CN108642855A - The low alkali technique of the low acid of crofting - Google Patents

The low alkali technique of the low acid of crofting Download PDF

Info

Publication number
CN108642855A
CN108642855A CN201810651488.2A CN201810651488A CN108642855A CN 108642855 A CN108642855 A CN 108642855A CN 201810651488 A CN201810651488 A CN 201810651488A CN 108642855 A CN108642855 A CN 108642855A
Authority
CN
China
Prior art keywords
low
acid
crofting
concentration
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810651488.2A
Other languages
Chinese (zh)
Inventor
姜伟
庄寒良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heilongjiang Jinda Linen Co Ltd
Original Assignee
Heilongjiang Jinda Linen Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heilongjiang Jinda Linen Co Ltd filed Critical Heilongjiang Jinda Linen Co Ltd
Priority to CN201810651488.2A priority Critical patent/CN108642855A/en
Publication of CN108642855A publication Critical patent/CN108642855A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/20Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
    • D06L4/22Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents
    • D06L4/24Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide
    • D06L4/26Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide combined with specific additives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The present invention relates to a kind of low alkali techniques of the low acid of crofting, it belongs to flax processing technology field.Flax roving is first carried out pickling by the present invention, rove is subjected to low sour high temperature Asia drift processing again, then rove is subjected to low-temperature low-alkali oxygen bleaching bleaching, finally by rove washes clean, the present invention uses the low alkali bleaching process of low acid, can reduce the degree of injury of soda acid and hydrogen peroxide to fiber, and entire technique uses the low alkali technique of low acid, pollution treatment difficulty can be reduced, has improvement to environmental protection.

Description

The low alkali technique of the low acid of crofting
Technical field
The present invention relates to a kind of low alkali techniques of the low acid of crofting, can effectively improve the quality of line, especially strength Be obviously improved, be it is a kind of first carrying out low sour high temperature Asia drift processing to flax roving, then carry out low-temperature low-alkali oxygen bleaching bleaching process, it is main To be applied to the production of crofting yarn process, it belongs to flax processing technology field.
Background technology
Because of flax characteristic:Impurity divides low more, and the hardness of yarn is high, elongation is low;To remove impurity, the general use of drift is boiled Stronger Asia oxygen bleaching process is to improve division and the spinnability of fiber.
Since conventional sub- oxygen bleaching process is reacted under the conditions of higher bronsted lowry acids and bases bronsted lowry, have to fiber a degree of Damage causes fiber short down more and causes strength to decline and increase with numb particle.
Publication date is on 04 06th, 2016, in the Chinese patent of Publication No. 103966672B, discloses a kind of title For the patent of invention of " flax soda boiling high temperature Asia bleaching process ".The patent first carries out soda boiling degumming to flaxen fiber, then carries out high temperature Sub- bleaching process carries out chlorite bleaching to flaxen fiber, and using dechlorination, flax fiber degumming and bleaching process is completed in washing.Although The patent is small to fibre damage, and impurity elimination is abundant, and soft yarns improve, but are reacted under the conditions of higher bronsted lowry acids and bases bronsted lowry, There is a degree of damage to fiber, causes fiber short down more and cause strength to decline and increase with numb particle, therefore it still exists Drawbacks described above.
Therefore, a kind of reduction soda acid of raising and hydrogen peroxide can reduce pollution treatment difficulty, have to environmental protection to the degree of injury of fiber The low alkali technique of the low acid of improved crofting, it appears particularly necessary.
Invention content
It is an object of the invention to overcome above-mentioned deficiency existing in the prior art, and a kind of rational technology is provided, not dropped It under the premise of low line whiteness, improves the strength of yarn while reducing the particle of yarn, first carry out low sour high temperature Asia drift processing, then The low alkali technique of the low acid of crofting of low-temperature low-alkali oxygen bleaching bleaching is carried out again.
Technical solution is used by the present invention solves the above problems:The low alkali technique of the low acid of the crofting, feature exist In:Apply in crofting yarn process the specific steps are:
(1)Pickling:Using 98% sulfuric acid, infiltration refining agent, handled 20 minutes under the conditions of 30 DEG C;
(2)Asia drift:Using 98% sulfuric acid, infiltration refining agent, 31% sodium chlorite, sodium nitrate, 65 DEG C are raised to 1 DEG C/minute from 30 DEG C, It is handled 30 minutes under the conditions of 65 DEG C;
(3)Washing is clean;
(4)Oxygen bleaching:Using 98% soda ash, sodium silicate, 27.5% hydrogen peroxide, hydrogen peroxide bleaching stabilizer and chelated dispersants, with 1 DEG C/minute from 40 DEG C are raised to 80 DEG C, are handled 30 minutes under the conditions of 80 DEG C;
(5)Washing is clean.
Preferably, step of the present invention(1)In, a concentration of 1.5g/L of use of 98% sulfuric acid.
Preferably, step of the present invention(1)In, permeate a concentration of 1.0g/L of use of refining agent.
Preferably, step of the present invention(2)In, a concentration of 0.5g/L of use of 98% sulfuric acid.
Preferably, step of the present invention(2)In, permeate a concentration of 0.5g/L of use of refining agent.
Preferably, step of the present invention(2)In, a concentration of 9.0g/L of use of 31% sodium chlorite.
Preferably, step of the present invention(2)In, a concentration of 1.5g/L of use of sodium nitrate.
Preferably, step of the present invention(4)In, a concentration of 4.0g/L of use of 98% soda ash;The use of sodium silicate is dense Degree is 3.0g/L;A concentration of 5.5g/L of use of 27.5% hydrogen peroxide;A concentration of 1.0g/L of use of hydrogen peroxide bleaching stabilizer;Chelating point A concentration of 0.5g/L of use of powder.
Preferably, pickling process of the present invention uses bath raio for 1:7.
Preferably, 98% sulfuric acid of the present invention, 31% sodium chlorite, the percentage of 98% soda ash and 27.5% hydrogen peroxide are equal It is weight percentage.
Compared with prior art, the present invention haing the following advantages and effect:1, it using the low alkali bleaching process of low acid, can reduce The degree of injury of soda acid and hydrogen peroxide to fiber;2, since entire technique uses the low alkali technique of low acid, pollution treatment difficulty can be reduced, it is right Environmental protection has improvement.
Specific implementation mode
Below by embodiment, the present invention is described in further detail, following embodiment be explanation of the invention and The invention is not limited in following embodiments.
Embodiment.
In the present embodiment, by taking L36Nm as an example, the low alkali technique of the low acid of crofting is applied in crofting yarn process Detailed process it is as follows.
(1)Pickling:Bath raio 1:7, use the infiltration for using a concentration of 1.5g/L for 98% sulfuric acid and using a concentration of 1.0g/L Refining agent LUN(Hensel steps), handled 20 minutes under the conditions of 30 DEG C.
(2)Asia drift:Using the infiltration refining agent LUN for using 98% sulfuric acid of a concentration of 0.5g/L, using a concentration of 0.5g/L (Hensel steps), using a concentration of 9.0g/L 31% sodium chlorite and using a concentration of 1.5g/L sodium nitrate, with 1 DEG C/minute from 30 DEG C 65 DEG C are raised to, are handled 30 minutes under the conditions of 65 DEG C;pH=3.5.
(3)Washing is clean.
(4)Oxygen bleaching:Using using 98% soda ash of a concentration of 4.0g/L, the sodium silicate for using a concentration of 3.0g/L, use 27.5% hydrogen peroxide of a concentration of 5.5g/L, the hydrogen peroxide bleaching stabilizer EVP using a concentration of 1.0g/L(Bu Saite)It is a concentration of with using The chelated dispersants ZB of 0.5g/L(Bu Saite), 80 DEG C are raised to 1 DEG C/minute from 40 DEG C, is handled 30 minutes under the conditions of 80 DEG C;pH= 9.5-9.0。
(5)Washing is clean.
98% sulfuric acid of the present embodiment, 31% sodium chlorite, 98% soda ash and 27.5% hydrogen peroxide percentage be weight hundred Divide ratio.
Washing process uses traditional washing washing process after the drift of the present embodiment.
The present embodiment improves the quality of yarn by high sub- low oxygen process, specifically:1)Asia drift is using low sour high-temperature and high concentration To carry out --- low acid need to use raising temperature side to keep sub- drift reaction abundant, and in addition Asia drift is opposite to the damage of fiber wants small, can adopt With sub- drift dosage is increased to improve fiber division, to provide condition to reduce oxygen bleaching;2)Oxygen bleaching uses low alkali Low Drift Temperature, due to Asia drift has aggravated, and under the premise of can reducing oxygen bleaching degree without influencing whiteness, reduces the excessive division and damage to fiber as possible And it reduces numb grain and improves strength.
Flax roving is first carried out pickling by the present embodiment technique, then rove is carried out low sour high temperature Asia drift processing, then will Rove carries out low-temperature low-alkali oxygen bleaching bleaching, finally by rove washes clean;The process characteristic:Compared with normal process reduction acid alkali With dioxygen water, to mitigate the damage of soda acid and hydrogen peroxide to fiber.
By above-mentioned elaboration, those skilled in the art can implement.
Furthermore, it is necessary to illustrate, the specific embodiment described in this specification, the shape of parts and components is named Claiming etc. can be different, described in this specification above content is only to structure of the invention example explanation.It is all according to The equivalence changes or simple change done according to the structure, feature and principle described in inventional idea of the present invention, are included in this hair In the protection domain of bright patent.Those skilled in the art can do described specific embodiment various The modify or supplement or adopt similar mode of various kinds substitutes, and without departing from structure of the invention or surmounts present claims Range defined in book, is within the scope of protection of the invention.

Claims (10)

1. a kind of low alkali technique of the low acid of crofting, it is characterised in that:Apply in crofting yarn process the specific steps are:
(1)Pickling:Using 98% sulfuric acid, infiltration refining agent, handled 20 minutes under the conditions of 30 DEG C;
(2)Asia drift:Using 98% sulfuric acid, infiltration refining agent, 31% sodium chlorite, sodium nitrate, 65 DEG C are raised to 1 DEG C/minute from 30 DEG C, It is handled 30 minutes under the conditions of 65 DEG C;
(3)Washing is clean;
(4)Oxygen bleaching:Using 98% soda ash, sodium silicate, 27.5% hydrogen peroxide, hydrogen peroxide bleaching stabilizer and chelated dispersants, with 1 DEG C/minute from 40 DEG C are raised to 80 DEG C, are handled 30 minutes under the conditions of 80 DEG C;
(5)Washing is clean.
2. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(1)In, 98% sulphur A concentration of 1.5g/L of use of acid.
3. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(1)In, infiltration essence Refine a concentration of 1.0g/L of use of agent.
4. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(2)In, 98% sulphur A concentration of 0.5g/L of use of acid.
5. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(2)In, infiltration essence Refine a concentration of 0.5g/L of use of agent.
6. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(2)In, 31% is sub- A concentration of 9.0g/L of use of sodium chlorate.
7. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(2)In, sodium nitrate A concentration of 1.5g/L of use.
8. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The step(4)In, 98% is pure A concentration of 4.0g/L of use of alkali;A concentration of 3.0g/L of use of sodium silicate;A concentration of 5.5g/L of use of 27.5% hydrogen peroxide; A concentration of 1.0g/L of use of hydrogen peroxide bleaching stabilizer;A concentration of 0.5g/L of use of chelated dispersants.
9. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:The pickling process uses bath raio It is 1:7.
10. the low alkali technique of the low acid of crofting according to claim 1, it is characterised in that:98% sulfuric acid, 31% sub- chlorine The percentage of sour sodium, 98% soda ash and 27.5% hydrogen peroxide is weight percentage.
CN201810651488.2A 2018-06-22 2018-06-22 The low alkali technique of the low acid of crofting Pending CN108642855A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810651488.2A CN108642855A (en) 2018-06-22 2018-06-22 The low alkali technique of the low acid of crofting

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810651488.2A CN108642855A (en) 2018-06-22 2018-06-22 The low alkali technique of the low acid of crofting

Publications (1)

Publication Number Publication Date
CN108642855A true CN108642855A (en) 2018-10-12

Family

ID=63753363

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810651488.2A Pending CN108642855A (en) 2018-06-22 2018-06-22 The low alkali technique of the low acid of crofting

Country Status (1)

Country Link
CN (1) CN108642855A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109295735A (en) * 2018-10-19 2019-02-01 江苏联发纺织股份有限公司 A kind of production technology of pure flax cheese

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021283A1 (en) * 1994-02-07 1995-08-10 Warwick International Group Limited Process for bleaching textiles
CN1268590A (en) * 2000-04-26 2000-10-04 黑龙江金亚纺织集团有限公司 Flax fancy yarn and its spinning method
CN102409414A (en) * 2011-09-16 2012-04-11 东嘉麻棉(常州)有限公司 Short flax fiber degumming and bleaching process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021283A1 (en) * 1994-02-07 1995-08-10 Warwick International Group Limited Process for bleaching textiles
CN1268590A (en) * 2000-04-26 2000-10-04 黑龙江金亚纺织集团有限公司 Flax fancy yarn and its spinning method
CN102409414A (en) * 2011-09-16 2012-04-11 东嘉麻棉(常州)有限公司 Short flax fiber degumming and bleaching process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109295735A (en) * 2018-10-19 2019-02-01 江苏联发纺织股份有限公司 A kind of production technology of pure flax cheese

Similar Documents

Publication Publication Date Title
US20100192308A1 (en) Method for scouring and bleaching cotton fabric with composite enzyme preparation in one bath
CN103361956A (en) Low-temperature oxygen-bleaching technology for flax
CN103821006A (en) Elastic polyester-cotton fabric dyeing and finishing pretreatment method
CN105239352B (en) A kind of anti-bacterial wet-absorbing wet spinning Chinese dimity boiling and bleaching process
CN101054746A (en) Spinning technique for flax tow fine count
CN107201642A (en) Flax high-quality yarn bleaching process
CN103469600A (en) Enzyme scouring agent for linen fibers
CN101440526B (en) Preparation of kendir spinnable fiber
CN103469564A (en) Method for scouring linen fibers by enzyme
CN108642855A (en) The low alkali technique of the low acid of crofting
CN110130125A (en) A method of improving rescutched tow dyeability
CN112482014A (en) Room-temperature bleaching method for cashmere loose fibers
CN110042647B (en) High-whiteness low-temperature bleaching method for cashmere or wool
CN105297419A (en) Dyeing, finishing and processing method of short flax fiber
CN107227609A (en) A kind of pre-treating method of ramie people cotton interwoven fabric
WO2024078396A1 (en) Method for preparing yarn from sugarcane
CN107313260A (en) One pre-treating method for growing flax people's cotton elastic fabric
CN115748279B (en) Production process of refined cotton for filter paper
CN108301054A (en) A kind of Degumming method of flaxen fiber
CN101608399B (en) Dyeing pretreatment process for linen-cotton blended fabric
CN111021101A (en) Dyeing method of high-color-fastness smooth anti-wrinkle cotton fabric
CN102691113A (en) Sodium chlorite-hydrogen peroxide bleaching integrated bath process of flax
CN105780455A (en) Energy-saving process for degumming and bleaching flax
KR101061436B1 (en) Towel Dyeing Pretreatment Method
CN104805686A (en) Original natural color processing technology for fabric

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181012