CN108641478A - A kind of rapid draing LED light UV curing ink-jet and preparation method thereof - Google Patents
A kind of rapid draing LED light UV curing ink-jet and preparation method thereof Download PDFInfo
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- CN108641478A CN108641478A CN201810288356.8A CN201810288356A CN108641478A CN 108641478 A CN108641478 A CN 108641478A CN 201810288356 A CN201810288356 A CN 201810288356A CN 108641478 A CN108641478 A CN 108641478A
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- led light
- rapid draing
- resin
- curing ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a kind of rapid draing LED light UV curing ink-jets and preparation method thereof, which includes the following raw material：Resin, trifunctional monomer, Monofunctional monomers, photoinitiator TPO/90,784 initiator of visible light, 2 isopropyl thioxanthones, levelling agent, butyl ester cosolvent, nano color paste；Wherein, the resin is aliphatic carbamate acrylic resin, and the aliphatic carbamate acrylic resin index parameter includes：Functional group is 3, glass transition temperature TG is 35 DEG C, molecular weight is 600~1200, viscosity is 800~1500/25 DEG C.Rapid draing solidification may be implemented in rapid draing LED light UV curing ink-jet provided by the present application（Without heating, the irradiations such as LED are only needed）, production efficiency is high, can be printed in cambered surface（LED light can be irradiated to）, the pattern stereoscopic impression printed out is strong.
Description
Technical field
The present invention relates to ink-jet preparing technical field, more particularly to a kind of rapid draing LED light UV curing ink-jet and its
Preparation method.
Background technology
Ink (ink, printing ink) is the important materials for printing, it is by printing or air brushing by pattern, text
Word shows on the substrate.Ink includes main component and auxiliary element, they equably mix and are formed through repeat-rolling
A kind of stickiness colloidal fluid.It is made of link stuff (resin), pigment, filler, auxiliary agent and solvent etc..For books and periodicals, packing and decorating,
The various printings such as building decoration and electronic circuit plank.As social demand increases, ink kind and yield also respective extension and
Increase.LED ink is directed to the glass ceramics UV-LED water transfer inks of marble paper industry special project research and development, which, which has, can be achieved height
Print duplication brush, low energy consumption, curing rate is fast, flexibility is good, is posted that stretching property of position is strong, high gloss, lovely luster are, it can be achieved that polychrome set
The features such as print.
Invention content
The present invention provides a kind of rapid draing LED light UV curing ink-jets and preparation method thereof.
The present invention provides following schemes：
A kind of rapid draing LED light UV curing ink-jet, including：
Include the raw material of following mass percent：
Resin 18%~25%, trifunctional monomer TMPTA5%~15%, Monofunctional monomers' ACMO25%~35%,
Photoinitiator TPO/9078%~15%, 784 initiator 1.0%~2.0% of visible light, 2- isopropyl thioxanthones 0.5%~
2.0%, levelling agent 0.2%~0.5%, butyl ester cosolvent 15%~25%, nano color paste 5%~10%；
Wherein, the resin is aliphatic carbamate acrylic resin, the aliphatic carbamate acrylic acid
Resin index parameter includes：Functional group is 3, glass transition temperature TG is 35 DEG C, molecular weight is 600~1200, viscosity be 800~
1500/25℃。
Preferably：Include the raw material of following mass percent：
Resin 19%, trifunctional monomer TMPTA10%, Monofunctional monomers ACMO31%, photoinitiator TPO/
9015%, 784 initiator 1.2% of visible light, 2- isopropyl thioxanthones 0.5%, levelling agent 0.3%, butyl ester cosolvent 15%,
Nano color paste 8%.
Preferably：Include the raw material of following mass percent：
Resin 20%, trifunctional monomer TMPTA10%, Monofunctional monomers ACMO30%, photoinitiator TPO/
9016%, 784 initiator 1.2% of visible light, 2- isopropyl thioxanthones 0.5%, levelling agent 0.3%, butyl ester cosolvent 16%,
Nano color paste 6%.
Preferably：784 initiator of the visible light includes bis- fluoro- 3- pyrroles's phenyl titanocenes of double 2,6-.
A kind of preparation method of the rapid draing LED light UV curing ink-jet, the method includes：
Each raw material, resin 18%~25%, trifunctional monomer TMPTA5%~15%, list are taken by following mass percent
Monomer's ACMO25%~35%, 2- isopropyl thioxanthones 0.5%~2.0%, levelling agent 0.2%~0.5%, butyl ester
Cosolvent 15%~25% and nano color paste 5%~10%；Above-mentioned raw materials are put into nano-level grinder together and are ground
Until fineness, which reaches 0.3 nanometer or less, stops raw material after being ground, control operation dimension is no more than 45~55 in process of lapping
℃；
Photoinitiator TPO/9078%~15% and 784 initiator of visible light is added after to the grinding in raw material
1.0%~2.0% mixing is up to the rapid draing LED light UV curing ink-jet.
Preferably：Control operation dimension is no more than 50 DEG C in the process of lapping.
According to specific embodiment provided by the invention, the invention discloses following technique effects：
By the invention it is possible to a kind of rapid draing LED light UV curing ink-jet and preparation method thereof be realized, in a kind of realization
Under mode, which includes the raw material of following mass percent：Resin 18%~25%, trifunctional monomer TMPTA5%~
15%, Monofunctional monomers' ACMO25%~35%, photoinitiator TPO/9078%~15%, 784 initiator 1.0% of visible light
~2.0%, 2- isopropyl thioxanthones 0.5%~2.0%, levelling agent 0.2%~0.5%, butyl ester cosolvent 15%~25%,
Nano color paste 5%~10%；Wherein, the resin is aliphatic carbamate acrylic resin, the aliphatic amines first
Acid esters acrylic resin index parameter includes：Functional group is 3, glass transition temperature TG is 35 DEG C, molecular weight is 600~1200, viscous
Degree is 800~1500/25 DEG C.Rapid draing solidification may be implemented in rapid draing LED light UV curing ink-jet provided by the present application
(not having to heating, only need the irradiations such as LED), production efficiency is high, can be printed in cambered surface and (can be irradiated to LED light), prints
The pattern stereoscopic impression gone out is strong.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained, shall fall within the protection scope of the present invention.
This application provides a kind of rapid draing LED light UV curing ink-jets, which is characterized in that including following mass percent
Raw material：
Resin 18%~25%, trifunctional monomer TMPTA5%~15%, Monofunctional monomers' ACMO25%~35%,
Photoinitiator TPO/9078%~15%, 784 initiator 1.0%~2.0% of visible light, 2- isopropyl thioxanthones 0.5%~
2.0%, levelling agent 0.2%~0.5%, butyl ester cosolvent 15%~25%, nano color paste 5%~10%；
Wherein, the resin is aliphatic carbamate acrylic resin, the aliphatic carbamate acrylic acid
Resin index parameter includes：Functional group is 3, glass transition temperature TG is 35 DEG C, molecular weight is 600~1200, viscosity be 800~
1500/25℃。
Further, 784 initiator of the visible light includes bis- fluoro- 3- pyrroles's phenyl titanocenes of double 2,6-.The application carries
The bis- fluoro- 3- pyrroles's phenyl titanocenes of double 2,6- supplied, can be used in ultraviolet light or visible-light curing is based on unsaturated prescription system:
Such as in simple function and polyfunctional monomer in the acrylate copolymer system of diluent.The energy in the existing system of not oxygen
Obtain excellent performance.It is unique to absorb wave crest and efficient induced so that 784 especially suitable for photoresist (resists),
Print battery plate (printing plates), and other optical storage apparatus (optical layers, holograms, laser
Direct imaging, stereolithography) can be in ultraviolet light, it is seen that and light (indigo plant in spectrum, green section) is more suitable for swashing
Light:Ar-Laser(488nm).
Present invention also provides a kind of preparation method of the rapid draing LED light UV curing ink-jet, the method includes：
Each raw material, resin 18%~25%, trifunctional monomer TMPTA5%~15%, list are taken by following mass percent
Monomer's ACMO25%~35%, 2- isopropyl thioxanthones 0.5%~2.0%, levelling agent 0.2%~0.5%, butyl ester
Cosolvent 15%~25% and nano color paste 5%~10%；Above-mentioned raw materials are put into nano-level grinder together and are ground
Until fineness, which reaches 0.3 nanometer or less, stops raw material after being ground, control operation dimension is no more than 45~55 in process of lapping
℃；
Photoinitiator TPO/9078%~15% and 784 initiator of visible light is added after to the grinding in raw material
1.0%~2.0% mixing is up to the rapid draing LED light UV curing ink-jet.
In order to further illustrate scheme provided by the present application, describe in detail below by specific embodiment：
Embodiment 1
A kind of preparation method for rapid draing LED light UV curing ink-jet that the embodiment of the present invention 1 provides, the method
Including：
Each raw material, resin 19%, trifunctional monomer TMPTA10%, Monofunctional monomers are taken by following mass percent
ACMO31%, 2- isopropyl thioxanthone 0.5%, levelling agent 0.3%, butyl ester cosolvent 15%, nano color paste 8%；It will be above-mentioned
Raw material be put into together in nano-level grinder be ground until fineness reach 0.3 nanometer or less stopping ground after raw material, grind
Control operation dimension is no more than 50 DEG C during mill；
Photoinitiator TPO/9015% and 784 initiator of visible light, 1.2% mixing is added after to the grinding in raw material
Up to the rapid draing LED light UV curing ink-jet.
Embodiment 2
A kind of preparation method for rapid draing LED light UV curing ink-jet that the embodiment of the present invention 2 provides, the method
Including：
Each raw material, resin 20%, trifunctional monomer TMPTA10%, Monofunctional monomers are taken by following mass percent
ACMO30%, 2- isopropyl thioxanthone 0.5%, levelling agent 0.3%, butyl ester cosolvent 16%, nano color paste 6%；It will be above-mentioned
Raw material be put into together in nano-level grinder be ground until fineness reach 0.3 nanometer or less stopping ground after raw material, grind
Control operation dimension is no more than 50 DEG C during mill；
Photoinitiator TPO/9016% and 784 initiator of visible light, 1.2% mixing is added after to the grinding in raw material
Up to the rapid draing LED light UV curing ink-jet.
In short, rapid draing LED light UV curing ink-jet provided by the present application, may be implemented rapid draing solidification and (does not have to add
Heat only needs the irradiations such as LED), production efficiency is high, can be printed in cambered surface and (can be irradiated to LED light), the pattern printed out
Three-dimensional sense is strong.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the scope of the present invention.It is all
Any modification, equivalent replacement, improvement and so within the spirit and principles in the present invention, are all contained in protection scope of the present invention
It is interior.
Claims (6)
1. a kind of rapid draing LED light UV curing ink-jet, which is characterized in that include the raw material of following mass percent：
Resin 18%~25%, trifunctional monomer TMPTA5%~15%, Monofunctional monomers' ACMO25%~35%, photoinitiator
TPO/90 78%~15%, 784 initiator 1.0%~2.0% of visible light, 2- isopropyl thioxanthones 0.5%~2.0%, levelling agent
0.2%~0.5%, butyl ester cosolvent 15%~25%, nano color paste 5%~10%；Wherein, the resin is aliphatic carbamate
Acrylic resin, the aliphatic carbamate acrylic resin index parameter include：Functional group is 3, glass transition temperature TG
It is 600~1200 for 35 DEG C, molecular weight, viscosity is 800~1500/25 DEG C.
2. rapid draing LED light UV curing ink-jet according to claim 1, which is characterized in that including following quality percentage
The raw material of ratio：
It is resin 19%, trifunctional monomer TMPTA10%, Monofunctional monomers ACMO31%, photoinitiator TPO/90 15%, visible
784 initiator 1.2% of light, 2- isopropyl thioxanthones 0.5%, levelling agent 0.3%, butyl ester cosolvent 15%, nano color paste 8%.
3. rapid draing LED light UV curing ink-jet according to claim 1, which is characterized in that including following quality percentage
The raw material of ratio：
It is resin 20%, trifunctional monomer TMPTA10%, Monofunctional monomers ACMO30%, photoinitiator TPO/90 16%, visible
784 initiator 1.2% of light, 2- isopropyl thioxanthones 0.5%, levelling agent 0.3%, butyl ester cosolvent 16%, nano color paste 6%.
4. rapid draing LED light UV curing ink-jet according to claim 1, which is characterized in that the visible light 784 causes
Agent includes bis- fluoro- 3- pyrroles's phenyl titanocenes of double 2,6-.
5. the preparation method of rapid draing LED light UV curing ink-jet, feature described in a kind of Claims 1-4 any one exist
In, the method includes：Each raw material is taken by following mass percent, resin 18%~25%, trifunctional monomer TMPTA5%~
15%, Monofunctional monomers' ACMO25%~35%, 2- isopropyl thioxanthones 0.5%~2.0%, levelling agent 0.2%~0.5%, butyl ester
Cosolvent 15%~25% and nano color paste 5%~10%；Above-mentioned raw materials are put into together in nano-level grinder be ground until
Fineness reaches 0.3 nanometer or less and stops raw material after being ground, and control operation dimension is no more than 45~55 DEG C in process of lapping；To
Photoinitiator TPO/90 78%~15% and 784 initiator of visible light, 1.0%~2.0% mixing is added after the grinding in raw material
Up to the rapid draing LED light UV curing ink-jet.
6. according to the method described in claim 5, it is characterized in that, control operation dimension is no more than 50 in the process of lapping
℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810288356.8A CN108641478A (en) | 2018-04-03 | 2018-04-03 | A kind of rapid draing LED light UV curing ink-jet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810288356.8A CN108641478A (en) | 2018-04-03 | 2018-04-03 | A kind of rapid draing LED light UV curing ink-jet and preparation method thereof |
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|---|---|
| CN108641478A true CN108641478A (en) | 2018-10-12 |
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| CN201810288356.8A Pending CN108641478A (en) | 2018-04-03 | 2018-04-03 | A kind of rapid draing LED light UV curing ink-jet and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110511667A (en) * | 2019-10-12 | 2019-11-29 | 无锡阿尔梅新材料有限公司 | A kind of LED UV solidification permanent anti-static stiffened coating for TAC film |
| CN110642525A (en) * | 2019-08-29 | 2020-01-03 | 珠海北玻电子玻璃有限公司 | Preparation method of toughened glass assembly and toughened glass assembly |
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| CN102925027A (en) * | 2012-11-15 | 2013-02-13 | 深圳市深赛尔股份有限公司 | UV (ultraviolet) duct gloss oil |
| CN105153810A (en) * | 2015-09-21 | 2015-12-16 | 珠海诚威电子有限公司 | Flexible LED-UV jet ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110642525A (en) * | 2019-08-29 | 2020-01-03 | 珠海北玻电子玻璃有限公司 | Preparation method of toughened glass assembly and toughened glass assembly |
| CN110511667A (en) * | 2019-10-12 | 2019-11-29 | 无锡阿尔梅新材料有限公司 | A kind of LED UV solidification permanent anti-static stiffened coating for TAC film |
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Application publication date: 20181012 |