CN108676273A - A kind of abrasive floor glue and preparation method thereof - Google Patents

A kind of abrasive floor glue and preparation method thereof Download PDF

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Publication number
CN108676273A
CN108676273A CN201810288016.5A CN201810288016A CN108676273A CN 108676273 A CN108676273 A CN 108676273A CN 201810288016 A CN201810288016 A CN 201810288016A CN 108676273 A CN108676273 A CN 108676273A
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CN
China
Prior art keywords
parts
floor glue
abrasive floor
calcium carbonate
powder
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Pending
Application number
CN201810288016.5A
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Chinese (zh)
Inventor
王宝辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Gao Ming Han Chen Plastic Co Ltd
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Foshan Gao Ming Han Chen Plastic Co Ltd
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Filing date
Publication date
Application filed by Foshan Gao Ming Han Chen Plastic Co Ltd filed Critical Foshan Gao Ming Han Chen Plastic Co Ltd
Priority to CN201810288016.5A priority Critical patent/CN108676273A/en
Publication of CN108676273A publication Critical patent/CN108676273A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0004—Cutting, tearing or severing, e.g. bursting; Cutter details
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/06—Embossing
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B2038/0052—Other operations not otherwise provided for
    • B32B2038/0076—Curing, vulcanising, cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/72—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/744—Non-slip, anti-slip
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00—Floor coverings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

Abstract

A kind of abrasive floor glue of the present invention, according to weight ratio, 100 parts of Corvic, 20 30 parts of haloflex, 24 parts of barium stearate, 80 100 parts of calcium carbonate, 25 parts of superfine alumina silicate, 24 parts of calcium carbonate crystal whisker, 12 parts of nano-titanium oxide, 58 parts of chlorinated paraffin, 24 parts of sorbic acid, 24 parts of anti-skid wearable powder, the anti-skid wearable powder are the mixture of diamond dust, hollow ceramic micro mist and gluey graphite powder, and three's mass ratio is 10:10:3.The present invention has excellent wear-resisting property, and product compactness higher, wear-resisting and skid resistance is more preferable, and service life is long, is more suitable for hospital, airport, subway, the big public place of the flows of the people such as megastore uses.

Description

A kind of abrasive floor glue and preparation method thereof
Technical field
The invention belongs to floor glue production fields, specifically, being related to a kind of abrasive floor glue and preparation method thereof.
Background technology
PVC floor is also referred to as " light body floor ", it is the floor using pvc material production.Simultaneously PVC floor because The advantages that low with production cost, service life is long, and environment protecting is good and be increasingly used widely.
But there is also some shortcomingss for current PVC floor, are mainly manifested in non-skid property difference etc., these problems Many puzzlements are brought to user, also hamper the promotion and popularization of PVC floor to a certain extent.
Invention content
The present invention overcomes the disadvantages of the prior art, provides a kind of abrasive floor glue and preparation method thereof, rises anti-skidding Excellent effect increases the application scenario of floor glue, expands the use scope of floor glue.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of abrasive floor glue, according to weight ratio, 100 parts of Corvic, 20-30 parts of haloflex, stearic acid 2-4 parts of barium, 80-100 parts of calcium carbonate, 2-5 parts of superfine alumina silicate, 2-4 parts of calcium carbonate crystal whisker, 1-2 parts of nano-titanium oxide, chlorination stone 5-8 parts of wax, 2-4 parts of sorbic acid, 2-4 parts of anti-skid wearable powder, the anti-skid wearable powder are diamond dust, hollow ceramic micro mist and glue The mixture of graphite powder, three's mass ratio are 10:10:3.
Further, according to weight ratio, 100 parts of Corvic, 25 parts of haloflex, 3 parts of barium stearate, calcium carbonate 90 parts, 3 parts of superfine alumina silicate, 3 parts of calcium carbonate crystal whisker, 1.5 parts of nano-titanium oxide, 6 parts of chlorinated paraffin, 2-4 parts of sorbic acid is anti-skidding 3 parts of abrasion-resistant powder, the anti-skid wearable powder are the mixture of diamond dust, hollow ceramic micro mist and gluey graphite powder, three's mass ratio It is 10:10:3.
Further, it is additionally added 2-3 parts of zinc silicate.
Further, it is additionally added 2-3 parts of nano silicon dioxide.
Further, it is additionally added 2-5 parts of calcium zinc stabilizer.
A kind of preparation method of abrasive floor glue, includes the following steps：
1) raw material is put into stirring at low speed 3-4 minutes in batch mixer, is then transferred to high-speed stirred 6-7 minutes, temperature 90-100 DEG C is risen to, is transferred to stirring at low speed again 3-4 minutes, mixed material is discharged into the dispersion of stirring at low speed pot and is cooled to room Temperature then drains into storage tank, then is sent into double screw extruder by screw conveyor and fully heats, and shears, and plasticizing enters back into list Screw extruder further heats, plasticizing, is granulated by exporting cut-out, is finally cooled to room temperature the PVC granule being granulated；
2) calendering formation：PVC granule is transported to calender and is squeezed into coiled material；
3) heating plasticizing：Coiled material obtained by step 2) is sent into electrical heating baking oven, warm area drops to 190 again by 190 to 220 DEG C DEG C, make the abundant heating plasticizing of material；
4) secondary calendering：Step 3) products obtained therefrom is entered into two calenders, in 150 DEG C of extrusion formings；
5) back segment is handled：Base material gluing is carried out heating at 180 DEG C with step 4) products obtained therefrom to be bonded, is then pressed Flower, cooling, cutting edge, surface UV processing, thermal stress are eliminated, again cooling winding, and obtained product is abrasive floor glue.
6) abrasive floor glue surface passes through silicic acid immersion treatment.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention has excellent wear-resisting property, and product compactness higher, wear-resisting and skid resistance is more preferable, and service life is long, It is more suitable for hospital, airport, subway, the big public place of the flows of the people such as megastore uses.
Specific implementation mode
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of abrasive floor glue of the present invention, 100 parts of Corvic, 25 parts of haloflex, barium stearate 3 Part, 90 parts of calcium carbonate, 3 parts of superfine alumina silicate, 3 parts of calcium carbonate crystal whisker, 1.5 parts of nano-titanium oxide, 6 parts of chlorinated paraffin, sorbic acid 2-4 parts, 3 parts of anti-skid wearable powder, the anti-skid wearable powder is the mixture of diamond dust, hollow ceramic micro mist and gluey graphite powder, Three's mass ratio is 10:10:3, it is additionally added 2.5 parts of zinc silicate, is additionally added 2.3 parts of nano silicon dioxide, zinc silicate and nanometer two Silica effectively increases the wearability of floor glue, and zinc silicate also makes floor glue surface generate small lines, increases frictional force, separately Outer to be additionally added 2.5 parts of calcium zinc stabilizer, calcium zinc stabilizer promotes zinc silicate, nano silicon dioxide and Corvic to combine, In conjunction with closer stabilization.
A kind of preparation method of abrasive floor glue, includes the following steps：
1) raw material is put into stirring at low speed 3-4 minutes in batch mixer, is then transferred to high-speed stirred 6-7 minutes, temperature 90-100 DEG C is risen to, is transferred to stirring at low speed again 3-4 minutes, mixed material is discharged into the dispersion of stirring at low speed pot and is cooled to room Temperature then drains into storage tank, then is sent into double screw extruder by screw conveyor and fully heats, and shears, and plasticizing enters back into list Screw extruder further heats, plasticizing, is granulated by exporting cut-out, is finally cooled to room temperature the PVC granule being granulated；
2) calendering formation：PVC granule is transported to calender and is squeezed into coiled material；
3) heating plasticizing：Coiled material obtained by step 2) is sent into electrical heating baking oven, warm area drops to 190 again by 190 to 220 DEG C DEG C, make the abundant heating plasticizing of material；
4) secondary calendering：Step 3) products obtained therefrom is entered into two calenders, in 150 DEG C of extrusion formings；
5) back segment is handled：Base material gluing is carried out heating at 180 DEG C with step 4) products obtained therefrom to be bonded, is then pressed Flower, cooling, cutting edge, surface UV processing, thermal stress are eliminated, again cooling winding, and obtained product is abrasive floor glue.
6) abrasive floor glue surface generates tiny pit and line on floor glue surface by silicic acid immersion treatment, silicic acid Road increases its frictional force.
Obtained abrasive floor glue is tested for the property, result is as follows：
Finally it should be noted that：It these are only the preferred embodiment of the present invention, be not intended to restrict the invention, although With reference to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned Technical solution recorded in each embodiment is modified or equivalent replacement of some of the technical features, but it is all Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in the protection of the present invention Within the scope of.

Claims (7)

1. a kind of abrasive floor glue, which is characterized in that according to weight ratio, 100 parts of Corvic, haloflex 20-30 Part, 2-4 parts of barium stearate, 80-100 parts of calcium carbonate, 2-5 parts of superfine alumina silicate, 2-4 parts of calcium carbonate crystal whisker, nano-titanium oxide 1-2 Part, 5-8 parts of chlorinated paraffin, 2-4 parts of sorbic acid, 2-4 parts of anti-skid wearable powder, the anti-skid wearable powder is diamond dust, hollow ceramic The mixture of micro mist and gluey graphite powder, three's mass ratio are 10:10:3.
2. a kind of abrasive floor glue according to claim 1, which is characterized in that according to weight ratio, Corvic 100 Part, 25 parts of haloflex, 3 parts of barium stearate, 90 parts of calcium carbonate, 3 parts of superfine alumina silicate, 3 parts of calcium carbonate crystal whisker are nano oxidized 1.5 parts of titanium, 6 parts of chlorinated paraffin, 2-4 parts of sorbic acid, 3 parts of anti-skid wearable powder, the anti-skid wearable powder are diamond dust, hollow ceramic The mixture of micro mist and gluey graphite powder, three's mass ratio are 10:10:3.
3. a kind of abrasive floor glue according to claim 1, which is characterized in that be additionally added 2-3 parts of zinc silicate.
4. a kind of abrasive floor glue according to claim 1, which is characterized in that be additionally added 2-3 parts of nano silicon dioxide.
5. a kind of abrasive floor glue according to claim 1, which is characterized in that be additionally added 2-5 parts of calcium zinc stabilizer.
6. a kind of preparation method of abrasive floor glue according to claim 1, which is characterized in that include the following steps：
1) raw material is put into stirring at low speed 3-4 minutes in batch mixer, is then transferred to high-speed stirred 6-7 minutes, temperature rise To 90-100 DEG C, it is transferred to stirring at low speed again 3-4 minutes, mixed material is discharged into the dispersion of stirring at low speed pot and is cooled to room temperature, so After be discharged into storage tank, then by screw conveyor be sent into double screw extruder fully heat, shear, plasticizing, enter back into single screw rod Extruder further heats, plasticizing, is granulated by exporting cut-out, is finally cooled to room temperature the PVC granule being granulated；
2) calendering formation：PVC granule is transported to calender and is squeezed into coiled material；
3) heating plasticizing：Coiled material obtained by step 2) is sent into electrical heating baking oven, warm area drops to 190 DEG C by 190 to 220 DEG C, makes again The abundant heating plasticizing of material；
4) secondary calendering：Step 3) products obtained therefrom is entered into two calenders, in 150 DEG C of extrusion formings；
5) back segment is handled：Base material gluing is carried out heating at 180 DEG C with step 4) products obtained therefrom to be bonded, is then embossed, it is cold But, cutting edge, surface UV processing, thermal stress are eliminated, again cooling winding, and obtained product is abrasive floor glue.
7. a kind of preparation method of abrasive floor glue according to claim 6, which is characterized in that abrasive floor glue surface Pass through silicic acid immersion treatment.
CN201810288016.5A 2018-04-03 2018-04-03 A kind of abrasive floor glue and preparation method thereof Pending CN108676273A (en)

Priority Applications (1)

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CN201810288016.5A CN108676273A (en) 2018-04-03 2018-04-03 A kind of abrasive floor glue and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810288016.5A CN108676273A (en) 2018-04-03 2018-04-03 A kind of abrasive floor glue and preparation method thereof

Publications (1)

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CN108676273A true CN108676273A (en) 2018-10-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109968624A (en) * 2019-03-08 2019-07-05 东莞市中扶实业有限公司 A kind of processing technology of wood-imitating plastic plate

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101864123A (en) * 2010-06-18 2010-10-20 吉林吉瑞莱板材科技有限公司 Nano microcrystal wood floor and production method thereof
CN102850685A (en) * 2011-06-29 2013-01-02 上海大巨龙蓬盖新材料有限公司 PVC granular permeable coiled floor, and its preparation method
CN106905638A (en) * 2017-03-13 2017-06-30 安徽天润塑业有限公司 A kind of flame-proof environmental protection PVC floors and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101864123A (en) * 2010-06-18 2010-10-20 吉林吉瑞莱板材科技有限公司 Nano microcrystal wood floor and production method thereof
CN102850685A (en) * 2011-06-29 2013-01-02 上海大巨龙蓬盖新材料有限公司 PVC granular permeable coiled floor, and its preparation method
CN106905638A (en) * 2017-03-13 2017-06-30 安徽天润塑业有限公司 A kind of flame-proof environmental protection PVC floors and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109968624A (en) * 2019-03-08 2019-07-05 东莞市中扶实业有限公司 A kind of processing technology of wood-imitating plastic plate

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Application publication date: 20181019