CN108659660A - A kind of preparation method of the water-fast heat-resisting aqueous woodware paint of wood artwork - Google Patents
A kind of preparation method of the water-fast heat-resisting aqueous woodware paint of wood artwork Download PDFInfo
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- CN108659660A CN108659660A CN201810598270.5A CN201810598270A CN108659660A CN 108659660 A CN108659660 A CN 108659660A CN 201810598270 A CN201810598270 A CN 201810598270A CN 108659660 A CN108659660 A CN 108659660A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of wood artwork preparation methods of water-fast heat-resisting aqueous woodware paint, dispersant is added into distilled water, color stuffing stirs into paste, water-and acrylate lotion, styrene-acrylic emulsion, antiblocking agent, coalescents, thickener, antifoaming agent is added and is stirred continuously, and the nano silicon dioxide of surface modification treatment, the processed multi-walled carbon nanotube of dual modified nitration mixture is added, it adds ammonium hydroxide and adjusts pH, be uniformly mixing to obtain water-fast heat-resisting aqueous woodware paint.Using nano silicon dioxide as reinforcement, with dispersant sodium carboxymethylcellulose and silane coupling agent KH560, to nano silicon dioxide, dispersibility is modified in water, dispersibility of the modified nano silicon dioxide in aqueous woodware paint is more uniform, it covers with paint, lacquer, colour wash, etc. in wood surface, the adhesive force of coating, impact resistance, hardness, ageing-resistant performance are improved.
Description
Technical field
The invention belongs to wood artwork treatment technology technical fields, and in particular to a kind of wood artwork is with water-fast heat-resisting
Aqueous woodware paint preparation method.
Background technology
Styrene-acrylic emulsion（Styrene-acrylate emulsion）It is to be obtained through emulsion copolymerization by styrene and acrylate monomer.
Styrene-acrylic emulsion is that more system is studied in emulsion polymerization, is important non-crosslinked type lotion, is had in wood artwork processing
It and is widely applied.But conventional styrene-acrylic emulsion have poor water resistance, thermal stability is relatively low, weatherability is not good enough, coating strength not
The defects of high, is unfavorable for the improvement of wood artwork wear-resisting and waterproof performance and Antimicrobial preservative.With the hair of nanometer science and technology
Exhibition, the preparation of nanometer particle-modified lotion and its functionalized application, have caused extensive concern.The present invention is with styrene-acrylic emulsion
For complex, using the nano silicon dioxide of surface modification, the processed multi-walled carbon nanotube of dual modified nitration mixture to its into
Row is modified, to be prepared for wood artwork with water-fast hot water resistance woodcare paint.
Invention content
The purpose of the present invention is for existing problem, provide a kind of water-fast heat-resisting aqueous wooden ware of wood artwork
The preparation method of paint, the aqueous woodware paint prepared in this way have good water-fast heat resistance, cover with paint, lacquer, colour wash, etc. in wood surface, apply
The adhesive force of layer, impact resistance, hardness, ageing-resistant performance are improved.
The present invention is achieved by the following technical solutions：
A kind of wood artwork preparation method of water-fast heat-resisting aqueous woodware paint, includes the following steps：
（1）The surface modification treatment of nano silicon dioxide：
Into 0.4-0.6 parts of dispersants 1:Distilled water is added in 90-110, is sufficiently stirred dissolving, and 0.9-1.1 parts of addition is silane coupled
Agent after stirring evenly, adds 5-7 parts of nano silicon dioxides, aqueous silica suspension is obtained after stirring evenly；
（2）The preparation of the dual modified processed multi-walled carbon nanotube of nitration mixture：
240-260 parts of ethyl alcohol are added into the processed multi-walled carbon nanotube of 2-3 parts of nitration mixture and 0.01-0.02 parts of polypyrrole alkanones
With the mixed dispersion liquid of water, it is ultrasonically treated 25-30min, 0.04-0.06 parts of silane coupling agents are added, ultrasonic 10-15min is on the rocks
Vinegar acid for adjusting pH is 3-4, is warming up to 70-73 DEG C and is stirred to react 3-4h, nano ferriferrous oxide ultrasonic disperse 25-30min is added,
It after being stirred to react 3-4h at 50-53 DEG C, is cooled to room temperature, centrifuges, with absolute ethyl alcohol and distillation water washing 3-5 times, in 50-55
It is dried in vacuo 2-3d at DEG C, obtains dual modified multi-walled carbon nanotube；
（3）The preparation of water-fast hot water resistance woodcare paint：
0.1-0.2 parts of dispersants are added into 6-7 parts of distilled water, color stuffing stirs into paste, 65-70 parts of water soluble acrylic acids of addition
Ester lotion, 20-30 part styrene-acrylic emulsion, 3-4 parts of antiblocking agents, 3-4 parts of coalescents, 0.5-1.5 parts of thickeners, 0.03-0.04
Part antifoaming agent is simultaneously stirred continuously, and resulting material in (1), (2) is added, and it is 7-8 to add ammonium hydroxide and adjust pH, stirs 30-
35min obtains water-fast heat-resisting aqueous woodware paint.
Further, step（1）Middle dispersant is sodium carboxymethylcellulose, silane coupling agent KH560.
Further, step（2）The surface of middle multi-walled carbon nanotube purifies：
Mixed acid solution is added into multi-walled carbon nanotube（Volume ratio is 3:1 98% concentrated sulfuric acid is mixed with 68% concentrated nitric acid）, ultrasound
After 30-35min, it is stirred at reflux reaction 3-4h at 90-92 DEG C, is diluted with distilled water and the filtering that cools down, repeatedly washing is filtered extremely
Neutrality is dried in vacuo 22-24h at 50-53 DEG C, obtains the processed multi-walled carbon nanotube of nitration mixture.
Further, step（2）The volume ratio of middle second alcohol and water is 3:1, silane coupling agent KH570.
Further, step（3）Middle dispersant is FSJ-502；Color stuffing by 8-9 parts of titanium dioxides, 6-7 parts of coarse whitings, 6-7 parts
Superfine talcum powder forms；Styrene-acrylic emulsion solid content is 45-50%；Coalescents are butyl glycol ether.
The present invention has the following advantages compared with prior art：
（1）Using nano silicon dioxide as reinforcement, with dispersant sodium carboxymethylcellulose and silane coupling agent KH560 to nanometer two
Dispersibility is modified silica in water, and dispersibility of the modified nano silicon dioxide in aqueous woodware paint is more equal
It is even, it covers with paint, lacquer, colour wash, etc. in wood surface, the adhesive force of coating, impact resistance, hardness, ageing-resistant performance are improved.
（2）Surface is carried out to multi-walled carbon nanotube with nitration mixture first to purify, through nitration mixture processing rear surface be grafted with carboxyl and
Then hydroxyl is modified the multi-walled carbon nanotube of surface after purification with silane coupling agent, then in multi-walled carbon nanotube table
Face loads nano ferriferrous oxide particle, new organic group and Fe-O keys occurs；Pass through nano ferriferrous oxide and silane
Coupling agent KH570 is dual modified to the processed multi-walled carbon nanotube of nitration mixture, can significantly improve the heat-resisting quantity and heat of woodcare paint
Stability, modified woodcare paint is good to the wetability of wood artwork, adhesive property is good.
（3）Using water-and acrylate lotion, styrene-acrylic emulsion as film forming matter, be aided with water, dispersant, color stuffing, antiblocking agent,
Coalescents, antifoaming agent, thickener prepare water-fast heat-resisting aqueous woodware paint.
Specific implementation mode
Embodiment 1
A kind of wood artwork preparation method of water-fast heat-resisting aqueous woodware paint, includes the following steps：
（1）The surface modification treatment of nano silicon dioxide：
Into 0.4 part of dispersant 1:90 are added distilled water, are sufficiently stirred dissolving, and 0.9 part of silane coupling agent is added, stirs evenly
Afterwards, 5 parts of nano silicon dioxides are added, aqueous silica suspension is obtained after stirring evenly；
（2）The preparation of the dual modified processed multi-walled carbon nanotube of nitration mixture：
The mixing of 240 parts of second alcohol and waters is added into the processed multi-walled carbon nanotube of 2 parts of nitration mixture and 0.01 part of polypyrrole alkanone
Dispersion liquid is ultrasonically treated 25min, and 0.04 part of silane coupling agent, ultrasonic 10min is added, and vinegar acid for adjusting pH on the rocks is 3-4, heating
It is stirred to react 3h to 70-73 DEG C, nano ferriferrous oxide ultrasonic disperse 25min is added, after being stirred to react 3h at 50-53 DEG C,
It is cooled to room temperature, centrifuges, with absolute ethyl alcohol and distillation water washing 3 times, be dried in vacuo 2d at 50-55 DEG C, obtain dual modified
Multi-walled carbon nanotube；
（3）The preparation of water-fast hot water resistance woodcare paint：
0.1 part of dispersant is added into 6 parts of distilled water, color stuffing stirs into paste, addition 65 parts of water-and acrylate lotions, 20
Part styrene-acrylic emulsion, 3 parts of antiblocking agents, 3 parts of coalescents, 0.5 part of thickener, 0.03 part of antifoaming agent are simultaneously stirred continuously, and are added
(1), resulting material in (2), it is 7-8 to add ammonium hydroxide and adjust pH, stirs 35min, obtains water-fast heat-resisting aqueous woodware paint.
Further, step（1）Middle dispersant is sodium carboxymethylcellulose, silane coupling agent KH560.
Further, step（2）The surface of middle multi-walled carbon nanotube purifies：
Mixed acid solution is added into multi-walled carbon nanotube（Volume ratio is 3:1 98% concentrated sulfuric acid is mixed with 68% concentrated nitric acid）, ultrasound
After 35min, it is stirred at reflux reaction 3h at 90-92 DEG C, is diluted with distilled water and the filtering that cools down, repeatedly washing is filtered to neutrality,
It is dried in vacuo 22h at 50-53 DEG C, obtains the processed multi-walled carbon nanotube of nitration mixture.
Further, step（2）The volume ratio of middle second alcohol and water is 3:1, silane coupling agent KH570.
Further, step（3）Middle dispersant is FSJ-502；Color stuffing is by 8 parts of titanium dioxides, 6 parts of coarse whitings, 6 parts of ultra-fine cunnings
Mountain flour forms；Styrene-acrylic emulsion solid content is 45%；Coalescents are butyl glycol ether.
Embodiment 2
A kind of wood artwork preparation method of water-fast heat-resisting aqueous woodware paint, includes the following steps：
（1）The surface modification treatment of nano silicon dioxide：
Into 0.6 part of dispersant 1:110 are added distilled water, are sufficiently stirred dissolving, and 1.1 parts of silane coupling agents are added, stir evenly
Afterwards, 7 parts of nano silicon dioxides are added, aqueous silica suspension is obtained after stirring evenly；
（2）The preparation of the dual modified processed multi-walled carbon nanotube of nitration mixture：
The mixing of 260 parts of second alcohol and waters is added into the processed multi-walled carbon nanotube of 3 parts of nitration mixture and 0.02 part of polypyrrole alkanone
Dispersion liquid is ultrasonically treated 30min, and 0.06 part of silane coupling agent, ultrasonic 15min is added, and vinegar acid for adjusting pH on the rocks is 3-4, heating
It is stirred to react 4h to 70-73 DEG C, nano ferriferrous oxide ultrasonic disperse 30min is added, after being stirred to react 4h at 50-53 DEG C,
It is cooled to room temperature, centrifuges, with absolute ethyl alcohol and distillation water washing 3 times, be dried in vacuo 3d at 50-55 DEG C, obtain dual modified
Multi-walled carbon nanotube；
（3）The preparation of water-fast hot water resistance woodcare paint：
0.2 part of dispersant is added into 7 parts of distilled water, color stuffing stirs into paste, addition 70 parts of water-and acrylate lotions, 30
Part styrene-acrylic emulsion, 4 parts of antiblocking agents, 4 parts of coalescents, 1.5 parts of thickeners, 0.04 part of antifoaming agent are simultaneously stirred continuously, and are added
(1), resulting material in (2), it is 7-8 to add ammonium hydroxide and adjust pH, stirs 35min, obtains water-fast heat-resisting aqueous woodware paint.
Further, step（1）Middle dispersant is sodium carboxymethylcellulose, silane coupling agent KH560.
Further, step（2）The surface of middle multi-walled carbon nanotube purifies：
Mixed acid solution is added into multi-walled carbon nanotube（Volume ratio is 3:1 98% concentrated sulfuric acid is mixed with 68% concentrated nitric acid）, ultrasound
After 35min, it is stirred at reflux reaction 4h at 90-92 DEG C, is diluted with distilled water and the filtering that cools down, repeatedly washing is filtered to neutrality,
It is dried in vacuo 22h at 50-53 DEG C, obtains the processed multi-walled carbon nanotube of nitration mixture.
Further, step（2）The volume ratio of middle second alcohol and water is 3:1, silane coupling agent KH570.
Further, step（3）Middle dispersant is FSJ-502；Color stuffing is by 9 parts of titanium dioxides, 7 parts of coarse whitings, 7 parts of ultra-fine cunnings
Mountain flour forms；Styrene-acrylic emulsion solid content is 50%；Coalescents are butyl glycol ether.
Comparative example 1
This comparative example 1 compared with Example 1, in step（3）In the nano silicon dioxide of surface modification treatment is not added, remove
In addition method and step all same.
Comparative example 2
This comparative example 2 compared with Example 2, in step（3）In the processed multi wall carbon of dual modified nitration mixture is not added
Nanotube, method and step all same in addition to this.
Control group
Application No. is：A kind of willow-plaited process product paint disclosed in 201710410504.
Mechanics in order to compare aqueous woodware paint produced by the present invention uses quality, water-fast heat resistance, to above-mentioned implementation
Example 1, embodiment 2, comparative example 1,2 method of comparative example correspond to the corresponding paint of woodcare paint and control group obtained and press
Performance detection is carried out according to professional standard, specific correction data is as shown in table 1 below：
Table 1
The nano silicon dioxide that surface modification treatment is not added is not added for comparative example 1 it can be seen from upper table 1, and comparison is real
It applies example 2 and is not added and the processed multi-walled carbon nanotube of dual modified nitration mixture is not added, it is the hardness of paint film of aqueous woodware paint, water-fast
Property, adhesive force and resistant of high or low temperature are obviously deteriorated；Quality is used by the synthesis mechanics of aqueous woodware paint made from the method for the present invention
It has obtained apparent improvement to be promoted, there is very strong heat-resisting water resistance, good mechanics can be kept to use quality, stability
By force, safe to use, service life is long, great popularizing value and the market competitiveness.
Claims (5)
1. a kind of wood artwork preparation method of water-fast heat-resisting aqueous woodware paint, which is characterized in that include the following steps：
（1）The surface modification treatment of nano silicon dioxide：
Into 0.4-0.6 parts of dispersants 1:Distilled water is added in 90-110, is sufficiently stirred dissolving, and 0.9-1.1 parts of addition is silane coupled
Agent after stirring evenly, adds 5-7 parts of nano silicon dioxides, aqueous silica suspension is obtained after stirring evenly；
（2）The preparation of the dual modified processed multi-walled carbon nanotube of nitration mixture：
240-260 parts of ethyl alcohol are added into the processed multi-walled carbon nanotube of 2-3 parts of nitration mixture and 0.01-0.02 parts of polypyrrole alkanones
With the mixed dispersion liquid of water, it is ultrasonically treated 25-30min, 0.04-0.06 parts of silane coupling agents are added, ultrasonic 10-15min is on the rocks
Vinegar acid for adjusting pH is 3-4, is warming up to 70-73 DEG C and is stirred to react 3-4h, nano ferriferrous oxide ultrasonic disperse 25-30min is added,
It after being stirred to react 3-4h at 50-53 DEG C, is cooled to room temperature, centrifuges, with absolute ethyl alcohol and distillation water washing 3-5 times, in 50-55
It is dried in vacuo 2-3d at DEG C, obtains dual modified multi-walled carbon nanotube；
（3）The preparation of water-fast hot water resistance woodcare paint：
0.1-0.2 parts of dispersants are added into 6-7 parts of distilled water, color stuffing stirs into paste, 65-70 parts of water soluble acrylic acids of addition
Ester lotion, 20-30 part styrene-acrylic emulsion, 3-4 parts of antiblocking agents, 3-4 parts of coalescents, 0.5-1.5 parts of thickeners, 0.03-0.04
Part antifoaming agent is simultaneously stirred continuously, and resulting material in (1), (2) is added, and it is 7-8 to add ammonium hydroxide and adjust pH, stirs 30-
35min obtains water-fast heat-resisting aqueous woodware paint.
2. a kind of wood artwork according to claim 1 preparation method of water-fast heat-resisting aqueous woodware paint, special
Sign is, step（1）Middle dispersant is sodium carboxymethylcellulose, silane coupling agent KH560.
3. a kind of wood artwork according to claim 1 preparation method of water-fast heat-resisting aqueous woodware paint, special
Sign is, step（2）The surface of middle multi-walled carbon nanotube purifies：
Mixed acid solution is added into multi-walled carbon nanotube（Volume ratio is 3:1 98% concentrated sulfuric acid is mixed with 68% concentrated nitric acid）, ultrasound
After 30-35min, it is stirred at reflux reaction 3-4h at 90-92 DEG C, is diluted with distilled water and the filtering that cools down, repeatedly washing is filtered extremely
Neutrality is dried in vacuo 22-24h at 50-53 DEG C, obtains the processed multi-walled carbon nanotube of nitration mixture.
4. a kind of wood artwork according to claim 1 preparation method of water-fast heat-resisting aqueous woodware paint, special
Sign is, step（2）The volume ratio of middle second alcohol and water is 3:1, silane coupling agent KH570.
5. a kind of wood artwork according to claim 1 preparation method of water-fast heat-resisting aqueous woodware paint, special
Sign is, step（3）Middle dispersant is FSJ-502；Color stuffing is by 8-9 parts of titanium dioxides, 6-7 parts of coarse whitings, 6-7 parts of superfine talcum powders
Composition；Styrene-acrylic emulsion solid content is 45-50%；Coalescents are butyl glycol ether.
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| CN201810598270.5A CN108659660A (en) | 2018-06-12 | 2018-06-12 | A kind of preparation method of the water-fast heat-resisting aqueous woodware paint of wood artwork |
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| CN201810598270.5A CN108659660A (en) | 2018-06-12 | 2018-06-12 | A kind of preparation method of the water-fast heat-resisting aqueous woodware paint of wood artwork |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112322126A (en) * | 2020-10-30 | 2021-02-05 | 江西玉龙防水科技有限公司 | Anti-aging coating and preparation method thereof |
| CN116445034A (en) * | 2023-04-26 | 2023-07-18 | 苏州中亚油墨有限公司 | Environment-friendly high-adhesion gravure ink and preparation method thereof |
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| CN105176218A (en) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | Aqueous nano-coating and preparation process thereof |
| CN107601461A (en) * | 2017-10-30 | 2018-01-19 | 西南交通大学 | A kind of magnetic composite of Fe 3 O 4 coating carbon nanotube and preparation method thereof |
| CN107803181A (en) * | 2017-10-18 | 2018-03-16 | 甘肃省商业科技研究所有限公司 | The preparation and application of the carbon nano-tube modified composite of magnetic ferroferric oxide nano-particles |
| CN107858055A (en) * | 2017-11-16 | 2018-03-30 | 君子兰化工（上海）有限公司 | The high weather resistant water-thinned mould proof varnish of woodenware |
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- 2018-06-12 CN CN201810598270.5A patent/CN108659660A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104592818A (en) * | 2014-12-16 | 2015-05-06 | 三棵树涂料股份有限公司 | High-temperature-resistant high-pressure-resistant water-based wood paint and preparation method thereof |
| CN105176218A (en) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | Aqueous nano-coating and preparation process thereof |
| CN107803181A (en) * | 2017-10-18 | 2018-03-16 | 甘肃省商业科技研究所有限公司 | The preparation and application of the carbon nano-tube modified composite of magnetic ferroferric oxide nano-particles |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112322126A (en) * | 2020-10-30 | 2021-02-05 | 江西玉龙防水科技有限公司 | Anti-aging coating and preparation method thereof |
| CN116445034A (en) * | 2023-04-26 | 2023-07-18 | 苏州中亚油墨有限公司 | Environment-friendly high-adhesion gravure ink and preparation method thereof |
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Application publication date: 20181016 |