A kind of preparation method of high-performance medical textile material
Technical field:
The present invention relates to field of medical materials, are specifically related to a kind of preparation method of high-performance medical textile material.
Background technology:
Since 21st century, the Nonwovens In Technology in China obtains full progress, wherein medical non-woven fabrics
Production and application development it is especially prominent.But the medical textile in China there are still quality unqualified, qualification authentication blank etc.
Problem.Develop frequency in order to hold China's medical textile again, and study its developing direction, I makes this research.
Textile material is applied to medical field and starts to walk very early, and ancient Egyptian just understands flax with natural glue bond before 4000
Yarn is sewed up a wound, so that wound can heal in time, mummy is wrapped up with the fabric of medicinal plant treatment, to prevent it from rotting.
Also early useful flaxen fiber makees suture in the history records of ancient Chinese, the record bound up a wound and stopped blooding with cotton.Textile material exists
Medically there is very useful value.Tensile properties use the natural fibers such as cotton, hair, fiber crops earliest, with the development of science and technology,
Synthetic fibers are largely used again.Especially make encouraging progress in recent years to the research of biodegradable fiber, degradableization
It learns fiber and chitin fiber starts the concern for causing people.At the same time, the popularization of medical non-woven cloth, makes chemical fibre
Application range further expands, and the development of medical textile material also more and more shows huge vigor.
Medical textile is the fabrics for industrial use based on fiber and fabric using medical application as characteristic.Medical spinning
Fabric must it is nontoxic, without allergy, non-carcinogenesis, do not play any variation of physically or chemically performance in disinfection.Most common day
Right fiber is cotton, silk and regenerated fiber viscose rayon yarn, they be widely used as Nonimplantation material (wound dressing, bandage etc.) and
Health care product (bedding, clothing, diaper, sanitary napkin, wipe etc.);The chemical fibre being often used includes polyester, gathers
Amide, polytetrafluoroethylene (PTFE) (PTFE), polypropylene, carbon fiber and glass fibre.Compared with the woven medical textile of traditional pure cotton,
Medical non-woven fabric has high to bacterium, dust filterability, and surgical infection rate is low, and sterilization is convenient, is easy to and other materials
The features such as compound.As disposable medical supplies it is convenient that health is not used only, moreover it is possible to effectively prevent bacterium sense in nonwoven products
Dye and medicine origin sex-intergrade infection.But presently commercially available medical textile is usually present that penetrability is poor, anti-microbial property is bad asks
Topic.
Invention content:
It is medical made from this method the object of the present invention is to provide a kind of preparation method of high-performance medical textile material
The moisture-penetrable ventilated property of textile is good, has certain anti-microbial property, and elasticity is big, and prepares simply, at low cost.
To achieve the above object, the present invention uses following technical scheme:
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;
(2) sodium alginate is dissolved in deionized water, sodium alginate soln is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 1-4h is stirred to react at 45-55 DEG C;It then cools to room temperature, alginic acid made from step (2) is added
Sodium solution, continuation are stirred to react 40-80min, then filter, and be freeze-dried at room temperature, are made sodium alginate-modified
Polypropylene non-woven fabric;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
As a preferred embodiment of the above technical solution, in step (1), the condition of the corona treatment is:Apply voltage to put
Electric frequency is 13.5MHz, power 100-130W, time 10-15s.
As a preferred embodiment of the above technical solution, in step (2), the mass concentration of the sodium alginate soln is 10-20%.
As a preferred embodiment of the above technical solution, in step (3), the mass ratio of DCC, N-N- HOSu NHS
(1-1.5):1.
As a preferred embodiment of the above technical solution, in step (3), DCC, the mass ratio for pre-processing polypropylene non-woven fabric are
(0.33-0.85):1.
As a preferred embodiment of the above technical solution, in step (3), the pretreatment polypropylene non-woven fabric, sodium alginate soln
Mass ratio be 3:(5-9).
As a preferred embodiment of the above technical solution, in step (3), the temperature of the freeze-drying is -10~-15 DEG C, freezing
The dry time is 8-15h.
The invention has the advantages that:
Medical textile material produced by the present invention includes sodium alginate-modified polypropylene non-woven fabric, terylene face successively
Material, sodium alginate-modified polypropylene fibre, permeable water vapour permeability is excellent, soft comfortable, has certain anti-microbial property;
The present invention is modified polypropylene non-woven fabric using sodium alginate, effectively improve textile pro-skin performance and
The water vapour permeability of anti-microbial property, textile is also further improved.Medical textile material produced by the present invention can be used for making
Make the products such as medical protective garment, Medical operation cap.
Specific implementation mode:
In order to better understand the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;Wherein, the condition of corona treatment is:Application tension discharge frequency is 13.5MHz, and power is
100-130W, time 10-15s;
(2) sodium alginate is dissolved in deionized water, the sodium alginate soln that mass concentration is 10% is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 1h is stirred to react at 45-55 DEG C;It then cools to room temperature, sodium alginate made from step (2) is added
Solution, continuation are stirred to react 40min, then filter, and be freeze-dried at room temperature, and sodium alginate-modified polypropylene is made
Non-woven fabrics;Wherein, the mass ratio 1 of DCC, N-N- HOSu NHS:1;DCC, the mass ratio for pre-processing polypropylene non-woven fabric
It is 0.33:1;It is described pretreatment polypropylene non-woven fabric, sodium alginate soln mass ratio be 3:5;The temperature of the freeze-drying
It it is -10 DEG C, the time of freeze-drying is 8h;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
Embodiment 2
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;Wherein, the condition of corona treatment is:Application tension discharge frequency is 13.5MHz, and power is
100-130W, time 10-15s;
(2) sodium alginate is dissolved in deionized water, the sodium alginate soln that mass concentration is 20% is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 4h is stirred to react at 45-55 DEG C;It then cools to room temperature, sodium alginate made from step (2) is added
Solution, continuation are stirred to react 80min, then filter, and be freeze-dried at room temperature, and sodium alginate-modified polypropylene is made
Non-woven fabrics;Wherein, the mass ratio 1.5 of DCC, N-N- HOSu NHS:1;DCC, the quality for pre-processing polypropylene non-woven fabric
Than being 0.85:1;It is described pretreatment polypropylene non-woven fabric, sodium alginate soln mass ratio be 3:9;The temperature of the freeze-drying
Degree is -15 DEG C, and the time of freeze-drying is 15h;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
Embodiment 3
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;Wherein, the condition of corona treatment is:Application tension discharge frequency is 13.5MHz, and power is
100-130W, time 10-15s;
(2) sodium alginate is dissolved in deionized water, the sodium alginate soln that mass concentration is 12% is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 2h is stirred to react at 45-55 DEG C;It then cools to room temperature, sodium alginate made from step (2) is added
Solution, continuation are stirred to react 50min, then filter, and be freeze-dried at room temperature, and sodium alginate-modified polypropylene is made
Non-woven fabrics;Wherein, the mass ratio 1.1 of DCC, N-N- HOSu NHS:1;DCC, the quality for pre-processing polypropylene non-woven fabric
Than being 0.45:1;It is described pretreatment polypropylene non-woven fabric, sodium alginate soln mass ratio be 3:5.5;The freeze-drying
Temperature is -10 DEG C, and the time of freeze-drying is 10h;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
Embodiment 4
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;Wherein, the condition of corona treatment is:Application tension discharge frequency is 13.5MHz, and power is
100-130W, time 10-15s;
(2) sodium alginate is dissolved in deionized water, the sodium alginate soln that mass concentration is 14% is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 3h is stirred to react at 45-55 DEG C;It then cools to room temperature, sodium alginate made from step (2) is added
Solution, continuation are stirred to react 60min, then filter, and be freeze-dried at room temperature, and sodium alginate-modified polypropylene is made
Non-woven fabrics;Wherein, the mass ratio 1.2 of DCC, N-N- HOSu NHS:1;DCC, the quality for pre-processing polypropylene non-woven fabric
Than being 0.55:1;It is described pretreatment polypropylene non-woven fabric, sodium alginate soln mass ratio be 3:6;The temperature of the freeze-drying
Degree is -10 DEG C, and the time of freeze-drying is 11h;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
Embodiment 5
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;Wherein, the condition of corona treatment is:Application tension discharge frequency is 13.5MHz, and power is
100-130W, time 10-15s;
(2) sodium alginate is dissolved in deionized water, the sodium alginate soln that mass concentration is 16% is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 3.5h is stirred to react at 45-55 DEG C;It then cools to room temperature, alginic acid made from step (2) is added
Sodium solution, continuation are stirred to react 70min, then filter, and be freeze-dried at room temperature, are made sodium alginate-modified poly- third
Alkene non-woven fabrics;Wherein, the mass ratio 1.3 of DCC, N-N- HOSu NHS:1;DCC, the matter for pre-processing polypropylene non-woven fabric
Amount is than being 0.65:1;It is described pretreatment polypropylene non-woven fabric, sodium alginate soln mass ratio be 3:7;The freeze-drying
Temperature is -15 DEG C, and the time of freeze-drying is 13h;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
Embodiment 6
A kind of preparation method of high-performance medical textile material, includes the following steps:
(1) polypropylene non-woven fabric is cleaned up with clear water, corona treatment is then carried out in low temperature ammonia, be made
Pre-process polypropylene non-woven fabric;Wherein, the condition of corona treatment is:Application tension discharge frequency is 13.5MHz, and power is
100-130W, time 10-15s;
(2) sodium alginate is dissolved in deionized water, the sodium alginate soln that mass concentration is 18% is made;
(3) DCC, N-N- HOSu NHS are dissolved in obtained solution in deionized water, polypropylene non-woven will be pre-processed
Cloth is added in solution, and 4h is stirred to react at 45-55 DEG C;It then cools to room temperature, sodium alginate made from step (2) is added
Solution, continuation are stirred to react 75min, then filter, and be freeze-dried at room temperature, and sodium alginate-modified polypropylene is made
Non-woven fabrics;Wherein, the mass ratio 1.4 of DCC, N-N- HOSu NHS:1;DCC, the quality for pre-processing polypropylene non-woven fabric
Than being 0.75:1;It is described pretreatment polypropylene non-woven fabric, sodium alginate soln mass ratio be 3:8.5;The freeze-drying
Temperature is -15 DEG C, and the time of freeze-drying is 14h;
(4) by sodium alginate-modified polypropylene non-woven fabric, polyester fabric, sodium alginate-modified polypropylene non-woven Bouyei
Secondary stacking is bonded using polyurethane hot melt between polypropylene non-woven fabric and polyester fabric, is pressed by pressure roller, and doctor is made
Use textile material.
Performance test
1, medical textile material obtained above is used into standard JIS L 1092-1998A, ASTM1670 and ASTM
1671 carry out water resistance, resistant to blood performance and bacterium blocking performance respectively is tested, and test result is shown as zero infiltration, closes
Lattice.
2, water vapour permeability test is carried out using standard JIS L1099.Test display:Medical textile material produced by the present invention
The moisture permeability of material is 60000g/ (m2More than for 24 hours), water vapour permeability is excellent.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.