CN108624263A - One planting sand picture is fixed the sand glue and preparation method thereof with oiliness - Google Patents

One planting sand picture is fixed the sand glue and preparation method thereof with oiliness Download PDF

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Publication number
CN108624263A
CN108624263A CN201810121918.XA CN201810121918A CN108624263A CN 108624263 A CN108624263 A CN 108624263A CN 201810121918 A CN201810121918 A CN 201810121918A CN 108624263 A CN108624263 A CN 108624263A
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China
Prior art keywords
sand
glue
oiliness
fixed
picture
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Pending
Application number
CN201810121918.XA
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Chinese (zh)
Inventor
马国艳
李小瑞
沈丁
沈一丁
姜娈
杨凯
李雪研
成航航
武哲
闫峰
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Shaanxi University of Science and Technology
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Shaanxi University of Science and Technology
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Application filed by Shaanxi University of Science and Technology filed Critical Shaanxi University of Science and Technology
Priority to CN201810121918.XA priority Critical patent/CN108624263A/en
Publication of CN108624263A publication Critical patent/CN108624263A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J143/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
    • C09J143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5435Silicon-containing compounds containing oxygen containing oxygen in a ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/544Silicon-containing compounds containing nitrogen

Abstract

The present invention relates to a planting sand pictures to be fixed the sand glue and preparation method thereof with oiliness.Current market sales of main problem existing for glue of fixing the sand is that permeability is bad, slow drying speed, do after it sometimes appear that cracking and it is non-watertight.The present invention is using hardness and soft vinyl monomer as primary raw material, by introducing function monomer, a planting sand picture is prepared to be fixed the sand glue with oiliness, and there is excellent photostability and weatherability, good water-fast, alkaline-resisting, chemical resistance and adhesive property, can form good luster and water-fast film at room temperature, bonding is secured, it is not easy to peel off, the grains of sand such as colored sand, glaze can be securely fixed on wood-block or glass, the dry rear grains of sand are difficult to scratch.

Description

One planting sand picture is fixed the sand glue and preparation method thereof with oiliness
Technical field
The invention belongs to sand to draw articles for use fields, and in particular to a planting sand picture is fixed the sand glue and preparation method thereof with oiliness.
Background technology
Sand draw be it is a kind of by sand by drawing a picture on glass after, be fixed with special glue, finally carry out Unique graphics art of mounting.Sand draws the aesthetic conceptions in conjunction with modern, relies on deep cultural deposits and cultural connotation.Using production From the natural colored sand of magical the Nature, manually it is refined.Works are accumulate with distinct lines and soft color by art up The deep thought contained shows as popular aesthetic feeling, and great visual impact has reached unique artistic concept and ornamental effect The perfect adaptation of fruit.
However the glue that commonly fixes the sand currently on the market is polyester resin, but permeability is bad, is easily destroyed picture, dry speed Degree is slow, will appear cracking after dry, and water proofing property is poor.
Invention content
It is an object of the invention to overcome the above-mentioned prior art, a planting sand picture is provided and is fixed the sand glue and its system with oiliness Preparation Method, the permeability for solving existing product is bad, occurs being cracked after dry and non-water-tight problem, and accelerates its drying speed Degree.
The technical solution adopted in the present invention is:
One planting sand picture is fixed the sand the preparation method of glue with oiliness, it is characterised in that:Mass fraction is pressed below,
(1) oil-soluble ethylene base class monomer, functional monomer and initiator are mixed, obtains solution A, set aside for use;
(2) 8%~25% solution A is taken to be added in organic solvent under stiring, in 60~85 DEG C of back flow reactions 10~ 25min;
(3) remaining solution A is slowly dropped into the system of (2), 2~4h of time for adding;
(4) after dripping off, continue the 2~6h of insulation reaction that flows back, be cooled to room temperature, obtain Solutions Solution B;
(5) solution B and organic solvent are pressed 15~100:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness;
In the solution B:
Oil-soluble ethylene base class monomer 20%~73%;
Functional monomer 0.5%~8%;
Initiator 0.1%~1%;
Surplus is organic solvent.
The oil-soluble ethylene base class monomer structure formula is as follows, for two or more such as lower structure:
Wherein, R1 is the linear or branched alkyl group of H or C1~C4;R2 is the linear or branched alkyl group of C1~C6.
The functional monomer is gamma-aminopropyl-triethoxy-silane, γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy One or more of silane, γ-methacryloxypropyl trimethoxy silane.
The initiator is azodiisobutyronitrile or benzoyl peroxide.
The one kind or several of the organic solvent in hexamethylene, absolute ethyl alcohol, butanone, n,N-Dimethylformamide Kind.
The one planting sand picture is fixed the sand glue with the oiliness husky picture obtained by the preparation method of glue that fixes the sand with oiliness.
The present invention has the following advantages:
The present invention is that main Material synthesis fixes the sand glue with vinyl monomer, has excellent photostability and weatherability, Good water-fast, alkaline-resisting, chemical resistance and adhesive property, can form good luster and water-fast film at room temperature, bonding jail Gu being not easy to peel off, the grains of sand such as colored sand, glaze can be securely fixed on wood-block or glass.
Specific implementation mode
The present invention will be described in detail With reference to embodiment.
The present invention provides the preparation method that a planting sand picture fixes the sand glue with oiliness, presses mass fraction below,
(1) oil-soluble ethylene base class monomer, functional monomer and initiator are mixed, obtains solution A, set aside for use;
(2) 8%~25% solution A is taken to be added in organic solvent under stiring, in 60~85 DEG C of back flow reactions 10~ 25min;
(3) remaining solution A is slowly dropped into the system of (2), 2~4h of time for adding;
(4) after dripping off, continue the 2~6h of insulation reaction that flows back, be cooled to room temperature, obtain Solutions Solution B;
(5) solution B and organic solvent are pressed 15~100:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness;
In the solution B:
Oil-soluble ethylene base class monomer 20%~73%;
Functional monomer 0.5%~8%;
Initiator 0.1%~1%;
Surplus is organic solvent.
The oil-soluble ethylene base class monomer structure formula is as follows, for two or more such as lower structure:
Wherein, R1 is the linear or branched alkyl group of H or C1~C4;R2 is the linear or branched alkyl group of C1~C6.
The functional monomer is gamma-aminopropyl-triethoxy-silane, γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy One or more of silane, γ-methacryloxypropyl trimethoxy silane.
The initiator is azodiisobutyronitrile or benzoyl peroxide.
The one kind or several of the organic solvent in hexamethylene, absolute ethyl alcohol, butanone, n,N-Dimethylformamide Kind.
The one planting sand picture is fixed the sand glue with the oiliness husky picture obtained by the preparation method of glue that fixes the sand with oiliness.
Embodiment 1:
(1) 20g oil-soluble ethylene base class monomer, 0.1g functional monomers and 0.1g initiators are mixed, obtain solution A, Set aside for use;
(2) 25% A is taken to be added under stiring in 79.8g organic solvents, in 60 DEG C of back flow reaction 25min;
(3) remaining A is slowly dropped into (2), time for adding 2h;
(4) after dripping off, continue the insulation reaction 4h that flows back, be cooled to room temperature, obtain solution B;
(5) B and organic solvent are pressed 100:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness.
Wherein:
The oil-soluble ethylene base class monomer structure formula is
Mass ratio is 1:1;
The functional monomer is gamma-aminopropyl-triethoxy-silane;
The initiator is azodiisobutyronitrile;
The organic solvent is butanone.
Embodiment 2:
(1) 60g oil-soluble ethylene base class monomer, 6g functional monomers and 0.5g initiators are mixed, obtains solution A, it is quiet It sets for use;
(2) 15% A is taken to be added under stiring in 33.5g organic solvents, in 85 DEG C of back flow reaction 20min;
(3) remaining A is slowly dropped into (2), time for adding 4h;
(4) after dripping off, continue the insulation reaction 4h that flows back, be cooled to room temperature, obtain solution B;
(5) B and organic solvent are pressed 20:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness.
Wherein:
The oil-soluble ethylene base class monomer structure formula is
Mass ratio is 8:2;
Functional monomer γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy silicane;
The initiator is benzoyl peroxide;
The organic solvent is N,N-dimethylformamide.
Embodiment 3:
(1) 73g oil-soluble ethylene base class monomer, 8g functional monomers and 1g initiators are mixed, obtains solution A, stood For use;
(2) 20% A is taken to be added under stiring in 18g organic solvents, in 80 DEG C of back flow reaction 25min;
(3) remaining A is slowly dropped into (2), time for adding 3h;
(4) after dripping off, continue the insulation reaction 3h that flows back, be cooled to room temperature, obtain solution B;
(5) B and organic solvent are pressed 15:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness.
Wherein:
The oil-soluble ethylene base class monomer structure formula is
Mass ratio is 6: 3:1;
Functional monomer γ-methacryloxypropyl trimethoxy silane;
The initiator is azodiisobutyronitrile;
The organic solvent is absolute ethyl alcohol.
Embodiment 4:
(1) 40g oil-soluble ethylene base class monomer, 5g functional monomers and 0.8g initiators are mixed, obtains solution A, it is quiet It sets for use;
(2) 8% A is taken to be added under stiring in 54.2g organic solvents, in 70 DEG C of back flow reaction 10min;
(3) remaining A is slowly dropped into (2), time for adding 2h;
(4) after dripping off, continue the insulation reaction 6h that flows back, be cooled to room temperature, obtain solution B;
(5) B and organic solvent are pressed 30:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness.
Wherein:
The oil-soluble ethylene base class monomer structure formula is
Mass ratio is 7:3;
The functional monomer is γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy silicanes and γ-methacryloxy Propyl trimethoxy silicane mass ratio is 1:1 mixture;
The initiator is benzoyl peroxide;
The organic solvent is hexamethylene.
Embodiment 5:
(1) 50g oil-soluble ethylene base class monomer, 6g functional monomers and 0.6g initiators are mixed, obtains solution A, it is quiet It sets for use;
(2) 25% A is taken to be added under stiring in 43.4g organic solvents, in 78 DEG C of back flow reaction 25min;
(3) remaining A is slowly dropped into (2), time for adding 2h;
(4) after dripping off, continue the insulation reaction 2h that flows back, be cooled to room temperature, obtain solution B;
(5) B and organic solvent are pressed 15~100:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness.
Wherein:
The oil-soluble ethylene base class monomer structure formula is
Mass ratio is 6:2:2;
The functional monomer is gamma-aminopropyl-triethoxy-silane, γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy silicon Alkane and γ-methacryloxypropyl trimethoxy silane mass ratio are 1:1:1 mixture
The initiator is azodiisobutyronitrile;
The organic solvent is absolute ethyl alcohol.
Present disclosure is not limited to cited by embodiment, and those of ordinary skill in the art are by reading description of the invention And to any equivalent transformation that technical solution of the present invention is taken, it is that claim of the invention is covered.

Claims (6)

  1. The preparation method of glue 1. a planting sand picture is fixed the sand with oiliness, it is characterised in that:Mass fraction is pressed below,
    (1) oil-soluble ethylene base class monomer, functional monomer and initiator are mixed, obtains solution A, set aside for use;
    (2) 8%~25% solution A is taken to be added in organic solvent under stiring, in 60~85 DEG C of 10~25min of back flow reaction;
    (3) remaining solution A is slowly dropped into the system of (2), 2~4h of time for adding;
    (4) after dripping off, continue the 2~6h of insulation reaction that flows back, be cooled to room temperature, obtain Solutions Solution B;
    (5) solution B and organic solvent are pressed 15~100:100 mass ratio, which mixes, to be fixed the sand glue to get husky picture with oiliness;
    In the solution B:
    Oil-soluble ethylene base class monomer 20%~73%;
    Functional monomer 0.5%~8%;
    Initiator 0.1%~1%;
    Surplus is organic solvent.
  2. The preparation method of glue 2. planting sand picture according to claim 1 is fixed the sand with oiliness, it is characterised in that:The oil is molten Sex ethylene base class monomer structure formula is as follows, for two or more such as lower structure:
    Wherein, R1 is the linear or branched alkyl group of H or C1~C4;R2 is the linear or branched alkyl group of C1~C6.
  3. The preparation method of glue 3. planting sand picture according to claim 1 is fixed the sand with oiliness, it is characterised in that:The function Property monomer be gamma-aminopropyl-triethoxy-silane, γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy silicane, γ-methacryl One or more of oxygroup propyl trimethoxy silicane.
  4. The preparation method of glue 4. planting sand picture according to claim 1 is fixed the sand with oiliness, it is characterised in that:The initiation Agent is azodiisobutyronitrile or benzoyl peroxide.
  5. The preparation method of glue 5. planting sand picture according to claim 1 is fixed the sand with oiliness, it is characterised in that:Described is organic Solvent is selected from one or more of hexamethylene, absolute ethyl alcohol, butanone, n,N-Dimethylformamide.
  6. 6. planting sand picture according to claim 1 is fixed the sand with the oiliness husky picture obtained by the preparation method of glue that fixes the sand with oiliness Glue.
CN201810121918.XA 2018-02-07 2018-02-07 One planting sand picture is fixed the sand glue and preparation method thereof with oiliness Pending CN108624263A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810121918.XA CN108624263A (en) 2018-02-07 2018-02-07 One planting sand picture is fixed the sand glue and preparation method thereof with oiliness

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810121918.XA CN108624263A (en) 2018-02-07 2018-02-07 One planting sand picture is fixed the sand glue and preparation method thereof with oiliness

Publications (1)

Publication Number Publication Date
CN108624263A true CN108624263A (en) 2018-10-09

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113861988A (en) * 2021-10-26 2021-12-31 华南理工大学 Hyperbranched epoxy oligosiloxane sand-fixing material and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993675A (en) * 2010-11-02 2011-03-30 北京高盟新材料股份有限公司 Silane coupling agent modified acrylic pressure sensitive adhesive and preparation method thereof
CN103254857A (en) * 2013-05-11 2013-08-21 北京化工大学 Alcohol-soluble self-crosslinking acrylic resin adhesive and preparation method thereof
CN104015546A (en) * 2014-06-16 2014-09-03 亿利沙材料科技有限责任公司 Craft sand painting and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993675A (en) * 2010-11-02 2011-03-30 北京高盟新材料股份有限公司 Silane coupling agent modified acrylic pressure sensitive adhesive and preparation method thereof
CN103254857A (en) * 2013-05-11 2013-08-21 北京化工大学 Alcohol-soluble self-crosslinking acrylic resin adhesive and preparation method thereof
CN104015546A (en) * 2014-06-16 2014-09-03 亿利沙材料科技有限责任公司 Craft sand painting and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113861988A (en) * 2021-10-26 2021-12-31 华南理工大学 Hyperbranched epoxy oligosiloxane sand-fixing material and preparation method and application thereof

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