CN108676441A - A kind of glass self-cleaning coating formula - Google Patents

A kind of glass self-cleaning coating formula Download PDF

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Publication number
CN108676441A
CN108676441A CN201810561036.5A CN201810561036A CN108676441A CN 108676441 A CN108676441 A CN 108676441A CN 201810561036 A CN201810561036 A CN 201810561036A CN 108676441 A CN108676441 A CN 108676441A
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agent
dispersant
solvent
cleaning coating
resin
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冯智勇
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Zhaoqing Founder Of Amperex Technology Ltd
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Zhaoqing Founder Of Amperex Technology Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of glass self-cleaning coating formulas, include the constituent of following mass percent：Hydroxylated acrylic resin 20 40%, fluorocarbon resin 10 20%, high hydroxy polyester resin 10 20%, ethyl orthosilicate 4 8%, polyether modified silicon oil 1 5%, aliphatic isocyanates dimer 1 5%, butyl acetate 1 5%, titanium dioxide 15 30%, titanium phosphate 5 15%, zinc naphthenate 0.5 1.5%, hydroxyl modified siloxane auxiliary agent 1 3%, dispersant 1 3%, antifoaming agent 1 3%, anti-settling agent 1 3%, PH conditioning agents 1 3%, mill base 2 10%, surplus are solvent, inventive formulation coating paint film appearance surface more flat smooth；Static minimal contact angle is big, and surface tension is low, and hydro-oleophobicity is good, is effectively improved the anti-pollution characteristic of coating surface；And hardness is high, and toughness is high；Glossiness increases, the superpower hydrophobic self-cleaning function of natural imitation circle lotus leaf, and droplet is slid rapidly on lotus leaf in coating surface just like falling, and coating surface keeps cleaning.

Description

A kind of glass self-cleaning coating formula
Technical field
The present invention relates to technical field of coatings, specifically a kind of glass self-cleaning coating formula.
Background technology
Glassware is one of essential daily necessities of each family, and general glassware is water white transparency, but It is that there is also stained glass works at present, this is obtained generally by brushing glass coating.
Glass coating is one kind of coating, and glass surface is usually very smooth, and common coating is difficult attached in glass surface It, good glass coating forms stable and hard paint film in glass surface, can show high transparency, high glaze in appearance The characteristics of.Usual viscosity is relatively low in construction, while not will produce sagging phenomenon again.What it can stablize is adhered to glass wares Surface carries out beautiful and decoration effect by different colors to glass wares, and glass coating industry development is swift and violent at present.
It is counted according to the Ministry of Information Industry, domestic annual potential 300,000,000,000 yuans of the profession in China in 2014 is kept a public place clean market Demand, and increasing every year with 10%.The either cleaning of skin or keeping a public place clean for inside, traditional cleaning mode is It can not meet the requirement of environmental protection consumption reduction instantly, tradition cleaning industry revolution is overturned in the development of automatically cleaning technology, if by automatically cleaning skill Art is combined with glass coating, that will necessarily bring huge economic and social benefit.
Invention content
The purpose of the present invention is to provide a kind of glass self-cleaning coating formulas, to solve mentioned above in the background art ask Topic.
To achieve the above object, the present invention provides the following technical solutions：
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 20- 40%, fluorocarbon resin 10-20%, high hydroxy polyester resin 10-20%, ethyl orthosilicate 4-8%, polyether modified silicon oil 1-5%, Aliphatic isocyanates tripolymer 1-5%, butyl acetate 1-5%, titanium dioxide 15-30%, titanium phosphate 5-15%, zinc naphthenate 0.5-1.5%, hydroxyl modified siloxane auxiliary agent 1-3%, dispersant 1-3%, antifoaming agent 1-3%, anti-settling agent 1-3%, PH tune It is solvent to save agent 1-3%, mill base 2-10%, surplus.
As further scheme of the invention：Include the constituent of following mass percent：Hydroxylated acrylic resin 2535%, fluorocarbon resin 12-18%, high hydroxy polyester resin 12-18%, ethyl orthosilicate 5-7%, polyether modified silicon oil 1.5- 4.5%, aliphatic isocyanates tripolymer 1.5-4.5%, butyl acetate 1.5-4.5%, titanium dioxide 18-25%, titanium phosphate 6- 12%, zinc naphthenate 0.6-1.1%, hydroxyl modified siloxane auxiliary agent 1.5-2.5%, dispersant 1.5-2.5%, antifoaming agent 1.5-2.5%, anti-settling agent 1.5-2.5%, PH conditioning agent 1.5-2.5%, mill base 3-8%, surplus are solvent.
As further scheme of the invention：Include the constituent of following mass percent：Hydroxylated acrylic resin 28-32%, fluorocarbon resin 13-16%, high hydroxy polyester resin 13-16%, ethyl orthosilicate 5.5-6.5%, polyether-modified silicon Oily 2-4%, aliphatic isocyanates tripolymer 2-4%, butyl acetate 2-4%, titanium dioxide 20-22%, titanium phosphate 8-10%, ring Alkanoic acid zinc 0.8-1%, hydroxyl modified siloxane auxiliary agent 1.8-2.2%, dispersant 1.8-2.2%, antifoaming agent 1.8-2.2%, Anti-settling agent 1.8-2.2%, PH conditioning agent 1.8-2.2%, mill base 4-6%, surplus are solvent.
As further scheme of the invention：Include the constituent of following mass percent：Hydroxylated acrylic resin 28%, fluorocarbon resin 15%, high hydroxy polyester resin 15%, ethyl orthosilicate 6%, polyether modified silicon oil 3%, aliphatic isocyanide Acid esters tripolymer 3%, butyl acetate 3%, titanium dioxide 21%, titanium phosphate 9%, zinc naphthenate 0.9%, hydroxyl modified siloxane Auxiliary agent 2%, dispersant 2%, antifoaming agent 2%, anti-settling agent 2%, PH conditioning agents 2%, mill base 5%, surplus are solvent.
As further scheme of the invention：Include the constituent of following mass percent：Hydroxylated acrylic resin 30%, fluorocarbon resin 14%, high hydroxy polyester resin 13%, ethyl orthosilicate 5.5%, polyether modified silicon oil 2.5%, aliphatic Isocyanate trimer 3.5%, butyl acetate 4%, titanium dioxide 20%, titanium phosphate 8.5%, zinc naphthenate 1%, hydroxyl are modified It is siloxanes auxiliary agent 1.8%, dispersant 1.9%, antifoaming agent 2.2%, anti-settling agent 2%, PH conditioning agents 1.8%, mill base 4.5%, remaining Amount is solvent.
As further scheme of the invention：The dispersant is dispersant DH-5350, dispersant DH-5380, disperses Any one in agent DH-5211, dispersant DH-966, dispersant DH-6854, dispersant DH-5040, dispersant DH-5029.
As further scheme of the invention：The antifoaming agent is polyether-type antifoaming agent, organic Polyester Defoamer, mine Any one in object oils antifoaming agent, organic silicon defoamer, polyether ester modified organic silicon antifoaming agent.
As further scheme of the invention：The anti-settling agent is organobentonite, castor oil derivative, modified hydrogenated Any one in castor oil, aerosil, the N-Methyl pyrrolidone solution of modified polyurea, polyamide wax.
As further scheme of the invention：The PH conditioning agents are citric acid, tartaric acid, malic acid, sodium citrate In any one.
As further scheme of the invention：The solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, Isopropanol, benzyl alcohol mass ratio be 10: 5: 3: 2.
The present invention provides a kind of glass self-cleaning coating formulas, have the advantages that：
Hydroxyl modified siloxane auxiliary agent is added in inventive formulation, than the painting for not adding hydroxyl modified siloxane auxiliary agent Material, paint film appearance surface more flat smooth；Static minimal contact angle is big, and surface tension is low, and hydro-oleophobicity is good, effectively carries The high anti-pollution characteristic of coating surface；And hardness is high, and toughness is high；Glossiness increases.Because of Hydroxylated acrylic resin, fluorine carbon tree Fat, the coating surface tension of high hydroxy polyester resin composition are very low, and titanium dioxide, titanium phosphate can float to rapidly coating surface, and It is fixed on coating surface by hydroxyl and-NCO reactions, pollutant is made to be difficult to attach to coating surface, it is resistance to make paint film have Pickup performance, and paint film polluting proofing property can be effectively ensured can persistently, the superpower hydrophobic self-cleaning function of natural imitation circle lotus leaf, droplet exists Coating surface is slid rapidly on lotus leaf just like falling, and coating surface keeps cleaning.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 20%, Fluorocarbon resin 10%, high hydroxy polyester resin 10%, ethyl orthosilicate 4%, polyether modified silicon oil 1%, aliphatic isocyanates Tripolymer 1%, butyl acetate 1%, titanium dioxide 15%, titanium phosphate 5%, zinc naphthenate 0.5%, hydroxyl modified siloxane auxiliary agent 1%, dispersant DH-5350 1%, polyether-type antifoaming agent 1%, organobentonite 1%, citric acid 1%, mill base 2%, surplus are Solvent, solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol mass ratio be 10: 5: 3: 2.
Embodiment 2
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 20- 40%, fluorocarbon resin 10-20%, high hydroxy polyester resin 20%, ethyl orthosilicate 8%, polyether modified silicon oil 5%, aliphatic Isocyanate trimer 5%, butyl acetate 5%, titanium dioxide 30%, titanium phosphate 15%, zinc naphthenate 1.5%, hydroxyl are modified Siloxanes auxiliary agent 3%, dispersant DH-5380 3%, organic Polyester Defoamer 3%, castor oil derivative 3%, tartaric acid 3%, mill base 10%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol Mass ratio be 10: 5: 3: 2.
Embodiment 3
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 25%, Fluorocarbon resin 12%, high hydroxy polyester resin 12%, ethyl orthosilicate 5%, polyether modified silicon oil 1.5%, aliphatic isocyanic acid Ester tripolymer 1.5%, butyl acetate 1.5%, titanium dioxide 18%, titanium phosphate 6%, zinc naphthenate 0.6%, hydroxyl are modified silica Alkane auxiliary agent 1.5%, dispersant DH-5211 1.5%, mineral oil defoaming agent 1.5%, modified hydrogenated castor oil 1.5%, apple Acid 1.5%, mill base 3%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzene The mass ratio of methanol is 10: 5: 3: 2.
Embodiment 4
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 35%, Fluorocarbon resin 18%, high hydroxy polyester resin 18%, ethyl orthosilicate 7%, polyether modified silicon oil 4.5%, aliphatic isocyanic acid Ester tripolymer 4.5%, butyl acetate 4.5%, titanium dioxide 25%, titanium phosphate 12%, zinc naphthenate 1.1%, hydroxyl modified silicon Oxygen alkane auxiliary agent 2.5%, dispersant DH-966 2.5%, organic silicon defoamer 2.5%, aerosil 2.5%, sodium citrate 2.5%, mill base 8%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzene first The mass ratio of alcohol is 10: 5: 3: 2.
Embodiment 5
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 28- 32%, fluorocarbon resin 13%, high hydroxy polyester resin 13%, ethyl orthosilicate 5.5%, polyether modified silicon oil 2%, aliphatic are different Cyanate tripolymer 2%, butyl acetate 2%, titanium dioxide 20%, titanium phosphate 8%, zinc naphthenate 0.8%, hydroxyl are modified silica The N- methyl of alkane auxiliary agent 1.8%, dispersant DH-6854 1.8%, polyether ester modified organic silicon antifoaming agent 1.8%, modified polyurea Pyrrolidone solution 1.8%, sodium citrate 1.8%, mill base 4%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzene first Alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol mass ratio be 10: 5: 3: 2.
Embodiment 6
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 32%, Fluorocarbon resin 16%, high hydroxy polyester resin 16%, ethyl orthosilicate 6.5%, polyether modified silicon oil 4%, aliphatic isocyanic acid Ester tripolymer 4%, butyl acetate 4%, titanium dioxide 22%, titanium phosphate 10%, zinc naphthenate 1%, hydroxyl modified siloxane help Agent 2.2%, dispersant DH-5040 2.2%, polyether ester modified organic silicon antifoaming agent 2.2%, polyamide wax 2.2%, citric acid Sodium 2.2%, mill base 6%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzene The mass ratio of methanol is 10: 5: 3: 2.
Embodiment 7
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Olefin(e) acid resin 28% in hydroxyl, Fluorocarbon resin 15%, high hydroxy polyester resin 15%, ethyl orthosilicate 6%, polyether modified silicon oil 3%, aliphatic isocyanates Tripolymer 3%, butyl acetate 3%, titanium dioxide 21%, titanium phosphate 9%, zinc naphthenate 0.9%, hydroxyl modified siloxane auxiliary agent 2%, dispersant DH-5029 2%, polyether ester modified organic silicon antifoaming agent 2%, polyamide wax 2%, sodium citrate 2%, mill base 5%, surplus be solvent, solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol mass ratio It is 10: 5: 3: 2.
Embodiment 8
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 30%, Fluorocarbon resin 14%, high hydroxy polyester resin 13%, ethyl orthosilicate 5.5%, polyether modified silicon oil 2.5%, aliphatic isocyanide Acid esters tripolymer 3.5%, butyl acetate 4%, titanium dioxide 20%, titanium phosphate 8.5%, zinc naphthenate 1%, hydroxyl are modified silica Alkane auxiliary agent 1.8%, dispersant DH-5029 1.9%, polyether ester modified organic silicon antifoaming agent 2.2%, polyamide wax 2%, lemon Sour sodium 1.8%, mill base 4.5%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropyl Alcohol, benzyl alcohol mass ratio be 10: 5: 3: 2.
Embodiment 9
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 20%, Fluorocarbon resin 20%, high hydroxy polyester resin 10%, ethyl orthosilicate 8%, polyether modified silicon oil 1%, aliphatic isocyanates Tripolymer 5%, butyl acetate 1%, titanium dioxide 30%, titanium phosphate 5%, zinc naphthenate 1.5%, hydroxyl modified siloxane auxiliary agent 1%, dispersant DH-5029 3%, polyether ester modified organic silicon antifoaming agent 1%, polyamide wax 3%, sodium citrate 1%, mill base 10%, surplus be solvent, solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol mass ratio It is 10: 5: 3: 2.
Embodiment 10
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 40%, Fluorocarbon resin 10%, high hydroxy polyester resin 20%, ethyl orthosilicate 4%, polyether modified silicon oil 5%, aliphatic isocyanates Tripolymer 1%, butyl acetate 5%, titanium dioxide 15%, titanium phosphate 15%, zinc naphthenate 0.5%, hydroxyl modified siloxane help Agent 3%, dispersant DH-5029 1%, polyether ester modified organic silicon antifoaming agent 3%, polyamide wax 1%, sodium citrate 3%, color Slurry 2%, surplus be solvent, solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropyl alcohol, benzyl alcohol quality Than being 10: 5: 3: 2.
Embodiment 11
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 20%, Fluorocarbon resin 10%, high hydroxy polyester resin 10%, ethyl orthosilicate 4%, polyether modified silicon oil 1%, aliphatic isocyanates Tripolymer 1%, butyl acetate 1%, titanium dioxide 15%, titanium phosphate 5%, zinc naphthenate 0.5%, hydroxyl modified siloxane auxiliary agent 3%, dispersant DH-5029 3%, polyether ester modified organic silicon antifoaming agent 3%, polyamide wax 3%, sodium citrate 3%, mill base 10%, surplus be solvent, solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol mass ratio It is 10: 5: 3: 2.
Embodiment 12
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 40%, Fluorocarbon resin 20%, high hydroxy polyester resin 20%, ethyl orthosilicate 8%, polyether modified silicon oil 5%, aliphatic isocyanates Tripolymer 5%, butyl acetate 5%, titanium dioxide 30%, titanium phosphate 15%, zinc naphthenate 1.5%, hydroxyl modified siloxane help Agent 1%, dispersant DH-5029 1%, polyether ester modified organic silicon antifoaming agent 1%, polyamide wax 1%, sodium citrate 1%, color Slurry 2%, surplus be solvent, solvent be water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol quality Than being 10: 5: 3: 2.
Embodiment 13
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 25%, Fluorocarbon resin 18%, high hydroxy polyester resin 12%, ethyl orthosilicate 7%, polyether modified silicon oil 1.5%, aliphatic isocyanic acid Ester tripolymer 4.5%, butyl acetate 1.5%, titanium dioxide 25%, titanium phosphate 6%, zinc naphthenate 1.1%, hydroxyl are modified silica Alkane auxiliary agent 1.5%, dispersant DH-5029 2.5%, polyether ester modified organic silicon antifoaming agent 1.5%, polyamide wax 2.5%, lemon Lemon acid sodium 1.5%, mill base 8%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropyl Alcohol, benzyl alcohol mass ratio be 10: 5: 3: 2.
Embodiment 14
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 35%, Fluorocarbon resin 12%, high hydroxy polyester resin 18%, ethyl orthosilicate 5%, polyether modified silicon oil 4.5%, aliphatic isocyanic acid Ester tripolymer 1.5%, butyl acetate 1.5%, titanium dioxide 18%, titanium phosphate 6%, zinc naphthenate 0.6%, hydroxyl are modified silica Alkane auxiliary agent 2.5%, dispersant DH-5029 2.5%, polyether ester modified organic silicon antifoaming agent 2.5%, polyamide wax 2.5%, lemon Lemon acid sodium 2.5%, mill base 8%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropyl Alcohol, benzyl alcohol mass ratio be 10: 5: 3: 2.
Embodiment 15
A kind of glass self-cleaning coating formula, includes the constituent of following mass percent：Hydroxylated acrylic resin 35%, Fluorocarbon resin 18%, high hydroxy polyester resin 18%, ethyl orthosilicate 7%, polyether modified silicon oil 4.5%, aliphatic isocyanic acid Ester tripolymer 4.5%, butyl acetate 4.5%, titanium dioxide 25%, titanium phosphate 12%, zinc naphthenate 1.1%, hydroxyl modified silicon Oxygen alkane auxiliary agent 1.5%, dispersant DH-5029 1.5%, polyether ester modified organic silicon antifoaming agent 1.5%, polyamide wax 1.5%, Sodium citrate 1.5%, mill base 3%, surplus are solvent, and solvent is water, ethyl alcohol, isopropanol, benzyl alcohol, the water, ethyl alcohol, isopropyl Alcohol, benzyl alcohol mass ratio be 10: 5: 3: 2.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective It makes a variety of changes.

Claims (10)

1. a kind of glass self-cleaning coating formula, which is characterized in that include the constituent of following mass percent：Hydroxy acrylic acid Resin 20-40%, fluorocarbon resin 10-20%, high hydroxy polyester resin 10-20%, ethyl orthosilicate 4-8%, polyether-modified silicon Oily 1-5%, aliphatic isocyanates tripolymer 1-5%, butyl acetate 1-5%, titanium dioxide 15-30%, titanium phosphate 5-15%, ring Alkanoic acid zinc 0.5-1.5%, hydroxyl modified siloxane auxiliary agent 1-3%, dispersant 1-3%, antifoaming agent 1-3%, anti-settling agent 1- 3%, PH conditioning agents 1-3%, mill base 2-10%, surplus are solvent.
2. glass self-cleaning coating formula according to claim 1, which is characterized in that include the composition of following mass percent Ingredient：Hydroxylated acrylic resin 25-35%, fluorocarbon resin 12-18%, high hydroxy polyester resin 12-18%, ethyl orthosilicate 5- 7%, polyether modified silicon oil 1.5-4.5%, aliphatic isocyanates tripolymer 1.5-4.5%, butyl acetate 1.5-4.5%, titanium White powder 18-25%, titanium phosphate 6-12%, zinc naphthenate 0.6-1.1%, hydroxyl modified siloxane auxiliary agent 1.5-2.5%, dispersion Agent 1.5-2.5%, antifoaming agent 1.5-2.5%, anti-settling agent 1.5-2.5%, PH conditioning agent 1.5-2.5%, mill base 3-8%, surplus For solvent.
3. glass self-cleaning coating formula according to claim 1, which is characterized in that include the composition of following mass percent Ingredient：Hydroxylated acrylic resin 28-32%, fluorocarbon resin 13-16%, high hydroxy polyester resin 13-16%, ethyl orthosilicate 5.5-6.5%, polyether modified silicon oil 2-4%, aliphatic isocyanates tripolymer 2-4%, butyl acetate 2-4%, titanium dioxide 20- 22%, titanium phosphate 8-10%, zinc naphthenate 0.8-1%, hydroxyl modified siloxane auxiliary agent 1.8-2.2%, dispersant 1.8- 2.2%, antifoaming agent 1.8-2.2%, anti-settling agent 1.8-2.2%, PH conditioning agent 1.8-2.2%, mill base 4-6%, surplus are solvent.
4. glass self-cleaning coating formula according to claim 1, which is characterized in that include the composition of following mass percent Ingredient：Hydroxylated acrylic resin 28%, fluorocarbon resin 15%, high hydroxy polyester resin 15%, ethyl orthosilicate 6%, polyethers change Property silicone oil 3%, aliphatic isocyanates tripolymer 3%, butyl acetate 3%, titanium dioxide 21%, titanium phosphate 9%, zinc naphthenate 0.9%, hydroxyl modified siloxane auxiliary agent 2%, dispersant 2%, antifoaming agent 2%, anti-settling agent 2%, PH conditioning agents 2%, mill base 5%, surplus is solvent.
5. glass self-cleaning coating formula according to claim 1, which is characterized in that include the composition of following mass percent Ingredient：Hydroxylated acrylic resin 30%, fluorocarbon resin 14%, high hydroxy polyester resin 13%, ethyl orthosilicate 5.5%, polyethers Modified silicon oil 2.5%, aliphatic isocyanates tripolymer 3.5%, butyl acetate 4%, titanium dioxide 20%, titanium phosphate 8.5%, ring Alkanoic acid zinc 1%, hydroxyl modified siloxane auxiliary agent 1.8%, dispersant 1.9%, antifoaming agent 2.2%, anti-settling agent 2%, PH are adjusted Agent 1.8%, mill base 4.5%, surplus are solvent.
6. glass self-cleaning coating formula according to claim 1, which is characterized in that the dispersant is dispersant DH- 5350, dispersant DH-5380, dispersant DH-5211, dispersant DH-966, dispersant DH-6854, dispersant DH-5040, point Any one in powder DH-5029.
7. glass self-cleaning coating formula according to claim 1, which is characterized in that the antifoaming agent defoams for polyether-type Appointing in agent, organic Polyester Defoamer, mineral oil defoaming agent, organic silicon defoamer, polyether ester modified organic silicon antifoaming agent Meaning is a kind of.
8. glass self-cleaning coating formula according to claim 1, which is characterized in that the anti-settling agent be organobentonite, N-Methyl pyrrolidone solution, the polyamide of castor oil derivative, modified hydrogenated castor oil, aerosil, modified polyurea Any one in wax.
9. glass self-cleaning coating formula according to claim 1, which is characterized in that the PH conditioning agents are citric acid, wine Any one in stone acid, malic acid, sodium citrate.
10. glass self-cleaning coating formula according to claim 1, which is characterized in that the solvent is water, ethyl alcohol, isopropyl Alcohol, benzyl alcohol, the water, ethyl alcohol, isopropanol, benzyl alcohol mass ratio be 10: 5: 3: 2.
CN201810561036.5A 2018-05-31 2018-05-31 A kind of glass self-cleaning coating formula Pending CN108676441A (en)

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* Cited by examiner, † Cited by third party
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CN111621229A (en) * 2020-05-25 2020-09-04 广东德仁光电科技有限公司 Modified AF (aluminum fluoride) coating material, preparation method thereof and coating method
CN115678359A (en) * 2022-08-25 2023-02-03 中远关西涂料（上海）有限公司 Preparation method of anti-icing fluorocarbon coating for wind power blade
EP4104939A4 (en) * 2020-02-12 2023-08-02 Nippon Steel Corporation Metal plate coating material and coated metal plate production method using same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4104939A4 (en) * 2020-02-12 2023-08-02 Nippon Steel Corporation Metal plate coating material and coated metal plate production method using same
CN111621229A (en) * 2020-05-25 2020-09-04 广东德仁光电科技有限公司 Modified AF (aluminum fluoride) coating material, preparation method thereof and coating method
CN111621229B (en) * 2020-05-25 2022-04-22 广东德仁光电科技有限公司 Modified AF (aluminum fluoride) coating material, preparation method thereof and coating method
CN115678359A (en) * 2022-08-25 2023-02-03 中远关西涂料（上海）有限公司 Preparation method of anti-icing fluorocarbon coating for wind power blade

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Application publication date: 20181019