CN108641569A - A kind of environment protecting water-based paint - Google Patents
A kind of environment protecting water-based paint Download PDFInfo
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- CN108641569A CN108641569A CN201810294126.2A CN201810294126A CN108641569A CN 108641569 A CN108641569 A CN 108641569A CN 201810294126 A CN201810294126 A CN 201810294126A CN 108641569 A CN108641569 A CN 108641569A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment protecting water-based paint, raw material includes by weight：80 100 parts of major ingredient, 5 10 parts of soybean oil compound, 12 parts of iron oxide red, 12 parts of aluminium triphosphate, 12 parts of pentaerythritol ester, 27 parts of bentonite, 25 parts of wollastonite in powder, 16 parts of glass fibre, 26 parts of calcium sulfate crystal whiskers, 24 parts of zinc oxide, 4 10 parts of propylene glycol, 25 parts of coalescents, 12 parts of preservative, 12 parts of thickener, 12 parts of dispersant, 12 parts of antifoaming agent, 12 parts of levelling agent, 12 parts of polybutylacrylate latex, 12 parts of mould inhibitor, 26 parts of water.Soybean oil compound is prepared with following technique：Liquid soy oil, polyvinyl alcohol, water are mixed, sodium peroxydisulfate stirring is added, divinylbenzene is added, sodium peroxydisulfate stirring is added in heating stirring, and styrene, methyl methacrylate, heating stirring is added, and cooling obtains soybean oil compound.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of environment protecting water-based paints.
Background technology
In the current whole world all under the overall background for advocating energy-saving and environmental protection, green, the environmental protection of building becomes construction industry
One big task.In the current whole world, or indoor decorative paint can only accomplish environmental protection, but high temperature resistance is poor, to have simultaneously
Standby not only environmental protection but also high temperature resistant are current research emphasis.
Invention content
Technical problems based on background technology, the present invention propose a kind of environment protecting water-based paint, and high temperature resistance is good,
Excellent in mechanical performance, and safety and environmental protection.
A kind of environment protecting water-based paint proposed by the present invention, raw material include by weight：80-100 parts of major ingredient, soybean oil is multiple
Close 5-10 parts of object, 1-2 parts of iron oxide red, 1-2 parts of aluminium triphosphate, 1-2 parts of pentaerythritol ester, 2-7 parts of bentonite, wollastonite in powder
2-5 parts, 1-6 parts of glass fibre, 2-6 parts of calcium sulfate crystal whiskers, 2-4 parts of zinc oxide, 4-10 parts of propylene glycol, 2-5 parts of coalescents, prevent
Rotten agent 1-2 parts, 1-2 parts of thickener, 1-2 parts of dispersant, 1-2 parts of antifoaming agent, 1-2 parts of levelling agent, polybutylacrylate latex 1-2
Part, 1-2 parts of mould inhibitor, 2-6 parts of water.
Preferably, major ingredient includes by weight：Poly- 40-70 parts of toluene glycidol ether of neighbour, bisphenol f type epoxy resin 20-
40 parts.
Preferably, levelling agent is butanol, thickener model XJ-AT702.
Preferably, soybean oil compound is prepared with following technique：Liquid soy oil, polyvinyl alcohol, water are mixed, were added
Sodium sulphate stirs, and divinylbenzene is added, and heating stirring is added sodium peroxydisulfate stirring, styrene, methyl methacrylate is added
Ester, heating stirring, cooling obtain soybean oil compound.
Preferably, in the preparation process of soybean oil compound, liquid soy oil, polyvinyl alcohol, water, sodium peroxydisulfate, diethyl
Alkenyl benzene, sodium peroxydisulfate, styrene, methyl methacrylate weight ratio be 30-40：1-2：20-50：0.1-0.2：2-6：
0.1-0.2：1-6：1-2.
Preferably, soybean oil compound is prepared with following technique：Liquid soy oil, polyvinyl alcohol, water are mixed, were added
Sodium sulphate stirs 20-50min, mixing speed 2000-2400r/min, and divinylbenzene is added, is warming up to 90-96 DEG C of stirring
20-50min is added sodium peroxydisulfate and stirs 20-50min, mixing speed 2000-2400r/min, styrene, methyl-prop is added
E pioic acid methyl ester, is warming up to 90-96 DEG C of stirring 20-50min, and cooling obtains soybean oil compound.
The present invention reduces the use of a large amount of volatile organic solvents in construction with water as solvent, be beneficial to environmental protection and
The health of construction personnel, compared with existing water paint, high temperature resistance is good, strong adhesive force, good fluidity, mechanical property
It is excellent；And in soybean oil compound, using liquid soy oil as kernel, after divinylbenzene is appropriately crosslinked, in outer layers of polymer
It is good but also compatible with poly- adjacent toluene glycidol ether, bisphenol f type epoxy resin to be allowed to not only toughening effect for one layer of hard shell
Property it is excellent, cooperate with coalescents and iron oxide red, aluminium triphosphate, pentaerythritol ester, form network-like cross-linked structure,
Mechanical property is good, and high temperature resistance is excellent, and can be improved strong with coated substrate cohesive force, and adhesion property is excellent；Bentonite, silicon
Limestone flour, glass fibre, the intersolubility of calcium sulfate crystal whiskers and soybean oil compound are good, and binding force is strong, and mechanical property is fabulous.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of environment protecting water-based paint, raw material include：Major ingredient 80kg, soybean oil compound 10kg, iron oxide red 1kg, three
Poly aluminium phosphate 2kg, pentaerythritol ester 1kg, bentonite 7kg, wollastonite in powder 2kg, glass fibre 6kg, calcium sulfate crystal whiskers 2kg, oxygen
Change zinc 4kg, propylene glycol 4kg, coalescents 5kg, preservative 1kg, thickener XJ-AT702 2kg, dispersant 1kg, antifoaming agent
2kg, butanol 1kg, polybutylacrylate latex 2kg, mould inhibitor 1kg, water 6kg.
Major ingredient includes：Poly- neighbour's toluene glycidol ether 40g, bisphenol f type epoxy resin 40g.
Soybean oil compound is prepared with following technique：30g liquid soys oil, 2g polyvinyl alcohol, 20g water are mixed, are added
0.2g sodium peroxydisulfates stir 20min, mixing speed 2400r/min, and 2g divinylbenzenes are added, are warming up to 96 DEG C of stirrings
20min is added 0.2g sodium peroxydisulfates and stirs 20min, mixing speed 2400r/min, 1g styrene, 2g methacrylic acids is added
Methyl esters, is warming up to 90 DEG C of stirring 50min, and cooling obtains soybean oil compound.
Embodiment 2
A kind of environment protecting water-based paint, raw material include：Major ingredient 100kg, soybean oil compound 5kg, iron oxide red 2kg, three
Poly aluminium phosphate 1kg, pentaerythritol ester 2kg, bentonite 2kg, wollastonite in powder 5kg, glass fibre 1kg, calcium sulfate crystal whiskers 6kg, oxygen
Change zinc 2kg, propylene glycol 10kg, coalescents 2kg, preservative 2kg, thickener XJ-AT702 1kg, dispersant 2kg, antifoaming agent
1kg, butanol 2kg, polybutylacrylate latex 1kg, mould inhibitor 2kg, water 2kg.
Major ingredient includes：Poly- neighbour's toluene glycidol ether 70g, bisphenol f type epoxy resin 20g.
Soybean oil compound is prepared with following technique：40g liquid soys oil, 1g polyvinyl alcohol, 50g water are mixed, are added
0.1g sodium peroxydisulfates stir 50min, mixing speed 2000r/min, and 6g divinylbenzenes are added, are warming up to 90 DEG C of stirrings
50min is added 0.1g sodium peroxydisulfates and stirs 50min, mixing speed 2000r/min, 6g styrene, 1g methacrylic acids is added
Methyl esters, is warming up to 96 DEG C of stirring 20min, and cooling obtains soybean oil compound.
Embodiment 3
A kind of environment protecting water-based paint, raw material include：Major ingredient 85kg, soybean oil compound 8kg, iron oxide red 1.2kg, three
Poly aluminium phosphate 1.7kg, pentaerythritol ester 1.4kg, bentonite 6kg, wollastonite in powder 3kg, glass fibre 4kg, calcium sulfate crystal whiskers
3kg, zinc oxide 3.5kg, propylene glycol 6kg, coalescents 4kg, preservative 1.2kg, thickener XJ-AT702 1.7kg, dispersant
1.3kg, antifoaming agent 1.6kg, butanol 1.2kg, polybutylacrylate latex 1.7kg, mould inhibitor 1.4kg, water 5kg.
Major ingredient includes：Poly- neighbour's toluene glycidol ether 50g, bisphenol f type epoxy resin 35g.
Soybean oil compound is prepared with following technique：33g liquid soys oil, 1.8g polyvinyl alcohol, 30g water are mixed, added
Enter 0.18g sodium peroxydisulfates stirring 30min, mixing speed 2300r/min, 3g divinylbenzenes are added, are warming up to 94 DEG C of stirrings
30min is added 0.18g sodium peroxydisulfates and stirs 30min, mixing speed 2300r/min, 2g styrene, 1.8g methyl-props is added
E pioic acid methyl ester, is warming up to 92 DEG C of stirring 40min, and cooling obtains soybean oil compound.
Embodiment 4
A kind of environment protecting water-based paint, raw material include：Major ingredient 95kg, soybean oil compound 6kg, iron oxide red 1.8kg, three
Poly aluminium phosphate 1.3kg, pentaerythritol ester 1.6kg, bentonite 4kg, wollastonite in powder 4kg, glass fibre 2kg, calcium sulfate crystal whiskers
5kg, zinc oxide 2.5kg, propylene glycol 8kg, coalescents 3kg, preservative 1.8kg, thickener XJ-AT702 1.3kg, dispersant
1.7kg, antifoaming agent 1.4kg, butanol 1.8kg, polybutylacrylate latex 1.3kg, mould inhibitor 1.6kg, water 3kg.
Major ingredient includes：Poly- neighbour's toluene glycidol ether 60g, bisphenol f type epoxy resin 25g.
Soybean oil compound is prepared with following technique：37g liquid soys oil, 1.2g polyvinyl alcohol, 40g water are mixed, added
Enter 0.12g sodium peroxydisulfates stirring 40min, mixing speed 2100r/min, 5g divinylbenzenes are added, are warming up to 92 DEG C of stirrings
40min is added 0.12g sodium peroxydisulfates and stirs 40min, mixing speed 2100r/min, 4g styrene, 1.2g methyl-props is added
E pioic acid methyl ester, is warming up to 94 DEG C of stirring 30min, and cooling obtains soybean oil compound.
Embodiment 5
A kind of environment protecting water-based paint, raw material include：Major ingredient 90kg, soybean oil compound 7kg, iron oxide red 1.5kg, three
Poly aluminium phosphate 1.5kg, pentaerythritol ester 1.5kg, bentonite 5kg, wollastonite in powder 3.5kg, glass fibre 3kg, calcium sulfate crystal whiskers
4kg, zinc oxide 3kg, propylene glycol 7kg, coalescents 3.5kg, preservative 1.5kg, thickener XJ-AT702 1.5kg, dispersant
1.5kg, antifoaming agent 1.5kg, butanol 1.5kg, polybutylacrylate latex 1.5kg, mould inhibitor 1.5kg, water 7kg.
Major ingredient includes：Poly- neighbour's toluene glycidol ether 55g, bisphenol f type epoxy resin 30g.
Soybean oil compound is prepared with following technique：35g liquid soys oil, 1.5g polyvinyl alcohol, 35g water are mixed, added
Enter 0.15g sodium peroxydisulfates stirring 35min, mixing speed 2200r/min, 4g divinylbenzenes are added, are warming up to 93 DEG C of stirrings
35min is added 0.15g sodium peroxydisulfates and stirs 35min, mixing speed 2200r/min, 3g styrene, 1.5g methyl-props is added
E pioic acid methyl ester, is warming up to 93 DEG C of stirring 35min, and cooling obtains soybean oil compound.
5 gained environment protecting water-based paint of embodiment and commercially available ordinary epoxy resin coating are coated on sheet metal, Bao Gang
Plate is smooth, without the mechanical defects such as impression and point, and size is 50 × 120 × 1mm (pressing national standard GB1735-79), sheet metal into
Row oil removing, derusting ensure surface of thin steel sheet cleaning, drying, carry out the test of correlated performance after placement solidification in 24 hours at room temperature.
Wherein cold-hot alternation is tested：Model is put into Muffle furnace, is warming up to 800 DEG C, keeps the temperature 10h, takes out, is put into
1h is impregnated in cold water, is 1 period.Several periods repeatedly, observation paint film variation.Such as but without pull-away, cracking situation,
Illustrate that paint film cold-hot alternation is functional.
Salt fog resistance is tested：Model is put into salt fog machine, spray testing is done with the NaCl solution of 5wt%, observes model
Whether it is bubbled, gets rusty (GB/T1771-91).
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of environment protecting water-based paint, which is characterized in that its raw material includes by weight：80-100 parts of major ingredient, soybean oil is compound
5-10 parts of object, 1-2 parts of iron oxide red, 1-2 parts of aluminium triphosphate, 1-2 parts of pentaerythritol ester, 2-7 parts of bentonite, wollastonite in powder 2-
5 parts, 1-6 parts of glass fibre, 2-6 parts of calcium sulfate crystal whiskers, 2-4 parts of zinc oxide, 4-10 parts of propylene glycol, 2-5 parts of coalescents, anti-corrosion
1-2 parts of agent, 1-2 parts of thickener, 1-2 parts of dispersant, 1-2 parts of antifoaming agent, 1-2 parts of levelling agent, 1-2 parts of polybutylacrylate latex,
1-2 parts of mould inhibitor, 2-6 parts of water.
2. environment protecting water-based paint according to claim 1, which is characterized in that major ingredient includes by weight：Poly- neighbour's toluene shrinks
40-70 parts of glycerin ether, 20-40 parts of bisphenol f type epoxy resin.
3. environment protecting water-based paint according to claim 1 or claim 2, which is characterized in that levelling agent is butanol, thickener model
XJ-AT702。
4. according to any one of the claim 1-3 environment protecting water-based paints, which is characterized in that the following technique of soybean oil compound
It prepares：Liquid soy oil, polyvinyl alcohol, water are mixed, sodium peroxydisulfate stirring is added, divinylbenzene is added, heating stirring adds
Enter sodium peroxydisulfate stirring, styrene, methyl methacrylate, heating stirring is added, cooling obtains soybean oil compound.
5. environment protecting water-based paint according to claim 4, which is characterized in that in the preparation process of soybean oil compound, liquid
The weight ratio of soybean oil, polyvinyl alcohol, water, sodium peroxydisulfate, divinylbenzene, sodium peroxydisulfate, styrene, methyl methacrylate
For 30-40：1-2：20-50：0.1-0.2：2-6：0.1-0.2：1-6：1-2.
6. the environment protecting water-based paint according to claim 4 or 5, which is characterized in that soybean oil compound is prepared with following technique：
Liquid soy oil, polyvinyl alcohol, water are mixed, sodium peroxydisulfate is added and stirs 20-50min, mixing speed 2000-2400r/
Divinylbenzene is added in min, is warming up to 90-96 DEG C of stirring 20-50min, and sodium peroxydisulfate is added and stirs 20-50min, stirring speed
Degree is 2000-2400r/min, and styrene, methyl methacrylate is added, and is warming up to 90-96 DEG C of stirring 20-50min, cooling
To soybean oil compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810294126.2A CN108641569A (en) | 2018-03-30 | 2018-03-30 | A kind of environment protecting water-based paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810294126.2A CN108641569A (en) | 2018-03-30 | 2018-03-30 | A kind of environment protecting water-based paint |
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| CN108641569A true CN108641569A (en) | 2018-10-12 |
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| CN201810294126.2A Withdrawn CN108641569A (en) | 2018-03-30 | 2018-03-30 | A kind of environment protecting water-based paint |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265672A (en) * | 2013-05-22 | 2013-08-28 | 云南大学 | Method for preparing plant oil-based core-shell structural flexibilizer |
| CN104893499A (en) * | 2015-05-27 | 2015-09-09 | 芜湖县双宝建材有限公司 | Corrosion-resistant high-adhesive-force water-based metal paint |
| CN106349870A (en) * | 2016-08-27 | 2017-01-25 | 安徽省金盾涂料有限责任公司 | High-temperature-resistant epoxy coating with high adhesion and excellent mechanical properties |
| CN106883691A (en) * | 2017-04-18 | 2017-06-23 | 德阳森华新材料科技有限公司 | Cold aqueous non-corrosive metal (NCM) coating |
| CN107805351A (en) * | 2017-10-30 | 2018-03-16 | 安徽蓝德仪表有限公司 | A kind of oil gas engineering light thin-wall instrument cable |
-
2018
- 2018-03-30 CN CN201810294126.2A patent/CN108641569A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265672A (en) * | 2013-05-22 | 2013-08-28 | 云南大学 | Method for preparing plant oil-based core-shell structural flexibilizer |
| CN104893499A (en) * | 2015-05-27 | 2015-09-09 | 芜湖县双宝建材有限公司 | Corrosion-resistant high-adhesive-force water-based metal paint |
| CN106349870A (en) * | 2016-08-27 | 2017-01-25 | 安徽省金盾涂料有限责任公司 | High-temperature-resistant epoxy coating with high adhesion and excellent mechanical properties |
| CN106883691A (en) * | 2017-04-18 | 2017-06-23 | 德阳森华新材料科技有限公司 | Cold aqueous non-corrosive metal (NCM) coating |
| CN107805351A (en) * | 2017-10-30 | 2018-03-16 | 安徽蓝德仪表有限公司 | A kind of oil gas engineering light thin-wall instrument cable |
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Application publication date: 20181012 |