CN108619901A - Two butyryl house exhaust treatment process - Google Patents

Two butyryl house exhaust treatment process Download PDF

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Publication number
CN108619901A
CN108619901A CN201710176678.9A CN201710176678A CN108619901A CN 108619901 A CN108619901 A CN 108619901A CN 201710176678 A CN201710176678 A CN 201710176678A CN 108619901 A CN108619901 A CN 108619901A
Authority
CN
China
Prior art keywords
ozone
butyryl
organic matter
treatment process
activated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710176678.9A
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Chinese (zh)
Inventor
李玮
杨海明
荀本舟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Ze Yu Green Technology Co Ltd
Original Assignee
Shanghai Ze Yu Green Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Ze Yu Green Technology Co Ltd filed Critical Shanghai Ze Yu Green Technology Co Ltd
Priority to CN201710176678.9A priority Critical patent/CN108619901A/en
Publication of CN108619901A publication Critical patent/CN108619901A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Abstract

The invention discloses a kind of two butyryl house exhaust treatment process, the exhaust gas of two butyryl workshop device discharges contains volatile organic matter VOCs, when absorption, exhaust gas is introduced after activated carbon adsorption by wind turbine, by in catalysis oxidizing tower, inputting a small amount of ozone by ozone generation system, organic matter is in catalysis oxidizing tower through ozone oxidation, ultraviolet lamp tube and catalyst, the gas after reaction discharge after spray from exhaust tube.Air blows out the organic matter VOCs of absorption from activated carbon through activated carbon when desorption, it is introduced into catalysis oxidizing tower by wind turbine, a large amount of ozone are inputted by ozone generation system, organic matter is in catalysis oxidizing tower through ozone oxidation, ultraviolet lamp tube and catalyst, the present invention's makes full use of activated carbon renewable function and workshop low concentration gas feature, ensure activated carbon service life, rationally utilize the relationship of ozone generator and online monitoring data, control organic matter fully reacts, and greatly reduces chimney breast organic concentration.

Description

Two butyryl house exhaust treatment process
Technical field
The present invention relates to a kind for the treatment of process, more particularly to a kind of two butyryl house exhaust treatment process.
Background technology
1, traditional method, exhaust gas are sent into exhaust tube discharge after activated carbon adsorption, high frequency time are needed to regularly replace Activated carbon causes dangerous waste treating capacity big.
2, major pollutants (ether and dichloromethane etc.) saturated vapor pressure higher boiling is low in two butyryl house exhausts, volatilization Property it is strong, using conventional carbon adsorb method, absorption property is poor, and treatment effeciency is low.
3, workshop intermittence produces, and concentration of emission has larger difference, is easy volatile organic component when underload produces Stripping comes out, and causes discharge not up to standard.
4, traditional hot-air separating process, desorption discharge gas belongs to intermediate concentration, and has certain corrosivity, leads to two Secondary Processing tecchnics are complicated.
5, general activated carbon steam separating process, can cause a large amount of waste liquid to generate to form dangerous waste, cause secondary pollution. And in steam desorption process, organic matter facile hydrolysis generates corrosion impact to equipment, therefore it is required that improving equipment material grade.
6, general activated carbon steam separating process, the acidic materials of formation have large effect to activated carbon, increased The frequency that activated carbon is replaced.
Invention content
The technical problem to be solved by the present invention is to:Overcome the above problem, a kind of two butyryl house exhausts processing work is provided Skill.
To achieve the goals above, the technical solution adopted by the present invention is such:The two butyryl house exhausts of the present invention Treatment process, the exhaust gas of two butyryl workshop devices discharges contain volatile organic matter VOCs, and when absorption, exhaust gas is through activated carbon adsorption It is introduced afterwards by wind turbine, by catalysis oxidizing tower, inputting a small amount of ozone by ozone generation system, organic matter is in catalysis oxidation Through ozone oxidation, ultraviolet lamp tube and catalyst in tower, the gas after reaction discharges after spray from exhaust tube.Space-time is desorbed Gas blows out the organic matter VOCs of absorption from activated carbon through activated carbon, is introduced into catalysis oxidizing tower by wind turbine, passes through ozone Generating system inputs a large amount of ozone, and organic matter is in catalysis oxidizing tower through ozone oxidation, ultraviolet lamp tube and catalyst, reaction Gas afterwards discharges after spray from exhaust tube.By wind turbine, UV lamp pipe, ozone generation system open system when going into operation, normally In operation, the ozone amount of conveying can be adjusted by the data of on-line monitoring.
Further, as a specific structural form, the present invention is controlled by exporting online monitoring data into smelly Oxygen amount and ultraviolet lamp open number.
Further, as a specific structural form, the present invention can be adjusted by the variation of air quantity enters ozone amount With the unlatching number of ultraviolet lamp.
Further, as a specific structural form, the frequency of wind turbine of the present invention can according to Workshop Production situation and Import figure is monitored on-line to adjust.
Further, as a specific structural form, air bypass is arranged to be desorbed and can be into the present invention One desorption of row, another absorption mutually switching.
Further, as a specific structural form, adsorption process discharge gas of the present invention and air purging desorption row Deflation, which converges, passes through ozone Oxidation Treatment.
Further, as a specific structural form, ozone catalyst is arranged in the present invention, enhances the residence time and adds The decomposition of strong organic matter is removed with ozone.
Further, as a specific structural form, spray system is arranged in the present invention (can be arranged one with exhaust tube Change equipment), purification and washing is carried out to discharge gas.
Further, as a specific structural form, spray system of the present invention uses circulated sprinkling technique, only on a small quantity Discharging of waste liquid.
Compared with the prior art, the advantages of the present invention are as follows:The two butyryl house exhaust treatment process of the present invention are fully sharp With activated carbon renewable function and workshop low concentration gas feature, ensure activated carbon service life, rationally utilizes ozone generator With the relationship of online monitoring data, control organic matter fully reacts, and greatly reduces chimney breast organic concentration, operating flexibility Greatly, ability is well adapted to greatly for exhaust gas concentration variation.
Description of the drawings
Fig. 1 is two butyryl house exhaust treatment process figures of the invention;
In figure:1. ozone sends out system;2. the first adsorption tower;3, the second adsorption tower;4. wind turbine;5, ozone catalytic tower;6. row Inflator;7. pump;8, on-line monitoring system.
Fig. 2 is schematic structural view of the invention.
Specific implementation mode
In conjunction with the accompanying drawings, the present invention is further explained in detail.These attached drawings are simplified schematic diagram, only with Illustration illustrates the basic structure of the present invention, therefore it only shows the composition relevant to the invention.
The preferred embodiment of two butyryl house exhaust treatment process of the present invention as illustrated in fig. 1 and 2, two butyryl workshop devices The exhaust gas of discharge contains volatile organic matter VOCs, and when absorption, exhaust gas is introduced after activated carbon adsorption by wind turbine, and catalysis is passed through In oxidizing tower, a small amount of ozone is inputted by ozone generation system, organic matter is in catalysis oxidizing tower through ozone oxidation, ultraviolet lamp tube And catalyst, the gas after reaction discharge after spray from exhaust tube.When desorption air through activated carbon the organic of absorption Object VOCs is blown out from activated carbon, is introduced into catalysis oxidizing tower by wind turbine, inputs a large amount of ozone by ozone generation system, has Machine object is through ozone oxidation, ultraviolet lamp tube and catalyst in catalysis oxidizing tower, and the gas after reaction is after spray from exhaust Cylinder discharge.By wind turbine, UV lamp pipe, ozone generation system open system when going into operation, in normal operating, on-line monitoring can be passed through Data adjust the ozone amount of conveying.
By exporting online monitoring data control number is opened into ozone amount and ultraviolet lamp.
The unlatching number into ozone amount and ultraviolet lamp can be adjusted by the variation of air quantity.
The frequency of wind turbine can be adjusted according to Workshop Production situation and on-line monitoring import figure.
Setting air bypass come carry out be desorbed and can carry out one desorption, another absorption mutually switching.
Adsorption process discharge gas converges with air purging desorption discharge gas passes through ozone Oxidation Treatment.
Ozone catalyst is set, and the enhancing residence time removes with the decomposition for reinforcing organic matter with ozone.
Spray system (integration apparatus can be arranged with exhaust tube) is set, purification and washing is carried out to discharge gas.
Spray system uses circulated sprinkling technique, only a small amount of discharging of waste liquid.
The two butyryl house exhaust treatment process of this present invention make full use of activated carbon renewable function and workshop low concentration Exhaust gas feature ensures activated carbon service life, rationally utilizes the relationship of ozone generator and online monitoring data, controls organic matter Fully reaction, greatly reduces chimney breast organic concentration, and operating flexibility is big, and exhaust gas concentration variation is well adapted to greatly Ability.
The exhaust gas of two butyryl workshop devices discharges contains volatile organic matter VOCs, and when absorption, exhaust gas is through activated carbon adsorption It is introduced afterwards by wind turbine, by catalysis oxidizing tower, inputting a small amount of ozone by ozone generation system, organic matter is in catalysis oxidation Through ozone oxidation, ultraviolet lamp tube and catalyst in tower, the clean gas after reaction is discharged from exhaust tube.Air passes through when desorption Activated carbon blows out the organic matter VOCs of absorption from activated carbon, is introduced into catalysis oxidizing tower by wind turbine, is occurred by ozone System inputs a large amount of ozone, organic matter in catalysis oxidizing tower through ozone oxidation, ultraviolet lamp tube and catalyst, after reaction Clean gas is discharged from exhaust tube.Pass through wind turbine, UV lamp pipe, ozone generation system open system when going into operation.It, can in normal operating The ozone amount of conveying is adjusted by the data of on-line monitoring.
Key control point:
By exporting online monitoring data control number is opened into ozone amount and ultraviolet lamp;
The frequency of wind turbine can be adjusted according to Workshop Production situation and on-line monitoring import figure.
Setting air bypass come carry out be desorbed and can carry out one desorption, another absorption mutually switching.
It is enlightenment with above-mentioned desirable embodiment according to the present invention, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property range is not limited to the contents of the specification, it is necessary to determine its technical scope according to right.

Claims (9)

1. a kind of two butyryl house exhaust treatment process, it is characterised in that:The exhaust gas of two butyryl workshop device discharges contains volatilization Property organic matter VOCs, when absorption, exhaust gas is introduced after activated carbon adsorption by wind turbine, by catalysis oxidizing tower, passing through ozone Generating system inputs a small amount of ozone, and organic matter is in catalysis oxidizing tower through ozone oxidation, ultraviolet lamp tube and catalyst, reaction Gas afterwards discharges after spray from exhaust tube.Air blows the organic matter VOCs of absorption from activated carbon through activated carbon when desorption Go out, be introduced into catalysis oxidizing tower by wind turbine, a large amount of ozone is inputted by ozone generation system, organic matter is in catalysis oxidizing tower Through ozone oxidation, ultraviolet lamp tube and catalyst, the gas after reaction discharge after spray from exhaust tube.Pass through wind when going into operation Machine, UV lamp pipe, ozone generation system open system in normal operating, can adjust the ozone of conveying by the data of on-line monitoring Amount.
2. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:Number is monitored on-line by outlet According to control number is opened into ozone amount and ultraviolet lamp.
3. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:The variation tune of air quantity can be passed through Unlatching number of the section into ozone amount and ultraviolet lamp.
4. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:The frequency of wind turbine can be according to vehicle Between the condition of production and on-line monitoring import figure adjust.
5. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:Air bypass is set to carry out It is desorbed and can carry out a desorption, another absorption mutually switching.
6. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:Adsorption process discharges gas and sky Air-blowing sweeps desorption discharge gas and converges and pass through ozone Oxidation Treatment.
7. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:Ozone catalyst is set, is increased The strong residence time removes with the decomposition for reinforcing organic matter with ozone.
8. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:Spray system is set(It can be with Integration apparatus is arranged in exhaust tube), purification and washing is carried out to discharge gas.
9. two butyryl house exhaust treatment process according to claim 1, it is characterised in that:Spray system is sprayed using cycle Leaching technique, only a small amount of discharging of waste liquid.
CN201710176678.9A 2017-03-23 2017-03-23 Two butyryl house exhaust treatment process Pending CN108619901A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710176678.9A CN108619901A (en) 2017-03-23 2017-03-23 Two butyryl house exhaust treatment process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710176678.9A CN108619901A (en) 2017-03-23 2017-03-23 Two butyryl house exhaust treatment process

Publications (1)

Publication Number Publication Date
CN108619901A true CN108619901A (en) 2018-10-09

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Country Status (1)

Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112316686A (en) * 2020-09-27 2021-02-05 昆山盛庆隆环保设备有限公司 Multistage waste gas treatment process
CN113082942A (en) * 2021-05-14 2021-07-09 中珪环科(杭州)环保科技有限公司 Heterogeneous multistage oxidation treatment device of VOCs waste gas
CN114005569A (en) * 2021-10-29 2022-02-01 华能核能技术研究院有限公司 Low-radioactivity organic waste liquid treatment system

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101053758A (en) * 2006-04-14 2007-10-17 福建新大陆环保科技有限公司 Device for photochemical degradating pollution gas
GB201006660D0 (en) * 2010-04-21 2010-06-09 Dyson Technology Ltd An air treating appliance
CN204582928U (en) * 2015-01-27 2015-08-26 江苏现代环保科技有限公司 Waste water, refuse depot foul gas cleaning equipment
CN104941382A (en) * 2015-06-11 2015-09-30 陆钢 Organic waste gas treatment device and method
CN106039956A (en) * 2016-08-16 2016-10-26 长沙威保特环保科技股份有限公司 Energy-saving multi-effect VOCs purification reactor and VOCs purification treatment method
CN206008465U (en) * 2016-07-11 2017-03-15 杭州博韵易环保科技有限公司 A kind of organic waste gas treatment system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101053758A (en) * 2006-04-14 2007-10-17 福建新大陆环保科技有限公司 Device for photochemical degradating pollution gas
GB201006660D0 (en) * 2010-04-21 2010-06-09 Dyson Technology Ltd An air treating appliance
CN204582928U (en) * 2015-01-27 2015-08-26 江苏现代环保科技有限公司 Waste water, refuse depot foul gas cleaning equipment
CN104941382A (en) * 2015-06-11 2015-09-30 陆钢 Organic waste gas treatment device and method
CN206008465U (en) * 2016-07-11 2017-03-15 杭州博韵易环保科技有限公司 A kind of organic waste gas treatment system
CN106039956A (en) * 2016-08-16 2016-10-26 长沙威保特环保科技股份有限公司 Energy-saving multi-effect VOCs purification reactor and VOCs purification treatment method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112316686A (en) * 2020-09-27 2021-02-05 昆山盛庆隆环保设备有限公司 Multistage waste gas treatment process
CN113082942A (en) * 2021-05-14 2021-07-09 中珪环科(杭州)环保科技有限公司 Heterogeneous multistage oxidation treatment device of VOCs waste gas
CN114005569A (en) * 2021-10-29 2022-02-01 华能核能技术研究院有限公司 Low-radioactivity organic waste liquid treatment system

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Application publication date: 20181009