CN108676322A - A kind of safety durable urea-formaldehyde moulding powder - Google Patents

A kind of safety durable urea-formaldehyde moulding powder Download PDF

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Publication number
CN108676322A
CN108676322A CN201810642670.1A CN201810642670A CN108676322A CN 108676322 A CN108676322 A CN 108676322A CN 201810642670 A CN201810642670 A CN 201810642670A CN 108676322 A CN108676322 A CN 108676322A
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parts
accounts
urea
safety durable
lauxite
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CN201810642670.1A
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刘梅芳
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Suzhou Xin Yi Alwayseal Technology Ltd
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Suzhou Xin Yi Alwayseal Technology Ltd
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Priority to CN201810642670.1A priority Critical patent/CN108676322A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)

Abstract

Present invention is disclosed a kind of safety durable urea-formaldehyde moulding powders, it is made of Lauxite, filler, weather resisting agent, lubricant, curing agent, stabilizer and antistatic agent, the filler is paper pulp, the weather resisting agent is single benzoic acid resorcinol, the lubricant is cyclohexyl stearate, the curing agent is phthalic acid, and the stabilizer is ammonium carbonate, and the antistatic agent is dodecyldimethylammonium hydroxide inner salt.The present invention has the characteristics that tack is good, adhesion strength is high, anti-aging, stability are good, antistatic, good toughness, safe.

Description

A kind of safety durable urea-formaldehyde moulding powder
Technical field
The present invention relates to a kind of safety durable urea-formaldehyde moulding powders.
Background technology
Lauxite is also known as urea formaldehyde resin.English abbreviation UF is urea and formaldehyde in catalyst (alkalinity or acidic catalyst Agent) under effect, it is polycondensed into initial stage Lauxite, then again under curing agent or promoter effect, forms insoluble, insoluble latter stage heat Thermosetting resin.Lauxite color after solidification is more shallow than phenolic resin, and be translucent shape, weak acid resistant, weak base, good insulation preformance, Wearability is splendid, cheap, it is the maximum kind of dosage in adhesive.Especially in the various wood-based plates of wood-processing industry In manufacture, Lauxite and its modified product account for 90% or so of the total dosage of adhesive.However, Lauxite that there are weatherabilities is poor, Just viscous disadvantage poor, brittleness is big, easy to aging.
Invention content
The purpose of the present invention is to provide one kind with tack is good, adhesion strength is high, anti-aging, stability is good, it is quiet to resist The safety durable urea-formaldehyde moulding powder of electricity, good toughness, safe feature.
The technical scheme is that a kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, profit Lubrication prescription, curing agent, stabilizer and antistatic agent composition, the filler are paper pulp, and the weather resisting agent is single benzoic acid isophthalic Two phenolic esters, the lubricant are cyclohexyl stearate, and the curing agent is phthalic acid, and the stabilizer is ammonium carbonate, institute Antistatic agent is stated as dodecyldimethylammonium hydroxide inner salt, parts by weight shared by each ingredient of safety durable urea-formaldehyde moulding powder are distinguished For:The Lauxite accounts for 77-95 parts, and the paper pulp accounts for 28-37 parts, and the list benzoic acid resorcinol accounts for 3-8 parts, described Cyclohexyl stearate accounts for 1-5 parts, and the phthalic acid accounts for 4-10 parts, and the ammonium carbonate accounts for 2-7 parts, the dimethyl Base glycine betaine accounts for 1-6 parts.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the safety durable urea-formaldehyde moulding powder Specially:The Lauxite accounts for 77 parts, and the paper pulp accounts for 28 parts, and the list benzoic acid resorcinol accounts for 3 parts, the tristearin Sour cyclohexyl accounts for 1 part, and the phthalic acid accounts for 4 parts, and the ammonium carbonate accounts for 2 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 1 Part.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the safety durable urea-formaldehyde moulding powder Specially:The Lauxite accounts for 84 parts, and the paper pulp accounts for 30 parts, and the list benzoic acid resorcinol accounts for 4 parts, the tristearin Sour cyclohexyl accounts for 2 parts, and the phthalic acid accounts for 5 parts, and the ammonium carbonate accounts for 3 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 3 Part.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the safety durable urea-formaldehyde moulding powder Specially:The Lauxite accounts for 88 parts, and the paper pulp accounts for 33 parts, and the list benzoic acid resorcinol accounts for 6 parts, the tristearin Sour cyclohexyl accounts for 3 parts, and the phthalic acid accounts for 7 parts, and the ammonium carbonate accounts for 5 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 4 Part.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the safety durable urea-formaldehyde moulding powder Specially:The Lauxite accounts for 92 parts, and the paper pulp accounts for 35 parts, and the list benzoic acid resorcinol accounts for 7 parts, the tristearin Sour cyclohexyl accounts for 4 parts, and the phthalic acid accounts for 9 parts, and the ammonium carbonate accounts for 6 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 5 Part.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the safety durable urea-formaldehyde moulding powder Specially:The Lauxite accounts for 95 parts, and the paper pulp accounts for 37 parts, and the list benzoic acid resorcinol accounts for 8 parts, the tristearin Sour cyclohexyl accounts for 5 parts, and the phthalic acid accounts for 10 parts, and the ammonium carbonate accounts for 7 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 6 parts.
Of the present invention is a kind of safety durable urea-formaldehyde moulding powder, has that tack is good, adhesion strength is high, anti-aging, steady Qualitative good, antistatic, good toughness, safe feature.
Specific implementation mode
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
Of the present invention is a kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, lubricant, is consolidated Agent, stabilizer and antistatic agent composition, the filler are paper pulp, and the weather resisting agent is single benzoic acid resorcinol, The lubricant is cyclohexyl stearate, and the curing agent is phthalic acid, and the stabilizer is ammonium carbonate, described antistatic Agent is dodecyldimethylammonium hydroxide inner salt, and parts by weight are respectively shared by each ingredient of safety durable urea-formaldehyde moulding powder:It is described Lauxite accounts for 77-95 parts, and the paper pulp accounts for 28-37 parts, and the list benzoic acid resorcinol accounts for 3-8 parts, the stearic acid Cyclohexyl accounts for 1-5 parts, and the phthalic acid accounts for 4-10 parts, and the ammonium carbonate accounts for 2-7 parts, the dodecyl dimethyl beet Alkali accounts for 1-6 parts.
Embodiment one
A kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, lubricant, curing agent, stabilizer and Antistatic agent forms, and the filler is paper pulp, and the weather resisting agent is single benzoic acid resorcinol, and the lubricant is tristearin Sour cyclohexyl, the curing agent are phthalic acid, and the stabilizer is ammonium carbonate, and the antistatic agent is dimethyl Base glycine betaine, parts by weight shared by each ingredient are specially in the safety durable urea-formaldehyde moulding powder:The Lauxite accounts for 77 Part, the paper pulp accounts for 28 parts, and the list benzoic acid resorcinol accounts for 3 parts, and the cyclohexyl stearate accounts for 1 part, neighbour's benzene Dioctyl phthalate accounts for 4 parts, and the ammonium carbonate accounts for 2 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 1 part.
Embodiment two
A kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, lubricant, curing agent, stabilizer and Antistatic agent forms, and the filler is paper pulp, and the weather resisting agent is single benzoic acid resorcinol, and the lubricant is tristearin Sour cyclohexyl, the curing agent are phthalic acid, and the stabilizer is ammonium carbonate, and the antistatic agent is dimethyl Base glycine betaine, parts by weight shared by each ingredient are specially in the safety durable urea-formaldehyde moulding powder:The Lauxite accounts for 84 Part, the paper pulp accounts for 30 parts, and the list benzoic acid resorcinol accounts for 4 parts, and the cyclohexyl stearate accounts for 2 parts, neighbour's benzene Dioctyl phthalate accounts for 5 parts, and the ammonium carbonate accounts for 3 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 3 parts.
Embodiment three
A kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, lubricant, curing agent, stabilizer and Antistatic agent forms, and the filler is paper pulp, and the weather resisting agent is single benzoic acid resorcinol, and the lubricant is tristearin Sour cyclohexyl, the curing agent are phthalic acid, and the stabilizer is ammonium carbonate, and the antistatic agent is dimethyl Base glycine betaine, parts by weight shared by each ingredient are specially in the safety durable urea-formaldehyde moulding powder:The Lauxite accounts for 88 Part, the paper pulp accounts for 33 parts, and the list benzoic acid resorcinol accounts for 6 parts, and the cyclohexyl stearate accounts for 3 parts, neighbour's benzene Dioctyl phthalate accounts for 7 parts, and the ammonium carbonate accounts for 5 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 4 parts.
Example IV
A kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, lubricant, curing agent, stabilizer and Antistatic agent forms, and the filler is paper pulp, and the weather resisting agent is single benzoic acid resorcinol, and the lubricant is tristearin Sour cyclohexyl, the curing agent are phthalic acid, and the stabilizer is ammonium carbonate, and the antistatic agent is dimethyl Base glycine betaine, parts by weight shared by each ingredient are specially in the safety durable urea-formaldehyde moulding powder:The Lauxite accounts for 92 Part, the paper pulp accounts for 35 parts, and the list benzoic acid resorcinol accounts for 7 parts, and the cyclohexyl stearate accounts for 4 parts, neighbour's benzene Dioctyl phthalate accounts for 9 parts, and the ammonium carbonate accounts for 6 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 5 parts.
Embodiment five
A kind of safety durable urea-formaldehyde moulding powder, by Lauxite, filler, weather resisting agent, lubricant, curing agent, stabilizer and Antistatic agent forms, and the filler is paper pulp, and the weather resisting agent is single benzoic acid resorcinol, and the lubricant is tristearin Sour cyclohexyl, the curing agent are phthalic acid, and the stabilizer is ammonium carbonate, and the antistatic agent is dimethyl Base glycine betaine, parts by weight shared by each ingredient are specially in the safety durable urea-formaldehyde moulding powder:The Lauxite accounts for 95 Part, the paper pulp accounts for 37 parts, and the list benzoic acid resorcinol accounts for 8 parts, and the cyclohexyl stearate accounts for 5 parts, neighbour's benzene Dioctyl phthalate accounts for 10 parts, and the ammonium carbonate accounts for 7 parts, and the dodecyldimethylammonium hydroxide inner salt accounts for 6 parts.
Of the present invention is a kind of safety durable urea-formaldehyde moulding powder, and the present invention is with tack is good, adhesion strength is high, anti-old Change, stability is good, antistatic, good toughness, safe feature.
The foregoing is merely the specific implementation modes of the present invention, but scope of protection of the present invention is not limited thereto, any Those skilled in the art within the technical scope disclosed by the invention, can without the variation that creative work is expected or It replaces, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Subject to fixed protection domain.

Claims (6)

1. a kind of safety durable urea-formaldehyde moulding powder, it is characterised in that:By Lauxite, filler, weather resisting agent, lubricant, solidification Agent, stabilizer and antistatic agent composition, the filler are paper pulp, and the weather resisting agent is single benzoic acid resorcinol, institute It is cyclohexyl stearate to state lubricant, and the curing agent is phthalic acid, and the stabilizer is ammonium carbonate, the antistatic agent For dodecyldimethylammonium hydroxide inner salt, parts by weight are respectively shared by each ingredient of safety durable urea-formaldehyde moulding powder:The urea Urea formaldehyde accounts for 77-95 parts, and the paper pulp accounts for 28-37 parts, and the list benzoic acid resorcinol accounts for 3-8 parts, the stearic acid ring Own ester accounts for 1-5 parts, and the phthalic acid accounts for 4-10 parts, and the ammonium carbonate accounts for 2-7 parts, the dodecyldimethylammonium hydroxide inner salt Account for 1-6 parts.
2. safety durable urea-formaldehyde moulding powder according to claim 1, it is characterised in that:The safety durable ureaformaldehyde compression moulding Parts by weight shared by each ingredient are specially in powder:The Lauxite accounts for 77 parts, and the paper pulp accounts for 28 parts, between the list benzoic acid Benzenediol ester accounts for 3 parts, and the cyclohexyl stearate accounts for 1 part, and the phthalic acid accounts for 4 parts, and the ammonium carbonate accounts for 2 parts, described Dodecyldimethylammonium hydroxide inner salt accounts for 1 part.
3. safety durable urea-formaldehyde moulding powder according to claim 1, it is characterised in that:The safety durable ureaformaldehyde compression moulding Parts by weight shared by each ingredient are specially in powder:The Lauxite accounts for 84 parts, and the paper pulp accounts for 30 parts, between the list benzoic acid Benzenediol ester accounts for 4 parts, and the cyclohexyl stearate accounts for 2 parts, and the phthalic acid accounts for 5 parts, and the ammonium carbonate accounts for 3 parts, described Dodecyldimethylammonium hydroxide inner salt accounts for 3 parts.
4. safety durable urea-formaldehyde moulding powder according to claim 1, it is characterised in that:The safety durable ureaformaldehyde compression moulding Parts by weight shared by each ingredient are specially in powder:The Lauxite accounts for 88 parts, and the paper pulp accounts for 33 parts, between the list benzoic acid Benzenediol ester accounts for 6 parts, and the cyclohexyl stearate accounts for 3 parts, and the phthalic acid accounts for 7 parts, and the ammonium carbonate accounts for 5 parts, described Dodecyldimethylammonium hydroxide inner salt accounts for 4 parts.
5. safety durable urea-formaldehyde moulding powder according to claim 1, it is characterised in that:The safety durable ureaformaldehyde compression moulding Parts by weight shared by each ingredient are specially in powder:The Lauxite accounts for 92 parts, and the paper pulp accounts for 35 parts, between the list benzoic acid Benzenediol ester accounts for 7 parts, and the cyclohexyl stearate accounts for 4 parts, and the phthalic acid accounts for 9 parts, and the ammonium carbonate accounts for 6 parts, described Dodecyldimethylammonium hydroxide inner salt accounts for 5 parts.
6. safety durable urea-formaldehyde moulding powder according to claim 1, it is characterised in that:The safety durable ureaformaldehyde compression moulding Parts by weight shared by each ingredient are specially in powder:The Lauxite accounts for 95 parts, and the paper pulp accounts for 37 parts, between the list benzoic acid Benzenediol ester accounts for 8 parts, and the cyclohexyl stearate accounts for 5 parts, and the phthalic acid accounts for 10 parts, and the ammonium carbonate accounts for 7 parts, described Dodecyldimethylammonium hydroxide inner salt accounts for 6 parts.
CN201810642670.1A 2018-06-21 2018-06-21 A kind of safety durable urea-formaldehyde moulding powder Pending CN108676322A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102344644A (en) * 2011-04-26 2012-02-08 南京化工职业技术学院 Electric-breakdown-resistant environment-friendly amino molding plastic and production technique thereof
CN103849115A (en) * 2012-11-30 2014-06-11 吴文娟 Processing method of urea-formaldehyde moulding powder
CN105542391A (en) * 2016-02-02 2016-05-04 温州达源贸易有限公司 Urea-formaldehyde molding powder and preparation method thereof
CN107936466A (en) * 2017-11-30 2018-04-20 东莞菌怕怕科技实业有限公司 A kind of manufacture method of the beautiful material of colorful electricity and its electric beautiful product

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102344644A (en) * 2011-04-26 2012-02-08 南京化工职业技术学院 Electric-breakdown-resistant environment-friendly amino molding plastic and production technique thereof
CN103849115A (en) * 2012-11-30 2014-06-11 吴文娟 Processing method of urea-formaldehyde moulding powder
CN105542391A (en) * 2016-02-02 2016-05-04 温州达源贸易有限公司 Urea-formaldehyde molding powder and preparation method thereof
CN107936466A (en) * 2017-11-30 2018-04-20 东莞菌怕怕科技实业有限公司 A kind of manufacture method of the beautiful material of colorful electricity and its electric beautiful product

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Application publication date: 20181019