CN108658186A - A kind of processing method of leather sewage - Google Patents

A kind of processing method of leather sewage Download PDF

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Publication number
CN108658186A
CN108658186A CN201710188642.2A CN201710188642A CN108658186A CN 108658186 A CN108658186 A CN 108658186A CN 201710188642 A CN201710188642 A CN 201710188642A CN 108658186 A CN108658186 A CN 108658186A
Authority
CN
China
Prior art keywords
coagulant
sewage
chloride
complex element
leather
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710188642.2A
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Chinese (zh)
Inventor
王皓平
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710188642.2A priority Critical patent/CN108658186A/en
Publication of CN108658186A publication Critical patent/CN108658186A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/22Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
    • C02F2103/24Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof from tanneries

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a kind of new leather sewage processing methods.Leather sewage is handled using the method and coagulant of the present invention, with good sewage processing effect, the advantages that coagulant reaction is fully, residuals are few, pharmaceutical use is small in water, including in sewage conduct or exit pass through spray pipeline be added coagulant, this method is to connect at least one additional pipeline on spray pipeline, be added in coagulant the complex element (or being compound substance) for improving coagulant efficiency by additional pipeline, complex element mix with coagulant after into sewage conduct is interior or the sewage in exit;The coagulant is bodied ferric sulfate, aluminium polychloride diallyldimethylammonium chloride, diallyldimethylammonium chloride or acrylic amine copolymer;The complex element is calcium chloride, magnesium chloride, magnesium sulfate, zinc sulfate, zinc chloride, phosphoric acid, sulfuric acid, hydrochloric acid, activated silicic acid, diallyldimethylammonium chloride, diallyldimethylammonium chloride or acrylic amine copolymer.

Description

A kind of processing method of leather sewage
Technical field
The present invention relates to a kind of processing methods of leather sewage, belong to technical field of sewage.
Background technology
In leather sewage processing and purification of water quality, coagulation is one of them very important unit, it is to pass through coagulation Agent changes the state of particulate matter in water, so that suspension sexual element and colloid composition in water is detached from, being formed under certain conditions can It is deposited or the flco of dissolved air flotation makes this part flco separate then by precipitation or air supporting.In coagulating treatment, for Coagulant used in different types of sewage is the key that processing, therefore has many researchers to be opened in positive research The composite coagulant or flocculant for sending out new, and the various coagulant of existing processing leather sewage mainly still use molysite Or aluminium salt, there is no do good differentiation for leather sewage;Complex process is also an important list in sewage disposal simultaneously Member, on complex process on there are problems that compounding time and dosage some, such as during handling leather sewage, just There are coagulant to react slow with leather sewage and the problems such as coagulant does not react with the suspended matter in water, lead to coagulant In metallic element residual in water, produce secondary pollution, while the reaction of coagulant is incomplete, also creates coagulant Waste, further increase the expense of sewage disposal.
Invention content
The object of the present invention is to provide a kind of new leather sewage processing methods.Utilize the method and coagulation of the present invention Agent handles leather sewage, has a good sewage processing effect, and fully, in water residuals are few for coagulant reaction, pharmaceutical use is small The advantages that
Technical scheme of the present invention:A kind of processing method of leather sewage, including in sewage conduct or exit passes through spray Coagulant is added in pipeline, and this method is to connect at least one additional pipeline on spray pipeline, by additional pipeline in coagulant The interior complex element (or being compound substance) being added for improving coagulant efficiency, after complex element is mixed with coagulant In into sewage conduct or in the sewage in exit;The coagulant is bodied ferric sulfate, aluminium polychloride diallyl two Ammonio methacrylate, diallyldimethylammonium chloride or acrylic amine copolymer;The complex element is calcium chloride, chlorination Magnesium, magnesium sulfate, zinc sulfate, zinc chloride, phosphoric acid, sulfuric acid, hydrochloric acid, activated silicic acid, diallyldimethylammonium chloride, two allyls Base alkyl dimethyl ammonium chloride or acrylic amine copolymer.
Above-mentioned leather sewage processing method is, the time that complex element is mixed with coagulant is less than 10 seconds, then again into Enter in sewage conduct or the sewage in exit.
Above-mentioned leather sewage processing method is, the time that complex element is mixed with coagulant is 4~7 seconds, then again into Enter in sewage conduct or the sewage in exit.
Above-mentioned leather sewage processing method is that 1000 parts of coagulant is often added by mass parts, corresponding that complex element is added It is 0.5~100 part.
Leather sewage processing method above-mentioned is that 1000 parts of coagulant is often added by mass parts, corresponding that complex element is added It is 0.5~20 part.
Leather sewage processing method above-mentioned is that 1000 parts of coagulant is often added by mass parts, corresponding that complex element is added It is 0.5~10 part.
Compared with the prior art, leather sewage is handled with coagulant using the method for the present invention, there is wastewater treatment efficiency Well, the advantages that coagulant reaction is fully, residuals are few, pharmaceutical use is small in water.
Applicant has found in long-term practice with experiment, after coagulant is mixed with the complex element of various composition, that is, produces A kind of raw inorganic polymer of more high polymerization degree, complex element refers to the various medicaments that can improve coagulant effect, but anti- During answering, inorganic polymer form can only be stablized in a short period of time, extend at any time, can make the nothing of high polymerization degree Machine macromolecule is gradually restored to original coagulation form, therefore complex element is put into coagulant and is mixed into input sewage instead The time answered needs to complete in seconds.Accordingly, applicant use by properly mixed coagulant with it is compound Element is separately launched, and is connect with sewage when forming the inorganic polymer form of high polymerization degree after coagulant is mixed with complex element It touches and achievees the effect that optimal coagulation.The dosage of coagulant 1/3 can be reduced using such method, and makes coagulant and dirt Suspended matter and glial response in water is more complete, and coagulant utilization is more thorough, reduces coagulant residual in water, avoids Secondary pollution to water quality.The applicant tests corresponding all kinds of sewage also according to this method repeatedly simultaneously, finds The most suitable coagulant of processing leather sewage institute and complex element and most suitable proportion relation, are in this way solving environment Reduce processing cost while pollution problem, and leather sewage can also secondary use, further section to treated Fund and Water Energy have been saved, environment is protected, there is good economic benefit and social benefit.
Specific implementation mode
The embodiment of the present invention, because of different types of coagulant such as bodied ferric sulfate, aluminium polychloride diallyl dimethyl Ammonium chloride, diallyldimethylammonium chloride or acrylic amine copolymer;It can react in a short time when mixing, shape At inorganic polymer form, therefore coagulant of the present invention and complex element (or compound substance) can be congener Matter, but can not use identical substance simultaneously as coagulant in drug feeding pipeline 2 and additional pipeline 3 in specifically used and answer Close element.
One drug feeding pipeline is set on the blow-off line of the leather sewage of flowing, one is connected in the side of drug feeding pipeline Coagulant is added by drug feeding pipeline in a additional pipeline, and the coagulant being added is that bodied ferric sulfate is alternatively aluminium polychloride Diallyldimethylammonium chloride, diallyldimethylammonium chloride or acrylic amine copolymer.And it is added by tube-carrier multiple Close element, the complex element being added be calcium chloride be alternatively magnesium chloride, magnesium sulfate, zinc sulfate, zinc chloride, phosphoric acid, sulfuric acid, Hydrochloric acid, activated silicic acid, diallyldimethylammonium chloride, diallyldimethylammonium chloride or acrylic amine copolymer.By matter 1000 parts of bodied ferric sulfates, aluminium polychloride, diallyldimethylammonium chloride, diene are often added by drug feeding pipeline for amount part Diallyidimethylammonium chloride or acrylic amine copolymer, it is corresponding that 2 parts of calcium chloride, magnesium chloride, sulfuric acid are added by additional pipeline Magnesium, zinc sulfate, zinc chloride, phosphoric acid, sulfuric acid, hydrochloric acid, activated silicic acid, diallyldimethylammonium chloride, diallydimethyl Ammonium chloride or acrylic amine copolymer, the coagulant being added and complex element are mixed in 10 seconds in drug feeding pipeline bottom, are formed Inorganic polymer form, and be in contact with the leather sewage of flowing rapidly so that medicament is uniformly diffused into rapidly leather sewage In, after being fully hydrolyzed, you can complete the processing to leather sewage, leather sewage is tested to treated, is discharged PH Value, COD value up to national standard, and treated leather sewage can also secondary use, save fund and Water Energy, With good economic benefit and social benefit.
The method is characterized in that after properly mixed coagulant is mixed with complex element, within the regular hour, quickly It launches in leather sewage and completes the chemical reaction in leather sewage processing procedure.Be not limited in through drug feeding pipeline and Additional pipeline launches coagulant and other dosing modes can also be used as long as disclosure satisfy that above-mentioned requirements in complex element.

Claims (3)

1. a kind of processing method of leather sewage, including in sewage conduct or coagulant is added by the pipeline that sprays in exit, It is characterized in that:At least one additional pipeline is connected on spray pipeline, is added in coagulant for carrying by additional pipeline The complex element of high coagulant efficiency, complex element enters after being mixed with coagulant in sewage conduct or the sewage in exit In;The coagulant is bodied ferric sulfate, aluminium polychloride diallyldimethylammonium chloride, diallydimethyl chlorine Change ammonium or acrylic amine copolymer;The complex element is calcium chloride, magnesium chloride, magnesium sulfate, zinc sulfate, zinc chloride, activation Silicic acid, phosphoric acid, sulfuric acid, hydrochloric acid, diallyldimethylammonium chloride, diallyldimethylammonium chloride or acrylic amine copolymerization Object.
2. leather sewage processing method according to claim 1, it is characterised in that:Complex element is mixed with coagulant Time is less than 7 seconds, then enters back into sewage conduct or the sewage in exit.
3. leather sewage processing method according to claim 2, it is characterised in that:Complex element is mixed with coagulant Time is 4~7 seconds, is then entered back into sewage conduct or the sewage in exit.
CN201710188642.2A 2017-03-27 2017-03-27 A kind of processing method of leather sewage Pending CN108658186A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710188642.2A CN108658186A (en) 2017-03-27 2017-03-27 A kind of processing method of leather sewage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710188642.2A CN108658186A (en) 2017-03-27 2017-03-27 A kind of processing method of leather sewage

Publications (1)

Publication Number Publication Date
CN108658186A true CN108658186A (en) 2018-10-16

Family

ID=63786143

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710188642.2A Pending CN108658186A (en) 2017-03-27 2017-03-27 A kind of processing method of leather sewage

Country Status (1)

Country Link
CN (1) CN108658186A (en)

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Application publication date: 20181016

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