservoir, adds 3 parts of polyethylene glycol -200,3 parts of dimethyl Silicone oil, 1.5 parts of paraffin oils, 2.5 parts of butyl glycol ethers etc. disperse solubilizer, add 475 parts of orange oils, 185 parts of turpentine oil, 170 parts of eucalyptus oils, 57 parts of ethyl alcohol equal solvents, stirring continue that 4 parts of acetic acid, 6 parts of ethyl acetates, 5 portions of vinegar are added wherein for several times afterwards The decontaminations auxiliary agents such as acid butyl ester, 8 parts of neopelexes, 7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, add 1 part of Moschus The preservatives such as careless phenol, 0.2 part of Sensiva SC50,1.8 parts of Phenoxyethanols and 20 parts of silica gel antistatic agents, seal simultaneously immediately Carried out in the state of being stirred continuously canned packaging can (compared with Example 1 adsorbent reduce, and with solvent make-up surplus).
Acquired solution is troubled liquor of the milky to milk yellow, without apparent viscosity, is layered after standing 5min, after layering on Layer clarification, solid absorbent sinks, but homogeneous phase can be returned after upper and lower shaken several times.
Test:On chemical fibre, hair, silk weaving object and slim cotton fabric, Fig. 4 is decontamination prepared by reference examples 5 of the present invention Agent handles thicker chemical & blended fabric, and Fig. 4 a is before decontamination, Fig. 4 b is after decontamination, spot are from left to right followed successively by greasy dirt, coffee, ash Dirt, this formula is only to part oil-dirt (such as edible oil, chilli oil, machine oil), part beverage spot (such as coffee, milk, milk Former times, ice cream etc.), surface layer dust etc. have certain clean effect (only having 80% using soil removal efficiency after 2-3 times), it is dry after powder End amount is few, therefore clean effect is limited, and powder easily removes, and fabric is submissiveer.
Above example, the formula of reference examples and other reference examples and effect such as table 1:
1 Examples 1 to 2 of table and 1~17 detergent formulations of reference examples and effect
As can be known from the above table, it mutually acts synergistically between each component of the present invention, plays clean effect jointly.
To sum up, Multifunctional decontaminating agent is washed in dry-cleaning of the invention, and oil-based solvent is different from common halogenated alkane, alkene Deng, and based on natural extract, and the mutual synergistic effect of each natural oil extract has been given full play to, while green peace Entirely.Adsorbent size controlling is at 10 μm or so, while facilitating dispersion, will not because powder is meticulous reach nanoscale due to human body It causes potentially to injure, it is nontoxic to be truly realized, it is environmental-friendly.
Multifunctional decontaminating agent is washed in the dry-cleaning of the present invention, will not be lumpd after absorbent powder drying, will not be adhered to and knit On object, slightly external force can remove, therefore be not easy to form the white round marking on the fabric, cause secondary pollution.On the contrary, using this After product, due to the effect of active principle, fabric can more compliant, difficult electrostatic, bright in luster.
Multifunctional decontaminating agent is washed in the dry-cleaning of the present invention, and solvent each component, dispersion solubilizer each component, decontamination auxiliary agent are each There is significant synergistic function between component, so once reducing or replacing the type of wherein different series component, Jiu Huizao At the decline of dirt-removing power.First, oil-based solvent of the invention is deep into fabric, by the various oil in fabric tissue gap Property soil molecules are surrounded completely, and according to the similar principle to mix, oily dirt molecule eventually falls out and is dissolved in oil-based solvent; For spots such as surface layer dust, iron rust, in a solvent in the environment of water composition, the surfactant (12 in decontamination auxiliary agent Sodium alkyl benzene sulfonate and sodium sulfate of polyethenoxy ether of fatty alcohol), mild organic acid play its good collaboration clean effect, i.e., The fine particles such as dust are wrapped up and fallen off by the long-chain molecules of surfactant, the insoluble matters such as iron rust, incrustation scale then with organic acid Metathesis reaction occurs for molecule, generates solable matter;Along with to improve detergent ingredient medium oil, aqueous for dispersion solubilizer The dispersibility and homogeneity of molecule to each other so that the effect between each active ingredient will not clash, and mutually promote instead, from And the dirt-removing power of detergent is made to greatly improve.Multifunctional decontaminating agent is washed in the dry-cleaning of the present invention, due to point of contained solubilizer Effect is dissipated, so that its oil-based solvent is promoted with aqueous solvent and the intermolecular compatibility of other water compositions, and further promote The performance of each ingredient decontamination and compatibility synergy to each other, to make the product serve not only as dry washing cleaning Agent uses, and can also play excellent dirt-removing functions in washing, realizes the splendid of dry-cleaning washing Multifunctional decontaminating agent and fits Ying Xing.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although with reference to preferable Embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the technology of the present invention Scheme is modified or replaced equivalently, and without departing from the spirit of the technical scheme of the invention and range, should all be covered in this hair In bright right.

Claims (9)

1. Multifunctional decontaminating agent is washed in a kind of dry-cleaning, it is characterised in that:Including solvent, decontamination auxiliary agent, dispersion solubilizer, wherein In terms of mass fraction, the dispersion solubilizer level is 3~12 parts, the decontamination auxiliary agent content is 20~35 parts, the solvent Content is 800~895 parts.
2. dry-cleaning washing Multifunctional decontaminating agent as described in claim 1, it is characterised in that:Further include, adsorbent, preservative, Antistatic agent, wherein in terms of mass fraction, the absorption agent content is 70~130 parts, the antiseptic content is 2~3 parts, The antistatic agent content is 10~20 parts.
3. dry-cleaning washing Multifunctional decontaminating agent as claimed in claim 1 or 2, it is characterised in that:The solvent is by orange oil, pine Fuel-economizing, eucalyptus oil, ethyl alcohol composition, in terms of mass fraction, the sweet orange oil content is 450~470 parts, the Turpentine -content is 155~175 parts, the folium eucalypti oil content be 150~160 parts, the ethanol content is 50~52 parts.
4. dry-cleaning washing Multifunctional decontaminating agent as claimed in claim 1 or 2, it is characterised in that:The decontamination auxiliary agent by acetic acid, Ethyl acetate, butyl acetate, neopelex, sodium sulfate of polyethenoxy ether of fatty alcohol composition, in terms of mass fraction, institute State that acetic acid content is 4 parts, the ethyl acetate content is 6 parts, the butyl acetate content is 5~6 parts, the detergent alkylate Sulfonic acid sodium content is 8 parts, the sodium sulfate of polyethenoxy ether of fatty alcohol content is 7 parts.
5. dry-cleaning washing Multifunctional decontaminating agent as claimed in claim 1 or 2, it is characterised in that:The dispersion solubilizer is by gathering Ethylene glycol -200, dimethicone, paraffin oil, butyl glycol ether composition, in terms of mass fraction, -200 content of the polyethylene glycol For 3~3.5 parts, the dimethyl-silicon oil content be 3~3.5 parts, the paraffin oil content is 1.5~2 parts, butyl glycol ether contains Amount is 2.5~3 parts.
6. dry-cleaning washing Multifunctional decontaminating agent as claimed in claim 2, it is characterised in that:The preservative by thymol, Sensiva SC50, Phenoxyethanol composition, in terms of mass fraction, the thymol content is 1 part, the Sensiva SC50 Content is 0.2 part, the Phenoxyethanol content is 1.8 parts.
7. Multifunctional decontaminating agent is washed in the dry-cleaning as described in claim 2 or 6, it is characterised in that:The adsorbent be 800~ The silica gel of 1500 mesh, in terms of mass fraction, the content of the silica gel of 800~1500 mesh is 100~130 parts.
8. Multifunctional decontaminating agent is washed in the dry-cleaning as described in claim 2 or 6, it is characterised in that:The antistatic agent is silica gel With antistatic agent, in terms of mass fraction, the content of the silica gel antistatic agent is 20 parts.
9. the preparation method of any dry-cleaning washing Multifunctional decontaminating agent of claim 2~8, it is characterised in that:Including 70 The dispersion solubilizer and 800~895 parts of solvent of 3~12 parts of addition in the silica gel of~130 parts of 800~1500 mesh, after mixing 20~35 parts of decontamination auxiliary agent, 2~3 parts of preservative and 10~20 parts of antistatic agents are added, seal immediately and are constantly stirring Canned packaging is carried out in the state of mixing.
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CN111334377A (en) * 2020-04-08 2020-06-26 刘水平 Phase-change down jacket dry cleaning agent and preparation method thereof

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CN101602985A (en) * 2008-06-10 2009-12-16 财团法人工业技术研究院 Remove the compoistion and method of use of spot
JP2010007075A (en) * 1997-09-15 2010-01-14 Procter & Gamble Co Laundry detergent composition with anionically modified, cyclic amine based polymer
CN101748009A (en) * 2008-12-17 2010-06-23 杨湧 Dry cleaner for removing clothes stains
CN106479726A (en) * 2016-09-22 2017-03-08 长兴净安环保科技有限公司 A kind of quick-dry type down jackets Dry Cleanerss and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1069064A (en) * 1992-05-29 1993-02-17 湖北省荆门市再生资源开发公司 Fabric spraying dry-cleaning agent and method for making thereof
JP2010007075A (en) * 1997-09-15 2010-01-14 Procter & Gamble Co Laundry detergent composition with anionically modified, cyclic amine based polymer
CN101602985A (en) * 2008-06-10 2009-12-16 财团法人工业技术研究院 Remove the compoistion and method of use of spot
CN101748009A (en) * 2008-12-17 2010-06-23 杨湧 Dry cleaner for removing clothes stains
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111334377A (en) * 2020-04-08 2020-06-26 刘水平 Phase-change down jacket dry cleaning agent and preparation method thereof
CN111334377B (en) * 2020-04-08 2021-11-23 西安优派日化有限公司 Phase-change down jacket dry cleaning agent and preparation method thereof

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