CN108589362B - A kind of dry isolated method of waste and old paper composite wallpaper - Google Patents

A kind of dry isolated method of waste and old paper composite wallpaper Download PDF

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Publication number
CN108589362B
CN108589362B CN201810468653.0A CN201810468653A CN108589362B CN 108589362 B CN108589362 B CN 108589362B CN 201810468653 A CN201810468653 A CN 201810468653A CN 108589362 B CN108589362 B CN 108589362B
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Prior art keywords
paper
separation
waste
wallpaper
old
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CN108589362A (en
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张建春
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Anhui Changtai Renewable Resources Co Ltd
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Anhui Changtai Renewable Resources Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • D21B1/32Defibrating by other means of waste paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • D21B1/34Kneading or mixing; Pulpers
    • D21B1/345Pulpers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21DTREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D5/00Purification of the pulp suspension by mechanical means; Apparatus therefor
    • D21D5/02Straining or screening the pulp
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of dry isolated methods of waste and old paper composite wallpaper, it is related to waste and old paper product recycling correlative technology field, it includes: (1) by waste and old paper composite wallpaper depth colour sorting that the waste and old paper composite wallpaper of the present invention, which does isolated method, (2) it is crushed crusher machine, (3) level-one separates, the second-order separation, three-level separation, it is completely separated and high efficiente callback, whole process is not paddled completely, traditional handicraft and commercial run are overturned, avoid water resource waste and waste water, a large amount of water pollutions are to environmental hazard caused by sewage discharge, and separation method is simple, it is simple using separation equipment, separation process is easy to operate uncomplicated, save input cost, greatly reduce the input cost of waste and old paper product recycling.

Description

A kind of dry isolated method of waste and old paper composite wallpaper
Technical field
The present invention relates to waste and old paper products to recycle correlative technology field, and in particular to a kind of dry separation of waste and old paper composite wallpaper Method.
Background technique
It is compound and form to be generally the paper such as the plastic cement such as PE, PP and brown paper, cardboard for paper-plastic stick wallpaper currently on the market Novel wallpaper.And usual paper-plastic stick uses resin application methods, such as hand brush in the production of paper-plastic stick wallpaper, machine applies, spraying etc. Mode reaches plastic box paper and closely combines for a long time.
Wallpaper finishing, the later period will generate a large amount of waste and old paper-plastic stick wallpapers, and waste and old wallpaper is largely eliminated and causes to provide Source amount is taken and environmental pollution, therefore is necessary to the recycling of waste and old paper composite wallpaper.
In traditional handicraft, paper separation is to utilize the method for changing plastic realization paper separation after heating.(1) heat point Method utilizes the method for changing plastic realization paper separation after heating;(2) hygroscopic water method will obtain light from dry point-score separation equipment Material is sent into pulper, and the paper pulp blended is flowed out from the aperture on sorting plate, and the plastics left are then from a separation outlet Discharge is then fed into dewaterer dehydration, is re-fed into air separator and is separated;(3) electronic partition method is by paper and plastics Mixture is sent into seperator by oscillating feeder, and fall into rotation pulverizes drum, be then delivered to by wire electrodes with pulverize Between the corona zone that is formed, paper is attracted to electrode, and plastics are still attached on rotary drum, as bulging rotation plasticity falls on its bottom Portion collects.Had a significant impact using humidity when this method to separating resulting, when mixture humidity is 15%, though paper and modeling can be made Material separation, but plasticity can still be polluted by a large amount of paper, when humidity is improved to 50% or more, plasticity and paper can be made to be kept completely separate.
In the art, CN201610538265.6 discloses a kind of waste and old composite paper-plastic material paper separation life The separation method of production system staticly settles → paper pulp extruding → modeling by paper separation → paper pulp removal of impurities → paper pulp in this application Piece compression packing and etc., it realizes waste and old composite paper-plastic material paper separation and improves production efficiency, suitable for country's classification The purpose that any waste and old composite paper-plastic material and water resource recycle.
Chinese Patent Application No.: 201020605314.1, publication date: the patent document of 2012.01.04 discloses a kind of ring Guarantor's type paper separation system device, by pulverizer, conveyer belt, drum sieve, the first washing stock tank, vibrating screen, conveyance conduit, second Composition is linked in sequence in washing stock tank, vibration slanted screen, and vibration slanted screen is also respectively connected with press master and baling press, using rubbing, leaching The programs such as bubble, screening, are effectively peeled off discarded composite paper-plastic material, and the paper conversion after removing is reduced to paper pulp, will shell Plastics from rear centralized recovery can be directly granulated, and not only waste and old paper material be turned waste into wealth, but also solve environmental issue.But it should Utility model washer twice, needs a large amount of water to complete, and be easy to cause the waste of water resource, in order to sufficiently impregnate, The pulp washing time is also longer.A large amount of water are used in the separation process of paper-plastic stick wallpaper in the art, cause water resource unrestrained Take but caused by Heisui River, waste water, sewage discharge, caused by a large amount of water pollutions to environmental hazard.
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of dry isolated method of waste and old paper composite wallpaper.Including Sorting is broken to be separated two modules with paper and can realize and be completely separated to two kinds of materials of paper-plastic stick wallpaper, and separation process is It is first sorted, is crushed by shade, level-one separation, the second-order separation, three-level separation is completely separated and high efficiente callback, Whole process is not paddled completely, has overturned traditional handicraft and commercial run, avoids water resource waste and waste water, sewage discharge Caused by a large amount of water pollutions to environmental hazard.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of dry isolated method of waste and old paper composite wallpaper, includes the following steps:
(1) it sorts: the waste and old paper composite wallpaper elder generation artificial screening of recycling being shrugged off into a large amount of dusts, removes clod, iron block Equal junks;Waste and old paper composite wallpaper is divided into 2 major class simultaneously: dark colour wallpaper and light colour wallpaper will classify waste and old Paper-plastic stick wallpaper is orderly placed in ventilation, drying, clean place;
Shade is identified: passing through publicity: g=R*0.299+G*0.587+B*0.114,
It is light color as g >=192;
It is dark color as g < 192;
(2) it is crushed: sorted waste and old paper composite wallpaper being put into respectively and carries out slice shearing-crushing in crusher, break Broken wallpaper range 3-10cm × 3-10cm;
(3) it separates:
(a) the blocky paper-plastic stick wallpaper after shearing-crushing is entered by pipeline and grinds separation equipment one fraction of progress From, moulding composite wallpaper by the gear grinding shredded paper in equipment in level-one separation becomes clastic, in attrition process plastics and The available separation of papery, obtained clast part be PVC or PE plastics, be partially paper product, partially for PVC or PE not with paper The separated paper-plastic stick clast of matter, while starting air blast in level-one separation, it is separated using the difference of paper specific gravity by wind-force Paper clast through grinding, wherein PE or PVC enters magnetic separation separation equipment by grinding the plastics separate pipeline of separation equipment, wood Matter fiber enters dry closing paper scrap workshop, PVC or the non-paper-plastic stick clast of PE by another separate pipeline by grinding The plastics separate pipeline of separation equipment enters magnetic separation separation equipment;
(b) after paper clast completes level-one separation, the second-order separation is carried out in magnetic separation separation equipment, the second-order separation passes through magnetic Choosing separation paper separates, after magnetic separation separation by wood fibre and PVC by propeller break up with progradation constantly forward, at Function enters separator, separates three-level separation i.e. thorough point for reaching paper with magnetic separation by the specific gravity screening of wind-force in the separator From plastic scrap enters plastic conduit collector, and paper clast enters shredded paper collector.
Wherein above-mentioned crusher operating condition: 35-55 DEG C of temperature, it is crushed shearing force size: 50-120N;Broken revolving speed: 800-1200rpm。
Wherein it is broken as the paper of 0.05-1cm × 0.05-1cm to grind paper-plastic stick wallpaper for the level-one separation middle gear Bits.
Wherein air blast wind-force size in the level-one separation are as follows: 300-600m3/H.
The wherein wind-force size in the separator are as follows: 500-1000m3/H.
Wherein the operating temperature of above-mentioned magnetic separation separation equipment is 40-55 DEG C.
The beneficial effects of the present invention are:
(1) paper separation method of the present invention is completely separated waste and old paper product and high efficiente callback, whole process are complete It does not paddle, has overturned traditional handicraft and commercial run, avoid a large amount of water caused by water resource waste and waste water, sewage discharge Pollution is to environmental hazard.
(2) recycling in the method for the present invention to waste and old paper product, may be implemented being kept completely separate for paper, and of the invention is waste and old Various waste and old paper wallpapers are processed into clast, and pass through by grinding separation equipment by composite paper-plastic material paper separation system The high grinding forces rubbing circulation for grinding separation equipment, the paper in clast is rubbed and is separated;Matching by magnetic separation separation equipment again Cooperation with generate high intensity wind-force carry out magnetic separation, by paper pulp after magnetic separation by propeller break up with progradation constantly forward, at Function enters separator, realizes the purpose that paper is kept completely separate, and be pipelining, labor intensity of workers is low, realizes Improve production efficiency, suitable for the waste and old composite paper-plastic material of country's classification and the purpose of anhydrous resource circulation utilization;
(3) in separation method of the present invention, separation method is simple, and simple using separation equipment, separation process is easy to operate not Complexity saves input cost, greatly reduces the input cost of waste and old paper product recycling.
(4) paper scrap after separation method separation of the present invention and plastic scrap may not necessarily can enter subsequent by reprocessing Processing, plastic scrap can enter plastics weight processed and applied in plastics arts;Shredded paper can be directly entered paper scrap post-processing neck Domain is applied to paper regeneration etc., and this method solves the problems, such as that paper waste material is not easy as paper making raw material;It has widened again The raw material field of raw paper production;Generation without secondary pollution in production process has been truly realized the reasonable utilization of regenerated resources, realizes Maximizing the benefits alleviates the processing load of solid waste, protects environment.
Specific embodiment:
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of dry isolated method of waste and old paper composite wallpaper, includes the following steps:
(1) it sorts: the waste and old paper composite wallpaper elder generation artificial screening of recycling being shrugged off into a large amount of dusts, removes clod, iron block Equal junks;Waste and old paper composite wallpaper is divided into 2 major class simultaneously: dark colour wallpaper and light colour wallpaper will classify waste and old Paper-plastic stick wallpaper is orderly placed in ventilation, drying, clean place;
Shade is identified: passing through publicity: g=R*0.299+G*0.587+B*0.114,
It is light color as g >=192;
It is dark color as g < 192;
(2) it is crushed: sorted waste and old paper composite wallpaper being put into respectively and carries out slice shearing-crushing in crusher, break Broken wallpaper range 4-8cm × 3-10cm;
(3) it separates:
(a) the blocky paper-plastic stick wallpaper after shearing-crushing is entered by pipeline and grinds separation equipment one fraction of progress From, moulding composite wallpaper by the gear grinding shredded paper in equipment in level-one separation becomes clastic, in attrition process plastics and The available separation of papery, obtained clast part be PVC or PE plastics, be partially paper product, partially for PVC or PE not with paper The separated paper-plastic stick clast of matter, while starting air blast in level-one separation, it is separated using the difference of paper specific gravity by wind-force Paper clast through grinding, wherein PE or PVC enters magnetic separation separation equipment by grinding the plastics separate pipeline of separation equipment, wood Matter fiber enters dry closing paper scrap workshop, PVC or the non-paper-plastic stick clast of PE by another separate pipeline by grinding The plastics separate pipeline of separation equipment enters magnetic separation separation equipment;
(b) after paper clast completes level-one separation, the second-order separation is carried out in magnetic separation separation equipment, the second-order separation passes through magnetic Choosing separation paper separates, after magnetic separation separation by wood fibre and PVC by propeller break up with progradation constantly forward, at Function enters separator, separates three-level separation i.e. thorough point for reaching paper with magnetic separation by the specific gravity screening of wind-force in the separator From plastic scrap enters plastic conduit collector, and paper clast enters shredded paper collector.
Wherein above-mentioned crusher operating condition: temperature 45 C is crushed shearing force size: 90-100N;Broken revolving speed: 1000rpm。
Wherein the level-one separation middle gear, which grinds paper-plastic stick wallpaper, becomes the paper of 0.05-0.8cm × 0.05-0.5cm Mould clast
Wherein air blast wind-force size in the level-one separation are as follows: 400m3/H.
The wherein wind-force size in the separator are as follows: 800m3/H.
Wherein the operating temperature of above-mentioned magnetic separation separation equipment is 48-50 DEG C.
Embodiment 2
A kind of dry isolated method of waste and old paper composite wallpaper, includes the following steps:
(1) it sorts: the waste and old paper composite wallpaper elder generation artificial screening of recycling being shrugged off into a large amount of dusts, removes clod, iron block Equal junks;Waste and old paper composite wallpaper is divided into 2 major class simultaneously: dark colour wallpaper and light colour wallpaper will classify waste and old Paper-plastic stick wallpaper is orderly placed in ventilation, drying, clean place;
Shade is identified: passing through publicity: g=R*0.299+G*0.587+B*0.114,
It is light color as g >=192;
It is dark color as g < 192;
(2) it is crushed: sorted waste and old paper composite wallpaper being put into respectively and carries out slice shearing-crushing in crusher, break Broken wallpaper range 3-6cm × 4-10cm;
(3) it separates:
(a) the blocky paper-plastic stick wallpaper after shearing-crushing is entered by pipeline and grinds separation equipment one fraction of progress From, moulding composite wallpaper by the gear grinding shredded paper in equipment in level-one separation becomes clastic, in attrition process plastics and The available separation of papery, obtained clast part be PVC or PE plastics, be partially paper product, partially for PVC or PE not with paper The separated paper-plastic stick clast of matter, while starting air blast in level-one separation, it is separated using the difference of paper specific gravity by wind-force Paper clast through grinding, wherein PE or PVC enters magnetic separation separation equipment by grinding the plastics separate pipeline of separation equipment, wood Matter fiber enters dry closing paper scrap workshop, PVC or the non-paper-plastic stick clast of PE by another separate pipeline by grinding The plastics separate pipeline of separation equipment enters magnetic separation separation equipment;
(b) after paper clast completes level-one separation, the second-order separation is carried out in magnetic separation separation equipment, the second-order separation passes through magnetic Choosing separation paper separates, after magnetic separation separation by wood fibre and PVC by propeller break up with progradation constantly forward, at Function enters separator, separates three-level separation i.e. thorough point for reaching paper with magnetic separation by the specific gravity screening of wind-force in the separator From plastic scrap enters plastic conduit collector, and paper clast enters shredded paper collector.
Wherein above-mentioned crusher operating condition: 40-45 DEG C of temperature, it is crushed shearing force size: 120N;Broken revolving speed: 1200rpm。
Wherein the level-one separation middle gear, which grinds paper-plastic stick wallpaper, becomes the paper of 0.05-0.8cm × 0.05-0.8cm Mould clast
Wherein air blast wind-force size in the level-one separation are as follows: 500m3/H.
The wherein wind-force size in the separator are as follows: 1000m3/H.
Wherein the operating temperature of above-mentioned magnetic separation separation equipment is 50-55 DEG C.
Reference examples 1:
A kind of method of waste and old paper composite wallpaper separation, includes the following steps:
(1) it sorts: the waste and old paper composite wallpaper elder generation artificial screening of recycling being shrugged off into a large amount of dusts, removes clod, iron block Equal junks;Waste and old paper composite wallpaper is divided into 2 major class simultaneously: dark colour wallpaper and light colour wallpaper will classify waste and old Paper-plastic stick wallpaper is orderly placed in ventilation, drying, clean place;
Shade is identified: passing through publicity: g=R*0.299+G*0.587+B*0.114,
It is light color as g >=192;
It is dark color as g < 192;
(2) it is crushed: sorted waste and old paper composite wallpaper being put into respectively and carries out slice shearing-crushing in crusher, break Broken wallpaper range 3-10cm × 3-10cm;
(3) it separates:
(a) the blocky paper-plastic stick wallpaper after shearing-crushing is entered by pipeline and grinds separation equipment one fraction of progress From, moulding composite wallpaper by the gear grinding shredded paper in equipment in level-one separation becomes clastic, in attrition process plastics and The available separation of papery, obtained clast part be PVC or PE plastics, be partially paper product, partially for PVC or PE not with paper The separated paper-plastic stick clast of matter, while starting air blast in level-one separation, it is separated using the difference of paper specific gravity by wind-force Paper clast through grinding, wherein PE or PVC enters magnetic separation separation equipment by grinding the plastics separate pipeline of separation equipment, wood Matter fiber enters dry closing paper scrap workshop by another separate pipeline.
Wherein above-mentioned crusher operating condition: 50-55 DEG C of temperature, it is crushed shearing force size: 100N;Broken revolving speed: 1000rpm。
Wherein it is broken as the paper of 0.05-1cm × 0.05-1cm to grind paper-plastic stick wallpaper for the level-one separation middle gear Bits
Wherein air blast wind-force size in the level-one separation are as follows: 500m3/H.
To experiment investigation is carried out respectively in embodiment provided by the invention, embodiment and reference examples method are subjected to waste paper It is investigated after modeling wallpaper processing, and is reference examples 2 with CN201610538265.6, as a result such as table 1;
Detection project Embodiment 1 Embodiment 2 Reference examples 1 Reference examples 2
Paper separation rate % 99.5% 99.6% 96.8% 97.3%
Save water resource Without water Without water Use a large amount of water Use a large amount of water
Rate of recovery % 98.9% 99.3% 95.6% 98.6%
Found out by the above item detection, the waste and old paper wallpaper separation method of the present invention is under different technology conditions, the present invention Under the premise of saving great lot of water resources, paper separation rate and the waste and old paper rate of recovery are same as or better than traditional handicraft.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of dry isolated method of waste and old paper composite wallpaper, which comprises the steps of:
(1) it sorts: the waste and old paper composite wallpaper elder generation artificial screening of recycling being shrugged off into a large amount of dusts, removal clod, iron block are waste and old Sundries;Waste and old paper composite wallpaper is divided into 2 major class: dark colour wallpaper and light colour wallpaper simultaneously, the waste and old paper that will classify is answered The paper that combines harmoniously orderly is placed in ventilation, drying, clean place;
Shade is identified: passing through publicity: g=R*0.299+G*0.587+B*0.114,
It is light color as g >=192;
It is dark color as g < 192;
(2) it is crushed: sorted waste and old paper composite wallpaper being put into respectively and carries out slice shearing-crushing, crushing wall in crusher Paper range 3-10cm × 3-10cm;
(3) it separates:
(a) the blocky paper-plastic stick wallpaper after shearing-crushing is entered by pipeline and grinds separation equipment progress level-one separation, Moulding composite wallpaper by the gear grinding shredded paper in equipment in level-one separation becomes clastic, and plastics and papery obtain in attrition process To separation, it is partially paper product that obtained clast part, which is PVC or PE plastics, the paper not separated with papery for PVC or PE partially Compound chips are moulded, while starting air blast in level-one separation, the paper ground is separated by wind-force using the difference of paper specific gravity Clast is moulded, wherein PE or PVC enters magnetic separation separation equipment by grinding the plastics separate pipeline of separation equipment, and wood fibre passes through Another separate pipeline enters dry closing paper scrap workshop, and the paper-plastic stick clast that PVC or PE are not separated with papery passes through mill The plastics separate pipeline of broken separation equipment enters magnetic separation separation equipment;
(b) after paper clast completes level-one separation, the second-order separation is carried out in magnetic separation separation equipment, the second-order separation passes through magnetic separation point Separated from paper, after magnetic separation separation by wood fibre and PVC or PE by propeller break up with progradation constantly forward, at Function enters separator, separates three-level separation i.e. thorough point for reaching paper with magnetic separation by the specific gravity screening of wind-force in the separator From plastic scrap enters plastic conduit collector, and paper clast enters shredded paper collector.
2. the dry isolated method of waste and old paper composite wallpaper according to claim 1, it is characterised in that: wherein above-mentioned broken Machine operating condition: 35-55 DEG C of temperature, it is crushed shearing force size: 50-120N;Broken revolving speed: 800-1200rpm.
3. the dry isolated method of waste and old paper composite wallpaper according to claim 1, it is characterised in that: the wherein level-one Separation middle gear, which grinds paper-plastic stick wallpaper, becomes the paper clast of 0.05-1cm × 0.05-1cm.
4. the dry isolated method of waste and old paper composite wallpaper according to claim 1, it is characterised in that: the wherein level-one Air blast wind-force size in separation are as follows: 300-600m3/H.
5. the dry isolated method of waste and old paper composite wallpaper according to claim 1, it is characterised in that: the wherein separation Wind-force size in device are as follows: 500-1000m3/H.
6. the dry isolated method of waste and old paper composite wallpaper according to claim 1, it is characterised in that: wherein above-mentioned magnetic separation The operating temperature of separation equipment is 40-55 DEG C.
CN201810468653.0A 2018-05-16 2018-05-16 A kind of dry isolated method of waste and old paper composite wallpaper Expired - Fee Related CN108589362B (en)

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Publication number Priority date Publication date Assignee Title
CN115228900A (en) * 2022-07-25 2022-10-25 苏州嘉诺智能装备有限公司 Paper-plastic separation system and paper-plastic separation method for waste paper treatment

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CN101947538A (en) * 2010-08-19 2011-01-19 朱海生 Resource recycling system of discarded papers, plastics or composite materials thereof
CN101972769A (en) * 2010-11-05 2011-02-16 朱海生 Medical rubbish harmless resource comprehensive utilization system
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Publication number Priority date Publication date Assignee Title
JP4355072B2 (en) * 1999-12-22 2009-10-28 Dowaホールディングス株式会社 Separation and collection method and apparatus for communication equipment
CN101884997A (en) * 2010-07-09 2010-11-17 深圳市兖能环保科技有限公司 Process for comprehensively treating garbage
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CN101972769A (en) * 2010-11-05 2011-02-16 朱海生 Medical rubbish harmless resource comprehensive utilization system
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