CN108660740A - A kind of nano-functional finishing agent and preparation method thereof - Google Patents
A kind of nano-functional finishing agent and preparation method thereof Download PDFInfo
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- CN108660740A CN108660740A CN201810432927.0A CN201810432927A CN108660740A CN 108660740 A CN108660740 A CN 108660740A CN 201810432927 A CN201810432927 A CN 201810432927A CN 108660740 A CN108660740 A CN 108660740A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 40
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000006185 dispersion Substances 0.000 claims abstract description 34
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000000919 ceramic Substances 0.000 claims abstract description 16
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 239000002131 composite material Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 11
- 239000007924 injection Substances 0.000 claims description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 7
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 3
- BGOFCVIGEYGEOF-UJPOAAIJSA-N helicin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=CC=C1C=O BGOFCVIGEYGEOF-UJPOAAIJSA-N 0.000 claims description 3
- 239000011344 liquid material Substances 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- 238000005119 centrifugation Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002927 oxygen compounds Chemical class 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 13
- 230000036039 immunity Effects 0.000 abstract description 9
- 239000004753 textile Substances 0.000 abstract description 8
- 230000003115 biocidal effect Effects 0.000 abstract description 7
- 230000036541 health Effects 0.000 abstract description 6
- 238000013461 design Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 description 9
- 230000009471 action Effects 0.000 description 8
- 150000002191 fatty alcohols Chemical class 0.000 description 8
- 239000007921 spray Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- -1 Fluorine octyl sulfonyl compound Chemical class 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000009988 textile finishing Methods 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical class OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000004298 light response Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The present invention relates to textile technology field more particularly to a kind of nano-functional finishing agent and preparation method thereof, the nano-functional finishing agent includes the component of following parts by weight:Nano-TiO250~100 parts of dispersion liquid, nanometer g C3N45~10 parts of 10~20 parts of particle, 20~40 parts of emulsifier and far-infrared ceramic powder.The nano-functional finishing agent dosage of the present invention is few, environmentally protective, has the function of antibiotic health care, improves immunity;Process design is ingenious, and feeding mode is unique, and system mixing is uniform, enhances the stability of finishing agent, improves production efficiency.The fabric for completing finishing technique using nano-functional finishing agent of the present invention has excellent anti-microbial property, wherein under the conditions of ultraviolet light, antibiotic property is more excellent.
Description
Technical field
The present invention relates to textile technology fields more particularly to a kind of nano-functional finishing agent and preparation method thereof.
Background technology
With significantly improving for people's living standard, more and more people focus on quality of life, and textile is as daily
Important material in life, people propose more, higher requirement to textile product, to drive textile auxiliary to process skill
The deep development of art.Textile finishing is to apply a kind of finishing agent on the fabric, it can change the surface property of fabric, to assign
The special function of fabric.Such as it is to handle fabric with the finishing agent with low surface tension that hydrophobic and oil repellent, which arranges, changes fiber
Surface characteristic makes fabric surface be not easy by water or glossy wet and sprawl, to achieve the purpose that hydrophobic and oil repellent.Soil resistant finish and easily
It is to make fabric be not easy to attach dirt under dress, use condition by the surface property or surface state of change fiber that decontamination, which arranges,
Dirt, or the dirt attached is easy to the processing technology of washing not recontamination.
Currently, textile finish various in style emerges one after another on the market, most commonly seen is acrylate containing fluorine
Compound, the concern with people to textile health problem, it has been observed that the ecological problem of organic fluorine chemistry product.Entirely
Fluorine octyl sulfonyl compound (PFOS) is the main active for textile water and oil repellent finish, the study found that PFOS exists
There is high persistence in environment, accumulated in aggregation and animal tissue in the environment, potential danger is generated to health and environment
Danger.In addition, the function that conventional finishing agent only has deodorization, absorbing sweat etc. single, cannot meet the growing health care demand of people,
Therefore, developing the functional textile finishing agent that a kind of security performance is high, can get well, improve immunity has great grind
Study carefully meaning.
Invention content
The present invention provides a kind of green ring to overcome the problems, such as that traditional textile finishing agent safety is low, have a single function
Protect, be with health role, improving the nano-functional finishing agent of immunity.
The present invention also provides a kind of preparation methods of efficient nano-functional finishing agent.
To achieve the goals above, the present invention uses following technical scheme:
A kind of nano-functional finishing agent, includes the component of following parts by weight:Nano-TiO250~100 parts of dispersion liquid, nanometer g-
C3N45~10 parts of 10~20 parts of particle, 20~40 parts of emulsifier and far-infrared ceramic powder.
Nano-functional finishing agent of the present invention is environmentally protective, does not contain fluorine-containing chemical, and there is reasonable between each component
Compatibility relationship, wherein fraction of nanometer g-C3N4Particle is uniformly distributed in nano-TiO2In dispersion liquid, nano-TiO is formed2/g-
C3N4Composite construction, TiO2It is ultraviolet light response semiconductor, g-C3N4It is visible light-responded semiconductor, compound, the collaboration increasing of the two
Effect, directly makees oxidant with the oxygen in air, significantly increases photocatalysis efficiency so that fabric surface generates largely negative oxygen
Ion improves antibiotic property, has certain immune performance.Nano-TiO2/g-C3N4Composite material is carried on fabric surface, fabric
Dry under the sunlight or indoor incandescent lamp under when, under ultraviolet light/radiation of visible light, nano-TiO2/g-C3N4Photo-catalyst
Generate negative oxygen ion.Key reaction mechanism is:When the light that energy is more than energy gap irradiates semiconductive particles, it is empty to generate electronics
Cave pair, the electrons in valence band transit to conduction band, become conduction band electron (e-), while leaving a hole (h in valence band+).Hole
With strong oxidizing property, can react with the substance for being adsorbed on microparticle surfaces.Electrons and holes by the effect of electric field force or
The mode of diffusion moves migration, moves to the hole of semiconductor surface usually by OH-And H2O is captured, and generates HO, HO is one
The kind very strong free radical of oxidability is the main active substances of photochemical catalytic oxidation almost without gas chromatography is selectively aoxidized,
And the electronics for moving to semiconductor surface is usually attracted to the electron acceptor O of microparticle surfaces2Capture generates O2-, HOO and super
A series of free radicals such as negative oxygen ion, can kill the bacterium in air, and sedimentation ground can be combined with anaphylactogens such as dusts in air
Face, purification air (dust fall effect).Activating cell boosts metabolism, and adjusts acid-base balance, increases blood dissolved oxygen amount, improves
Body immunity.
The present invention can be enhanced human immunity using far-infared ceramic powder body, and basic principle is as follows:Electricity in object
Son vibrations or excitation, will discharging radiation energy outward, as long as all objects can all have the outside spoke of infrared ray more than Kelvin zero degree
It penetrates.With the difference of all many conditions such as radiator material molecules structure and temperature, radiation wavelength is also different.In radiated wave
Duan Zhong, when in molecule atom or atomic group be changed into from the vibrational state of high-energy the vibrational state of low energy when, will produce
2.5~25 μm of far infrared radiation, after water flows through particle ball, under the action of its surface free energy, the surface tension of water can
From 72 × 10-3N·m-1It is reduced to 60 × 10-3N·m-1.It is shaken simultaneously by the activation of surface free energy, can not only activate moisture
Son makes hydrone be not easy to associate, and can also activate other macromolecule bulk liquids (such as oleic acid, aliphatic acid, amino acid),
Make fabric that there is activation, improves the immunity of the human body.
Preferably, the emulsifier is fatty alcohol polyoxyethylene ether.
Preferably, the nano-TiO2Dispersion liquid is using ethyl alcohol as solvent, the nano-TiO2Nano-TiO in dispersion liquid2's
Grain size is 50~100nm, the nanometer g-C3N4Grain size be 10~25nm.Compared with the nanometer g-C of small particle3N4Can fully it divide
It dissipates in nano-TiO2Nano-TiO in dispersion liquid2In the surrounding gap of particle, to form nano-TiO2/g-C3N4Composite material, it is real
Existing antibacterial, the effect of strengthen immunity.
Preferably, on the basis of far-infrared ceramic powder gross mass, the far-infrared ceramic powder is by following quality hundred
Divide the component composition of ratio:40% SiO2, 50% metal oxide and 10% AgCl.
Preferably, the metal oxide is selected from Al2O3, CaO and ZrO2One or more of.
A kind of preparation method of nano-functional finishing agent, includes the following steps:
(1) according to said ratio, by nano-TiO2Dispersion liquid is added in reaction kettle, then by nanometer g-C3N4Nano-TiO2Point
It in dispersion liquid, stirs evenly at room temperature, obtains nano-TiO2/g-C3N4Composite dispersion liquid;
(2) again in nano-TiO2/g-C3N4Far-infrared ceramic powder is added in composite dispersion liquid, is stirred under the conditions of 100~150 DEG C
30~60min is mixed, mixed liquor is obtained;
(3) it waits for that the mixed liquor that step (2) obtains is cooled to room temperature, emulsifier, room temperature is slowly added in mixed liquor after the cooling period
8~10h of lower high-speed stirred, rotating speed are 600~800r/min to get nano-functional finishing agent.
Preferably, the reaction kettle bottom is equipped with injection charging device, the nanometer g-C3N4It is logical with far-infrared ceramic powder
Overspray charging device is added in liquid material.In such a way that base injcction feeds intake so that solid powder can be mixed into liquid material
When, it due to the gravity of itself, settles, forms the convection current of vertical direction, to increase the uniformity of material, arrangement obtained
The performance of agent is more stable.
Preferably, being equipped with agitating device in the middle part of the reaction kettle, the agitating device includes agitating shaft and circular stirring
The spiral helicine mixing part that axis one encloses, the agitating shaft are externally provided with charging sleeve, and the outer wall of the charging sleeve is equipped with several bullets
Property cross open;In step (3), the emulsifier is added to by the sleeve that feeds in mixed liquor;When agitating device is in work
State, the elasticity cross open is in the open state under the action of the centrifugal force, and emulsifier is thrown out of flows into mixed liquor;When stirring
It mixes device to remain static, the elasticity cross open is in closed state.
Whether this kind of feeding mode can be fed intake by the working condition realization of control agitating device and inventory, and elasticity
Cross open is ingenious in design, can open under the action of the centrifugal force, and stationary state can automatically reset under elastic potential energy effect, stop
It feeds intake.
Preferably, being equipped with ultraviolet lamp tube between the agitating shaft and charging sleeve, the charging sleeve is translucent material,
In step (3), mixing time is 2~3h.Increase ultra violet lamp, nano-TiO in reaction kettle2/g-C3N4Composite dispersion liquid produces
Third contact of a total solar or lunar eclipse catalytic action substantially reduces the reaction time, improves production efficiency, increases the output value.
Therefore, the present invention has the advantages that:
(1) nano-functional finishing agent dosage of the invention is few, environmentally protective, has the function of antibiotic health care, improves immunity;
(2) process design is ingenious, and feeding mode is unique, and system mixing is uniform, enhances the stability of finishing agent, improves life
Produce efficiency.
Description of the drawings
Fig. 1 is the structural schematic diagram of reaction kettle of the present invention.
Fig. 2 is the vertical view of agitating device in reaction kettle of the present invention.
Fig. 3 is the structural schematic diagram of stirring apparatus for reaction kettle stationary state charging sleeve of the present invention.
Fig. 4 is the structural schematic diagram of stirring apparatus for reaction kettle working condition charging sleeve of the present invention.
In figure:Charging device 1 is sprayed, S-shaped nozzle 2, agitating shaft 3, mixing part 4, feed sleeve 5, elastic cross open 6,
Ultraviolet lamp tube 7.
Specific implementation mode
Below by specific embodiment, and in conjunction with attached drawing, the technical solutions of the present invention will be further described.
In the present invention, if not refering in particular to, all devices and raw material is commercially available or the industry is common are following
Method in embodiment is unless otherwise instructed this field conventional method.
Fig. 1 and Fig. 2 is the reaction kettle structural schematic diagram used in the embodiment of the present invention:Reaction kettle bottom, which is equipped with, carries S-shaped nozzle 2
Injection charging device 1, agitating device is equipped in the middle part of reaction kettle, agitating device includes agitating shaft 3 and enclosed around agitating shaft one
Spiral helicine mixing part 4 is added if agitating shaft is externally provided with by what closed cylinder bottom and the barrel equipped with dry elasticity cross open 6 were constituted
Expect that sleeve 5, charging sleeve are translucent material, feeding port is equipped at the sleeve upper end opening that feeds;Between agitating shaft and charging sleeve
Equipped with ultraviolet lamp tube 7.As shown in figure 3, when agitating device remains static, elastic cross open is in closed state;Such as Fig. 4
Shown, when agitating device is in running order, elastic cross open is in the open state under the action of the centrifugal force.
Embodiment 1
(1) it is the nano-TiO of 50nm by 500Kg average grain diameters2Alcohol dispersion liquid is added in the autoclave body of aforesaid reaction vessel, then
By the nanometer g-C that 100Kg grain sizes are 10nm3N4It is added in injection charging device, sprays into nano-TiO2In dispersion liquid, when injection,
Nozzle running orbit should twist, and diameter 200mm, the method for a circle pressure semicircle is uniformly slowly moved, then stirred at room temperature
Uniformly, nano-TiO is obtained2/g-C3N4Composite dispersion liquid;
(2) again in nano-TiO2/g-C3N450Kg far-infrared ceramic powders are added by spraying charging device in composite dispersion liquid
(the SiO of 40wt%2, the Al of 50wt%2O3With the AgCl of 10wt%), 60min is stirred under the conditions of 100 DEG C, obtains mixed liquor;
(3) it waits for that the mixed liquor that step (2) obtains is cooled to room temperature, 200Kg fatty alcohol polyoxyethylene ether is added to charging sleeve
It is interior, start agitating device, the elastic cross open of the outer wall for the sleeve that feeds opens under the action of the centrifugal, fatty alcohol polyoxyethylene ether
It flows out, is mixed into mixed liquor after cooling, at room temperature with 600r/min high-speed stirreds 10h to get nanometer from elastic cross open
Functional finish.
Embodiment 2
(1) it is the nano-TiO of 100nm by 1000Kg grain sizes2Alcohol dispersion liquid is added in the autoclave body of aforesaid reaction vessel, then will
200Kg grain sizes are the nanometer g-C of 25nm3N4It is added in injection charging device, sprays into nano-TiO2In dispersion liquid, when injection, spray
Head running orbit should twist, and diameter 300mm, the method for a circle pressure semicircle uniformly slowly moves, and then stirring is equal at room temperature
It is even, obtain nano-TiO2/g-C3N4Composite dispersion liquid;
(2) again in nano-TiO2/g-C3N4100Kg far-infrared ceramic powders are added by spraying charging device in composite dispersion liquid
(the SiO of 40wt%2, the ZrO of the CaO of 20wt%, 30wt%2With the AgCl of 10wt%), 30min is stirred under the conditions of 150 DEG C,
Obtain mixed liquor;
(3) it waits for that the mixed liquor that step (2) obtains is cooled to room temperature, 400Kg fatty alcohol polyoxyethylene ether is added to charging sleeve
It is interior, start agitating device, the elastic cross open of the outer wall for the sleeve that feeds opens under the action of the centrifugal, fatty alcohol polyoxyethylene ether
It flows out, is mixed into mixed liquor after cooling, at room temperature with 800r/min high-speed stirreds 8h to get nanometer work(from elastic cross open
It can property finishing agent.
Embodiment 3
(1) it is the nano-TiO of 80nm by 800Kg grain sizes2Alcohol dispersion liquid is added in the autoclave body of aforesaid reaction vessel, then will
150Kg grain sizes are the nanometer g-C of 20nm3N4It is added in injection charging device, sprays into nano-TiO2In dispersion liquid, when injection, spray
Head running orbit should twist, and diameter 250mm, the method for a circle pressure semicircle uniformly slowly moves, and then stirring is equal at room temperature
It is even, obtain nano-TiO2/g-C3N4Composite dispersion liquid;
(2) again in nano-TiO2/g-C3N480Kg far-infrared ceramic powders are added by spraying charging device in composite dispersion liquid
(the SiO of 40wt%2, 50wt%ZrO2With the AgCl of 10wt%), 50min is stirred under the conditions of 120 DEG C, obtains mixed liquor;
(3) it waits for that the mixed liquor that step (2) obtains is cooled to room temperature, 300Kg fatty alcohol polyoxyethylene ether and 8000Kg water is added
Into charging sleeve, start agitating device, the elastic cross open of the outer wall for the sleeve that feeds opens under the action of the centrifugal, fatty alcohol
Polyoxyethylene ether is flowed out from elastic cross open, is mixed into mixed liquor after cooling, ultraviolet lamp is opened, at room temperature with 700r/min
High-speed stirred 2h is to get nano-functional finishing agent.
Embodiment 4
(1) it is the nano-TiO of 65nm by 900Kg grain sizes2Alcohol dispersion liquid is added in the autoclave body of aforesaid reaction vessel, then will
125Kg grain sizes are the nanometer g-C of 22nm3N4It is added in injection charging device, sprays into nano-TiO2In dispersion liquid, when injection, spray
Head running orbit should twist, and diameter 200mm, the method for a circle pressure semicircle uniformly slowly moves, and then stirring is equal at room temperature
It is even, obtain nano-TiO2/g-C3N4Composite dispersion liquid;
(2) again in nano-TiO2/g-C3N470Kg far-infrared ceramic powders are added by spraying charging device in composite dispersion liquid
(the SiO of 40wt%2, the Al of 25wt%2O3, the ZrO of 25wt%2With the AgCl of 10wt%), it is stirred under the conditions of 145 DEG C
30min obtains mixed liquor;
(3) it waits for that the mixed liquor that step (2) obtains is cooled to room temperature, 230Kg fatty alcohol polyoxyethylene ether and 8000Kg water is added
Into charging sleeve, start agitating device, the elastic cross open of the outer wall for the sleeve that feeds opens under the action of the centrifugal, fatty alcohol
Polyoxyethylene ether is flowed out from elastic cross open, is mixed into mixed liquor after cooling, ultraviolet lamp is opened, at room temperature with 650r/min
High-speed stirred 3h is to get nano-functional finishing agent.
The usage amount of nano-functional finishing agent of the present invention is 0.1%~15% (owf).
By nano-functional finishing agent made from embodiment 1-4 according to bath raio (liquid object ratio) 25:1, fabric is put into correspondence
Solution in permanent room temperature ultrasound 1h, stands one hour after taking-up, once, then 50 DEG C of oven dryings, that is, complete for stirring per 30min
Finishing technique.
Antibiotic property to the fabric for completing finishing technique by nano-functional finishing agent made from 1-4 of the embodiment of the present invention
It can detect, the results are shown in Table 1:
1. testing result of table
As can be seen from Table 1, the fabric for completing finishing technique using nano-functional finishing agent of the present invention has excellent antibacterial
Performance, wherein under the conditions of ultraviolet light, antibiotic property is more excellent.
The nano-functional finishing agent dosage of the present invention is few, environmentally protective, the work(with antibiotic health care, raising immunity
Energy;Process design is ingenious, and feeding mode is unique, and system mixing is uniform, enhances the stability of finishing agent, improves production effect
Rate.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the present invention in any form, and is not surpassing
There are other variations and modifications under the premise of going out the technical solution recorded in claim.
Claims (9)
1. a kind of nano-functional finishing agent, which is characterized in that include the component of following parts by weight:Nano-TiO2Dispersion liquid 50~
100 parts, nanometer g-C3N45~10 parts of 10~20 parts of particle, 20~40 parts of emulsifier and far-infrared ceramic powder.
2. a kind of nano-functional finishing agent according to claim 1, which is characterized in that the emulsifier is poly alkyl alcohol
Ethylene oxide ether.
3. a kind of nano-functional finishing agent according to claim 1, which is characterized in that the nano-TiO2Dispersion liquid with
Ethyl alcohol is solvent, the nano-TiO2Nano-TiO in dispersion liquid2Grain size be 50~100nm, the nanometer g-C3N4Grain size
For 10~25nm.
4. a kind of nano-functional finishing agent according to claim 1, which is characterized in that with the total matter of far-infrared ceramic powder
On the basis of amount, the far-infrared ceramic powder is made of the component of following mass percent:40% SiO2, 50% metal oxygen
Compound and 10% AgCl.
5. a kind of nano-functional finishing agent according to claim 4, which is characterized in that the metal oxide is selected from
Al2O3, CaO and ZrO2One or more of.
6. a kind of preparation method of nano-functional finishing agent as described in claims 1 or 2 or 3 or 4 or 5, which is characterized in that
Include the following steps:
(1) according to said ratio, by nano-TiO2Dispersion liquid is added in reaction kettle, then by nanometer g-C3N4It is added to nanometer
TiO2It in dispersion liquid, stirs evenly at room temperature, obtains nano-TiO2/g-C3N4Composite dispersion liquid;
(2) again in nano-TiO2/g-C3N4Far-infrared ceramic powder is added in composite dispersion liquid, is stirred under the conditions of 100~150 DEG C
30~60min is mixed, mixed liquor is obtained;
(3) it waits for that the mixed liquor that step (2) obtains is cooled to room temperature, emulsifier, room temperature is slowly added in mixed liquor after the cooling period
8~10h is to get nano-functional finishing agent for lower stirring.
7. the preparation method of nano-functional finishing agent according to claim 6, which is characterized in that the reaction kettle bottom is set
There are injection charging device, the nanometer g-C3N4It is added in liquid material with far-infrared ceramic powder by spraying charging device.
8. the preparation method of nano-functional finishing agent according to claim 6, which is characterized in that in the middle part of the reaction kettle
Equipped with agitating device, the agitating device includes agitating shaft and the spiral helicine mixing part for surrounding the circle of agitating shaft one, the stirring
Axis is externally provided with charging sleeve, if the outer wall of the charging sleeve is equipped with dry elasticity cross open;In step (3), emulsifier is led to
Charging sleeve is crossed to be added in mixed liquor;When agitating device is in running order, the elasticity cross open is in centrifugation force effect
Under it is in the open state, emulsifier be thrown out of flow into mixed liquor in;When agitating device remains static, the elasticity cross is opened
Mouth is in closed state.
9. the preparation method of nano-functional finishing agent according to claim 6, which is characterized in that the agitating shaft with plus
Expect to be equipped with ultraviolet lamp tube between sleeve, the charging sleeve is translucent material, and in step (3), mixing time is 2~3h.
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KR20030042774A (en) * | 2001-11-23 | 2003-06-02 | 전효철 | Non-woven fabrics and fabrics mixed with synthetic resins, water-based foaming agent and natural materials, and applied to a certain amount on top of the fiber |
CN206184439U (en) * | 2016-11-16 | 2017-05-24 | 江苏海云花新材料有限公司 | Reation kettle is used with production of ultra -soft instantizer to weaving |
CN107034585A (en) * | 2017-04-19 | 2017-08-11 | 江苏大学 | A kind of g C3N4Nanofiber antibacterial film and preparation method thereof and purposes |
CN107897204A (en) * | 2017-11-06 | 2018-04-13 | 紫罗兰家纺科技股份有限公司 | A kind of production method of nano-titanium dioxide and nano zinc oxide hybridization finishing agent |
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2018
- 2018-05-08 CN CN201810432927.0A patent/CN108660740A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20030042774A (en) * | 2001-11-23 | 2003-06-02 | 전효철 | Non-woven fabrics and fabrics mixed with synthetic resins, water-based foaming agent and natural materials, and applied to a certain amount on top of the fiber |
CN206184439U (en) * | 2016-11-16 | 2017-05-24 | 江苏海云花新材料有限公司 | Reation kettle is used with production of ultra -soft instantizer to weaving |
CN107034585A (en) * | 2017-04-19 | 2017-08-11 | 江苏大学 | A kind of g C3N4Nanofiber antibacterial film and preparation method thereof and purposes |
CN107897204A (en) * | 2017-11-06 | 2018-04-13 | 紫罗兰家纺科技股份有限公司 | A kind of production method of nano-titanium dioxide and nano zinc oxide hybridization finishing agent |
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