CN108635311A - Hydrogen-rich facial mask raw material and hydrogen-rich facial mask - Google Patents

Hydrogen-rich facial mask raw material and hydrogen-rich facial mask Download PDF

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Publication number
CN108635311A
CN108635311A CN201810313838.4A CN201810313838A CN108635311A CN 108635311 A CN108635311 A CN 108635311A CN 201810313838 A CN201810313838 A CN 201810313838A CN 108635311 A CN108635311 A CN 108635311A
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China
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hydrogen
facial mask
agent
raw material
surplus
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Granted
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CN201810313838.4A
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CN108635311B (en
Inventor
邹继庆
李烨
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Dalian Shuangdi New Technology Research Institute Co Ltd
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Dalian Shuangdi New Technology Research Institute Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A61K8/987Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P29/00Non-central analgesic, antipyretic or antiinflammatory agents, e.g. antirheumatic agents; Non-steroidal antiinflammatory drugs [NSAID]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P39/00General protective or antinoxious agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/004Aftersun preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/08Anti-ageing preparations

Abstract

The hydrogen-rich facial mask generated the present invention relates to a kind of hydrogen-rich facial mask raw material and with the raw material, belongs to cosmetic technical field.The raw material includes containing 10 40% sodium bicarbonates, 1 5% calcium salt, 0.1 10% hydrolysis coral, the A agent of surplus hydrolytic collagen and B agent containing 25 40% moisturizer, 0.1 0.5% citric acid, 0.001 1% catalyst, 0.001 0.1% preservative, balance deionized water;The facial mask can be by carrying out mixing generation the raw material with any existing mask matrix material.The facial mask hydrogen content that is generated using the raw material is higher, the holding time is lasting, to have better anti-inflammatory, radioresistance and uvioresistant effect, and effectively realize that repair radiation and ultraviolet light damages caused by skin, the effect of can promoting fibrocyte collage synthesis simultaneously, remove free radical and inhibit horn cell dead, and then reaching the crease-resistant anti-aging of beauty Eradicates acnes.

Description

Hydrogen-rich facial mask raw material and hydrogen-rich facial mask
Technical field
The facial mask generated the present invention relates to a kind of facial mask raw material and with the raw material, belongs to cosmetic technical field.
Background technology
Hydrogen has superpower penetration capacity as a kind of novel, excellent antioxidant, it is believed that being capable of delaying skin Aging, removal color spot, toxin-expelling and face nourishing.
Hydrogen molecule is as a kind of safe antioxidant, based on anti-oxidant, derives anti-inflammatory response, anti-cell The effects such as apoptosis and meronecrosis are not in any apparent ill effect while generating these effects.It is anti-oxidant with other Substance can only enter specific region difference, and the diffusivity of hydrogen is huge, and penetrability is strong, can enter body and any area of cell Domain plays antiopxidant effect.For beautifying skin can delay skin aging, anti-oxidant, anti-inflammatory, crease-resistant, beautifying face and moistering lotion.Hydrogen It is of great significance in the application of cosmetic field.
Though hydrogen has a related patents report in cosmetic mask field at present, Shortcomings, such as publicity patented technology The gel mask patent No. CN201610693705 containing hydrogen directly added using physical method using in facial mask The method of hydrogen.This patent disadvantage has three:First, hydrogen solubility is extremely low, density of hydrogen is saturated in 20 DEG C water of normal pressure It is difficult to realize to add hydrogen in facial mask liquid by 813umol/L;Second is that the penetrability due to hydrogen is extremely strong, hydrogen cannot in facial mask It is permanent to preserve;Third, hydrogen content cannot measure in the gel mask containing hydrogen, lack hydrogen content data according to.
Invention content
The technical problem to be solved in the invention is:Content height and resistance to Kubo are obtained in the facial mask used in real time in life The hydrogen deposited.
The present invention proposes that the first technical solution is as follows to solve above-mentioned technical problem:
A kind of raw material for generating hydrogen-rich facial mask, including A agent and B agent,
The A agent, including following weight percent composition:
Sodium bicarbonate 10-40%
Calcium salt 1-5%
Hydrolyze coral 0.1-10%
Surplus is hydrolytic collagen
The B agent, includes the raw material components of following weight percent:
Moisturizer 25-40%
Citric acid 0.1-0.5%
Catalyst 0.001-1%
Preservative 0.001-0.1%
Surplus is deionized water.
The present invention proposes that the second technical solution is as follows to solve above-mentioned technical problem:A kind of hydrogen-rich facial mask, it is characterised in that: The raw material of above-mentioned first technical solution carries out mixing generation with any existing mask matrix material.
1)Can be the C agent containing following weight percent composition for existing mask matrix material:
Moisturizer 5.5-55%
Hydrolyze avenin 1-10%
- 1 0.1-10% of palmityl triplet
Marine algae extract 0.1-10%
Aromatic 0.001-1%
Ribonucleic acid 2-5%
Preservative 0.001-5%
Surplus is deionized water;
Above-mentioned hydrogen-rich facial mask is through the A agent, B agent and C agent by weight 1:8-18:Following weight percent is generated after 1-11 mixing Component:
Sodium salt 0.5-5%
Calcium salt 0.03-0.4%
Hydrogen 0.05-0.2%
Carbon dioxide 0.04-0.24%
Preservative 0.03-2.5%
Hydrolyze coral 0.01-0.4%
Hydrolytic collagen 2-6%
Moisturizer 18-48%
Aromatic 0.0002-0.5%
Hydrolyze avenin 0.3-4.5%
- 1 0.01-3.5 % of palmityl triplet
Marine algae extract 0.05-2.5%
Ribonucleic acid 0.4-1.4%
Oxygen 0.4-1.6%
Catalyst 0.001-0.7%
Surplus is deionized water.
2)For existing mask matrix material, the D agent containing following weight percent composition can also be:
Hydroxyethyl cellulose 5-15%
Moisturizer 12-45%
Preservative 0.1-0.5%
Surplus is deionized water;
Above-mentioned hydrogen-rich facial mask presses 1 through the A agent, B agent and D agent:8-18:Following weight percent composition is generated after 1-11 mixing:
Sodium salt 0.5-5%
Calcium salt 0.03-0.4%
Moisturizer 15-40%
Hydrogen 0.05-0.2%
Carbon dioxide 0.04-0.24%
Preservative 0.08-0.2%
Hydrolyze coral 0.01-0.4%
Hydrolytic collagen 2-6%
Oxygen 0.4-1.6%
Catalyst 0.001-0.7%
Tocopherol(Vitamin E)1-16%
Hydroxyethyl cellulose 0.5-6%
Surplus is deionized water.
3) for existing mask matrix material, it can also be the E agent containing following weight percent composition:
Moisturizer 10-35%
Carbomer 1-17%
Triethanolamine 0.2-10%
Xanthans 0.5-5%
Hydroxyethyl cellulose 2-7%
Preservative 0.1-0.5%
Surplus is deionized water;
Above-mentioned hydrogen-rich facial mask presses 1 through the A agent, B agent and E agent:8-18:It is generated after 1-11 mixing as follows
Weight percent composition:
Sodium salt 0.5-5%
Calcium salt 0.03-0.4%
Hydrogen 0.05-0.2%
Carbon dioxide 0.04-0.24%
Preservative 0.08-0.2%
Hydrolyze coral 0.01-0.4%
Hydrolytic collagen 2-6%
Moisturizer 15-40%
Oxygen 0.4-1.6%
Catalyst 0.001-0.7%
Carbomer 0.7-3%
Triethanolamine 0.1-5%
Xanthans 0.1-3%
Hydroxyethyl cellulose 0.3-3.5%
Surplus is deionized water.
In above-mentioned first technical solution:
The catalyst be selected from nano aluminum and its oxide, Platinum Nanoparticles and its oxide, nanometer Cu and its oxides, nano silver and Its oxide, Technique of Nano Pd and its oxide, nanometer rhodium and its oxide, nanometer ruthenium and its oxide it is one or more.
The calcium salt is selected from calcium carbonate, calcium citrate, calcium lactate, calcium chloride, calcium hydroxide, calcium hydride, calcirm-fluoride, sulfuric acid It is one or more in calcium, calcium nitrate, calcium acetate.
It is sweet that the preservative is selected from iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, potassium sorbate, Phenoxyethanol, chlorobenzene It is one or more in ether, potassium sorbate, sodium benzoate, benzyl alcohol.
The moisturizer is selected from xylitol glucoside, anhydro xylitol, glycerine, 1,3-BDO, butanediol, poly- second two Alcohol, propylene glycol, hexylene glycol, xylitol, polypropylene glycol, D-sorbite it is one or more.
In above-mentioned second technical solution:
The moisturizer be selected from xylitol glucoside, anhydro xylitol, glycerine, 1,3-BDO, butanediol, polyethylene glycol, Propylene glycol, hexylene glycol, xylitol, polypropylene glycol, D-sorbite, Sodium Hyaluronate, rose wate it is one or more.
It is sweet that the preservative is selected from iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, potassium sorbate, Phenoxyethanol, chlorobenzene It is one or more in ether, potassium sorbate, sodium benzoate, benzyl alcohol.
The aromatic be selected from α-daphnone, Ergol, citronellol, cumarin, limonenes, geraniol, It is one or more in jasminolene, laurine, hydroxyl isohesyl 3- cyclohexenyl carbaldehydes, linalool, bergamot.
Compared with the especially hydrogeneous facial mask of existing facial mask, the beneficial effects of the invention are as follows:
1)Raw material provided by the invention, can be with when mix the facial mask of generation with a kind of existing any known common facial mask base-material Instant hydrogen manufacturing, so that it is guaranteed that endlessly generating hydrogen during facial mask use.
2) raw material provided by the invention generation hydrogen content in the mixing for generating facial mask is higher, the holding time is lasting, and And it can explicitly measure hydrogen content.
3)Due to being to generate hydrogen in real time, in the facial mask that the present invention generates, because hydrogen penetrability itself is by force and exclusive Anti-oxidation function, can in real time and skin contact, to have better anti-inflammatory, radioresistance and uvioresistant effect, and It effectively realizes that repair radiation and ultraviolet light damages caused by skin, while fibrocyte collage synthesis can be promoted, removed freely The effect of base and inhibiting horn cell dead, and then reaching the crease-resistant anti-aging of beauty Eradicates acnes.
Specific implementation mode
Below in conjunction with specific embodiment, the present invention will be further described.
In following embodiment, all raw materials derive from it is commercially available, wherein sodium bicarbonate derive from Chinese medicines group chemical reagent Co., Ltd;Citric acid derives from Liaoning Quan Rui reagents Co., Ltd;Magnesium carbonate derives from long-range food additives Co., Ltd.
Embodiment 1
The raw material of hydrogen-rich facial mask provided in this embodiment is as follows:
A agent, including following weight percent raw material components:
Sodium bicarbonate 39%
Calcium lactate 1.2%
Calcium carbonate 2.1%
Hydrolyze coral 0.11%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Glycerine 39%
Citric acid 0.28%
Platinum Nanoparticles 0.00125%
Methyl hydroxybenzoate 0.1%
Surplus is deionized water.
The existing facial mask base-material C agent used, includes the raw material components of following weight percent:
Rose wate 38%
Hydrolyze avenin 6%
Palmityl triplet -1 0.12%
Marine algae extract 9.5%
Glycerine 7.1%
Butanediol 1.2%
Bergamot 0.002%
Ribonucleic acid 4.7%
Iodine propilolic alcohol butyl mephenesin Carbamate 2%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material C agent according to weight ratio 1:8:1 is mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Platinum Nanoparticles/PH5-6)=2H2↑+O2
2C6H8O7+ 3CaCO3 =(C6H5O7)2Ca3+3CO2↑+3H2O
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
Sodium bicarbonate 3.61%
Sodium citrate 0.9%
Calcium citrate 0.21%
Calcium lactate 0.12%
Hydrogen 0.05%
Platinum Nanoparticles 0.001%
Carbon dioxide 0.21%
Glycerine 31.91%
Hydrolysis coral 0.011%,
Hydrolytic collagen 5.759%
Butanediol 0.12%
Bergamot 0.0002%
Rose wate 3.8%
Hydrolyze avenin 0.6%
Palmityl triplet -1 0.012%
Marine algae extract 0.95%
Ribonucleic acid 0.47%
Methyl hydroxybenzoate 0.08%
Oxygen 0.4%
Iodine propilolic alcohol butyl mephenesin Carbamate 0.2%
Surplus is deionized water.
Embodiment 2
The raw material composition of hydrogen-rich facial mask in the present embodiment is as follows
A agent, including following weight percent raw material components:
Sodium bicarbonate 25%
Calcium nitrate 0.5%
Calcium sulfate 0.6%
Hydrolyze coral 9.5%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Butanediol 30%
Palladium oxide 1%
Citric acid 0.1%
Methyl hydroxybenzoate 0.05%
Surplus is deionized water.
The existing facial mask base-material C agent used, includes the raw material components of following weight percent:
Rose wate 21%
Hydrolyze avenin 1%
Palmityl triplet -1 9%
Marine algae extract 6%
Xylitol 0.5%
Butanediol 0.5%
Coumarin 1 %
Ribonucleic acid 3%
Benzyl alcohol 0.001%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material C agent according to weight ratio 1:18:11 are mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/palladium oxide/PH5-6)=2H2↑+O2
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
Sodium bicarbonate 0.75%
Sodium citrate 0.09%
Calcium nitrate 0.017%
Calcium sulfate 0.02%
Hydrogen 0.1%
Carbon dioxide 0.04%
Methyl hydroxybenzoate 0.03%
Hydrolyze coral 0.32%
Hydrolytic collagen 2.18%
Butanediol 18.2%
Rose wate 7.7%
Hydrolyze avenin 0.37%
- 1 3.3 % of palmityl triplet
Marine algae extract 2.2%
Ribonucleic acid 1.1%
Oxygen 0.8%
Palladium oxide 0.6%
Xylitol 0.18%
Cumarin 0.37%
Benzyl alcohol 0.00036%
Surplus is deionized water.
Embodiment 3
The raw material composition of hydrogen-rich facial mask in the present embodiment is as follows
A agent, including following weight percent raw material components:
Sodium bicarbonate 11%
Calcirm-fluoride 4%
Hydrolyze coral 5%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Propylene glycol 26%
Citric acid 0.45%
Nanometer Copper 0.1%
Methyl hydroxybenzoate 0.0015%
Surplus is deionized water.
The existing facial mask base-material C agent used, includes the raw material components of following weight percent:
Rose wate 8%
Hydrolyze avenin 9%
Palmityl triplet -1 4.6%
Marine algae extract 0.2%
Butanediol 14%
Linalool 0.5%
Ribonucleic acid 2.6%
Potassium sorbate 4.5%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material C agent according to weight ratio 1:9:9 are mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
0.29 % of sodium bicarbonate
Sodium citrate 0.32%
Calcirm-fluoride 0.21%
Hydrogen 0.2%
Carbon dioxide 0.15%
Methyl hydroxybenzoate 0.0007%
Oxygen 1.6%
Hydrolyze coral 0.26%
Hydrolytic collagen 4.2%
Propylene glycol 12.3%
Butanediol 6.6%
Nanometer Copper 0.047%
Rose wate 3.8%
Hydrolyze avenin 4.3%
Palmityl triplet -1 2.2%
Marine algae extract 0.09%
Linalool 0.24%
Ribonucleic acid 1.23%
Potassium sorbate 2.1%
Surplus is deionized water.
Embodiment 4
The raw material of hydrogen-rich facial mask provided in this embodiment is as follows:
A agent, including following weight percent raw material components:
Sodium bicarbonate 39%
Calcium lactate 1.2%
Calcium carbonate 2.1%
Hydrolyze coral 0.11%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Glycerine 39%
Citric acid 0.28%
Platinum Nanoparticles 0.00125%
Methyl hydroxybenzoate 0.1%
Surplus is deionized water.
The existing facial mask base-material D agent used, includes the raw material components of following weight percent:
Tocopherol(Vitamin E)16%
Hydroxyethyl cellulose 6%
Sodium Hyaluronate 20%
Glycerine 2.5%
Methyl hydroxybenzoate 0.45%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material D agent according to weight ratio 1:8:1 is mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
2C6H8O7+ 3CaCO3 = (C6H5O7)2Ca3+3CO2↑+3H2O
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
Sodium bicarbonate 3.61%
Sodium citrate 0.9%
Calcium citrate 0.21%
Calcium lactate 0.12%
Hydrogen 0.05%
Platinum Nanoparticles 0.001%
Carbon dioxide 0.21%
Oxygen 0.4%
Glycerine 31.45%
Hydrolyze coral 0.011%
Hydrolytic collagen 5.759%
Methyl hydroxybenzoate 0.125%
Tocopherol(Vitamin E)1.6%
Sodium Hyaluronate 2%
Hydroxyethyl cellulose 0.6%
Surplus is deionized water.
Embodiment 5
The raw material composition of hydrogen-rich facial mask in the present embodiment is as follows
A agent, including following weight percent raw material components:
Sodium bicarbonate 25%
Calcium nitrate 0.5%
Calcium sulfate 0.6%
Hydrolyze coral 9%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Butanediol 31%
Palladium oxide 1%
Citric acid 0.1%
Methyl hydroxybenzoate 0.05%
Surplus is deionized water.
The existing facial mask base-material D agent used, includes the raw material components of following weight percent:
Tocopherol(Vitamin E)42%
Hydroxyethyl cellulose 14%
Sodium Hyaluronate 12%
Glycerine 9%
Methyl hydroxybenzoate 0.15%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material D agent according to weight ratio 1:18:11 are mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
Sodium bicarbonate 0.75%
Sodium citrate 0.09%
Calcium nitrate 0.017%
Calcium sulfate 0.02%
Hydrogen 0.1%
Carbon dioxide 0.04%
Methyl hydroxybenzoate 0.085%
Hydrolyze coral 0.3%
Hydrolytic collagen 2.18%
Palladium oxide 0.6%
Butanediol 18.6%
Oxygen 0.8%
Glycerine 3.3%
Tocopherol(Vitamin E)15.4%
Sodium Hyaluronate 4.4%
Hydroxyethyl cellulose 5.13%
Surplus is deionized water.
Embodiment 6
The raw material composition of hydrogen-rich facial mask in the present embodiment is as follows
A agent, including following weight percent raw material components:
Sodium bicarbonate 11%
Calcirm-fluoride 5%
Hydrolyze coral 5%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Propylene glycol 26%
Citric acid 0.45%
Nanometer Copper 0.1%
Methyl hydroxybenzoate 0.0015%
Surplus is deionized water.
The existing facial mask base-material D agent used, includes the raw material components of following weight percent:
Tocopherol(Vitamin E)26%
Hydroxyethyl cellulose 10%
Sodium Hyaluronate 29%
Glycerine 14%
Methyl hydroxybenzoate 0.3%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material D agent according to weight ratio 1:9:9 are mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
0.29 % of sodium bicarbonate
Sodium citrate 0.32%
Calcirm-fluoride 0.21%
Hydrogen 0.2%
Carbon dioxide 0.15%
Methyl hydroxybenzoate 0.14%
Oxygen 1.6%
Hydrolyze coral 0.26%
Hydrolytic collagen 4.2%
Propylene glycol 12.3%
Nanometer Copper 0.047%
Glycerine 6.63%
Tocopherol(Vitamin E)12.31%
Sodium Hyaluronate 13.73%
Hydroxyethyl cellulose 4.73%
Surplus is deionized water.
Embodiment 7
The raw material of hydrogen-rich facial mask provided in this embodiment is as follows:
A agent, including following weight percent raw material components:
Sodium bicarbonate 39%
Calcium lactate 1.2%
Calcium carbonate 2.1%
Hydrolyze coral 0.11%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Glycerine 39%
Citric acid 0.28%
Platinum Nanoparticles 0.00125%
Methyl hydroxybenzoate 0.1%
Surplus is deionized water.
The existing facial mask base-material E agent used, includes the raw material components of following weight percent:
Propylene glycol 34%
Carbomer 16%
Triethanolamine 5.3%
Xanthans 3.6%
Hydroxyethyl cellulose 4.1%
Methyl hydroxybenzoate 0.1%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material E agent according to weight ratio 1:8:1 is mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
2C6H8O7+3CaCO3=(C6H5O7)2Ca3+3CO2↑+ 3H2O
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
Sodium bicarbonate 3.61%
Sodium citrate 0.9%
Calcium 0.21%
Calcium lactate 0.12%
Hydrogen 0.05%
Platinum Nanoparticles 0.001%
Oxygen 0.4%
Carbon dioxide 0.21%
Glycerine 33.91%
Hydrolyze coral 0.011%
Hydrolytic collagen 5.759%
Propylene glycol 3.4%
Carbomer 1.6%
Triethanolamine 0.53%
Xanthans 0.36%
Hydroxyethyl cellulose 0.41%
Methyl hydroxybenzoate 0.09%
Surplus is deionized water.
Embodiment 8
The raw material composition of hydrogen-rich facial mask in the present embodiment is as follows
A agent, including following weight percent raw material components:
Sodium bicarbonate 25%
Calcium nitrate 0.5%
Calcium sulfate 0.6%
Hydrolyze coral 9.5%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Butanediol 30%
Palladium oxide 1%
Citric acid 0.1%
Methyl hydroxybenzoate 0.05%
Surplus is deionized water.
The existing facial mask base-material E agent used, includes the raw material components of following weight percent:
Propylene glycol 12%
Carbomer 7.5%
Triethanolamine 0.3%
Xanthans 0.6%
Hydroxyethyl cellulose 2.2%
Methyl hydroxybenzoate 0.45%
Surplus is deionized water.
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material E agent according to weight ratio 1:18:11 are mixed.Reaction equation and composition are as follows after mixing:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
Sodium bicarbonate 0.75%
Sodium citrate 0.09%
Calcium nitrate 0.017%
Calcium sulfate 0.02%
Hydrogen 0.1%
Palladium oxide 0.6%
Oxygen 0.8%
Carbon dioxide 0.04%
Methyl hydroxybenzoate 0.195%
Hydrolyze coral 0.32%
Hydrolytic collagen 2.18%
Propylene glycol 4.4%
Carbomer 2.75%
Triethanolamine 0.11%
Xanthans 0.22%
Hydroxyethyl cellulose 0.81%
Surplus is deionized water.
Embodiment 9
The raw material composition of hydrogen-rich facial mask in the present embodiment is as follows
A agent, including following weight percent raw material components:
Sodium bicarbonate 11%
Calcirm-fluoride 4%
Hydrolyze coral 5%
Surplus is hydrolytic collagen.
B agent includes the raw material components of following weight percent:
Propylene glycol 26%
Citric acid 0.45%
Nanometer Copper 0.1%
Methyl hydroxybenzoate 0.0015%
Surplus is deionized water.
The existing facial mask base-material E agent used, includes the raw material components of following weight percent:
Propylene glycol 15%
Carbomer 1.6%
Triethanolamine 9.2%
Xanthans 4.8%
Hydroxyethyl cellulose 6.9%
Methyl hydroxybenzoate 0.3%
Surplus is deionized water
The facial mask of the present embodiment specifically generates:By above-mentioned raw materials A agent, B agent and existing facial mask base-material E agent according to weight ratio 1:9: 9 are mixed.The reaction equation generated after mixing is as follows:
3NaHCO3+C6H8O7=C6H5O7Na3+3H2O+3CO2
2H2O=(Hydrolyze coral/Nanometer Copper/PH5-6)=2H2↑+O2
The weight percent composition of the facial mask ultimately generated after mixing is as follows:
0.29 % of sodium bicarbonate
Sodium citrate 0.32%
Calcirm-fluoride 0.21%
Hydrogen 0.2%
Nanometer Copper 0.047%
Carbon dioxide 0.15%
Oxygen 1.6%
Hydrolyze coral 0.26%
Hydrolytic collagen 4.2%
Propylene glycol 19.4%
Carbomer 0.76%
Triethanolamine 4.36%
Xanthans 2.27%
Hydroxyethyl cellulose 3.27%
Methyl hydroxybenzoate 0.14%
Surplus is deionized water.
Hydrogen content and retention time measurement data in being generated to the hydrogen-rich facial mask of above-described embodiment is as follows:
Hydrogen content measures the titrimetry method that uses, and titrating solution selects the molten water element of MIZ Co., Ltd. of Japan manufacture quotient's production Concentration judges reagent.
Table 1 is the measurement data that hydrogen-rich facial mask hydrogen content changes over time, and sample one is the hydrogen-rich face that embodiment 1 generates Film liquid, sample two are the hydrogen-rich facial mask liquid of the generation of embodiment 2, sample three is the hydrogen-rich facial mask liquid of the generation of embodiment 3, sample four is The hydrogen-rich facial mask liquid of the generation of embodiment 4, sample five are the hydrogen-rich facial mask liquid of the generation of embodiment 5, sample six is what embodiment 6 generated Hydrogen-rich facial mask liquid, sample seven are the hydrogen-rich facial mask liquid of the generation of embodiment 7, sample eight is the hydrogen-rich facial mask liquid of the generation of embodiment 8, sample Product nine are the hydrogen-rich facial mask liquid that embodiment 9 generates.
1 hydrogen-rich facial mask hydrogen content of table changes with time
1 bearing reaction of table goes out hydrogen content height in hydrogen-rich facial mask, and the holding time is long, and hydrogen can measure.
Above-mentioned nine embodiments are extracted into three embodiments(Embodiment 1, embodiment 5, embodiment 9)The hydrogen-rich face of middle generation Film and " LUNA MOIST FACE MASK " hydrogen-rich facial mask of Japan's production compare, the hydrogen-rich facial mask and existing " LUNA of generation The effect of MOIST FACE MASK " hydrogen-rich facial masks, contrast experiment was as follows.
It is 30~50 years old to select 10 experiencers, 5 men and 5 Mies, age bracket, and (every night is clean within one week for continuous use Used behind face) above three embodiments and " LUNA MOIST FACE MASK " hydrogen-rich mask product, right face uses above three Mask product prepared by embodiment, left face use " LUNA MOIST FACE MASK " hydrogen-rich mask product, then according to using Impression and effect carry out comparative evaluation to facial mask properties.Main assessment is in the improvement using skin after a week, by surveying Examination person describes effect according to impression.
Evaluation project, which includes tender skin sense, comfort, moist feeling and skin after a week, improves degree, and standard is divided into A, B, C tri- A grade, A is excellent, B is good, C is general.
Specific test result is shown in Table 2
2 common facial mask of table and facial mask effect comparative evaluation containing hydrogen
2 data result of table, which reflects hydrogen-rich facial mask, to be improved in tender skin sense, comfort, moist feeling and skin after a week in degree project It is superior to Japanese " LUNA MOIST FACE MASK " mask product.
Disclosed above is only several specific embodiments, but the present invention is not limited to this, such as:1)Catalyst may be used also With one selected from nano aluminum and its oxide, nano silver and its oxide, nanometer rhodium and its oxide, nanometer ruthenium and its oxide Kind is a variety of;2)Calcium salt is also selected from one or more in calcium chloride, calcium hydroxide, calcium hydride, calcium acetate;3)Preservative It is also selected from iodine propilolic alcohol butyl mephenesin Carbamate, Phenoxyethanol, Chlorphenesin, potassium sorbate, sodium benzoate, benzyl alcohol It is one or more;4)Moisturizer is also selected from xylitol glucoside, anhydro xylitol, 1,3-BDO, polyethylene glycol, Glycol, xylitol, polypropylene glycol, D-sorbite it is one or more;5)Aromatic be also selected from α-daphnone, In Ergol, citronellol, limonenes, geraniol, jasminolene, laurine, hydroxyl isohesyl 3- cyclohexenyl carbaldehydes It is one or more;Etc..The changes that any person skilled in the art can think of should all fall into protection scope of the present invention.

Claims (8)

1. a kind of hydrogen-rich facial mask raw material, it is characterised in that including A agent and B agent,
The A agent includes following weight percent composition:
Sodium bicarbonate 10-40%
Calcium salt 1-5%
Hydrolyze coral 0.1-10%
Surplus is hydrolytic collagen;
The B agent includes following weight percent composition:
Moisturizer 25-40%
Citric acid 0.1-0.5%
Catalyst 0.001-1%
Preservative 0.001-0.1%
Surplus is deionized water.
2. a kind of hydrogen-rich facial mask, it is characterised in that:Using raw material as described in claim 1 and any existing mask matrix material into Row mixing generates.
3. hydrogen-rich facial mask as claimed in claim 2, it is characterised in that:The mask matrix material is the C agent containing following component:
Moisturizer 5.5-55%
Hydrolyze avenin 1-10%
- 1 0.1-10% of palmityl triplet
Marine algae extract 0.1-10%
Aromatic 0.001-1%
Ribonucleic acid 2-5%
Preservative 0.001-5%
Surplus is deionized water;
The hydrogen-rich facial mask is through the A agent, B agent and C agent by weight 1:8-18:Following weight percent is generated after 1-11 mixing Component:
Sodium salt 0.5-5%
Calcium salt 0.03-0.4%
Hydrogen 0.05-0.2%
Carbon dioxide 0.04-0.24%
Preservative 0.03-2.5%
Hydrolyze coral 0.01-0.4%
Hydrolytic collagen 2-6%
Moisturizer 18-48%
Aromatic 0.0002-0.5%
Hydrolyze avenin 0.3-4.5%
- 1 0.01-3.5 % of palmityl triplet
Marine algae extract 0.05-2.5%
Ribonucleic acid 0.4-1.4%
Oxygen 0.4-1.6%
Catalyst 0.001-0.7%
Surplus is deionized water.
4. hydrogen-rich facial mask as claimed in claim 2, it is characterised in that:The mask matrix material contains following component
D agent:
Tocopherol(Vitamin E)15-45%
Hydroxyethyl cellulose 5-15%
Moisturizer 12-45%
Preservative 0.1-0.5%
Surplus is deionized water;
The hydrogen-rich facial mask presses 1 through the A agent, B agent and D agent:8-18:Following weight percent composition is generated after 1-11 mixing:
Sodium salt 0.5-5%
Calcium salt 0.03-0.4%
Moisturizer 15-40%
Hydrogen 0.05-0.2%
Carbon dioxide 0.04-0.24%
Preservative 0.08-0.2%
Hydrolyze coral 0.01-0.4%
Hydrolytic collagen 2-6%
Oxygen 0.4-1.6%
Catalyst 0.001-0.7%
Tocopherol(Vitamin E)1-16%
Hydroxyethyl cellulose 0.5-6%
Surplus is deionized water.
5. hydrogen-rich facial mask as claimed in claim 2, it is characterised in that:The mask matrix material contains following component
E agent:
Moisturizer 10-35%
Carbomer 1-17%
Triethanolamine 0.2-10%
Xanthans 0.5-5%
Hydroxyethyl cellulose 2-7%
Preservative 0.1-0.5%
Surplus is deionized water;
The hydrogen-rich facial mask presses 1 through the A agent, B agent and E agent:8-18:Following weight percent composition is generated after 1-11 mixing:
Sodium salt 0.5-5%
Calcium salt 0.03-0.4%
Hydrogen 0.05-0.2%
Carbon dioxide 0.04-0.24%
Preservative 0.08-0.2%
Hydrolyze coral 0.01-0.4%
Hydrolytic collagen 2-6%
Moisturizer 15-40%
Oxygen 0.4-1.6%
Catalyst 0.001-0.7%
Carbomer 0.7-3%
Triethanolamine 0.1-5%
Xanthans 0.1-3%
Hydroxyethyl cellulose 0.3-3.5%
Surplus is deionized water.
6. hydrogen-rich facial mask raw material as described in claim 1, it is characterised in that:The catalyst is selected from nano aluminum and its oxidation Object, Platinum Nanoparticles and its oxide, nanometer Cu and its oxides, nano silver and its oxide, Technique of Nano Pd and its oxide, nanometer rhodium And its oxide, nanometer ruthenium and its oxide it is one or more;
The calcium salt be selected from calcium carbonate, calcium citrate, calcium lactate, calcium chloride, calcium hydroxide, calcium hydride, calcirm-fluoride, calcium sulfate, It is one or more in calcium nitrate, calcium acetate;
The preservative is selected from iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, potassium sorbate, Phenoxyethanol, Chlorphenesin, mountain It is one or more in potassium sorbate, sodium benzoate, benzyl alcohol;
The moisturizer be selected from xylitol glucoside, anhydro xylitol, glycerine, 1,3-BDO, butanediol, polyethylene glycol, Propylene glycol, hexylene glycol, xylitol, polypropylene glycol, D-sorbite it is one or more.
7. the hydrogen-rich facial mask as described in claim 3,4 or 5, it is characterised in that:The moisturizer is selected from xylitol glucoside, takes off Water xylitol, glycerine, 1,3-BDO, butanediol, polyethylene glycol, propylene glycol, hexylene glycol, xylitol, polypropylene glycol, sorbose Alcohol, Sodium Hyaluronate, rose wate it is one or more;
The preservative is selected from iodine propilolic alcohol butyl mephenesin Carbamate, methyl hydroxybenzoate, potassium sorbate, Phenoxyethanol, Chlorphenesin, mountain It is one or more in potassium sorbate, sodium benzoate, benzyl alcohol.
8. hydrogen-rich facial mask as claimed in claim 3, it is characterised in that:The aromatic is selected from α-daphnone, benzene first Acid benzyl ester, citronellol, cumarin, limonenes, geraniol, jasminolene, laurine, hydroxyl isohesyl 3- cyclohexenyl group first It is one or more in aldehyde, linalool, bergamot.
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