CN108659768A - A kind of assembled architecture high performance sealant and preparation method thereof - Google Patents
A kind of assembled architecture high performance sealant and preparation method thereof Download PDFInfo
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- CN108659768A CN108659768A CN201810497690.4A CN201810497690A CN108659768A CN 108659768 A CN108659768 A CN 108659768A CN 201810497690 A CN201810497690 A CN 201810497690A CN 108659768 A CN108659768 A CN 108659768A
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- high performance
- assembled architecture
- galapectite
- sealant
- performance sealant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of assembled architecture high performance sealants, in parts by weight, including following components：60 80 parts of end-silicane-group modified polyether, 0.5 2 parts of modified filler, 12 parts of nano-calcium carbonate, 0.075 0.13 parts of dispersant, 14 parts of plasticizer, 0.1 0.6 parts of ultra-violet absorber, 0.1 1 parts of adhesion promoters, 0.5 1.5 parts of curing agent.The invention also discloses the preparation methods of the high performance sealant.Fluid sealant adhesive strength disclosed by the invention is big, and stability is good, and high temperature resistance is excellent, and adhesive force is good, and service life is long, and prepares simply, at low cost.
Description
Technical field：
The present invention relates to construction materials, are specifically related to a kind of assembled architecture high performance sealant.
Background technology：
Assembled architecture refers to being built made of assemble in site with prefabricated component.The advantages of this building is to build speed
Degree is fast, and climate conditionality is small, saves labour and construction quality can be improved.From the point of view of entire industrial chain, assembled architecture
It is uniformly manufactured in factory from planning, design, production to operation, it can be realized to greatest extent in the life cycle management of building
It is energy saving, save land, be water-saving, section material.A large amount of building subassembly is machined by Workshop Production, and component type mainly has：Side fascia,
Lining, superimposed sheet, balcony, air-conditioning plate, stair, precast beam, prefabricated post etc..
Assembled architecture is built made of factory-made component, assembled in situ, will be existed between more component
The construction joint that horizontal, vertical abutment joint or prefabricated components are connect with cast-in-place concrete, easily leads to deformation, cracking and leakage, and sealing is anti-
Water provides the basic guarantee for using function for assembled architecture.Common buildings waterproof fluid sealant include mainly silicone sealant,
Polyurethane sealant and modified silicone seal gum (also known as polyether seal glue, abbreviation MS fluid sealants) etc..MS fluid sealant molecular backbones
For the macromolecular polyethers of methoxy silane sealing end, is formed using Si-O-Si as the three-dimensional space network structure of skeleton after solidification, both had
There are the good durability of silicone sealant, anti-deformational displacement ability, and there is the good caking property of polyurethane sealant, can cover with paint, lacquer, colour wash, etc.
Property, low contamination, and most of base materials are bonded good；It can be exposed to outdoor application for a long time, built particularly suitable for assembled
Build the sealing waterproof of exterior wall plate stitch.But currently used MS fluid sealants water resistance is bad, intensity is also required to further improve.
Invention content：
The object of the present invention is to provide a kind of assembled architecture high performance sealants, and the fluid sealant adhesive strength is big, surely
Qualitative good, high temperature resistance is excellent, and adhesive force is good, and service life is long.
The invention also discloses the preparation methods of the fluid sealant.
To achieve the above object, the present invention uses following technical scheme：
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Wherein, the preparation method of modified filler includes the following steps：
(1) galapectite is placed in progress immersion treatment 5-11h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane
In the ethanol solution of coupling agent, it is stirred at reflux reaction 7-13h at 40-60 DEG C, is cooled to room temperature after reaction, filters, it will
Precipitation is washed, is dried, and modified galapectite is made；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 1-3h sinks
After shallow lake, filter, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, is burnt under inert gas atmosphere
Knot processing 4-9h, is made modified filler.
As a preferred embodiment of the above technical solution, the dispersant is neopelex, lauryl sodium sulfate, gathers
Acrylic acid receive in one kind.
As a preferred embodiment of the above technical solution, the ultra-violet absorber is three Zo class ultra-violet absorbers of benzo.
As a preferred embodiment of the above technical solution, the adhesion promoters are γ-aminopropyltrimethoxysilane.
As a preferred embodiment of the above technical solution, the curing agent is dibutyl tin laurate.
As a preferred embodiment of the above technical solution, in step (1), the mass concentration of the hydrochloric acid solution is 11-20%.
As a preferred embodiment of the above technical solution, in step (1), the galapectite, silane coupling agent mass ratio be 1：
(0.05-0.15)。
As a preferred embodiment of the above technical solution, in step (2), the zinc nitrate, cerous nitrate, citric acid, modified galapectite
Mass ratio be 4:0.5：(0.1-0.3):(0.65-1.33).
As a preferred embodiment of the above technical solution, in step (3), the temperature of the sintering processes is 400-550 DEG C.
A kind of preparation method of assembled architecture high performance sealant, which is characterized in that include the following steps：
1) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
It is stirred 1-2h at 0.1MPa, 85-95 DEG C, mixture is made；
2) above-mentioned mixture is cooled to 50-70 DEG C, plasticizer is then added, ultra-violet absorber, adhesion promoters, consolidates
Agent is stirred 15-30min, and high performance sealant is made.
The invention has the advantages that：
Galapectite intensity is big, water-tolerant, be added in fluid sealant can be effectively improved the water resistance of fluid sealant with
And intensity, but galapectite can influence the original excellent adhesive property of fluid sealant, in order to solve this technical problem, the present invention is first
Galapectite material is first subjected to impregnation using hydrochloric acid solution, then galapectite surface is activated using silane coupling agent
Modified galapectite is made in processing, and surface-active site is more, and the last present invention is using the method for co-precipitation in galapectite surface system
The zinc oxide of standby doping cerium, and the dosage of each component is effectively adjusted, modified filler stability obtained is good, is not influencing fluid sealant
The intensity and durability of fluid sealant are effectively improved under the premise of adhesive property.
The present invention rationally adjusts the dosage and preparation condition of fluid sealant each component, and fluid sealant adhesive strength obtained is big,
Stability is good, and high temperature resistance is excellent, and adhesive force is good, and service life is long.
Specific implementation mode：
In order to better understand the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Preparation method includes the following steps：
(1) galapectite is placed in progress immersion treatment 5h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane idol
In the ethanol solution for joining agent, it is stirred at reflux reaction 7h at 40 DEG C, is cooled to room temperature after reaction, filters, precipitation is carried out
Washing, dry, obtained modified galapectite；Wherein, galapectite, silane coupling agent mass ratio be 1：0.05；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；Wherein, zinc nitrate, cerous nitrate, lemon
Acid, the mass ratio for being modified galapectite are 4:0.5：0.1:0.65；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 1-3h sinks
After shallow lake, filter, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, under inert gas atmosphere
Modified filler is made in sintering processes 4h at 400 DEG C；
(4) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
0.1MPa, 1h is stirred at 85 DEG C, mixture is made；
(5) above-mentioned mixture is cooled to 50 DEG C, plasticizer, ultra-violet absorber, adhesion promoters, solidification is then added
Agent is stirred 15min, and high performance sealant is made.
Embodiment 2
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Preparation method includes the following steps：
(1) galapectite is placed in progress immersion treatment 11h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane idol
In the ethanol solution for joining agent, it is stirred at reflux reaction 13h at 60 DEG C, is cooled to room temperature after reaction, filters, precipitation is carried out
Washing, dry, obtained modified galapectite；Wherein, galapectite, silane coupling agent mass ratio be 1：0.15；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；Wherein, zinc nitrate, cerous nitrate, lemon
Acid, the mass ratio for being modified galapectite are 4:0.5：0.3:1.33；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 3h, precipitation
After, it filters, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, 550 under inert gas atmosphere
Modified filler is made in sintering processes 9h at DEG C；
(4) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
0.1MPa, 2h is stirred at 95 DEG C, mixture is made；
(5) above-mentioned mixture is cooled to 50-70 DEG C, then be added plasticizer, ultra-violet absorber, adhesion promoters,
Curing agent is stirred 30min, and high performance sealant is made.
Embodiment 3
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Preparation method includes the following steps：
(1) galapectite is placed in progress immersion treatment 6h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane idol
In the ethanol solution for joining agent, it is stirred at reflux reaction 8h at 45 DEG C, is cooled to room temperature after reaction, filters, precipitation is carried out
Washing, dry, obtained modified galapectite；Wherein, galapectite, silane coupling agent mass ratio be 1：0.07；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；Wherein, zinc nitrate, cerous nitrate, lemon
Acid, the mass ratio for being modified galapectite are 4:0.5：0.15:0.75；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 1.5h sinks
After shallow lake, filter, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, under inert gas atmosphere
Modified filler is made in sintering processes 5h at 450 DEG C；
(4) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
0.1MPa, 1.2h is stirred at 85 DEG C, mixture is made；
(5) above-mentioned mixture is cooled to 55 DEG C, plasticizer, ultra-violet absorber, adhesion promoters, solidification is then added
Agent is stirred 20min, and high performance sealant is made.
Embodiment 4
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Preparation method includes the following steps：
(1) galapectite is placed in progress immersion treatment 7h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane idol
In the ethanol solution for joining agent, it is stirred at reflux reaction 9h at 50 DEG C, is cooled to room temperature after reaction, filters, precipitation is carried out
Washing, dry, obtained modified galapectite；Wherein, galapectite, silane coupling agent mass ratio be 1：0.09；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；Wherein, zinc nitrate, cerous nitrate, lemon
Acid, the mass ratio for being modified galapectite are 4:0.5：0.2:0.95；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 2h, precipitation
After, it filters, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, 500 under inert gas atmosphere
Modified filler is made in sintering processes 6h at DEG C；
(4) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
0.1MPa, 1.4h is stirred at 90 DEG C, mixture is made；
(5) above-mentioned mixture is cooled to 60 DEG C, plasticizer, ultra-violet absorber, adhesion promoters, solidification is then added
Agent is stirred 25min, and high performance sealant is made.
Embodiment 5
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Preparation method includes the following steps：
(1) galapectite is placed in progress immersion treatment 8h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane idol
In the ethanol solution for joining agent, it is stirred at reflux reaction 10h at 55 DEG C, is cooled to room temperature after reaction, filters, precipitation is carried out
Washing, dry, obtained modified galapectite；Wherein, galapectite, silane coupling agent mass ratio be 1：0.11；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；Wherein, zinc nitrate, cerous nitrate, lemon
Acid, the mass ratio for being modified galapectite are 4:0.5：0.2:1.05；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 2h, precipitation
After, it filters, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, 520 under inert gas atmosphere
Modified filler is made in sintering processes 7h at DEG C；
(4) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
0.1MPa, 1.6h is stirred at 90 DEG C, mixture is made；
(5) above-mentioned mixture is cooled to 65 DEG C, plasticizer, ultra-violet absorber, adhesion promoters, solidification is then added
Agent is stirred 20min, and high performance sealant is made.
Embodiment 6
A kind of assembled architecture high performance sealant, in parts by weight, including following components：
Preparation method includes the following steps：
(1) galapectite is placed in progress immersion treatment 10h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane idol
In the ethanol solution for joining agent, it is stirred at reflux reaction 12h at 55 DEG C, is cooled to room temperature after reaction, filters, precipitation is carried out
Washing, dry, obtained modified galapectite；Wherein, galapectite, silane coupling agent mass ratio be 1：0.13；
(2) by zinc nitrate, cerous nitrate obtained mixed liquor soluble in water, after then addition citric acid is uniformly mixed, then
Modified galapectite made from step (1) is added, after being dispersed with stirring uniformly, dispersion liquid is made；Wherein, zinc nitrate, cerous nitrate, lemon
Acid, the mass ratio for being modified galapectite are 4:0.5：0.25:1.25；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 2.5h sinks
After shallow lake, filter, it is dry, solid powder is made；Solid powder obtained is placed in Muffle furnace, under inert gas atmosphere
Modified filler is made in sintering processes 8h at 500 DEG C；
(4) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, be in vacuum degree
0.1MPa, 1.8h is stirred at 90 DEG C, mixture is made；
(5) above-mentioned mixture is cooled to 65 DEG C, plasticizer, ultra-violet absorber, adhesion promoters, solidification is then added
Agent is stirred 30min, and high performance sealant is made.
GB/T 5281998 tests the tensile strength of fluid sealant produced by the present invention according to national standards, and test result is：
The tensile strength of high performance sealant produced by the present invention is 6.2-6.9MPa.
GB/T 5282008 tests the shear strength of fluid sealant produced by the present invention according to national standards, and test result is：
The shear strength of high performance sealant produced by the present invention is 5.5-6.0MPa.
GB/T 5281998 tests the tearing strength of fluid sealant produced by the present invention according to national standards, and test result is：
The tearing strength of high performance sealant produced by the present invention is 45-52MPa.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of assembled architecture high performance sealant, which is characterized in that in parts by weight, including following components：
Wherein, the preparation method of modified filler includes the following steps：
(1) galapectite is placed in progress immersion treatment 5-11h in hydrochloric acid solution, then taken out, it is dry, it is subsequently placed in silane coupled
In the ethanol solution of agent, it is stirred at reflux reaction 7-13h at 40-60 DEG C, is cooled to room temperature after reaction, filters, will precipitate
It washed, dried, modified galapectite is made；
(2) zinc nitrate, cerous nitrate obtained mixed liquor soluble in water are added after then addition citric acid is uniformly mixed
Modified galapectite made from step (1), after being dispersed with stirring uniformly, is made dispersion liquid；
(3) dispersion liquid obtained above and sodium hydroxide solution are added in reactor simultaneously, stirring precipitation 1-3h has been precipitated
Bi Hou is filtered, dry, and solid powder is made；Solid powder obtained is placed in Muffle furnace, under inert gas atmosphere at sintering
4-9h is managed, modified filler is made.
2. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that the dispersant is ten
One kind in dialkyl benzene sulfonic acids sodium, lauryl sodium sulfate, sodium polyacrylate.
3. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that the ultraviolet radiation absorption
Agent is three Zo class ultra-violet absorbers of benzo.
4. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that the adhesion promoters
For γ-aminopropyltrimethoxysilane.
5. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that the curing agent is two
Dibutyl tin laurate.
6. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that described in step (1)
The mass concentration of hydrochloric acid solution is 11-20%.
7. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that described in step (1)
Galapectite, silane coupling agent mass ratio be 1：(0.05-0.15).
8. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that described in step (2)
Zinc nitrate, cerous nitrate, citric acid, modified galapectite mass ratio be 4:0.5：(0.1-0.3):(0.65-1.33).
9. a kind of assembled architecture high performance sealant as described in claim 1, which is characterized in that described in step (3)
The temperature of sintering processes is 400-550 DEG C.
10. a kind of preparation method of assembled architecture high performance sealant as described in claim 1 to 9 is any, feature
It is, includes the following steps：
1) end-silicane-group modified polyether, modified filler, nano-calcium carbonate dispersant is uniform, vacuum degree be 0.1MPa,
It is stirred 1-2h at 85-95 DEG C, mixture is made；
2) above-mentioned mixture is cooled to 50-70 DEG C, plasticizer, ultra-violet absorber, adhesion promoters, solidification is then added
Agent is stirred 15-30min, and high performance sealant is made.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810497690.4A CN108659768A (en) | 2018-05-22 | 2018-05-22 | A kind of assembled architecture high performance sealant and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810497690.4A CN108659768A (en) | 2018-05-22 | 2018-05-22 | A kind of assembled architecture high performance sealant and preparation method thereof |
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| CN108659768A true CN108659768A (en) | 2018-10-16 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112724904A (en) * | 2020-12-31 | 2021-04-30 | 佛山市三水日邦化工有限公司 | Graphene heating floor tile adhesive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102602981A (en) * | 2011-01-21 | 2012-07-25 | 吉林师范大学 | Non-toxic environment-friendly preparation method of ZnO nanometer rod |
| CN104119704A (en) * | 2013-04-27 | 2014-10-29 | 中国科学院化学研究所 | Surface modification treatment method of halloysite nanotube |
| CN105567148A (en) * | 2016-02-26 | 2016-05-11 | 广州市白云化工实业有限公司 | Silane-modified polyether adhesive for sealing fabricated concrete buildings and manufacturing method thereof |
-
2018
- 2018-05-22 CN CN201810497690.4A patent/CN108659768A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102602981A (en) * | 2011-01-21 | 2012-07-25 | 吉林师范大学 | Non-toxic environment-friendly preparation method of ZnO nanometer rod |
| CN104119704A (en) * | 2013-04-27 | 2014-10-29 | 中国科学院化学研究所 | Surface modification treatment method of halloysite nanotube |
| CN105567148A (en) * | 2016-02-26 | 2016-05-11 | 广州市白云化工实业有限公司 | Silane-modified polyether adhesive for sealing fabricated concrete buildings and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 秦建华等: "《中国西南地区矿产资源》", 31 October 2016, 中国地质大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112724904A (en) * | 2020-12-31 | 2021-04-30 | 佛山市三水日邦化工有限公司 | Graphene heating floor tile adhesive and preparation method thereof |
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