CN108641449A - A kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions - Google Patents
A kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions Download PDFInfo
- Publication number
- CN108641449A CN108641449A CN201810534310.XA CN201810534310A CN108641449A CN 108641449 A CN108641449 A CN 108641449A CN 201810534310 A CN201810534310 A CN 201810534310A CN 108641449 A CN108641449 A CN 108641449A
- Authority
- CN
- China
- Prior art keywords
- parts
- silica
- antibacterial
- environmental protection
- coating material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
- C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Abstract
The present invention provides a kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions, is related to technical field of coatings, includes the component of following parts by weight：40 60 parts of lotion, 4 12 parts of pigment, 20 35 parts of filler, 10 20 parts of bamboo charcoal powder, 26 parts of Ag-carried antibacterial silica, 48 parts of Silica-coated titanium oxide powder, 13 parts of zinc oxide, 0.2 0.6 parts of cerium oxide, 4 10 parts of auxiliary agent, 100 150 parts of deionized water, the present invention also have good antibacterial and deodorization functions on the basis of low VOC, low formaldehyde.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of environmental protection coating material and its system with antibacterial and deodorization functions
Preparation Method.
Background technology
Finishing coating used is widely used, usage amount is big, still, since chemical synthesis substance is too many, especially formaldehyde,
Serious pollution air, even results in user and disease occurs.As people's living standard improves, the requirement to coating is also increasingly
Height also has more and more users' selection to use environmental protection coating material, and environmental protection coating material refers to the performance indicator of coating products, safety index
Under the premise of meeting respective product standard, while the coating products that the technology for meeting the proposition of National Environmental famous special product requires,
Currently, the requirement for environmental protection coating material is not limited only to low VOC, low formaldehyde, also to have the function of antibacterial and deodorization etc..
Invention content
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of environmental protection coating materials and its system with antibacterial and deodorization functions
Preparation Method also has good antibacterial and deodorization functions on the basis of low VOC, low formaldehyde.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：40-60 parts of lotion, face
4-12 parts of material, 20-35 parts of filler, 10-20 parts of bamboo charcoal powder, 2-6 parts of Ag-carried antibacterial silica, Silica-coated titanium oxide powder
4-8 parts of body, 1-3 parts of zinc oxide, 0.2-0.6 parts of cerium oxide, 4-10 parts of auxiliary agent, 100-150 parts of deionized water.
Preferably, include the component of following parts by weight：45-55 parts of lotion, 6-10 parts of pigment, 25-30 parts of filler, bamboo charcoal powder
12-18 parts, 2.5-4.5 parts of Ag-carried antibacterial silica, 4.5-6.5 parts of Silica-coated titanium oxide powder, zinc oxide 1.5-
2.5 parts, 0.3-0.5 parts of cerium oxide, 5-8 parts of auxiliary agent, 110-140 parts of deionized water.
Preferably, include the component of following parts by weight：50 parts of lotion, 26 parts of filler, 15 parts of bamboo charcoal powder, carries silver at 8 parts of pigment
4 parts of antibacterial silica, 5 parts of Silica-coated titanium oxide powder, 2 parts of zinc oxide, 0.4 part of cerium oxide, 6 parts of auxiliary agent, go from
120 parts of sub- water.
Preferably, include the component of following parts by weight：48 parts of lotion, 28 parts of filler, 16 parts of bamboo charcoal powder, carries silver at 7 parts of pigment
3.5 parts of antibacterial silica, 6 parts of Silica-coated titanium oxide powder, 2.4 parts of zinc oxide, 0.35 part of cerium oxide, 7 parts of auxiliary agent,
130 parts of deionized water.
Preferably, the lotion is appointing in acrylic emulsion, aqueous alkide resin emulsion, styrene-acrylic emulsion, silicone acrylic emulsion
Meaning is a kind of.
Preferably, it is 1 that the filler, which is weight ratio,:1 kaolin and precipitated calcium carbonate mixture.
Preferably, the preparation method of the Ag-carried antibacterial silica is：It is molten that silver nitrate is added dropwise into porous silica
Liquid is warming up to 40-60 DEG C, shakes filtering, washing, drying, 560-565 DEG C of sintering after 2-4h, after cooling, grinding.
Preferably, which is characterized in that a concentration of 0.3-0.6mol/L of the silver nitrate solution.
Preferably, the preparation method of the Silica-coated titanium oxide powder is：It is added into titanium sulfate solution porous
Silica is added with stirring ammonium hydroxide, is warming up to 40-50 DEG C, continues to filter after stirring 20-40min, be dried after washing, 500-
510 DEG C of sintering, after cooling, grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 60-80min, grinding obtains slurry, slurry is injected in paint mixing tank, moderate-speed mixer
Lower addition lotion, is then at the uniform velocity added auxiliary agent, continues to stir 30-40min.
(3) advantageous effect
The present invention provides a kind of environmental protection coating materials and preparation method thereof with antibacterial and deodorization functions, have beneficial below
Effect：
Ag-carried antibacterial silica and Silica-coated titanium oxide powder are added in environmental protection coating material of the present invention to be had very well
Antibacterial, bactericidal effect, under the catalytic action of cerium oxide, zinc oxide has good deodorizing effect, Er Qiejing at room temperature
Detection and experiment are crossed, the performance indicator of environmental protection coating material product of the present invention, safety index meet GB/T9756-2001 standards, have
Have a wide range of applications.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, shall fall within the protection scope of the present invention.
Embodiment 1：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：48 parts of acrylic emulsion,
7 parts of pigment, weight ratio 1:1 kaolin and 28 parts of precipitated calcium carbonate mixture, 16 parts of bamboo charcoal powder, Ag-carried antibacterial silica
3.5 parts, 6 parts of Silica-coated titanium oxide powder, 2.4 parts of zinc oxide, 0.35 part of cerium oxide, 7 parts of auxiliary agent, deionized water 130
Part.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.5mol/L's into porous silica
Silver nitrate solution is warming up to 50 DEG C, shakes filtering, washing, drying, 562 DEG C of sintering after 3h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 45 DEG C, continues to filter after stirring 30min, be dried after washing, 505 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 70min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 35min.
Embodiment 2：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：Aqueous alkide resin breast
50 parts of liquid, 8 parts of pigment, 26 parts of filler, 15 parts of bamboo charcoal powder, 4 parts of Ag-carried antibacterial silica, Silica-coated titanium oxide powder
5 parts, 2 parts of zinc oxide, 0.4 part of cerium oxide, 6 parts of auxiliary agent, 120 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.3mol/L's into porous silica
Silver nitrate solution is warming up to 55 DEG C, shakes filtering, washing, drying, 560 DEG C of sintering after 4h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 42 DEG C, continues to filter after stirring 25min, be dried after washing, 503 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 75min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 30min.
Embodiment 3：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：45 parts of styrene-acrylic emulsion, face
Material 6 parts, 25 parts of filler, 12 parts of bamboo charcoal powder, 2.5 parts of Ag-carried antibacterial silica, 4.5 parts of Silica-coated titanium oxide powder,
1.5 parts of zinc oxide, 0.3 part of cerium oxide, 5 parts of auxiliary agent, 110 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.6mol/L's into porous silica
Silver nitrate solution is warming up to 40 DEG C, shakes filtering, washing, drying, 560 DEG C of sintering after 2.2h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 50 DEG C, continues to filter after stirring 35min, be dried after washing, 510 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 70min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 40min.
Embodiment 4：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：55 parts of silicone acrylic emulsion, face
Material 10 parts, 30 parts of filler, 18 parts of bamboo charcoal powder, 4.5 parts of Ag-carried antibacterial silica, 6.5 parts of Silica-coated titanium oxide powder,
2.5 parts of zinc oxide, 0.5 part of cerium oxide, 8 parts of auxiliary agent, 140 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.3mol/L's into porous silica
Silver nitrate solution is warming up to 40 DEG C, shakes filtering, washing, drying, 560 DEG C of sintering after 2h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 40 DEG C, continues to filter after stirring 20min, be dried after washing, 500 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 60min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 30min.
Embodiment 5：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：40 parts of acrylic emulsion,
4 parts of pigment, 20 parts of filler, 10 parts of bamboo charcoal powder, 2 parts of Ag-carried antibacterial silica, 4 parts of Silica-coated titanium oxide powder, oxygen
Change 1 part of zinc, 0.2 part of cerium oxide, 4 parts of auxiliary agent, 100 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.6mol/L's into porous silica
Silver nitrate solution is warming up to 60 DEG C, shakes filtering, washing, drying, 565 DEG C of sintering after 4h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 50 DEG C, continues to filter after stirring 40min, be dried after washing, 510 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 80min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 40min.
Embodiment 6：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：Aqueous alkide resin breast
60 parts of liquid, 12 parts of pigment, 35 parts of filler, 20 parts of bamboo charcoal powder, 6 parts of Ag-carried antibacterial silica, Silica-coated titanium oxide powder
8 parts of body, 3 parts of zinc oxide, 0.6 part of cerium oxide, 10 parts of auxiliary agent, 150 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.4mol/L's into porous silica
Silver nitrate solution is warming up to 50 DEG C, shakes filtering, washing, drying, 565 DEG C of sintering after 3h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 45 DEG C, continues to filter after stirring 40min, be dried after washing, 500 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 65min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 30min.
Embodiment 7：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：Aqueous alkide resin breast
60 parts, 4 parts of pigment, 35 parts of filler, 10 parts of bamboo charcoal powder, 6 parts of Ag-carried antibacterial silica, Silica-coated titanium oxide powder 8
Part, 3 parts of zinc oxide, 0.2 part of cerium oxide, 4 parts of auxiliary agent, 150 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.5mol/L's into porous silica
Silver nitrate solution is warming up to 40 DEG C, shakes filtering, washing, drying, 560 DEG C of sintering after 4h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 50 DEG C, continues to filter after stirring 20min, be dried after washing, 500 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 70min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 40min.
Embodiment 8：
A kind of environmental protection coating material with antibacterial and deodorization functions, includes the component of following parts by weight：60 parts of silicone acrylic emulsion, face
10 parts of material, 30 parts of filler, 20 parts of bamboo charcoal powder, 5 parts of Ag-carried antibacterial silica, 5 parts of Silica-coated titanium oxide powder, oxidation
2 parts of zinc, 0.5 part of cerium oxide, 5 parts of auxiliary agent, 100 parts of deionized water.
The preparation method of above-mentioned Ag-carried antibacterial silica is：It is added dropwise a concentration of 0.3mol/L's into porous silica
Silver nitrate solution is warming up to 50 DEG C, shakes filtering, washing, drying, 560 DEG C of sintering after 2h, after cooling, grinding.
The preparation method of above-mentioned Silica-coated titanium oxide powder is：Porous silica is added into titanium sulfate solution
Silicon is added with stirring ammonium hydroxide, is warming up to 40 DEG C, continues to filter after stirring 30min, be dried after washing, 500 DEG C of sintering, after cooling,
Grinding.
The preparation method of the above-mentioned environmental protection coating material with antibacterial and deodorization functions, preparation method are：Deionized water is added
Into Scattered Kettle, it is added with stirring pigment, filler, bamboo charcoal powder, Ag-carried antibacterial silica, Silica-coated titanium oxide powder
Body, zinc oxide, cerium oxide, after high-speed stirred 70min, grinding obtains slurry, and slurry is injected in paint mixing tank, under moderate-speed mixer plus
Enter lotion, auxiliary agent is then at the uniform velocity added, continues to stir 30min.
The properties detection of environmental protection coating material prepared by 1-3 of the embodiment of the present invention is as shown in table 1 below：
Table 1
The anti-microbial property detection of environmental protection coating material prepared by 1-3 of the embodiment of the present invention is as shown in table 2 below：
Detection method is with plate count nutrient agar, addition 1:100 lake flushing liquid 1ml, coating sample 0.1g, is stirred
It is put into incubator and is cultivated for 24 hours after mixing, taking-up counts to get clump count, is counted after being added without coating sample culture under the same conditions
The clump count that number obtains, finally calculates sterilizing rate.
Table 2
By taking triethylamine, methyl mercaptan are to represent stench as an example, illustrate the deodorization of the environmental protection coating material prepared by the embodiment of the present invention 1
Performance, with 150g/m2Ratio, the environmental protection coating material prepared by the embodiment of the present invention 1 is painted on cement plate, which is placed in
In glass container, respectively into glass container inject triethylamine, methyl mercaptan, triethylamine, methyl mercaptan a concentration of 500ppm, then
With gas Chromatographic Determination, its concentration changes with time, and the results are shown in Table 3.
Table 3：
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, it will be understood by those of ordinary skill in the art that：It still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features；And these modification or
It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.
Claims (10)
1. a kind of environmental protection coating material with antibacterial and deodorization functions, which is characterized in that include the component of following parts by weight：Lotion
40-60 parts, 4-12 parts of pigment, 20-35 parts of filler, 10-20 parts of bamboo charcoal powder, 2-6 parts of Ag-carried antibacterial silica, silica packet
Wrap up in 4-8 parts of titanium oxide powder, 1-3 parts of zinc oxide, 0.2-0.6 parts of cerium oxide, 4-10 parts of auxiliary agent, 100-150 parts of deionized water.
2. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that including following parts by weight
Component：45-55 parts of lotion, 6-10 parts of pigment, 25-30 parts of filler, 12-18 parts of bamboo charcoal powder, Ag-carried antibacterial silica 2.5-
4.5 parts, 4.5-6.5 parts of Silica-coated titanium oxide powder, 1.5-2.5 parts of zinc oxide, 0.3-0.5 parts of cerium oxide, auxiliary agent 5-8
Part, 110-140 parts of deionized water.
3. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that including following parts by weight
Component：50 parts of lotion, 8 parts of pigment, 26 parts of filler, 15 parts of bamboo charcoal powder, 4 parts of Ag-carried antibacterial silica, Silica-coated
5 parts of titanium oxide powder, 2 parts of zinc oxide, 0.4 part of cerium oxide, 6 parts of auxiliary agent, 120 parts of deionized water.
4. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that including following parts by weight
Component：48 parts of lotion, 7 parts of pigment, 28 parts of filler, 16 parts of bamboo charcoal powder, 3.5 parts of Ag-carried antibacterial silica, silica packet
Wrap up in 6 parts of titanium oxide powder, 2.4 parts of zinc oxide, 0.35 part of cerium oxide, 7 parts of auxiliary agent, 130 parts of deionized water.
5. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that the lotion is propylene
Any one in yogurt liquid, aqueous alkide resin emulsion, styrene-acrylic emulsion, silicone acrylic emulsion.
6. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that the filler is weight
Than being 1:1 kaolin and precipitated calcium carbonate mixture.
7. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that the Ag-carried antibacterial two
The preparation method of silica is：Silver nitrate solution is added dropwise into porous silica, is warming up to 40-60 DEG C, shakes mistake after 2-4h
Filter, washing, drying, 560-565 DEG C of sintering, after cooling, grinding.
8. the environmental protection coating material with antibacterial and deodorization functions as claimed in claim 7, which is characterized in that it is characterized in that, institute
State a concentration of 0.3-0.6mol/L of silver nitrate solution.
9. the environmental protection coating material with antibacterial and deodorization functions as described in claim 1, which is characterized in that the silica packet
The preparation method for wrapping up in titanium oxide powder is：Porous silica is added into titanium sulfate solution, is added with stirring ammonium hydroxide, is warming up to
40-50 DEG C, continues to filter after stirring 20-40min, be dried after washing, 500-510 DEG C of sintering, after cooling, grinding.
10. the preparation method of the environmental protection coating material as claimed in any one of claims 1-9 wherein with antibacterial and deodorization functions, special
Sign is that preparation method is：Deionized water is added in Scattered Kettle, pigment is added with stirring, filler, bamboo charcoal powder, carries silver-colored resist
Bacterium silica, Silica-coated titanium oxide powder, zinc oxide, cerium oxide, after high-speed stirred 60-80min, grinding is starched
Slurry is injected in paint mixing tank, lotion is added under moderate-speed mixer, auxiliary agent is then at the uniform velocity added by material, continues to stir 30-40min i.e.
It can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810534310.XA CN108641449A (en) | 2018-05-29 | 2018-05-29 | A kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810534310.XA CN108641449A (en) | 2018-05-29 | 2018-05-29 | A kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108641449A true CN108641449A (en) | 2018-10-12 |
Family
ID=63758774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810534310.XA Pending CN108641449A (en) | 2018-05-29 | 2018-05-29 | A kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108641449A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885580A (en) * | 2019-12-06 | 2020-03-17 | 湖南太子化工涂料有限公司 | Environment-friendly paint additive with deodorization function and preparation method thereof |
| CN115403988A (en) * | 2022-09-01 | 2022-11-29 | 林德(广东)新材料有限公司 | Formaldehyde-removing negative ion coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1459474A (en) * | 2002-05-20 | 2003-12-03 | 中国科学院理化技术研究所 | Micromesohole silicon dioxide heterocompound and its preparation method and use |
| CN1515637A (en) * | 2003-01-06 | 2004-07-28 | 上海敏涛实业发展有限公司 | Nano bacteria-killing paint |
| CN107047827A (en) * | 2017-04-13 | 2017-08-18 | 江南大学 | A kind of composite membrane for filling silicon-based nano silver-series antibacterial agent and its preparation method and application |
-
2018
- 2018-05-29 CN CN201810534310.XA patent/CN108641449A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1459474A (en) * | 2002-05-20 | 2003-12-03 | 中国科学院理化技术研究所 | Micromesohole silicon dioxide heterocompound and its preparation method and use |
| CN1515637A (en) * | 2003-01-06 | 2004-07-28 | 上海敏涛实业发展有限公司 | Nano bacteria-killing paint |
| CN107047827A (en) * | 2017-04-13 | 2017-08-18 | 江南大学 | A kind of composite membrane for filling silicon-based nano silver-series antibacterial agent and its preparation method and application |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885580A (en) * | 2019-12-06 | 2020-03-17 | 湖南太子化工涂料有限公司 | Environment-friendly paint additive with deodorization function and preparation method thereof |
| CN115403988A (en) * | 2022-09-01 | 2022-11-29 | 林德(广东)新材料有限公司 | Formaldehyde-removing negative ion coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103193444B (en) | Silicic acid mud interior wall decorating material and preparation method thereof | |
| CN105400239B (en) | A kind of preparation method of modifying super hydrophobicity silica | |
| CN101745271B (en) | Compound photocatalysis antimicrobial air filter material and preparation method thereof | |
| CN106479303A (en) | A kind of water-proof antibiotic coating | |
| CN104356793A (en) | Multiplex aldehyde-removal internal wall latex paint and preparation method thereof | |
| CN105368164A (en) | Plant ecological interior wall coating and preparation method thereof | |
| CN107090216A (en) | A kind of interior wall coating for purifying air and preparation method thereof | |
| CN108641449A (en) | A kind of environmental protection coating material and preparation method thereof with antibacterial and deodorization functions | |
| CN104987808A (en) | Environmentally friendly shell powder functional coating and preparation method therefor and uses thereof | |
| CN104497726A (en) | Sprayable diatom-based styrene-acrylic interior wall coating having humidity-regulating function and preparation method of sprayable diatom-based styrene-acrylic interior wall coating | |
| CN105086650A (en) | Environment-friendly architectural paint capable of absorbing formaldehyde and preparation method of architectural paint | |
| CN107096574A (en) | Photocatalyst formaldehyde removing composition and preparation method thereof | |
| CN104725935A (en) | Tipping paper anti-bacterial aqueous printing ink | |
| CN107629665A (en) | Physical absorption and chemical catalysis combine antibiotic paint for removing formaldehyde and preparation method thereof | |
| CN109321069A (en) | A kind of liquid shell powder paint and preparation method thereof | |
| CN110484080A (en) | A kind of interior wall water paint and preparation method thereof | |
| CN111286227B (en) | Formaldehyde removal additive for coating and application method thereof | |
| CN101148552A (en) | Micro VOC anion environmental protection inner wall paint | |
| CN106957563B (en) | A kind of coating | |
| CN103627217A (en) | Environmentally-friendly titanium type pigment and process for preparing pigment by adopting grafting bridging method | |
| CN1636459A (en) | Bordeaux mixture as nutrient protecting agent | |
| CN102531461A (en) | Negative ion inorganic dry powder coating and preparation method and construction process thereof | |
| CN109206960A (en) | A kind of conch meal interior wall air cleaning sealing wax | |
| KR20050118756A (en) | Water-based ceramic photocatalyst paint and manufacturing method thereof | |
| CN107523113A (en) | Purify antimicrobial form emulsion paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181012 |