CN108641510A - A kind of aqueous fire-proof coating and preparation method thereof - Google Patents

A kind of aqueous fire-proof coating and preparation method thereof Download PDF

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Publication number
CN108641510A
CN108641510A CN201810262811.7A CN201810262811A CN108641510A CN 108641510 A CN108641510 A CN 108641510A CN 201810262811 A CN201810262811 A CN 201810262811A CN 108641510 A CN108641510 A CN 108641510A
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China
Prior art keywords
proof coating
fire
aqueous fire
aqueous
water
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Pending
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CN201810262811.7A
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Chinese (zh)
Inventor
翟勇强
周侃
陈伟杰
刘华夏
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Guangdong Jushi Technology Research Co., Ltd
QINGYUAN MEINUOKE NEW MATERIAL Co.,Ltd.
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Presafer (Qingyuan) Phosphor Chemical Co Ltd
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Priority to CN201810262811.7A priority Critical patent/CN108641510A/en
Publication of CN108641510A publication Critical patent/CN108641510A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of aqueous fire-proof coating and preparation method thereof, which is made of the raw material of following mass percentage：Organic binder：20%~30%；Fire retardant：20%~50%；White color stuffing：20%~30%；Auxiliary agent：0~5%；Water：Surplus.Preparation method is as follows：1) water and auxiliary agent are added in dispersing apparatus, are uniformly dispersed under conditions of vacuumizing；2) white color stuffing and fire retardant is added, temperature of charge is risen to 80 DEG C~90 DEG C using shear heat, is persistently dispersed with stirring 1.5~2.5h；3) it is passed through cooling circulating water, temperature of charge is down to room temperature, organic binder is added, is dispersed to 20 μm of fineness hereinafter, sieving.The flame retardant property of the aqueous fire-proof coating of the present invention reaches as defined in GB8624 2006 A grades, and reflecting rate is more than 95%, safety and environmental protection, and the cracking resistance of paint film and water resistance are excellent after film forming, and adhesion strength on base material is high.

Description

A kind of aqueous fire-proof coating and preparation method thereof
Technical field
The present invention relates to a kind of aqueous fire-proof coatings and preparation method thereof.
Background technology
Fireproof coating, which is one kind, can improve material refractory ability, slow down propagation of flame spread speed, or in certain time Interior energy prevents the coating of burning, can also be called anti-flaming dope.As environmental requirement is higher and higher and the hair of new technologies and materials Exhibition, aqueous fire-proof coating will replace organic solvent type fireproof coating completely, this is inevitable development trend.Currently, water-based fireproof The research of coating is burning hot, many aqueous fire-proof coating products occurs, makes a lot of progress, but existing water-based fireproof applies There is apparent performance deficiency in material product, such as：102876172 B of CN disclose a kind of aqueous fire-proof coating, due to introducing Expanded graphite, can only do the coating of grey and black, and reflecting rate is relatively low, if shone for the indoor high-power light of needs Bright, energy consumption is more, and non-ignitable grade is also not achieved in the flame retardant property of the aqueous fire-proof coating；103242721 B of CN are disclosed A kind of fireproof coating, flame retardant property have reached non-ignitable grade, but non-due to introducing more water-soluble substances and non-white Transparent material, whiteness is relatively low, and reflecting rate is relatively low, and water resistance is also poor.
Therefore, it is necessary to develop, a kind of excellent fireproof performance, reflecting rate be high, aqueous fire-proof coating of excellent combination property.
Invention content
The purpose of the present invention is to provide a kind of aqueous fire-proof coatings and preparation method thereof.
The technical solution used in the present invention is：
A kind of aqueous fire-proof coating is made of the raw material of following mass percentage：
Organic binder：20%~30%；
Fire retardant：20%~50%；
White color stuffing：20%~30%；
Auxiliary agent：0~5%；
Water：Surplus.
The organic binder is styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, silicone acrylic emulsion, chlorine acrylic emulsion, pure-acrylic emulsion, polyurethane breast At least one of liquid.
The fire retardant is organic phosphate, hypophosphites, Quadrafos, pyrophosphate, melamine, dicyandiamide, three Poly cyanamid cyanurate, polyphosphoric acid melamine, melamine pyrophosphate, magnesium hydroxide, aluminium hydroxide, Polyborosiloxane, boron At least one of acid, zinc borate, 3.5 hydrate zinc borates.
The whiteness of the fire retardant is more than 96.
The white color stuffing is at least one in titanium dioxide, lithopone, calcium carbonate, barium sulfate, talcum powder, silicon powder Kind.
The whiteness of the white color stuffing is more than 99.
The auxiliary agent is at least one of pH adjusting agent, wetting dispersing agent, thickener, auxiliary rheological agents, fungicide.
The preparation method of above-mentioned aqueous fire-proof coating, includes the following steps：
1) water and auxiliary agent are added in dispersing apparatus, are uniformly dispersed under conditions of vacuumizing；
2) white color stuffing and fire retardant is added, temperature of charge is risen to 80 DEG C~90 DEG C using shear heat, it is lasting to stir Disperse 1.5~2.5h；
3) be passed through cooling circulating water, temperature of charge be down to room temperature, organic binder is added, be dispersed to 20 μm of fineness with Under, sieving obtains aqueous fire-proof coating.
The beneficial effects of the invention are as follows：The flame retardant property of the aqueous fire-proof coating of the present invention reaches GB8624-2006《Building Material and product burns grading performance》A grades defined (non-ignitable rank), reflecting rate is more than 95%, safety and environmental protection, paint film after film forming Cracking resistance and water resistance it is excellent, adhesion strength on base material is high.
1) white color stuffing and fire retardant are warming up to 80 DEG C~90 DEG C by the present invention using shear heat, carry out high temperature mixing, White color stuffing and fire-retardant particles can be dispersed to its minimum size, promote between them it is mutual be fitted into, significantly Improve the flame retarding efficiency of fire retardant；
2) acrylate and vinyl acetate emulsion, chlorine acrylic emulsion etc. in the present invention by thermally decompose itself can be at there is association between charcoal, with fire retardant Same synergistic effect；
3) polyaminoester emulsion in the present invention can be discharged the inert gases such as ammonia, nitrogen by thermal decomposition, and its decomposition obtains Isocyanates can also improve the flame retardant property of aqueous fire-proof coating at charcoal.
Specific implementation mode
A kind of aqueous fire-proof coating is made of the raw material of following mass percentage：
Organic binder：20%~30%；
Fire retardant：20%~50%；
White color stuffing：20%~30%；
Auxiliary agent：0~5%；
Water：Surplus.
Preferably, the organic binder be styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, silicone acrylic emulsion, chlorine acrylic emulsion, pure-acrylic emulsion, At least one of polyaminoester emulsion.
Preferably, the fire retardant be organic phosphate, it is hypophosphites, Quadrafos, pyrophosphate, melamine, double Cyanamide, melamine cyanurate, polyphosphoric acid melamine, melamine pyrophosphate, magnesium hydroxide, aluminium hydroxide, poly- silicon boron At least one of oxygen alkane, boric acid, zinc borate, 3.5 hydrate zinc borates.
Preferably, the whiteness of the fire retardant is more than 96.
Preferably, the white color stuffing is in titanium dioxide, lithopone, calcium carbonate, barium sulfate, talcum powder, silicon powder It is at least one.
Preferably, the whiteness of the white color stuffing is more than 99.
Preferably, the auxiliary agent is at least one in pH adjusting agent, wetting dispersing agent, thickener, auxiliary rheological agents, fungicide Kind.
The preparation method of above-mentioned aqueous fire-proof coating, includes the following steps：
1) water and auxiliary agent are added in dispersing apparatus, are uniformly dispersed under conditions of vacuumizing；
2) white color stuffing and fire retardant is added, temperature of charge is risen to 80 DEG C~90 DEG C using shear heat, it is lasting to stir Disperse 1.5~2.5h；
3) be passed through cooling circulating water, temperature of charge be down to room temperature, organic binder is added, be dispersed to 20 μm of fineness with Under, sieving obtains aqueous fire-proof coating.
The present invention is made further explanation and description with reference to specific embodiment.
Embodiment 1：
A kind of aqueous fire-proof coating, raw material composition are as shown in the table：
A kind of raw material of 1 aqueous fire-proof coating of table forms table
Raw material Mass percent (%)
Acrylate and vinyl acetate emulsion EZ 1120 20
Ammonium polyphosphate EPFR-APP262 30
Magnesium hydroxide 7
Titanium dioxide 15
Lithopone 10
Wetting dispersing agent 2
Auxiliary rheological agents 1
Water 15
Total amount 100
Embodiment 2：
A kind of aqueous fire-proof coating, raw material composition are as shown in the table：
A kind of raw material of 2 aqueous fire-proof coating of table forms table
Raw material Mass percent (%)
Chlorine acrylic emulsion EZ 3066 23
Polyphosphoric acid melamine MPP-300 20
Zinc borate 10
Lithopone 15
Calcium carbonate 10
Wetting dispersing agent 1.5
Auxiliary rheological agents 1
Fungicide 0.5
Water 19
Total amount 100
Embodiment 3：
A kind of aqueous fire-proof coating, raw material composition are as shown in the table：
A kind of raw material of 3 aqueous fire-proof coating of table forms table
Raw material Mass percent (%)
Polyaminoester emulsion Dispercoll U53 21
Melamine cyanurate MCA-25 30
Organic hypo-aluminum orthophosphate OPS 330 10
Talcum powder 12
Silicon powder 8
Wetting dispersing agent 1.5
Fungicide 0.5
Water 17
Total amount 100
Embodiment 4：
A kind of aqueous fire-proof coating, raw material composition are as shown in the table：
A kind of raw material of 4 aqueous fire-proof coating of table forms table
Raw material Mass percent (%)
Acrylate and vinyl acetate emulsion EZ 1120 15
Polyaminoester emulsion Dispercoll U53 10
Ammonium polyphosphate EPFR-APP262 15
Organic hypo-aluminum orthophosphate OPS 330 13
Titanium dioxide 16
Silicon powder 12
Wetting dispersing agent 2.5
Thickener 0.5
Auxiliary rheological agents 1
Water 15
Total amount 100
Embodiment 5：
A kind of aqueous fire-proof coating, raw material composition are as shown in the table：
A kind of raw material of 5 aqueous fire-proof coating of table forms table
Raw material Mass percent (%)
Polyaminoester emulsion Dispercoll U53 27
Melamine cyanurate MCA-25 30
Aluminium hydroxide 12
Lithopone 12
Silicon powder 8
Wetting dispersing agent 1
Water 10
Total amount 100
Test case：
The aqueous fire-proof coating prepared to Examples 1 to 5 is tested for the property, and test result is as follows shown in table：
The performance test results of the aqueous fire-proof coating of 6 Examples 1 to 5 of table
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications, Equivalent substitute mode is should be, is included within the scope of the present invention.

Claims (8)

1. a kind of aqueous fire-proof coating, it is characterised in that：It is made of the raw material of following mass percentage：
Organic binder：20%~30%；
Fire retardant：20%~50%；
White color stuffing：20%~30%；
Auxiliary agent：0~5%；
Water：Surplus.
2. aqueous fire-proof coating according to claim 1, it is characterised in that：The organic binder is styrene-acrylic emulsion, vinegar At least one of acrylic emulsion, silicone acrylic emulsion, chlorine acrylic emulsion, pure-acrylic emulsion, polyaminoester emulsion.
3. aqueous fire-proof coating according to claim 1, it is characterised in that：The fire retardant is organic phosphate, secondary phosphorus Hydrochlorate, Quadrafos, pyrophosphate, melamine, dicyandiamide, melamine cyanurate, polyphosphoric acid melamine, pyrophosphoric acid At least one of melamine, magnesium hydroxide, aluminium hydroxide, Polyborosiloxane, boric acid, zinc borate, 3.5 hydrate zinc borates.
4. aqueous fire-proof coating according to claim 3, it is characterised in that：The whiteness of the fire retardant is more than 96.
5. aqueous fire-proof coating according to claim 1, it is characterised in that：The white color stuffing is titanium dioxide, vertical moral At least one of powder, calcium carbonate, barium sulfate, talcum powder, silicon powder.
6. aqueous fire-proof coating according to claim 5, it is characterised in that：The whiteness of the white color stuffing is more than 99.
7. aqueous fire-proof coating according to claim 1, it is characterised in that：The auxiliary agent is pH adjusting agent, wetting and dispersing At least one of agent, thickener, auxiliary rheological agents, fungicide.
8. the preparation method of the aqueous fire-proof coating described in any one of claim 1~7, it is characterised in that：Including following Step：
1) water and auxiliary agent are added in dispersing apparatus, are uniformly dispersed under conditions of vacuumizing；
2) white color stuffing and fire retardant is added, temperature of charge is risen to 80 DEG C~90 DEG C using shear heat, is persistently dispersed with stirring 1.5~2.5h；
3) it is passed through cooling circulating water, temperature of charge is down to room temperature, organic binder is added, is dispersed to 20 μm of fineness hereinafter, mistake Sieve, obtains aqueous fire-proof coating.
CN201810262811.7A 2018-03-28 2018-03-28 A kind of aqueous fire-proof coating and preparation method thereof Pending CN108641510A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109575781A (en) * 2018-10-31 2019-04-05 韶关市合众化工有限公司 A kind of structure type polyurethane flame-proof antibiotic coating
CN110938341A (en) * 2019-12-17 2020-03-31 和县明生环保材料有限责任公司 Preparation method of veneer heat-insulation fireproof coating
CN113652157A (en) * 2021-08-24 2021-11-16 东莞市巴德迩新材料有限公司 High-wear-resistance polyurethane water-based paint and preparation method thereof
CN114213891A (en) * 2021-12-09 2022-03-22 河南三棵树新材料科技有限公司 Preparation method of hybrid flame retardant and water-based steel structure fireproof coating
CN114507462A (en) * 2022-02-25 2022-05-17 海鹰空天材料研究院(苏州)有限责任公司 Fireproof flame-retardant coating and preparation method thereof
CN114904739A (en) * 2022-06-16 2022-08-16 广东百安环保新材料有限公司 Water-based fireproof coating for steel structure and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101397469A (en) * 2008-11-11 2009-04-01 中国核动力研究设计院 Fire-resisting paint and preparation method thereof
CN102911566A (en) * 2012-10-26 2013-02-06 清远市普塞呋磷化学有限公司 Waterproof efficient intumescent fire retardant coating
CN104610816A (en) * 2014-12-31 2015-05-13 大连东信微波技术有限公司 Outdoor waterproof weather-proof wave-absorbing material and preparation method thereof
CN106349769A (en) * 2016-08-26 2017-01-25 佛山科学技术学院 Waterborne inorganic flame-retardant coating and preparation method thereof
CN107513328A (en) * 2016-06-17 2017-12-26 清远市普塞呋磷化学有限公司 A kind of Transparent expansion type fire-retardant paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101397469A (en) * 2008-11-11 2009-04-01 中国核动力研究设计院 Fire-resisting paint and preparation method thereof
CN102911566A (en) * 2012-10-26 2013-02-06 清远市普塞呋磷化学有限公司 Waterproof efficient intumescent fire retardant coating
CN104610816A (en) * 2014-12-31 2015-05-13 大连东信微波技术有限公司 Outdoor waterproof weather-proof wave-absorbing material and preparation method thereof
CN107513328A (en) * 2016-06-17 2017-12-26 清远市普塞呋磷化学有限公司 A kind of Transparent expansion type fire-retardant paint and preparation method thereof
CN106349769A (en) * 2016-08-26 2017-01-25 佛山科学技术学院 Waterborne inorganic flame-retardant coating and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109575781A (en) * 2018-10-31 2019-04-05 韶关市合众化工有限公司 A kind of structure type polyurethane flame-proof antibiotic coating
CN110938341A (en) * 2019-12-17 2020-03-31 和县明生环保材料有限责任公司 Preparation method of veneer heat-insulation fireproof coating
CN113652157A (en) * 2021-08-24 2021-11-16 东莞市巴德迩新材料有限公司 High-wear-resistance polyurethane water-based paint and preparation method thereof
CN114213891A (en) * 2021-12-09 2022-03-22 河南三棵树新材料科技有限公司 Preparation method of hybrid flame retardant and water-based steel structure fireproof coating
CN114507462A (en) * 2022-02-25 2022-05-17 海鹰空天材料研究院(苏州)有限责任公司 Fireproof flame-retardant coating and preparation method thereof
CN114904739A (en) * 2022-06-16 2022-08-16 广东百安环保新材料有限公司 Water-based fireproof coating for steel structure and preparation method thereof

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