CN108588329A - A method of improving lime stone mud cake compression moulding rate - Google Patents

A method of improving lime stone mud cake compression moulding rate Download PDF

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Publication number
CN108588329A
CN108588329A CN201810426653.4A CN201810426653A CN108588329A CN 108588329 A CN108588329 A CN 108588329A CN 201810426653 A CN201810426653 A CN 201810426653A CN 108588329 A CN108588329 A CN 108588329A
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CN
China
Prior art keywords
lime stone
mud cake
stone mud
resolution
compression moulding
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810426653.4A
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Chinese (zh)
Inventor
李卫东
龚滔
陈小东
陈红成
温忠义
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MCC Baosteel Technology Services Co Ltd
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MCC Baosteel Technology Services Co Ltd
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Priority to CN201810426653.4A priority Critical patent/CN108588329A/en
Publication of CN108588329A publication Critical patent/CN108588329A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The present invention provides a kind of method improving lime stone mud cake compression moulding rate, includes the following steps:Lime stone mud cake dryness in the sun to moisture content is no more than 10wt%;It stacks resolution and forms resolution material;Resolution material crushing, stirring is formed into mixture;The water glass of binder for accounting for resolution material 5wt% ~ 10wt% is added during crushing, stirring;Mixture enters ball press compression moulding.Simple and practicable by above-mentioned technical proposal in the application, lime stone mud cake balling ratio once freely falls to cement floor in 85% or more, and 2 meters of height, is not more than 5 pieces after broken;Lime stone mud cake is effectively raised using method in the application and is pressed into rate, lime stone mud cake pressure ball production line day 80 tons of constant.

Description

A method of improving lime stone mud cake compression moulding rate
Technical field
The present invention relates to a kind of field of steel-making, more particularly to a kind of method improving lime stone mud cake compression moulding rate.
Background technology
In recent years, China's steelmaking converter used forth generation wet method, and the dry method introduced;Make converter coal gas purification skill Art achieves breakthrough.
New OG is German Lucci corporation special technology, and Kawasaki, Japan heavy industry enjoys the right to use of the technology, and new OG methods are older OG method dust removing effects improve, and water consumption declines, but since it still continues to use the purification of a large amount of muddy water cycle washing dust-laden coal gas Mode, water consumption and power consumption are still higher.
LT dry method is a kind of converter gas purification machine-made egg-shaped or honey-comb coal briquets gas that Lurgi companies of Germany succeed in developing with Thyssen steel plant The dry cleaning system of recycling, which does not have to a large amount of turbid circulating waters and washs coal gas, using devaporizer+electrostatic precipitator " dry type " system of+gas cooler;With purification efficiency height, low energy consumption, briquetting system can be arranged in dry dust, and dust is through briquetting The characteristics of directly being utilized afterwards for converter.
A large amount of converter mud, dedusting are generated by OG methods, LT dry method electric dust-removing process in steelwork converter production process Ash, FeO, CaO of high-content theoretically can be used as making steel coolant recycling, but since bof sludge particle is thinner, Viscosity is smaller, and processing is very difficult, and utilization rate is low, leads to the waste of a large amount of available resources, while causing the dirt of plant environment Dye.It is useful for the technique that lime stone returns STEELMAKING PRODUCTION at present, but under mesolow, the direct pressing molding rate of lime stone mud cake It is extremely low.
Invention content
In view of the foregoing deficiencies of prior art, the purpose of the present invention is to provide a kind of compactings of raising lime stone mud cake The method of ratio of briquetting, for solving the problems, such as that steelwork converter sludge in the prior art and dedusting ash utilization rate are low.
In order to achieve the above objects and other related objects, the present invention obtains by the following technical programs.
The present invention provides a kind of method improving lime stone mud cake compression moulding rate, includes the following steps:
1) lime stone mud cake dryness in the sun to moisture content is no more than 10wt%;
2) it stacks resolution and forms resolution material;
3) resolution material crushing, stirring is formed into mixture;It is added during crushing, stirring and accounts for resolution material 5wt%~10wt% Sodium silicate binder;
4) mixture enters ball press compression moulding.
Preferably, in step 1), lime stone mud cake includes the following raw material ingredient and parts by weight:
Drying is to influence one of the factor of lime stone mud cake agglomerate intensity.Preferably, in step 1), in dryness in the sun to The quick lime of 5wt%~10wt% is added in lime stone mud cake.It is used in the application and accounts for lime stone mud cake 5wt%~10wt%'s Calcium lime powder carries out mixing stacking with lime stone mud cake, and dryness in the sun makes moisture content of the cake be no more than after reaction 10wt%, to ensure the requirement for meeting subsequent production.The quick lime main component is calcium oxide, is that calcium carbonate content is high Limestone is fired to 900 DEG C or more in the limekiln of ventilation to obtain the final product.
Preferably, it in step 1), carries out adding heat assisted drying using the waste heat generated in steelmaking process.
Preferably, in step 2), resolution at least 2 hours is stacked.
Preferably, crushing, stirring carries out in blender in step 3).
Preferably, the mixture is delivered to ball press by conveyer belt by the discharge port of blender.
Preferably, the waterglass in step 3) is added using Sprayable.
Preferably, in step 3), water is added in when crushing, stirring, and the water content for controlling mixture is no more than 7wt%.It is more excellent Water is added with Sprayable in selection of land.
In the application step 4) ball press be middle pressure ball press, be it is a kind of can will it is various do, wet mashes, be a kind of dependence Certainly reenter roll nip is made the higher ball equipment processed of unit weight to material.Ball press model ZY520-100 in the application, It presses ball press for middle hydraulic fluid, and roller diameter 520mm, maximum pressure is 100 tons between roller.Preferably, when in use, described The line pressure ratio of ball press is (1~2) ton/cm.
Preferably, further include being dried after compression moulding, the dry water content to lime stone mud cake is no more than 2wt%.It is highly preferred that dry temperature is 40~55 DEG C.
Disclosed herein as well is the lime stones that method as described above prepares.Preferably, the granularity of the lime stone For 5~30mm.
Disclosed herein as well is the purposes that such as above-mentioned lime stone is used for converter smelting steel grade in addition to silicon steel.
Simple and practicable by above-mentioned technical proposal in the application, lime stone mud cake balling ratio is in 85% or more, and 2 meters of height Degree once freely falls to cement floor, is not more than 5 pieces after broken;Lime stone mud cake is effectively raised using method in the application Be pressed into rate, lime stone mud cake pressure ball production line day 80 tons of constant, you can reach 80 tons with cycling and reutilization lime stone mud cake, stone The abundant recycling of lime stone mud cake, high degree solve the raw material it is original required for the processing costs such as high blowdown, and The design solves that original die mould balling ratio is low, the problem of balling-up intensity deficiency, and crucial institute is solved for lime stone mud cake production line Reducing the dust emission that balling-up enters stove process, is being conducive to that the environmentally protective metaplasia production of steel industry is further pushed to stride forward.
Specific implementation mode
Illustrate that embodiments of the present invention, those skilled in the art can be by this explanations by particular specific embodiment below Content disclosed by book understands other advantages and effect of the present invention easily.
Before further describing the specific embodiments of the present invention, it should be appreciated that protection scope of the present invention is not limited to down State specific specific embodiment;It is also understood that the term used in the embodiment of the present invention is specific specific in order to describe Embodiment, the protection domain being not intended to be limiting of the invention.The test method of actual conditions is not specified in the following example, Usually according to normal condition, or according to the condition proposed by each manufacturer.
When embodiment provides numberical range, it should be appreciated that except non-present invention is otherwise noted, two ends of each numberical range Any one numerical value can be selected between point and two endpoints.Unless otherwise defined, in the present invention all technologies for using and Scientific terminology is identical as the normally understood meaning of those skilled in the art of the present technique.Except used in embodiment specific method, equipment, Outside material, the record according to those skilled in the art to the grasp of the prior art and the present invention can also use and this Any method, equipment and the material of the similar or equivalent prior art of method, equipment described in inventive embodiments, material come real The existing present invention.
The main specifications of the raw material and equipment that are used in the embodiment of the present application is as follows.
Pending lime stone mud cake is by Zhong Ye bao steel technologies Co., Ltd in convertor steelmaking process transfer in the application The lime stone added in stove the cheese cake mass that precipitation aggregation for a long time is formed in roasting.
Ball press in the application uses high-pressure ball press, be it is a kind of can will various dry, wet mashes, be a kind of by object Material reenters the ball equipment processed that roll nip is pressed into unit weight compared with high product certainly.Ball press selection model ZY520- in the application 100, it is produced by Luoyang Zhongyuan Mining Machine Manufactor Co., Ltd., is high-pressure and hydraulic ball press, roller diameter 520mm, roller Maximum pressure is 100 tons between son.Specifically, in the production of the embodiment of the present application, the line pressure ratio for controlling the ball press is (1 ~2) ton/cm.
Embodiment 1
The lime stone mud cake used in the present embodiment includes the following raw material ingredient and parts by weight:
The method that lime stone mud cake compression moulding rate is improved in the present embodiment, includes the following steps:
By lime stone mud cake dryness in the sun, moisture content of the cake is reduced so that mud cake becomes powdering by bulk, in dryness in the sun The quick lime for adding 5wt% into lime stone mud cake in the process, stirs evenly;Through measuring moisture content as 8wt% after dryness in the sun;
Lime stone mud cake after dryness in the sun is stacked resolution and formed to clear up and expects to form within 2 hours resolution material;
Resolution material crushing, stirring is formed into mixture;Resolution material 5wt% is accounted for Sprayable addition during crushing, stirring Water glass of binder;If crushing, stirring needs can also spray water appropriate, the water content for controlling mixture is no more than 7wt%;
Mixture enters ball press compression moulding;
It is dried at 40 DEG C to the water content of lime stone mud cake and is no more than 2wt%.
Embodiment 2
The lime stone mud cake used in the present embodiment includes the following raw material ingredient and parts by weight:
The method that lime stone mud cake compression moulding rate is improved in the present embodiment, includes the following steps:
By lime stone mud cake dryness in the sun, moisture content of the cake is reduced so that mud cake becomes powdering by bulk, in dryness in the sun The quick lime for adding 6wt% into lime stone mud cake in the process, stirs evenly;It is through measuring moisture content after dryness in the sun 10wt%;
Lime stone mud cake after dryness in the sun is stacked resolution and formed to clear up and expects to form within 3 hours resolution material;
Resolution material crushing, stirring is formed into mixture;Resolution material 6wt% is accounted for Sprayable addition during crushing, stirring Water glass of binder;If crushing, stirring needs can also spray water appropriate, the water content for controlling mixture is no more than 7wt%;
Mixture enters ball press compression moulding;
It is dried at 45 DEG C to the water content of lime stone mud cake and is no more than 2wt%.
Embodiment 3
The lime stone mud cake used in the present embodiment includes the following raw material ingredient and parts by weight:
The method that lime stone mud cake compression moulding rate is improved in the present embodiment, includes the following steps:
By lime stone mud cake dryness in the sun, moisture content of the cake is reduced so that mud cake becomes powdering by bulk, in dryness in the sun The quick lime for adding 7wt% into lime stone mud cake in the process, stirs evenly;Through measuring moisture content as 6wt% after dryness in the sun;
Lime stone mud cake after dryness in the sun is stacked resolution and formed to clear up and expects to form within 3 hours resolution material;
Resolution material crushing, stirring is formed into mixture;Resolution material 8wt% is accounted for Sprayable addition during crushing, stirring Water glass of binder;If crushing, stirring needs can also spray water appropriate, the water content for controlling mixture is no more than 7wt%;
Mixture enters ball press compression moulding;
It is dried at 45 DEG C to the water content of lime stone mud cake and is no more than 2wt%.
Embodiment 4
The lime stone mud cake used in the present embodiment includes the following raw material ingredient and parts by weight:
The method that lime stone mud cake compression moulding rate is improved in the present embodiment, includes the following steps:
By lime stone mud cake dryness in the sun, moisture content of the cake is reduced so that mud cake becomes powdering by bulk, in dryness in the sun The quick lime for adding 9wt% into lime stone mud cake in the process, stirs evenly;Through measuring moisture content as 7wt% after dryness in the sun;
Lime stone mud cake after dryness in the sun is stacked resolution and formed to clear up and expects to form within 2 hours resolution material;
Resolution material crushing, stirring is formed into mixture;Resolution material 8wt% is accounted for Sprayable addition during crushing, stirring Water glass of binder;If crushing, stirring needs can also spray water appropriate, the water content for controlling mixture is no more than 7wt%;
Mixture enters ball press compression moulding;
It is dried at 45 DEG C to the water content of lime stone mud cake and is no more than 2wt%.
Embodiment 5
The lime stone mud cake used in the present embodiment includes the following raw material ingredient and parts by weight:
The method that lime stone mud cake compression moulding rate is improved in the present embodiment, includes the following steps:
By lime stone mud cake dryness in the sun, moisture content of the cake is reduced so that mud cake becomes powdering by bulk, in dryness in the sun The quick lime for adding 10wt% into lime stone mud cake in the process, stirs evenly;It is through measuring moisture content after dryness in the sun 6wt%;
Lime stone mud cake after dryness in the sun is stacked resolution and formed to clear up and expects to form within 2 hours resolution material;
Resolution material crushing, stirring is formed into mixture;Resolution material 10wt% is accounted for Sprayable addition during crushing, stirring Water glass of binder;If crushing, stirring needs can also spray water appropriate, the water content for controlling mixture is no more than 7wt%;
Mixture enters ball press compression moulding;
It is dried at 45 DEG C to the water content of lime stone mud cake and is no more than 2wt%.
After measured, the granularity for the lime stone that in the embodiment of the present application 1~5 prepared by method is 5~30mm, and lime stone mud cake 2 meters of height of limestone particle after 85% or more, compression moulding of balling ratio once freely fall to cement floor, it is broken after not More than 5 pieces, intensity is preferable.Above-mentioned lime stone is put into converter, molten steel composition is without exception, uninfluenced.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe The personage for knowing this technology can all carry out modifications and changes to above-described embodiment without violating the spirit and scope of the present invention.Cause This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as At all equivalent modifications or change, should by the present invention claim be covered.

Claims (10)

1. a kind of method improving lime stone mud cake compression moulding rate, includes the following steps:
1) lime stone mud cake dryness in the sun to moisture content is no more than 10wt%;
2) it stacks resolution and forms resolution material;
3) resolution material crushing, stirring is formed into mixture;It is added during crushing, stirring and accounts for the viscous of resolution material 5wt%~10wt% Tie agent waterglass;
4) mixture enters ball press compression moulding.
2. the method as described in claim 1, which is characterized in that in step 1), lime stone mud cake include the following raw material ingredient and Parts by weight:
3. the method as described in claim 1, which is characterized in that in step 1), add into lime stone mud cake in dryness in the sun Add the calcium oxide calcium lime powder of 5wt%~10wt%.
4. the method as described in claim 1, which is characterized in that in step 2), stack resolution at least 2 hours.
5. the method as described in claim 1, which is characterized in that in step 3), waterglass is added using Sprayable.
6. the method as described in claim 1, which is characterized in that in step 3), water is added in when crushing, stirring, and controls mixture Water content be no more than 7wt%.
7. the method as described in claim 1, which is characterized in that further include being dried after compression moulding, it is dry to stone The water content of lime stone mud cake is no more than 2wt%.
8. a kind of lime stone prepared by claim 1~7 any one of them method.
9. lime stone as claimed in claim 8, which is characterized in that the granularity of the lime stone is 5~30mm.
10. a kind of lime stone as claimed in claim 8 is used for the purposes of converter smelting steel grade in addition to silicon steel.
CN201810426653.4A 2018-05-07 2018-05-07 A method of improving lime stone mud cake compression moulding rate Pending CN108588329A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111961868A (en) * 2020-08-07 2020-11-20 阳春新钢铁有限责任公司 Digestion preparation method of converter waste sludge

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101559299A (en) * 2008-04-16 2009-10-21 中冶宝钢技术服务有限公司 Processing technology for recycle of metallurgical solid waste
CN105174914A (en) * 2015-08-13 2015-12-23 上海中冶环境工程科技有限公司 Method for preparing ceramsite with metallurgical waste slag as raw material
CN106636532A (en) * 2016-09-19 2017-05-10 中冶宝钢技术服务有限公司 Limestone mud cake re-production auxiliary material and preparation technique thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101559299A (en) * 2008-04-16 2009-10-21 中冶宝钢技术服务有限公司 Processing technology for recycle of metallurgical solid waste
CN105174914A (en) * 2015-08-13 2015-12-23 上海中冶环境工程科技有限公司 Method for preparing ceramsite with metallurgical waste slag as raw material
CN106636532A (en) * 2016-09-19 2017-05-10 中冶宝钢技术服务有限公司 Limestone mud cake re-production auxiliary material and preparation technique thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111961868A (en) * 2020-08-07 2020-11-20 阳春新钢铁有限责任公司 Digestion preparation method of converter waste sludge

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Application publication date: 20180928