CN108656650B - 一种抗菌除臭易清洁面料及其制备方法 - Google Patents

一种抗菌除臭易清洁面料及其制备方法 Download PDF

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CN108656650B
CN108656650B CN201810483594.4A CN201810483594A CN108656650B CN 108656650 B CN108656650 B CN 108656650B CN 201810483594 A CN201810483594 A CN 201810483594A CN 108656650 B CN108656650 B CN 108656650B
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魏宁
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Yajin Clothing Wuhan Co ltd
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Abstract

本发明提供一种抗菌除臭易清洁面料及其制备方法,清洁面料包括底层、清洁层和离型保护层;清洁层包括分离膜和抗菌阻隔层;抗菌阻隔层设置于分离膜上;分离膜的侧边区域包覆抗菌阻隔层的侧面,并贴附于抗菌阻隔层的上表面;多层清洁层依次设置于底层上;离型保护层设置在最外层清洁层的外表面上;抗菌阻隔层采用聚乙二醇、艾草纤维、聚丙烯酸钠、明胶、聚乙酰氨基葡糖、石墨烯。本发明制备的抗菌除臭易清洁面料,不仅具有抗菌除臭和防静电的作用,而且在使用中,通过将面料最外层的抗菌阻隔层去除,便能快速实现面料的清洁,具有抗菌能力强,清洁效率高的优点,该清洁面料能够应用在服装、洁净布、窗帘等方面,具有广阔的应用前景。

Description

一种抗菌除臭易清洁面料及其制备方法
技术领域
本发明涉及面料技术领域,特别涉及一种抗菌除臭易清洁面料及其制备方法。
背景技术
在医疗、家用、实验室和生产等领域中,为了适应洁净度的要求,复合面料的应用越来越广,现有的复合面料在使用后,往往需要进行进一步地杀菌消毒和清洗,一方面过度的清洗会损坏面料的表面材质,另一方面在紧急情况下,若没有相应的清洗工具,面料的清洁将即为不方便。
发明内容
为解决以上背景技术中存在的问题,本发明提供一种抗菌除臭易清洁面料,包括底层、清洁层和离型保护层;
所述清洁层包括分离膜和抗菌阻隔层;所述抗菌阻隔层设置于所述分离膜上;所述分离膜的侧边区域包覆所述抗菌阻隔层的侧面,并贴附于所述抗菌阻隔层的上表面;多层所述清洁层依次设置于所述底层上;
所述离型保护层设置在最外层所述清洁层的外表面上;所述抗菌阻隔层采用如下重量份的成分组成:
Figure GDA0002406629680000011
Figure GDA0002406629680000021
进一步地,所述抗菌阻隔层材料的制备方法为:
步骤a、将艾草纤维、明胶、石墨烯在100℃~130℃下混合,形成混合物M1;
步骤b、在混合物M1中加入聚丙烯酸钠和部分聚乙酰氨基葡糖,控制温度为60℃~80℃,形成混合物M2;
步骤c、在混合物M2中加入聚乙二醇和另一部分聚乙酰氨基葡糖,在30℃~50℃下搅拌10min~20min,形成所述抗菌阻隔层材料。
进一步地,步骤b中,加入聚丙烯酸钠和部分聚乙酰氨基葡糖后,通入电压,电压为3V~8V,通电时间为10~15min。
进一步地,所述分离膜采用下重量份的成分组成:
Figure GDA0002406629680000022
进一步地,所述分离膜的制备方法为:
S100、将热塑型丙烯酸树脂、十二碳醇酯和乙醚在90℃~120℃下混合搅拌;
S200、加入有机酸掺杂聚苯胺和γ-甲基丙烯酸丙酯基三甲氧基硅烷,温度控制在125℃~150℃,混合120min~200min;
S300、搅拌60min~90min,将得到的混合材料于150℃~200℃下热压成膜,即得到分离膜。
进一步地,S300中,热压成膜时,所述分离膜的厚度控制在0.1mm~0.5mm。
进一步地,所述底层采用棉布、麻布、涤纶、腈纶、活性炭棉中的一种制成。
进一步地,离型保护层采用硅油纸制成。
一种如上任意所述的抗菌除臭易清洁面料的制备方法,包括以下步骤:
步骤一、将分离膜设置在底层上表面;
步骤二、将抗菌阻隔层涂覆在分离膜表面,涂覆厚度控制在0.1mm~0.5mm,并在分离膜边缘0.5cm~2cm的表面区域不涂覆抗菌阻隔层,并于室温下冷却固化;
步骤三、将分离膜没有涂覆抗菌阻隔层的区域翻折至固化后的抗菌阻隔层上表面,并在抗菌阻隔层上表面覆盖另一层分离膜;
步骤四、重复步骤一至步骤二3至5次,最外一层抗菌阻隔层的上表面不覆盖分离膜;
步骤五、在最外一层抗菌阻隔层的上表面覆盖离型保护层后,于8Mpa~12Mpa压力下处理10min~15min,即得到抗菌除臭易清洁面料。
本发明制备的抗菌除臭易清洁面料,不仅具有抗菌除臭和防静电的作用,而且在使用中,通过将面料最外层的抗菌阻隔层去除,便能快速实现面料的清洁,具有抗菌能力强,清洁效率高的优点,该清洁面料能够应用在服装、洁净布、窗帘等方面,具有广阔的应用前景。
附图说明
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。
图1为本发明提供的抗菌除臭易清洁面料的结构示意图;
图2为图1的局部结构示意图。
附图标记:
100底层 200清洁层 300离型保护层
210分离膜 220抗菌阻隔层
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
在本发明的描述中,需要说明的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性。
本发明提供一种抗菌除臭易清洁面料,如图1和图2所示,包括底层100、清洁层200和离型保护层300;所述清洁层200包括分离膜210和抗菌阻隔层220;所述抗菌阻隔层220设置于所述分离膜210上;所述分离膜210的侧边区域包覆所述抗菌阻隔层220的侧面,并贴附于所述抗菌阻隔层220的上表面;多层所述清洁层200依次设置于所述底层100上;
所述离型保护层300设置在最外层所述清洁层200的外表面上;所述抗菌阻隔层220采用如下重量份的成分组成:
Figure GDA0002406629680000051
具体地,本发明提供的抗菌除臭易清洁面料中,底层100可以通过缝合或粘接的方式与多块清洁层200结合,清洁层200可以设置3~6层,相邻清洁层200之间通过粘接结合;而最表面的清洁层200上设置有离型保护层300,离型保护层300可以采用硅油纸制成,可以对面料在使用前起到保护作用,防止清洁层200在运输过程中就受到污染;而在面料的使用过程时,将面料的离型保护层300去除,使最外层的清洁层200作为面料的外表面,进而对外界的污染起到保护作用。当最外层的清洁层200受到污染时,此时仅需要将贴附于抗菌阻隔层220的上表面的分离膜210的侧边作为施力点,将分离膜210撕下的同时将最外层的抗菌阻隔层220也撕下;分离膜210不仅仅起到分离外层抗菌阻隔层220的作用,还能起到阻止外层的抗菌阻隔层220受到污染时而不影响下一层抗菌阻隔层220的作用;此外,分离膜210的叠放方式还能使在撕下最外层的抗菌阻隔层220时,避免下一层的抗菌阻隔层220一同被撕下。
更具体地,本发明提供的技术方案中,对抗菌阻隔层进行了进一步具体设计;其中,在抗菌阻隔层的组分中加入了艾草纤维,不仅能够起到基体韧性加强的作用,同时艾草纤维还具有除臭的作用,能够将去除吸附的异味;而聚乙酰氨基葡糖能够对细菌起到良好的杀灭作用;采用明胶作为基体,配合聚乙二醇,不仅能够有效成膜,使抗菌阻隔层具有的粘性,与分离膜进行粘接,还能对污染物具有一定吸附驻留作用,使污染物尤其是液体污染物溅落至抗菌阻隔层时不滴落至底面;聚丙烯酸钠混合在基体内,使导电离子能够在基体内移动,加强了基体的导电性能;而加入石墨烯,通过聚乙二醇的分散作用,能够使一定程度解决石墨烯容易团聚的问题,使石墨烯更均匀地分布在基体中,而通过石墨烯的网状结构,不仅能够对基体的韧性和结合力进行加强,也能在一定程度上增加其导电能力,使制备的清洁面料具有良好的导静电能力。
本发明制备的抗菌除臭易清洁面料,不仅具有抗菌除臭和防静电的作用,而且在使用中,通过将面料最外层的抗菌阻隔层去除,便能快速实现面料的清洁,具有抗菌能力强,清洁效率高的优点,该清洁面料能够应用在服装、洁净布、窗帘等方面,具有广阔的应用前景。
进一步地,所述抗菌阻隔层材料的制备方法为:
步骤a、将艾草纤维、明胶、石墨烯在100℃~130℃下混合,形成混合物M1;
步骤b、在混合物M1中加入聚丙烯酸钠和部分聚乙酰氨基葡糖,控制温度为60℃~80℃;优选地,可通入电压在3V~8V,通电时间为10~15min,形成混合物M2;其中,该步骤的通电处理,通过电压和通电时间的控制,再配合聚丙烯酸钠的导电离子,能够形成一定的电泳,能够非常好地解决石墨烯在发明提供的抗菌阻隔层中的不易分散且容易团聚的问题,使石墨烯在混合过程中更加均匀,进而发挥石墨烯网状结构的特性,大大提高了抗菌阻隔层的强度,且使抗菌阻隔层的导静电能够更加出色。
步骤c、在混合物M2中加入聚乙二醇和另一部分聚乙酰氨基葡糖,在30℃~50℃下搅拌10min~20min,形成所述抗菌阻隔层材料。
优选地,本发明的技术方案中,分离膜可采用下重量份的成分组成:
Figure GDA0002406629680000071
本发明提供了一种分离膜的实施例,该实施例中提供的分离膜中,采用热塑型丙烯酸树脂和十二碳醇酯作为成膜物主体,并加入γ-甲基丙烯酸丙酯基三甲氧基硅烷和有机酸掺杂聚苯胺,有机酸掺杂聚苯胺使分离膜具有良好的导电性能,而少量的γ-甲基丙烯酸丙酯基三甲氧基硅烷能够加强分离膜的整体强度,使分离膜在撕除的过程中不易破碎,而更方便去除。
其中地,所述分离膜的制备方法为:
S100、将热塑型丙烯酸树脂、十二碳醇酯和乙醚在90℃~120℃下混合搅拌;
S200、加入有机酸掺杂聚苯胺和γ-甲基丙烯酸丙酯基三甲氧基硅烷,温度控制在125℃~150℃,混合120min~200min;
S300、搅拌60min~90min,将得到的混合材料于150℃~200℃下热压成膜,即得到分离膜。
优选地,S300中,热压成膜时,所述分离膜的厚度控制在0.1mm~0.5mm。
优选地,所述底层100采用棉布、麻布、涤纶、腈纶、活性炭棉中的一种制成。
一种采用如上任一项所述的抗菌除臭易清洁面料的制备方法,包括以下步骤:
步骤一、将分离膜设置在底层上表面;
步骤二、将抗菌阻隔层涂覆在分离膜表面,涂覆厚度控制在0.1mm~0.5mm,并在分离膜边缘0.5cm~2cm的表面区域不涂覆抗菌阻隔层,并于室温下冷却固化;
步骤三、将分离膜没有涂覆抗菌阻隔层的区域翻折至固化后的抗菌阻隔层上表面,并在抗菌阻隔层上表面覆盖另一层分离膜;
步骤四、重复步骤一至步骤二3至5次,最外一层抗菌阻隔层的上表面不覆盖分离膜;
步骤五、在最外一层抗菌阻隔层的上表面覆盖离型保护层,并在8Mpa~12Mpa压力下处理10min~15min,即得到抗菌除臭易清洁面料。
优选地,在压力处理时,在底层的底侧设置热板,所述热板的温度为50℃~60℃;处理后,与室温下冷却;在该过程中,清洁面料越接近底侧受到的热辐射越多,其产生的粘度也越强,该工艺能够使在去除外层分离膜的过程中,而不将内侧的分离膜撕除,使分离膜能够逐一分离。
具体地,本发明提供以下实施例:
实施例1、
一、制备抗菌阻隔层材料:
1)、将6份艾草纤维、16份明胶、4份石墨烯在110℃下混合,形成混合物M1;
2)、在混合物M1中加入8份聚丙烯酸钠和2份聚乙酰氨基葡糖,控制温度为60℃,形成混合物M2;
3)、在混合物M2中加入6份聚乙二醇和4份聚乙酰氨基葡糖,在30℃下搅拌20min,形成所述抗菌阻隔层材料。
二、制备分离膜
1)、将10份热塑型丙烯酸树脂、6份十二碳醇酯和12份乙醚在90℃~120℃下混合搅拌;
2)、加入5份有机酸掺杂聚苯胺和1份γ-甲基丙烯酸丙酯基三甲氧基硅烷,温度控制在125℃,混合150min;
3)、搅拌60min,将得到的混合材料于180℃下热压成膜,即得到分离膜。
三、制备抗菌除臭易清洁面料
1)、将分离膜设置在底层上表面;
2)、将抗菌阻隔层涂覆在分离膜表面,涂覆厚度控制在0.2mm,并在分离膜边缘1.0cm的表面区域不涂覆抗菌阻隔层,并于室温下冷却固化;
3)、将分离膜没有涂覆抗菌阻隔层的区域翻折至固化后的抗菌阻隔层上表面,并在抗菌阻隔层上表面覆盖另一层分离膜;
4)、重复步骤1)~步骤3)3次,最外一层抗菌阻隔层的上表面不覆盖分离膜;
5)、在最外一层抗菌阻隔层的上表面覆盖离型保护层后,于10Mpa压力下处理15min,即得到抗菌除臭易清洁面料。
实施例2、
一、制备抗菌阻隔层材料:
1)、将8份艾草纤维、18份明胶、5份石墨烯在130℃下混合,形成混合物M1;
2)、在混合物M1中加入10份聚丙烯酸钠和2份聚乙酰氨基葡糖,控制温度为80℃,形成混合物M2;
3)、在混合物M2中加入8份聚乙二醇和6份聚乙酰氨基葡糖,在50℃下搅拌20min,形成所述抗菌阻隔层材料。
二、制备分离膜
1)、将15份热塑型丙烯酸树脂、9份十二碳醇酯和15份乙醚在120℃下混合搅拌;
2)、加入8份有机酸掺杂聚苯胺和2份γ-甲基丙烯酸丙酯基三甲氧基硅烷,温度控制在130℃,混合180min;
3)、搅拌90min,将得到的混合材料于200℃下热压成膜,即得到分离膜。
三、制备抗菌除臭易清洁面料
1)、将分离膜设置在底层上表面;
2)、将抗菌阻隔层涂覆在分离膜表面,涂覆厚度控制在0.2mm,并在分离膜边缘1.0cm的表面区域不涂覆抗菌阻隔层,并于室温下冷却固化;
3)、将分离膜没有涂覆抗菌阻隔层的区域翻折至固化后的抗菌阻隔层上表面,并在抗菌阻隔层上表面覆盖另一层分离膜;
4)、重复步骤1)~步骤3)3次,最外一层抗菌阻隔层的上表面不覆盖分离膜;
5)、在最外一层抗菌阻隔层的上表面覆盖离型保护层后,于10Mpa压力下处理15min,即得到抗菌除臭易清洁面料。
实施例3、
一、制备抗菌阻隔层材料:
1)、将8份艾草纤维、18份明胶、5份石墨烯在130℃下混合,形成混合物M1;
2)、在混合物M1中加入10份聚丙烯酸钠和2份聚乙酰氨基葡糖,控制温度为80℃,通入电压在3V~8V,通电时间为10~15min,形成混合物M2;
3)、在混合物M2中加入8份聚乙二醇和6份聚乙酰氨基葡糖,在50℃下搅拌20min,形成所述抗菌阻隔层材料。
二、制备分离膜
1)、将15份热塑型丙烯酸树脂、9份十二碳醇酯和15份乙醚在120℃下混合搅拌;
2)、加入8份有机酸掺杂聚苯胺和2份γ-甲基丙烯酸丙酯基三甲氧基硅烷,温度控制在130℃,混合180min;
3)、搅拌90min,将得到的混合材料于200℃下热压成膜,即得到分离膜。
三、制备抗菌除臭易清洁面料
1)、将分离膜设置在底层上表面;
2)、将抗菌阻隔层涂覆在分离膜表面,涂覆厚度控制在0.2mm,并在分离膜边缘1.0cm的表面区域不涂覆抗菌阻隔层,并于室温下冷却固化;
3)、将分离膜没有涂覆抗菌阻隔层的区域翻折至固化后的抗菌阻隔层上表面,并在抗菌阻隔层上表面覆盖另一层分离膜;
4)、重复步骤1)~步骤3)3次,最外一层抗菌阻隔层的上表面不覆盖分离膜;
5)、在最外一层抗菌阻隔层的上表面覆盖离型保护层后,于10Mpa压力下处理15min,即得到抗菌除臭易清洁面料。
将实施例1-3制备的抗菌除臭易清洁面料样品根据标准GB/T3917.2—1997的方法进行抗撕裂强度测试;采用GB12014-2009对实施例1-3制备的样品进行点对点电阻测试,测试结果如下所示:
表1
Figure GDA0002406629680000111
Figure GDA0002406629680000121
根据标准GB/T3917.2—1997,抗撕裂强度的一般标准约在100N,而发明实施例中制备的面料的康撕裂强度远高于现有技术的一般标准;而通过实施例2和实施例3可以看出,通过加入电压处理制备的面料的抗撕裂强度又有着进一步提高;通过点对点电阻的测试,可以看出,根据标准GB12014-2009本专利发明实施例中制备的面料满足A级要求,而通过实施例2和实施例3可以看出,通过加入电压处理制备的面料的抗静电能力有着显著进步。
尽管本文中较多的使用了诸如底层、清洁层、离型保护层、分离膜、抗菌阻隔层等术语,但并不排除使用其它术语的可能性。使用这些术语仅仅是为了更方便地描述和解释本发明的本质;把它们解释成任何一种附加的限制都是与本发明精神相违背的。
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。

Claims (8)

1.一种抗菌除臭易清洁面料,其特征在于:包括底层、清洁层和离型保护层;
所述清洁层包括分离膜和抗菌阻隔层;所述抗菌阻隔层设置于所述分离膜上;所述分离膜的侧边区域包覆所述抗菌阻隔层的侧面,并贴附于所述抗菌阻隔层的上表面;多层所述清洁层依次设置于所述底层上;
所述离型保护层设置在最外层所述清洁层的外表面上;所述抗菌阻隔层采用如下重量份的成分组成:
Figure FDA0002406629670000011
所述分离膜采用下重量份的成分组成:
Figure FDA0002406629670000012
2.根据权利要求1所述的抗菌除臭易清洁面料,其特征在于,所述抗菌阻隔层材料的制备方法为:
步骤a、将艾草纤维、明胶、石墨烯在100℃~130℃下混合,形成混合物M1;
步骤b、在混合物M1中加入聚丙烯酸钠和部分聚乙酰氨基葡糖,控制温度为60℃~80℃,形成混合物M2;
步骤c、在混合物M2中加入聚乙二醇和另一部分聚乙酰氨基葡糖,在30℃~50℃下搅拌10min~20min,形成所述抗菌阻隔层材料。
3.根据权利要求2所述的抗菌除臭易清洁面料,其特征在于:步骤b中,加入聚丙烯酸钠和部分聚乙酰氨基葡糖后,通入电压,电压为3V~8V,通电时间为10~15min。
4.根据权利要求1所述的抗菌除臭易清洁面料,其特征在于,所述分离膜的制备方法为:
S100、将热塑型丙烯酸树脂、十二碳醇酯和乙醚在90℃~120℃下混合搅拌;
S200、加入有机酸掺杂聚苯胺和γ-甲基丙烯酸丙酯基三甲氧基硅烷,温度控制在125℃~150℃,混合120min~200min;
S300、搅拌60min~90min,将得到的混合材料于150℃~200℃下热压成膜,即得到分离膜。
5.根据权利要求4所述的抗菌除臭易清洁面料,其特征在于:S300中,热压成膜时,所述分离膜的厚度控制在0.1mm~0.5mm。
6.根据权利要求1所述的抗菌除臭易清洁面料,其特征在于:所述底层采用棉布、麻布、涤纶、腈纶、活性炭棉中的一种制成。
7.根据权利要求1所述的抗菌除臭易清洁面料,其特征在于:离型保护层采用硅油纸制成。
8.一种根据权利要求1~7任一项所述的抗菌除臭易清洁面料的制备方法,其特征在于,包括以下步骤:
步骤一、将分离膜设置在底层上表面;
步骤二、将抗菌阻隔层涂覆在分离膜表面,涂覆厚度控制在0.1mm~0.5mm,并在分离膜边缘0.5cm~2cm的表面区域不涂覆抗菌阻隔层,并于室温下冷却固化;
步骤三、将分离膜没有涂覆抗菌阻隔层的区域翻折至固化后的抗菌阻隔层上表面,并在抗菌阻隔层上表面覆盖另一层分离膜;
步骤四、重复步骤一至步骤二3至5次,最外一层抗菌阻隔层的上表面不覆盖分离膜;
步骤五、在最外一层抗菌阻隔层的上表面覆盖离型保护层后,于8Mpa~12Mpa压力下处理10min~15min,即得到抗菌除臭易清洁面料。
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