CN108641600A - A kind of novel stone tablet rubbing protective agent and preparation method thereof - Google Patents
A kind of novel stone tablet rubbing protective agent and preparation method thereof Download PDFInfo
- Publication number
- CN108641600A CN108641600A CN201810477801.5A CN201810477801A CN108641600A CN 108641600 A CN108641600 A CN 108641600A CN 201810477801 A CN201810477801 A CN 201810477801A CN 108641600 A CN108641600 A CN 108641600A
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- CN
- China
- Prior art keywords
- cyclododecane
- stone tablet
- protective agent
- fluorine element
- raw material
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/04—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Abstract
The invention discloses a kind of novel stone tablet rubbing protective agents and preparation method thereof, which mainly includes the raw material of following mass ratio：Cyclododecane 5.6 11.5：Fluorine element polymer 10.5 21.The present invention uses cyclododecane for one of primary raw material, and cyclododecane has complete hydrophobicity so that it can be applied is used as waterproof barrier coating on the historical relic sensitive to water or aqueous solution.The fluorine element polymer used in the present invention selects Daikin GM 105D, not only has outstanding heat resistance, drug resistance, against weather, stain resistance and electrical characteristic etc., and with special property such as non-stick, self lubricities.The present invention compounds cyclododecane and fluorine element polymer to form composite material, improves intensity, permeability, alkali resistance, polluting proofing property, heat resistance, the against weather of product.And can effectively slow down the evaporation rate of cyclododecane, product volatility reduction can be removed freely.
Description
Technical field
The present invention relates to a kind of novel stone tablet rubbing protective agents and preparation method thereof, belong to historical relic's protection field.
Background technology
Stone tablet rubbing, word, the pattern referred to by the shape of an inscription on a tablet stone inscription and its above open up the scraps of paper to get off, are one, China
Ancient traditional technology.The basic skills of inscription rubbing is：First stone tablet surface clean is clean, the decorative pattern or word to be opened up as far as possible
It is clear to pick brush, is covered with sizeable rice paper, paper is gently soaked, then covers the paper protection of one layer of soft water suction on l Water Paper again
Paper is gently struck with hairbrush and is beaten, and l Water Paper is made to be attached to the object surface, the bumps that rise and fall with its decorative pattern word.Illiteracy is removed again
On that layer of paper dip in suitable ink with son is flutterred after waiting l Water Papers slightly dry, apply even on flutterring sub- face, gently flutterred in the image of protrusion
It beats, in white and black rubbing will be formed.But during inscription rubbing, due to alternation of wetting and drying, rubs and inevitably lead repeatedly
It causes stone tablet surface weathering and abrasion to pollute, damage is generated to stone tablet, causes the loss that can not be retrieved.Therefore it is a kind of both to be badly in need of research and development
Stone tablet can be protected, and not influence the stone tablet rubbing protective agent of rubbing.
Invention content
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of novel stone tablet rubbing protective agent and its preparation sides
Method, being capable of effective protection stone tablet.
To achieve the goals above, the technical solution adopted in the present invention is：
A kind of novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 5.6-11.5：Fluorine element polymerize
Object 10.5-21.
Novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 5.6-11.5：Solvent 15-48.4：
Fluorine element polymer 10.5-21：Diluent 22.5-42.
Preferably, novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 8.6-11.2：Solvent
31.2-48.4：Fluorine element polymer 12.9-19.8：Diluent 25.2-37.8.
Solvent is at least one of petroleum ether, normal heptane, hexamethylene；Diluent be PEGASOL 3040, EXXSOL D40,
At least one of butyl acetate.
Fluorine element polymer is great Jin GM-105D.
A kind of novel protectant preparation method of stone tablet rubbing, includes the following steps：
(1) cyclododecane and solvent are weighed respectively, is added in flask, and 60-80 DEG C of heating water bath stirring is formed after dissolving
Uniform solution system；
(2) it weighs diluent to be added in another flask, fluorine element is added in 60-80 DEG C of heating water bath stirring under agitation
Polymer, stirring form mixed solution system to being completely dissolved；
(3) the uniform solution system of step (1) is added into the mixed solution system of step (2), continues to be stirred
Uniformly, and in the case where being stirred continuously Temperature fall solidification to get.
Advantageous effect of the present invention：
1, the present invention use cyclododecane for one of primary raw material, and cyclododecane is with complete hydrophobicity so that it can be with
It applies and is used as waterproof barrier coating on the historical relic sensitive to water or aqueous solution.Cyclododecane has certain reinforcing strong simultaneously
Degree, can also distil, therefore can also be used as temporary support material, temperature pier agent completely at room temperature.In addition cyclododecane
It is also used as stripping layer material, temporary binders.5 DEG C or so of temperature variation all can to melt cyclododecane applicability and
Water resistance has different influences.
2, the fluorine element polymer that uses selects Daikin GM-105D in the present invention, not only has outstanding heat resistance, resistance to
Pharmacological property, against weather, stain resistance and electrical characteristic etc., and with special property such as non-stick, self lubricities.The present invention is by ring
Dodecane and fluorine element polymer compound to form composite material, improve the intensity of product, permeability, alkali resistance, polluting proofing property, resistance to
Hot, against weather.And can effectively slow down the evaporation rate of cyclododecane, product volatility reduction can be removed freely.
3, the present invention dissolves cyclododecane in a solvent, increases its permeability, reduces volatility；Diluent is used simultaneously
Fluorine element polymer is diluted, its stability can be kept, to enhance product performance.
4, compared with temperature pier material when historical relic is unearthed, the present invention is applicable not only to protection when historical relic is unearthed, and also uses
In the protection of the historical relics such as scenic spot, museum, exhibition center, such as the special guarantor of stone tablet, rock cave, stone carving, tile carving, mural painting one kind historical relic
Shield prevents stone cultural artifact rubbing because of alternation of wetting and drying, rubs repeatedly and causes surface weathering and abrasion pollution, also can be to word
Rubbing is protected.The protective agent of the present invention can be applied to the surface of any font, including sharp seamed edge, crack, protection
Clear writing extends the service life.
Description of the drawings
Fig. 1 is that 1 protectant film thickness of embodiment changes with time situation.
Fig. 2 is that 2 protectant film thickness of embodiment changes with time situation.
Fig. 3 is that 3 protectant film thickness of embodiment changes with time situation.
Fig. 4 is that 4 protectant film thickness of embodiment changes with time situation.
Fig. 5 is the experimental conditions that drip of 1 protective film of embodiment.
Specific implementation mode
The specific implementation mode of the present invention is described in further detail with reference to embodiments.
Embodiment 1
A kind of novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 10.5：Petroleum ether 24.6：
Normal heptane 23.8：Great Jin GM-105D 15.9：PEGASOL 3040 25.2.
The novel protectant preparation method of stone tablet rubbing, includes the following steps：
(1) cyclododecane, petroleum ether and normal heptane are weighed respectively, are added in flask, 70 DEG C of heating water bath stirrings, dissolving
Uniform solution system is formed afterwards；
(2) it weighs PEGASOL 3040 to be added in another flask, 65 DEG C of heating water bath stirrings are added big under agitation
Golden GM-105D, stirring form mixed solution system to being completely dissolved；
(3) the uniform solution system of step (1) is added into the mixed solution system of step (2), continues to be stirred
Uniformly, and in the case where being stirred continuously Temperature fall solidification to get.
Embodiment 2
A kind of novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 9.5：Petroleum ether 20.3：Ring
Hexane 25.8：Great Jin GM-105D 17.3：EXXSOL D40 27.1.
The novel protectant preparation method reference embodiment 1 of stone tablet rubbing, the difference is that, step (1) bath temperature
It it is 65 DEG C, step (2) bath temperature is 60 DEG C.
Embodiment 3
A kind of novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 11.2：Normal heptane 31.2：
Great Jin GM-105D 19.8：Butyl acetate 37.8.
The novel protectant preparation method reference embodiment 1 of stone tablet rubbing, the difference is that, step (1) bath temperature
It it is 65 DEG C, step (2) bath temperature is 75 DEG C.
Embodiment 4
A kind of novel stone tablet rubbing protective agent, includes the raw material of following mass ratio：Cyclododecane 8.6：Normal heptane 25.3：Ring
Hexane 21.6：Great Jin GM-105D 12.9：PEGASOL 3040 31.6.
The novel protectant preparation method reference embodiment 1 of stone tablet rubbing, the difference is that, step (1) bath temperature
It it is 61 DEG C, step (2) bath temperature is 70 DEG C.
Comparative example 1
1 protective agent as a comparison case includes the raw material of following mass ratio：Cyclododecane 70：Normal heptane 30.
Preparation method is with reference to embodiment 1.
Comparative example 2
2 protective agent as a comparison case includes the raw material of following mass ratio：Cyclododecane 70：Great Jin GM-105D 30.
Preparation method is with reference to embodiment 1.
Composite material is used for the Protective strategy of the Qing Dynasty of gantry museum stone tablet：
1, volatility is tested
The novel stone tablet rubbing protective agent 100g for weighing embodiment 1-4 respectively, is placed in 500ml glass beakers, 60 DEG C of water
After bath heating fusing, melt is coated in stone tablet surface with hairbrush rapidly, layer protecting film is formed, is covered in sample surfaces.Simultaneously
Film thickness is measured at room temperature to change with time (Fig. 1-4).And using the protective agent of comparative example 1-2 and cyclododecane as pair
According to the results are shown in Table 1.
Table 1：Evaporation rate (the unit of film at room temperature：μm/d)
Upper table the result shows that, can effectively slow down the rate of volatilization of cyclododecane using fluorine element polymer, and by cyclododecane
It is dissolved in solvent and diluent respectively with fluorine element polymer, the performance of product can be further increased, reduce cyclododecane
Volatility.
2, it drips experiment
The novel stone tablet rubbing protective agent 100g for weighing embodiment 1-4 respectively, is placed in 500ml glass beakers, 60 DEG C of water
After bath heating fusing, melt is coated in stone tablet surface with hairbrush rapidly, layer protecting film is formed, is covered in sample surfaces.As a result
It was found that water droplet is rolled in round bead shape and everywhere on rubbing surface, the static place of water droplet does not have water wave watermark, and sample surfaces are in super-hydrophobic
Shape, as shown in Fig. 5 (embodiment 1).
The foregoing is merely the embodiments that the present invention is best, and for those skilled in the art, the present invention can have
Various modifications and variations.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on, should all
It is included within protection scope of the present invention.
Claims (10)
1. a kind of novel stone tablet rubbing protective agent, which is characterized in that include the raw material of following mass ratio：Cyclododecane 5.6-
11.5：Fluorine element polymer 10.5-21.
2. novel stone tablet rubbing protective agent according to claim 1, which is characterized in that include the raw material of following mass ratio：
Cyclododecane 5.6-11.5：Solvent 15-48.4：Fluorine element polymer 10.5-21：Diluent 22.5-42.
3. novel stone tablet rubbing protective agent according to claim 2, which is characterized in that include the raw material of following mass ratio：
Cyclododecane 8.6-11.2：Solvent 31.2-48.4：Fluorine element polymer 12.9-19.8：Diluent 25.2-37.8.
4. novel stone tablet rubbing protective agent according to claim 2, which is characterized in that solvent is petroleum ether, normal heptane, ring
At least one of hexane；Diluent is at least one of PEGASOL 3040, EXXSOL D40, butyl acetate.
5. novel stone tablet rubbing protective agent according to claim 4, which is characterized in that include the raw material of following mass ratio：
Cyclododecane 10.5：Petroleum ether 24.6：Normal heptane 23.8：Fluorine element polymer 15.9：PEGASOL 3040 25.2.
6. novel stone tablet rubbing protective agent according to claim 4, which is characterized in that include the raw material of following mass ratio：
Cyclododecane 9.5：Petroleum ether 20.3：Hexamethylene 25.8：Fluorine element polymer 17.3：EXXSOL D40 27.1.
7. novel stone tablet rubbing protective agent according to claim 4, which is characterized in that include the raw material of following mass ratio：
Cyclododecane 11.2：Normal heptane 31.2：Fluorine element polymer 19.8：Butyl acetate 37.8.
8. novel stone tablet rubbing protective agent according to claim 4, which is characterized in that include the raw material of following mass ratio：
Cyclododecane 8.6：Normal heptane 25.3：Hexamethylene 21.6：Fluorine element polymer 12.9：PEGASOL 3040 31.6.
9. according to the novel stone tablet rubbing protective agent of claim 1-8 any one of them, which is characterized in that fluorine element polymer is big
Golden GM-105D.
10. a kind of novel protectant preparation method of stone tablet rubbing as claimed in claim 9, which is characterized in that including following
Step：
(1) cyclododecane and solvent are weighed respectively, is added in flask, and 60-80 DEG C of heating water bath stirring is formed uniform after dissolving
Solution system；
(2) it weighs diluent to be added in another flask, fluorine element polymerization is added in 60-80 DEG C of heating water bath stirring under agitation
Object, stirring form mixed solution system to being completely dissolved；
(3) the uniform solution system of step (1) is added into the mixed solution system of step (2), continues to be uniformly mixed,
And in the case where being stirred continuously Temperature fall solidification to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810477801.5A CN108641600B (en) | 2018-05-18 | 2018-05-18 | Stone stele rubbing protective agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810477801.5A CN108641600B (en) | 2018-05-18 | 2018-05-18 | Stone stele rubbing protective agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108641600A true CN108641600A (en) | 2018-10-12 |
| CN108641600B CN108641600B (en) | 2020-10-23 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108978343A (en) * | 2018-08-20 | 2018-12-11 | 四川博物院 | A kind of rubbing ink marks strengthening agent and preparation method thereof |
| CN114716263A (en) * | 2021-01-04 | 2022-07-08 | 奉节县文物保护管理中心 | Method for protecting stele cultural relics |
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| CN104631105A (en) * | 2015-01-27 | 2015-05-20 | 中国科学院上海高等研究院 | Application and method for temporarily reinforcing cultural relics in excavation site by one type of reinforcing material |
| CN104652124A (en) * | 2015-03-03 | 2015-05-27 | 中国科学院上海高等研究院 | Composite material with gradient melting points, and applications thereof in reinforcing of excavation site antiques |
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| US4382111A (en) * | 1980-05-07 | 1983-05-03 | Meisei Chemical Works Co., Ltd. | Method of treating fiber |
| CN102211947A (en) * | 2010-04-08 | 2011-10-12 | 泉州昌德化工有限公司 | Building stone surface curing agent and preparation method thereof |
| CN102453419A (en) * | 2010-10-26 | 2012-05-16 | 福建瑞森化工有限公司 | External insulation cleaning protective agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108978343A (en) * | 2018-08-20 | 2018-12-11 | 四川博物院 | A kind of rubbing ink marks strengthening agent and preparation method thereof |
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| CN114716263A (en) * | 2021-01-04 | 2022-07-08 | 奉节县文物保护管理中心 | Method for protecting stele cultural relics |
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| CN108641600B (en) | 2020-10-23 |
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Inventor after: Pei Dongjie Inventor after: Yang Zhenwei Inventor after: Yang Yuchuan Inventor after: Chen Lei Inventor after: Li Jingjing Inventor after: Wu Jiajun Inventor after: Wu Bin Inventor after: Liu Gang Inventor after: Yu Hang Inventor before: Pei Dongjie Inventor before: Li Jingjing Inventor before: Wu Bin Inventor before: Liu Gang Inventor before: Yu Hang |
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Effective date of registration: 20200316 Address after: 450000 southwest and northwest households, 17 / F, block B, incubation Building 2, National University Science and Technology Park, No. 11, Changchun Road, high tech Industrial Development Zone, Zhengzhou City, Henan Province Applicant after: ZHENGZHOU KEDOU TECHNOLOGY Co.,Ltd. Address before: 450000 Henan Zhengzhou High-tech Industrial Development Zone Changchun Road No.11 Henan National University Science and Technology Park Hatching Building 2 B, 17 storeys southwest and northwest households Applicant before: ZHENGZHOU SHANHU NANOMETER TECHNOLOGY Co.,Ltd. |
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