CN108625156A - 一种抗紫外线及抗电磁辐射多功能纺织品的制备方法 - Google Patents
一种抗紫外线及抗电磁辐射多功能纺织品的制备方法 Download PDFInfo
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Abstract
本发明公开了一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，首先制备抗紫外线及抗电磁辐射整理剂，之后将纺织品基布用抗紫外线及抗电磁辐射整理剂整理后得到；其中，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛5‑8份、纳米氧化锆3‑4份、纳米银微粒3‑4份、壳聚糖5‑6份、富勒烯纳米碳材料6‑8份、聚二甲基硅氧烷5‑6份、改性聚硅氧烷3‑4份、甲苯8‑10份、有机硅乳液1‑2份、烷基酚聚乙烯醚2‑4份、乙二醇单丁醚2‑3份、甘油4‑5份；韧性、强度、手感基本不受影响，抗紫外线性能优秀，抗电磁辐射性能优秀。
Description
技术领域
本发明涉及纺织用助剂领域，尤其是一种抗紫外线及抗电磁辐射多功能纺织品的制备方法。
背景技术
紫外线在日光中约占6％。适量的紫外线辐射具有杀菌作用并能促进维生素D的合成，有利于人体健康。但UV-A会透过表皮组织，使肌肉失去弹性，皮肤粗糙，形成皱纹，UV-B则和致癌物质有联系。抗紫外线纺织品是对紫外线有较强的吸收和反射能力的纺织品。随着科学技术的发展，电磁波辐射对人们生活和工作的影响越来越大。CN104047173A公开了一种永久性防电磁辐射织物，可以有效屏蔽电磁波，屏蔽性能好，但是其与织物的结合牢度差，且会影响织物的柔软性，耐腐蚀性能差。因此，目前对既能抗紫外线、又具有抗电磁辐射性能的多功能涂层织物整理剂在使用后，有的抗紫外线性能不佳，有的虽然具备抗紫外线和抗电磁辐射性能，但是织物的韧性、强度或手感和处理前相差较多。因此，需要一种新的抗紫外线及抗电磁辐射的多功能纺织品，既能保证抗紫外线和抗电磁辐射性能，同时纺织品的韧性、强度和手感保持稳定。
发明内容
本发明的目的在于提供一种抗紫外线及抗电磁辐射多功能纺织品的制备方法。
为实现上述目的，本发明采用以下内容：
一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，首先制备抗紫外线及抗电磁辐射整理剂，之后将纺织品基布用抗紫外线及抗电磁辐射整理剂整理后得到；其中，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛5-8份、纳米氧化锆3-4份、纳米银微粒3-4份、壳聚糖5-6份、富勒烯纳米碳材料6-8份、聚二甲基硅氧烷5-6份、改性聚硅氧烷3-4份、甲苯8-10份、有机硅乳液1-2份、烷基酚聚乙烯醚2-4份、乙二醇单丁醚2-3份、甘油4-5份。
进一步地，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛5-6份、纳米氧化锆3-4份、纳米银微粒3-4份、壳聚糖5-6份、富勒烯纳米碳材料6-8份、聚二甲基硅氧烷5-6份、改性聚硅氧烷3-4份、甲苯8-9份、有机硅乳液1-2份、烷基酚聚乙烯醚2-3份、乙二醇单丁醚2-3份、甘油4-5份。
进一步地，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛6份、纳米氧化锆4份、纳米银微粒4份、壳聚糖6份、富勒烯纳米碳材料6份、聚二甲基硅氧烷5份、改性聚硅氧烷3份、甲苯8份、有机硅乳液1份、烷基酚聚乙烯醚2份、乙二醇单丁醚2份、甘油4份。
进一步地，所述整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，之后将纺织品基布浸渍整理后得到。
进一步地，所述浸渍整理是浸渍两次后烘干。
进一步地，所述浸渍整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍25-30min；之后将浸渍体系抽取至负压，真空度为0.04-0.05MPa，浸渍10-15min；然后在65-67℃烘干1-1.5小时，再在室温静置22-24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
进一步地，所述浸渍整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍25-28min；之后将浸渍体系抽取至负压，真空度为0.045-0.05MPa，浸渍10-12min；然后在65-66℃烘干1-1.5小时，再在室温静置22-24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
进一步地，所述浸渍整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍26min；之后将浸渍体系抽取至负压，真空度为0.045MPa，浸渍12min；然后在66℃烘干1.2小时，再在室温静置24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
本发明具有以下优点：
本发明的抗紫外线及抗电磁辐射多功能纺织品的制备方法原料价格低廉，易获得，对人体不刺激，工艺简单；得到的抗紫外线及抗电磁辐射多功能纺织品的韧性、强度、手感基本不受影响，抗紫外线性能优秀，耐水洗，抗电磁辐射性能优秀。
具体实施方式
为了更清楚地说明本发明，下面结合优选实施例对本发明做进一步的说明。本领域技术人员应当理解，下面所具体描述的内容是说明性的而非限制性的，不应以此限制本发明的保护范围。
实施例1
一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，首先制备抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛6份、纳米氧化锆4份、纳米银微粒4份、壳聚糖6份、富勒烯纳米碳材料6份、聚二甲基硅氧烷5份、改性聚硅氧烷3份、甲苯8份、有机硅乳液1份、烷基酚聚乙烯醚2份、乙二醇单丁醚2份、甘油4份，通过将各原料混合分散制得。之后，将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍26min；之后将浸渍体系抽取至负压，真空度为0.045MPa，浸渍12min；然后在66℃烘干1.2小时，再在室温静置24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
对手感和韧性、强度进行测试，发现：实施例1得到的抗紫外线及抗电磁辐射多功能纺织品的韧性、强度、手感基本不受影响。
抗紫外线性能测试：取实施例1得到的抗紫外线及抗电磁辐射多功能纺织品样品，洗涤50次后进行抗紫外线性能测试评价。抗紫外线性能测试依据标准GB/T18830-2009《纺织品防紫外线性能的评定》，已达到防紫外线产品标准，具有优异的防紫外线功能。
抗电磁辐射性能测试：取实施例1得到的抗紫外线及抗电磁辐射多功能纺织品样品，洗涤50次后进行抗电磁辐射性能测试评价。依据标准GB/T 26383-2011《抗电磁辐射精梳毛织品》的方法测定，屏蔽效能为75.3dB，该纺织品的电磁屏蔽性能优异。
实施例2
一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，首先制备抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛5份、纳米氧化锆3份、纳米银微粒3份、壳聚糖5份、富勒烯纳米碳材料8份、聚二甲基硅氧烷6份、改性聚硅氧烷4份、甲苯8份、有机硅乳液1份、烷基酚聚乙烯醚2份、乙二醇单丁醚2份、甘油5份，通过将各原料混合分散制得。之后，将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍25min；之后将浸渍体系抽取至负压，真空度为0.04MPa，浸渍10min；然后在65℃烘干1.5小时，再在室温静置22小时，制得抗紫外线及抗电磁辐射多功能纺织品。
对手感和韧性、强度进行测试，发现：实施例2得到的抗紫外线及抗电磁辐射多功能纺织品的韧性、强度、手感基本不受影响。
抗紫外线性能测试：取实施例2得到的抗紫外线及抗电磁辐射多功能纺织品样品，洗涤40次后进行抗紫外线性能测试评价。抗紫外线性能测试依据标准GB/T18830-2009《纺织品防紫外线性能的评定》，已达到防紫外线产品标准，具有优异的防紫外线功能。
抗电磁辐射性能测试：取实施例2得到的抗紫外线及抗电磁辐射多功能纺织品样品，洗涤40次后进行抗电磁辐射性能测试评价。依据标准GB/T 26383-2011《抗电磁辐射精梳毛织品》的方法测定，屏蔽效能为74.5dB，该纺织品的电磁屏蔽性能优异。
实施例3
一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，首先制备抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛8份、纳米氧化锆4份、纳米银微粒4份、壳聚糖6份、富勒烯纳米碳材料6份、聚二甲基硅氧烷5份、改性聚硅氧烷3份、甲苯10份、有机硅乳液2份、烷基酚聚乙烯醚4份、乙二醇单丁醚3份、甘油5份，通过将各原料混合分散制得。之后，将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍30min；之后将浸渍体系抽取至负压，真空度为0.05MPa，浸渍15min；然后在67℃烘干1小时，再在室温静置23小时，制得抗紫外线及抗电磁辐射多功能纺织品。
对手感和韧性、强度进行测试，发现：实施例3得到的抗紫外线及抗电磁辐射多功能纺织品的韧性、强度、手感基本不受影响。
抗紫外线性能测试：取实施例3得到的抗紫外线及抗电磁辐射多功能纺织品样品，洗涤30次后进行抗紫外线性能测试评价。抗紫外线性能测试依据标准GB/T18830-2009《纺织品防紫外线性能的评定》，已达到防紫外线产品标准，具有优异的防紫外线功能。
抗电磁辐射性能测试：取实施例3得到的抗紫外线及抗电磁辐射多功能纺织品样品，洗涤30次后进行抗电磁辐射性能测试评价。依据标准GB/T 26383-2011《抗电磁辐射精梳毛织品》的方法测定，屏蔽效能为74.0dB，该纺织品的电磁屏蔽性能优异。
对比例
本发明使用纳米二氧化钛、纳米氧化锆、纳米银微粒、壳聚糖、富勒烯纳米碳材料等多种组分，各个组分之间相互作用，制造简单，原料价格低廉，易获得。本发明的抗紫外线及抗电磁辐射多功能纺织品的制备方法原料价格低廉，易获得，对人体不刺激，工艺简单；得到的抗紫外线及抗电磁辐射多功能纺织品的韧性、强度、手感基本不受影响，抗紫外线性能优秀，耐水洗，抗电磁辐射性能优秀。
显然，本发明的上述实施例仅仅是为清楚地说明本发明所作的举例，而并非是对本发明的实施方式的限定，对于所属领域的普通技术人员来说，在上述说明的基础上还可以做出其它不同形式的变化或变动，这里无法对所有的实施方式予以穷举，凡是属于本发明的技术方案所引伸出的显而易见的变化或变动仍处于本发明的保护范围之列。
Claims (8)
1.一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，首先制备抗紫外线及抗电磁辐射整理剂，之后将纺织品基布用抗紫外线及抗电磁辐射整理剂整理后得到；其中，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛5-8份、纳米氧化锆3-4份、纳米银微粒3-4份、壳聚糖5-6份、富勒烯纳米碳材料6-8份、聚二甲基硅氧烷5-6份、改性聚硅氧烷3-4份、甲苯8-10份、有机硅乳液1-2份、烷基酚聚乙烯醚2-4份、乙二醇单丁醚2-3份、甘油4-5份。
2.根据权利要求1所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛5-6份、纳米氧化锆3-4份、纳米银微粒3-4份、壳聚糖5-6份、富勒烯纳米碳材料6-8份、聚二甲基硅氧烷5-6份、改性聚硅氧烷3-4份、甲苯8-9份、有机硅乳液1-2份、烷基酚聚乙烯醚2-3份、乙二醇单丁醚2-3份、甘油4-5份。
3.根据权利要求2所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述抗紫外线及抗电磁辐射整理剂，按重量份数计，包括以下组分：纳米二氧化钛6份、纳米氧化锆4份、纳米银微粒4份、壳聚糖6份、富勒烯纳米碳材料6份、聚二甲基硅氧烷5份、改性聚硅氧烷3份、甲苯8份、有机硅乳液1份、烷基酚聚乙烯醚2份、乙二醇单丁醚2份、甘油4份。
4.根据权利要求1所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，之后将纺织品基布浸渍整理后得到。
5.根据权利要求4所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述浸渍整理是浸渍两次后烘干。
6.根据权利要求5所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述浸渍整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍25-30min；之后将浸渍体系抽取至负压，真空度为0.04-0.05MPa，浸渍10-15min；然后在65-67℃烘干1-1.5小时，再在室温静置22-24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
7.根据权利要求6所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述浸渍整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍25-28min；之后将浸渍体系抽取至负压，真空度为0.045-0.05MPa，浸渍10-12min；然后在65-66℃烘干1-1.5小时，再在室温静置22-24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
8.根据权利要求7所述的一种抗紫外线及抗电磁辐射多功能纺织品的制备方法，其特征在于，所述浸渍整理是将抗紫外线及抗电磁辐射整理剂置于浸液槽中，将纺织品基布在室温下浸渍26min；之后将浸渍体系抽取至负压，真空度为0.045MPa，浸渍12min；然后在66℃烘干1.2小时，再在室温静置24小时，制得抗紫外线及抗电磁辐射多功能纺织品。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112376268A (zh) * | 2020-11-17 | 2021-02-19 | 徐建平 | 一种富勒烯纺织面料的制备方法和应用 |
| CN116463850A (zh) * | 2023-03-22 | 2023-07-21 | 扬州泉生源电磁技术有限公司 | 一种抗电磁辐射材料及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6037280A (en) * | 1997-03-21 | 2000-03-14 | Koala Konnection | Ultraviolet ray (UV) blocking textile containing particles |
| CN105040426A (zh) * | 2015-07-07 | 2015-11-11 | 安徽理工大学 | 抗菌保暖防电磁辐射纺织面料及其制备方法 |
| CN106835675A (zh) * | 2016-12-23 | 2017-06-13 | 句容市申兔工艺针织厂 | 一种莫代尔织物的抗菌抗起球整理工艺 |
| CN107630350A (zh) * | 2017-10-20 | 2018-01-26 | 安徽亚源印染有限公司 | 一种亚麻人棉面料专用整理剂 |
| CN107724061A (zh) * | 2017-09-30 | 2018-02-23 | 江苏新瑞贝科技股份有限公司 | 一种多功能防紫外线整理剂及其制备方法 |
-
2018
- 2018-05-16 CN CN201810468209.9A patent/CN108625156A/zh not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6037280A (en) * | 1997-03-21 | 2000-03-14 | Koala Konnection | Ultraviolet ray (UV) blocking textile containing particles |
| CN105040426A (zh) * | 2015-07-07 | 2015-11-11 | 安徽理工大学 | 抗菌保暖防电磁辐射纺织面料及其制备方法 |
| CN106835675A (zh) * | 2016-12-23 | 2017-06-13 | 句容市申兔工艺针织厂 | 一种莫代尔织物的抗菌抗起球整理工艺 |
| CN107724061A (zh) * | 2017-09-30 | 2018-02-23 | 江苏新瑞贝科技股份有限公司 | 一种多功能防紫外线整理剂及其制备方法 |
| CN107630350A (zh) * | 2017-10-20 | 2018-01-26 | 安徽亚源印染有限公司 | 一种亚麻人棉面料专用整理剂 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112376268A (zh) * | 2020-11-17 | 2021-02-19 | 徐建平 | 一种富勒烯纺织面料的制备方法和应用 |
| CN116463850A (zh) * | 2023-03-22 | 2023-07-21 | 扬州泉生源电磁技术有限公司 | 一种抗电磁辐射材料及其制备方法 |
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