CN108588473A - A kind of Cu alloy material of motor device and preparation method thereof - Google Patents

A kind of Cu alloy material of motor device and preparation method thereof Download PDF

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Publication number
CN108588473A
CN108588473A CN201810540222.0A CN201810540222A CN108588473A CN 108588473 A CN108588473 A CN 108588473A CN 201810540222 A CN201810540222 A CN 201810540222A CN 108588473 A CN108588473 A CN 108588473A
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Prior art keywords
copper
alloy material
motor device
less
equal
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CN201810540222.0A
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Inventor
孙飞
赵勇
埃里克斯·高登
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Suzhou Lie Zhiai Alliance New Material Technology Shifts Co Ltd
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Suzhou Lie Zhiai Alliance New Material Technology Shifts Co Ltd
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Priority to CN201810540222.0A priority Critical patent/CN108588473A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting

Abstract

The invention discloses a kind of Cu alloy materials of motor device and preparation method thereof, are grouped as by the group of following weight percent:Zinc:0.8 1.1%, tin:0.8 1.1%, manganese:0.4 0.6%, nickel:0.4 0.6%, inevitable impurity iron is less than or equal to 0.03%, and inevitable impurity lead is less than or equal to 0.03%, and surplus is copper.The relatively low tin of chosen material price, zinc, manganese and nickel element under the premise of ensureing alloy material electric conductivity, reduce the cost of manufacture of material, while improving the intensity of material, hardness for replacing silver;The actual effect cure process effect for improving material, meets material and is used under 400 DEG C of environment;Promote service life of the material in Electronic locomotive conductive component.

Description

A kind of Cu alloy material of motor device and preparation method thereof
Technical field
The present invention relates to field of alloy material, more particularly to the Cu alloy material of a kind of motor device and its preparation side Method.
Background technology
TAg0.1 yellow golds are a kind of alloy materials, it is not reduce material by the way that a small amount of silver is added in copper Conduction, heat conduction and it is moulding while, for improving the softening temperature (recrystallization temperature) and creep strength of material.The material Tool has good wearability, electric conductivity and corrosion resistance, and when being such as fabricated to contact line, service life is higher 2-4 than general hard copper Times;And the features such as good conduction, heat conduction, anti-corrosion and processing performance, it can weld and be brazed;But the material actual effect is hard The effect of change is not notable, and easily causes " hydrogen disease ", should not high temperature (such as>370 DEG C) processing (annealing, weldering in reducing atmosphere Connect) and use;Therefore, intensity is generally improved using flow harden.The material is mainly used for making heat-resisting, conductive equipment, Such as motor commutator sheet, generator amature conductor, spot-wedling electrode, connection, lead, conducting wire, electrical tube material.With height The application of the fast development of fast railway, such material achieves progress, but since material cost is higher, and service life has It waits further increasing, use environment (being higher than 370 DEG C) needs further diversification etc., limits corresponding use.
Invention content
For the above defect of the existing technology, it is a primary object of the present invention to overcome the deficiencies in the prior art it Place discloses a kind of Cu alloy material of motor device and preparation method thereof, is grouped as by the group of following weight percent: Zinc:0.8-1.1%, tin:0.8-1.1%, manganese:0.4-0.6%, nickel:0.4-0.6%, inevitable impurity iron are less than or equal to 0.03%, inevitable impurity lead is less than or equal to 0.03%, and surplus is copper.
Further, it is grouped as by the group of following weight percent:Zinc:0.9%, tin:0.9%, manganese:0.45%, nickel: 0.45%, inevitable impurity iron is less than or equal to 0.03%, and inevitable impurity lead is less than or equal to 0.03%, and surplus is Copper.
Further, it is grouped as by the group of following weight percent:Zinc:0.95%, tin:0.95%, manganese:0.5%, nickel: 0.5%, inevitable impurity iron is less than or equal to 0.03%, and inevitable impurity lead is less than or equal to 0.03%, and surplus is Copper.
Further, it is grouped as by the group of following weight percent:Zinc:1.0%, tin:1.0%, manganese:0.55%, nickel: 0.55%, inevitable impurity iron is less than or equal to 0.03%, and inevitable impurity lead is less than or equal to 0.03%, and surplus is Copper.
The preparation method of the Cu alloy material of a kind of motor device provided by the invention, which is characterized in that including following Step:
1) copper is added in electric furnace and carries out melting, be gradually heating to 1280 DEG C, violent will then be added in copper solution into Row melting, smelting time are 1-2 hours;
2) tin, zinc, nickel are proportionally added in copper alloy water, and open agitating device and carries out mechanical agitation, it is complete 1050 DEG C are cooled to after.
3) composition detection is carried out to the copper alloy water that melting is completed, to determine its alloying component within acceptability limit;
4) vibrating device and agitating device are opened, and opens casting drawing equipment, is cast according to scheduled shape of product Blank proximate matter, casting temperature are 1080 DEG C;
5) the blank proximate matter that casting is completed is surface-treated, at corresponding product specification further processing It manages, after the completion packaging and storage.
Further, the electric furnace in step 1) is middle frequency furnace, and capacity is 500KG.
Further, the smelting temperature in step 2) is reduced to 1150-1200 DEG C,
Further, mixing speed is 260r/min, mixing time 15min in step 2).
Further, composition detection is carried out by Spike direct-reading spectrometer pairing Jinsui River in step 3).
Further, step 4) vibration frequency is set as 15-20 times/second, and mixing speed is set as 150r/min, drawing Speed is 15mm/min.
The advantageous effect that the present invention obtains:
The relatively low tin of chosen material price, zinc, manganese and nickel element are for replacing silver, before ensureing alloy material electric conductivity It puts, reduces the cost of manufacture of material, while improving the intensity of material, hardness;The actual effect cure process effect of material is improved, Meet material to use under 400 DEG C of environment;Promote service life of the material in Electronic locomotive conductive component.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiment to the present invention It is described in further detail.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not used to limit The fixed present invention.
Embodiment one
It is zinc (Zn) according to mass percent:0.8%, tin (Sn):0.8%, manganese (Mn):0.4%, nickel (Ni):0.4% And the copper of surplus weighs these raw materials.Inevitably contain some impurity in these raw materials, the present invention claims impurity irons (Fe) it is less than 0.03% relative to the mass percent of total raw material, mass percent of the impurity lead (Pb) relative to total raw material Less than 0.03%.
1) copper is added in the middle frequency furnace of 500KG and carries out melting, be gradually heating to 1280 DEG C, then by violent addition To melting is carried out in copper solution, smelting time is 1 hour;
2) tin, zinc, nickel are proportionally added in copper alloy water, temperature is reduced to 1150 DEG C, and opens stirring dress Carry out mechanical agitation is set, 15min is stirred with the mixing speed of 260r/min, is cooled to 1050 DEG C after the completion.
3) Spike direct-reading spectrometer is used to carry out composition detection to the copper alloy water that melting is completed, to determine its alloy Ingredient is within acceptability limit;
4) vibrating device and agitating device to be opened, and opens casting drawing equipment, vibration frequency is set as 15 times/second, Mixing speed is set as 150r/min, drawing speed 15mm/min, according to scheduled shape of product cast blank proximate matter, casting It is 1080 DEG C to make temperature;
5) the blank proximate matter that casting is completed is surface-treated, at corresponding product specification further processing It manages, after the completion packaging and storage.
The preparation-obtained copper-based alloy material of the method according to the invention (is labeled as LZCu-Sn1-Zn1-Mn0.5- Ni0.5) with the performance comparison such as following table of the TAg0.1 materials of the prior art:
Table 1
Embodiment two
It is zinc (Zn) according to mass percent:0.9%, tin (Sn):0.9%, manganese (Mn):0.45%, nickel (Ni): 0.45% and the copper of surplus weigh these raw materials.Inevitably contain some impurity in these raw materials, the present invention claims miscellaneous Matter iron (Fe) is less than 0.03% relative to the mass percent of total raw material, quality percentage of the impurity lead (Pb) relative to total raw material Than again smaller than 0.03%.
1) copper is added in the middle frequency furnace of 500KG and carries out melting, be gradually heating to 1280 DEG C, then by violent addition To melting is carried out in copper solution, smelting time is 1 hour;
2) tin, zinc, nickel are proportionally added in copper alloy water, temperature is reduced to 1160 DEG C, and opens stirring dress Carry out mechanical agitation is set, 15min is stirred with the mixing speed of 260r/min, is cooled to 1050 DEG C after the completion.
3) Spike direct-reading spectrometer is used to carry out composition detection to the copper alloy water that melting is completed, to determine its alloy Ingredient is within acceptability limit;
4) vibrating device and agitating device to be opened, and opens casting drawing equipment, vibration frequency is set as 16 times/second, Mixing speed is set as 150r/min, drawing speed 15mm/min, according to scheduled shape of product cast blank proximate matter, casting It is 1080 DEG C to make temperature;
5) the blank proximate matter that casting is completed is surface-treated, at corresponding product specification further processing It manages, after the completion packaging and storage.
The preparation-obtained copper-based alloy material of the method according to the invention (is labeled as LZCu-Sn1-Zn1-Mn0.5- Ni0.5) with the performance comparison such as following table of the TAg0.1 materials of the prior art:
Table 2
Embodiment three
It is zinc (Zn) according to mass percent:0.95%, tin (Sn):0.95%, manganese (Mn):0.5%, nickel (Ni): 0.5% and the copper of surplus weigh these raw materials.Inevitably contain some impurity in these raw materials, the present invention claims miscellaneous Matter iron (Fe) is less than 0.03% relative to the mass percent of total raw material, quality percentage of the impurity lead (Pb) relative to total raw material Than again smaller than 0.03%.
1) copper is added in the middle frequency furnace of 500KG and carries out melting, be gradually heating to 1280 DEG C, then by violent addition To melting is carried out in copper solution, smelting time is 1.5 hours;
2) tin, zinc, nickel are proportionally added in copper alloy water, temperature is reduced to 1170 DEG C, and opens stirring dress Carry out mechanical agitation is set, 15min is stirred with the mixing speed of 260r/min, is cooled to 1050 DEG C after the completion.
3) Spike direct-reading spectrometer is used to carry out composition detection to the copper alloy water that melting is completed, to determine its alloy Ingredient is within acceptability limit;
4) vibrating device and agitating device to be opened, and opens casting drawing equipment, vibration frequency is set as 17 times/second, Mixing speed is set as 150r/min, drawing speed 15mm/min, according to scheduled shape of product cast blank proximate matter, casting It is 1080 DEG C to make temperature;
5) the blank proximate matter that casting is completed is surface-treated, at corresponding product specification further processing It manages, after the completion packaging and storage.
The preparation-obtained copper-based alloy material of the method according to the invention (is labeled as LZCu-Sn1-Zn1-Mn0.5- Ni0.5) with the performance comparison such as following table of the TAg0.1 materials of the prior art:
Table 3
Example IV
It is zinc (Zn) according to mass percent:1.0%, tin (Sn):1.0%, manganese (Mn):0.55%, nickel (Ni): 0.55% and the copper of surplus weigh these raw materials.Inevitably contain some impurity in these raw materials, the present invention claims miscellaneous Matter iron (Fe) is less than 0.03% relative to the mass percent of total raw material, quality percentage of the impurity lead (Pb) relative to total raw material Than again smaller than 0.03%.
1) copper is added in the middle frequency furnace of 500KG and carries out melting, be gradually heating to 1280 DEG C, then by violent addition To melting is carried out in copper solution, smelting time is 2 hours;
2) tin, zinc, nickel are proportionally added in copper alloy water, temperature is reduced to 1190 DEG C, and opens stirring dress Carry out mechanical agitation is set, 15min is stirred with the mixing speed of 260r/min, is cooled to 1050 DEG C after the completion.
3) Spike direct-reading spectrometer is used to carry out composition detection to the copper alloy water that melting is completed, to determine its alloy Ingredient is within acceptability limit;
4) vibrating device and agitating device to be opened, and opens casting drawing equipment, vibration frequency is set as 19 times/second, Mixing speed is set as 150r/min, drawing speed 15mm/min, according to scheduled shape of product cast blank proximate matter, casting It is 1080 DEG C to make temperature;
5) the blank proximate matter that casting is completed is surface-treated, at corresponding product specification further processing It manages, after the completion packaging and storage.
The preparation-obtained copper-based alloy material of the method according to the invention (is labeled as LZCu-Sn1-Zn1-Mn0.5- Ni0.5) with the performance comparison such as following table of the TAg0.1 materials of the prior art:
Table 4
Embodiment five
It is zinc (Zn) according to mass percent:1.1%, tin (Sn):1.1%, manganese (Mn):0.6%, nickel (Ni):0.6% And the copper of surplus weighs these raw materials.Inevitably contain some impurity in these raw materials, the present invention claims impurity irons (Fe) it is less than 0.03% relative to the mass percent of total raw material, mass percent of the impurity lead (Pb) relative to total raw material Less than 0.03%.
1) copper is added in the middle frequency furnace of 500KG and carries out melting, be gradually heating to 1280 DEG C, then by violent addition To melting is carried out in copper solution, smelting time is 2 hours;
2) tin, zinc, nickel are proportionally added in copper alloy water, temperature is reduced to 1200 DEG C, and opens stirring dress Carry out mechanical agitation is set, 15min is stirred with the mixing speed of 260r/min, is cooled to 1050 DEG C after the completion.
3) Spike direct-reading spectrometer is used to carry out composition detection to the copper alloy water that melting is completed, to determine its alloy Ingredient is within acceptability limit;
4) vibrating device and agitating device to be opened, and opens casting drawing equipment, vibration frequency is set as 20 times/second, Mixing speed is set as 150r/min, drawing speed 15mm/min, according to scheduled shape of product cast blank proximate matter, casting It is 1080 DEG C to make temperature;
5) the blank proximate matter that casting is completed is surface-treated, at corresponding product specification further processing It manages, after the completion packaging and storage.
The preparation-obtained copper-based alloy material of the method according to the invention (is labeled as LZCu-Sn1-Zn1-Mn0.5- Ni0.5) with the performance comparison such as following table of the TAg0.1 materials of the prior art:
Table 5
As seen from the above table, according to the copper-based alloy material obtained by composition proportion disclosed by the invention and method, material is chosen The relatively low tin of material price, zinc, manganese and nickel element under the premise of ensureing alloy material electric conductivity, reduce material for replacing silver Cost of manufacture, while improving the intensity of material, hardness;The actual effect cure process effect for improving material, meets material at 400 DEG C It is used under environment;Promote service life of the material in Electronic locomotive conductive component.
The foregoing is merely a prefered embodiment of the invention, practical range not for the purpose of limiting the invention;If not departing from this The spirit and scope of invention, modify or equivalently replace the present invention, and should all cover the protection in the claims in the present invention In range.

Claims (10)

1. a kind of Cu alloy material of motor device, which is characterized in that be grouped as by the group of following weight percent:Zinc: 0.8-1.1%, tin:0.8-1.1%, manganese:0.4-0.6%, nickel:0.4-0.6%, inevitable impurity iron are less than or equal to 0.03%, inevitable impurity lead is less than or equal to 0.03%, and surplus is copper.
2. a kind of Cu alloy material of motor device according to claim 1, which is characterized in that by following weight percent Several groups are grouped as:Zinc:0.9%, tin:0.9%, manganese:0.45%, nickel:0.45%, inevitable impurity iron is less than or equal to 0.03%, inevitable impurity lead is less than or equal to 0.03%, and surplus is copper.
3. a kind of Cu alloy material of motor device according to claim 1, which is characterized in that by following weight percent Several groups are grouped as:Zinc:0.95%, tin:0.95%, manganese:0.5%, nickel:0.5%, inevitable impurity iron is less than or equal to 0.03%, inevitable impurity lead is less than or equal to 0.03%, and surplus is copper.
4. a kind of Cu alloy material of motor device according to claim 1, which is characterized in that by following weight percent Several groups are grouped as:Zinc:1.0%, tin:1.0%, manganese:0.55%, nickel:0.55%, inevitable impurity iron is less than or equal to 0.03%, inevitable impurity lead is less than or equal to 0.03%, and surplus is copper.
5. a kind of preparation method of the Cu alloy material of motor device according to any one of claims 1-4, special Sign is, includes the following steps:
1) copper is added in electric furnace and carries out melting, be gradually heating to 1280 DEG C, then melt violent be added in copper solution Refining, smelting time are 1-2 hours;
2) tin, zinc, nickel are proportionally added in copper alloy water, and open agitating device and carries out mechanical agitation, after the completion It is cooled to 1050 DEG C;
3) composition detection is carried out to the copper alloy water that melting is completed, to determine its alloying component within acceptability limit;
4) vibrating device and agitating device are opened, and opens casting drawing equipment, according to scheduled shape of product cast blank Proximate matter, casting temperature are 1080 DEG C;
5) the blank proximate matter that casting is completed is surface-treated, is handled according to corresponding product specification further processing, it is complete At rear packaging and storage.
6. a kind of preparation method of the Cu alloy material of motor device according to claim 5, which is characterized in that step 1) electric furnace in is middle frequency furnace, and capacity is 500KG.
7. a kind of preparation method of the Cu alloy material of motor device according to claim 5, which is characterized in that step 2) smelting temperature in is reduced to 1150-1200 DEG C.
8. a kind of preparation method of the Cu alloy material of motor device according to claim 5, which is characterized in that step 2) mixing speed is 260r/min, mixing time 15min in.
9. a kind of preparation method of the Cu alloy material of motor device according to claim 5, which is characterized in that step 3) composition detection is carried out by Spike direct-reading spectrometer pairing Jinsui River in.
10. a kind of preparation method of the Cu alloy material of motor device according to claim 5, which is characterized in that step Rapid 4) vibration frequency is set as 15-20 times/second, and mixing speed is set as 150r/min, drawing speed 15mm/min.
CN201810540222.0A 2018-05-30 2018-05-30 A kind of Cu alloy material of motor device and preparation method thereof Pending CN108588473A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111850343A (en) * 2020-07-31 2020-10-30 苏州列治埃盟新材料技术转移有限公司 Copper-based alloy material for generator rotor conductor and preparation method thereof
CN111876630A (en) * 2020-07-31 2020-11-03 苏州列治埃盟新材料技术转移有限公司 Copper alloy material for motor equipment and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107354340A (en) * 2017-09-14 2017-11-17 安徽天大铜业有限公司 A kind of copper alloy for cable copper core
CN107400799A (en) * 2017-08-07 2017-11-28 苏州列治埃盟新材料技术转移有限公司 A kind of copper-based alloy material for Electronic locomotive hardware device and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107400799A (en) * 2017-08-07 2017-11-28 苏州列治埃盟新材料技术转移有限公司 A kind of copper-based alloy material for Electronic locomotive hardware device and preparation method thereof
CN107354340A (en) * 2017-09-14 2017-11-17 安徽天大铜业有限公司 A kind of copper alloy for cable copper core

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111850343A (en) * 2020-07-31 2020-10-30 苏州列治埃盟新材料技术转移有限公司 Copper-based alloy material for generator rotor conductor and preparation method thereof
CN111876630A (en) * 2020-07-31 2020-11-03 苏州列治埃盟新材料技术转移有限公司 Copper alloy material for motor equipment and preparation method thereof

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