CN108659646A - One kind is waterborne to make scape new waterproof anti-corrosive primer and its processing technology - Google Patents
One kind is waterborne to make scape new waterproof anti-corrosive primer and its processing technology Download PDFInfo
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- CN108659646A CN108659646A CN201810513530.4A CN201810513530A CN108659646A CN 108659646 A CN108659646 A CN 108659646A CN 201810513530 A CN201810513530 A CN 201810513530A CN 108659646 A CN108659646 A CN 108659646A
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- iron oxide
- zinc
- corrosive primer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses it is a kind of it is waterborne make scape new waterproof anti-corrosive primer and its processing technology, component is by proportion by weight：10 15 parts of iron oxide reds, 46 parts of zinc carbonates, 5 parts of zinc oxide, 58 parts of nano materials, 0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part of dispersant with high efficiency, 0.1 part of ANP, 95,50 60 parts of antirust emulsions, 10 20 parts of water, 25 parts of propylene glycol.Indices of the present invention meet or exceed red iron oxide alkyd primer, iron oxide red, zinc yellow, iron black epoxy ester undercoat, zinc yellow, iron oxide red ethylene perchloride primer, leading indicator resistance to salt water as anti-corrosive primer reach 250 hours it is not blistering, it does not fall off, greatly exceed three of the above paint, indicate a kind of brand new ideas, the high-tech product of safety and environmental protection is ripe, it is widely used in shipbuilding, machinery, building, vehicle, the surface anticorrosion operation of the industries steel component such as oil tank, it is not environmentally friendly enough to solve the prior art, with certain toxicity and smell, the problem of influencing user's usage comfort.
Description
Technical field
It is specially a kind of waterborne to make scape new waterproof anti-corrosive primer and its processing work the present invention relates to chemical technology field
Skill.
Background technology
Antirust paint is a kind of coating for the chemistry or electrochemical corrosion protecting metal surfaces from air, seawater etc..It is main
It is divided into physical and chemically antirust paint two major classes.The former leans on the appropriate cooperation of pigment and paint vehicle, formed fine and close paint film with
Prevent the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint；The latter acts on by the chemistry suppression rust of rust resisting pigment, such as
Red lead, zinc chromate anti-rust paint etc..Antirust for metals such as bridge, ship, pipelines.
Antirust paint substantially oiliness and two kinds aqueous.Oily antirust varniss keeps the greasy removal of material surface difficult, seldom makes
With.Oily antirust varniss is easy to use, cheap, but because containing noxious materials such as nitrite, chromate, endangering to operating personnel
Evil is larger, and country has limited use, and such properties of product are single, cannot meet the antirust requirement of magnetic alloy material.It is aqueous
It is main component that metallic anti-rust paint, which selects metal strength chelating agent inositol hexaphosphate, with other several aqueous promoters compoundings and
At.Inositol hexaphosphate is the Nantural non-toxic Organic chemical products extracted from cereal crops, when it is as magnetic material antirust
In use, can rapidly be chelated with metal on surface, one layer of fine and close unimolecule complex compound protective film of formation can effectively inhibit gold for agent
The corrosion of category.Material surface after the product treatment keeps primary colors, it is not necessary to which washing can enter the next procedures such as application.
The patent of invention of Patent No. CN103483937A discloses a kind of antirust paint, each component by weight, phenylpropyl alcohol
75-80 parts of lotion, 20-30 parts of iron oxide red, 5-10 parts of polycarbonate, 10-15 parts of six phosphate ester of inositol, aluminium dihydrogen tripolyphosphate
1-3 parts, 0.5-2 parts of ferric solid-acid agent, 0.02-1 parts of silica, 100 parts of water.Although the invention is imitated with very strong fixation
Fruit, but it is not environmentally friendly enough, there is certain toxicity and smell, affect user's comforts of use, for this purpose, it is proposed that a kind of recessed
Painting plate ink and its production technology.
Invention content
The purpose of the present invention is to provide it is a kind of it is waterborne make scape new waterproof anti-corrosive primer and its processing technology, in solution
State the problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions：One kind is waterborne to make scape new waterproof anti-corrosive primer,
Component matches by mass percentage：10-15 parts of iron oxide reds, 4-6 parts of zinc carbonates, 5 parts of zinc oxide, 5-8 parts of nano materials,
0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part of dispersant with high efficiency, 0.1 part of ANP-95,50-60 parts of antirust emulsion, 10-20 parts
Water, 2-5 part propylene glycol.
Preferably, the antirust emulsion uses acrylic emulsion.
Preferably, the iron oxide red is 12 parts, and zinc carbonate is 5 parts, and nano material is 6 parts, and antirust emulsion is 50 parts, water
150 parts of position, propylene glycol are 5 parts.
A kind of processing technology waterborne for making scape new waterproof anti-corrosive primer, includes the following steps：In order by water, ANP-
95, charging basket is added in dispersant, antifoaming agent, propylene glycol, fungicide, after stirring evenly, after putting into nano material high speed dispersion, then puts into oxygen
Change iron oxide red, zinc oxide, trbasic zinc phosphate to stir evenly rear high speed dispersion, then grind, lotion and auxiliary agent paint, middle survey, filtering, finished product packet is added
Dress.
Preferably, described be stirred in rear container must not have lump.
Compared with prior art, the beneficial effects of the invention are as follows：The present invention is existed by certain reactive pigments and rust resisting pigment
Under the action of subacidity, and then the nitrogen base ionic group of Vapor recovery unit iron rust is formed, active iron rust is made to lose activity to reach and match
Position complexing makes in coating process in paint film fully penetrated to the micropore of steel surface, and iron rust is separated and is enclosed in paint
In slurry, is reacted to each other by slowly hydrolyzing after film forming, the heteropoly acid complex compound of indissoluble is further formed, by harmful iron rust
It is converted into beneficial protective layer, is firmly attached to metal surface, to obtain lasting inhibition and antirust purpose, with multiple functions list
Body and the special emulsion of olefines vinyl monomer complex reaction type emulsifier synthesis have extremely strong tightness and water resistance, are
Priming paint provides good adhesive force, nitrocellulose lacquer resistance and flexibility, and indices meet or exceed red iron oxide alkyd primer, iron
Red, zinc yellow, iron black epoxy ester undercoat, zinc yellow, iron oxide red ethylene perchloride primer, the leading indicator resistance to salt water as anti-corrosive primer reach
It is not blistering by 250 hours, it does not fall off, greatly exceeds three of the above paint, indicate a kind of brand new ideas, the height of safety and environmental protection
Sci-tech product is ripe, is widely used in the surface anticorrosion work of all steel components of the industries such as shipbuilding, machinery, building, vehicle, oil tank
Industry solves the problem of prior art is not environmentally friendly enough, has certain toxicity and smell, influences user's usage comfort.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention provides a kind of technical solution：
One kind is waterborne to make scape new waterproof anti-corrosive primer, and component matches by mass percentage is：10-15 parts of iron oxide
Red, 4-6 parts of zinc carbonate, 5 parts of zinc oxide, 5-8 parts of nano materials, 0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part of high efficiency dispersion
Agent, 0.1 part of ANP-95,50-60 parts of antirust emulsion, 10-20 parts of water, 2-5 parts of propylene glycol.
A kind of processing technology waterborne for making scape new waterproof anti-corrosive primer, includes the following steps：In order by water, ANP-
95, charging basket is added in dispersant, antifoaming agent, propylene glycol, fungicide, after stirring evenly, after putting into nano material high speed dispersion, then puts into oxygen
Change iron oxide red, zinc oxide, trbasic zinc phosphate to stir evenly rear high speed dispersion, then grind, lotion and auxiliary agent paint, middle survey, filtering, finished product packet is added
Dress.
Embodiment one：
One kind is waterborne to make scape new waterproof anti-corrosive primer, and component matches by mass percentage is：10 parts of iron oxide reds, 4
Part zinc carbonate, 5 parts of zinc oxide, 5 parts of nano materials, 0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part of dispersant with high efficiency, 0.1 part
ANP-95,50 parts of acrylic emulsions, 10 parts of water, 2 parts of propylene glycol.
Preparation method：Charging basket is added in water, ANP-95, dispersant, antifoaming agent, propylene glycol, fungicide in order, is stirred evenly
Afterwards, there must not be lump in container, after then putting into nano material high speed dispersion, then put into iron oxide red, zinc oxide, trbasic zinc phosphate
Rear high speed dispersion is stirred evenly, then is ground, lotion and auxiliary agent paint, middle survey, filtering, finished product packing is added.
Embodiment two：
One kind is waterborne to make scape new waterproof anti-corrosive primer, and component matches by mass percentage is：12 parts of iron oxide reds, 5
Part zinc carbonate, 5 parts of zinc oxide, 6 parts of nano materials, 0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part of dispersant with high efficiency, 0.1 part
ANP-95,50 parts of antirust emulsions, 15 parts of water, 4 parts of propylene glycol.
Preparation method：Charging basket is added in water, ANP-95, dispersant, antifoaming agent, propylene glycol, fungicide in order, is stirred evenly
Afterwards, there must not be lump in container, after then putting into nano material high speed dispersion, then put into iron oxide red, zinc oxide, trbasic zinc phosphate
Rear high speed dispersion is stirred evenly, then is ground, lotion and auxiliary agent paint, middle survey, filtering, finished product packing is added.
Embodiment three：
One kind is waterborne to make scape new waterproof anti-corrosive primer, and component matches by mass percentage is：15 parts of iron oxide reds, 6
Part zinc carbonate, 5 parts of zinc oxide, 8 parts of nano materials, 0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part of dispersant with high efficiency, 0.1 part
ANP-95,60 parts of antirust emulsions, 20 parts of water, 5 parts of propylene glycol.
Preparation method：Charging basket is added in water, ANP-95, dispersant, antifoaming agent, propylene glycol, fungicide in order, is stirred evenly
Afterwards, there must not be lump in container, after then putting into nano material high speed dispersion, then put into iron oxide red, zinc oxide, trbasic zinc phosphate
Rear high speed dispersion is stirred evenly, then is ground, lotion and auxiliary agent paint, middle survey, filtering, finished product packing is added.
The present invention by certain reactive pigments and rust resisting pigment under the action of subacidity, and then formed Vapor recovery unit iron rust
Nitrogen base ionic group, make active iron rust lose activity reach ligand complex effect, in coating process, paint film is made fully to ooze
Thoroughly in the micropore of steel surface, iron rust is separated and is enclosed in mill base, is reacted to each other by slowly hydrolyzing after film forming,
It is further formed the heteropoly acid complex compound of indissoluble, is beneficial protective layer by harmful rust transformation, is firmly attached to metal watch
Face is emulsified with obtaining lasting inhibition and antirust purpose with multiple functions monomer and olefines vinyl monomer complex reaction type
Agent synthesis special emulsion have extremely strong tightness and water resistance, for priming paint provide good adhesive force, nitrocellulose lacquer resistance and
Flexibility, indices meet or exceed red iron oxide alkyd primer, iron oxide red, zinc yellow, iron black epoxy ester undercoat, zinc yellow, iron oxide red mistake
Vinyl chloride priming paint, the leading indicator resistance to salt water as anti-corrosive primer reach 250 hours it is not blistering, do not fall off, greatly exceed
Three of the above paint, indicate a kind of brand new ideas, the high-tech product of safety and environmental protection is ripe, be widely used in shipbuilding, machinery,
The surface anticorrosion operation of all steel components of the industries such as building, vehicle, oil tank, it is not environmentally friendly enough to solve the prior art, has one
Fixed toxicity and smell, the problem of influencing user's usage comfort.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (5)
1. one kind is waterborne to make scape new waterproof anti-corrosive primer, it is characterised in that：Its component is by proportion by weight：10-15 parts of oxygen
Change iron oxide red, 4-6 part zinc carbonates, 5 parts of zinc oxide, 5-8 parts of nano materials, 0.1 part of fungicide, 0.1 part of antifoaming agent, 0.3 part it is efficient
Dispersant, 0.1 part of ANP-95,50-60 parts of antirust emulsion, 10-20 parts of water, 2-5 parts of propylene glycol.
2. one kind according to claim 1 is waterborne to make scape new waterproof anti-corrosive primer, it is characterised in that：The antirust emulsion
Using acrylic emulsion.
3. one kind according to claim 1 is waterborne to make scape new waterproof anti-corrosive primer, it is characterised in that：The iron oxide red
It it is 12 parts, zinc carbonate is 5 parts, and nano material is 6 parts, and antirust emulsion is 50 parts, 150 parts of water level, and propylene glycol is 5 parts.
4. a kind of processing technology waterborne for making scape new waterproof anti-corrosive primer, it is characterised in that：Include the following steps：In order will
Charging basket is added in water, ANP-95, dispersant, antifoaming agent, propylene glycol, fungicide, after stirring evenly, after putting into nano material high speed dispersion,
Iron oxide red, zinc oxide, trbasic zinc phosphate are put into again and stirs evenly rear high speed dispersion, then is ground, and lotion and auxiliary agent paint, middle survey, mistake is added
Filter, finished product packing.
5. a kind of processing technology waterborne for making scape new waterproof anti-corrosive primer according to claim 4, it is characterised in that：Institute
It states to be stirred in rear container and must not have lump.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810513530.4A CN108659646A (en) | 2018-05-25 | 2018-05-25 | One kind is waterborne to make scape new waterproof anti-corrosive primer and its processing technology |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810513530.4A CN108659646A (en) | 2018-05-25 | 2018-05-25 | One kind is waterborne to make scape new waterproof anti-corrosive primer and its processing technology |
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| Publication Number | Publication Date |
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| CN108659646A true CN108659646A (en) | 2018-10-16 |
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| CN201810513530.4A Pending CN108659646A (en) | 2018-05-25 | 2018-05-25 | One kind is waterborne to make scape new waterproof anti-corrosive primer and its processing technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112251078A (en) * | 2020-10-22 | 2021-01-22 | 福建暖湾实业有限公司 | Waterproof coating for water tank landscaping and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206446A (en) * | 2010-03-31 | 2011-10-05 | 王胜美 | Preparation method for water-based anti-rust paint for rusty surfaces |
| CN102993809A (en) * | 2012-11-26 | 2013-03-27 | 安徽西格尔涂料科技有限公司 | Preparation method of aqueous environmentally-friendly antirust primer |
| CN103834249A (en) * | 2013-12-31 | 2014-06-04 | 上海福岛化工科技发展有限公司 | Anti-flash-rust water-based acrylic acid iron red antirust priming paint and preparation method thereof |
| CN106634373A (en) * | 2015-11-03 | 2017-05-10 | 无锡市太湖防腐材料有限公司 | Waterborne zinc aluminum phosphate anti-rusting primer and preparation method thereof |
-
2018
- 2018-05-25 CN CN201810513530.4A patent/CN108659646A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206446A (en) * | 2010-03-31 | 2011-10-05 | 王胜美 | Preparation method for water-based anti-rust paint for rusty surfaces |
| CN102993809A (en) * | 2012-11-26 | 2013-03-27 | 安徽西格尔涂料科技有限公司 | Preparation method of aqueous environmentally-friendly antirust primer |
| CN103834249A (en) * | 2013-12-31 | 2014-06-04 | 上海福岛化工科技发展有限公司 | Anti-flash-rust water-based acrylic acid iron red antirust priming paint and preparation method thereof |
| CN106634373A (en) * | 2015-11-03 | 2017-05-10 | 无锡市太湖防腐材料有限公司 | Waterborne zinc aluminum phosphate anti-rusting primer and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 汪国平: "《船舶涂料与涂装技术》", 31 January 1998, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112251078A (en) * | 2020-10-22 | 2021-01-22 | 福建暖湾实业有限公司 | Waterproof coating for water tank landscaping and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20181016 |