CN108587820A - One kind industrial detergent containing Organic fluoride and preparation method thereof - Google Patents
One kind industrial detergent containing Organic fluoride and preparation method thereof Download PDFInfo
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- CN108587820A CN108587820A CN201810242463.7A CN201810242463A CN108587820A CN 108587820 A CN108587820 A CN 108587820A CN 201810242463 A CN201810242463 A CN 201810242463A CN 108587820 A CN108587820 A CN 108587820A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
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Abstract
The invention discloses a kind of industrial detergents containing Organic fluoride and preparation method thereof, belong to detergent technical field.The industrial detergent containing Organic fluoride, including following raw material：Soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, sodium citrate, sodium tripolyphosphate, carboxymethyl cellulose, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% 4 amino, 3,5 dichloro, 6 fluorine pyridine, 2 Fratol, deionized water, gibbsite type aluminum hydroxide particles, benzoyl peroxide, sodium lignin sulfonate；The industrial detergent containing Organic fluoride be through mixing, stir and etc. be made.The present invention is reinforcement system by using gibbsite type aluminum hydroxide particles, benzoyl peroxide, sodium lignin sulfonate, improves the washing performance of the industrial detergent containing Organic fluoride and oily separation property.
Description
Technical field
The invention belongs to detergent technical fields, and in particular to one kind industrial detergent containing Organic fluoride and preparation method thereof.
Background technology
In existing all kinds of detergent, what is played a major role is surfactant, and active principle is：In molecule RH-X structures
In, RH is hydro carbons hydrophobic group, and X is hydrophilic radical.The compound of this structure can make the table of its solution (generally aqueous solution)
Face tension reduces, and changes the interface state of system.When its solution reaches a certain concentration (carboxymethyl cellulose), just in the solution
Micelle is generated, to generate wetting, emulsification, blistering, solubilization, cleaning function.At present both at home and abroad all kinds of detergent formula and have
Pass standard regulation, the content of surfactant, nonionic are not less than 10%, and anionic is not less than 15%, to obtain higher
Quality (mainly improving detergency) is typically to increase the dosage of surfactant in formula, generally it is made to be increased to 18% or more,
Some is up to 25%-30%.Product cost thus is increased, limits the development of detergent, conventional washing agent is several in quality
Fail always to have compared with quantum jump over 10 years.Industrial development is getting faster, the sanitary condition in workshop is also required it is higher and higher, if
Machine vehicle device is the same also like pervious old-fashioned factory, there is many greasy dirts, not only influences the beautiful health for also influencing worker.
Chinese patent literature " detergent (the Authorization Notice No. containing organofluoro surfactants：CN1070227C it) " discloses
Detergent containing organofluoro surfactants, the fluorination self-clean type plastic plate, is made of the raw material of following weight parts：Soap base
2 parts, 2 parts of dodecyl benzene sulfonic acid, 1.5 parts of fatty alcohol polyoxyethylene ether, 0.5 part of cocoanut fatty acid diethanolamide, lemon
10 parts of sour sodium, 5 parts of sodium tripolyphosphate, 1 part of carboxymethyl cellulose, 10 parts of sodium metasilicate, 10% 2 parts of NaOH, 1 part of NaCl, firefly
0.1 part of optical brightener, 10% fluoro- 0.06 part of the pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, 65 parts of deionized water.
Compared with traditional detergent, detergency increases substantially for the invention, and the cost of raw material is greatly lowered, but there are washing performance,
The poor problem of oily separation property.
Invention content
The object of the present invention is to provide a kind of industrial detergents containing Organic fluoride and preparation method thereof, to solve in patent document
" detergent (the Authorization Notice No. containing organofluoro surfactants：CN1070227C) " disclosed containing organofluoro surfactants
On the basis of detergent, how to optimize component, dosage, method etc., improves washing performance, the oil of the industrial detergent containing Organic fluoride
From property the problem of.
In order to solve the above technical problems, the present invention uses following technical scheme：
A kind of industrial detergent containing Organic fluoride, including following raw material：Soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxy second
Alkene ether, cocoanut fatty acid diethanolamide, sodium citrate, sodium tripolyphosphate, carboxymethyl cellulose, sodium metasilicate, 10%
NaOH, NaCl, fluorescent bleaches, the 10% fluoro- pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, deionized water, three water
Aluminium stone-type aluminum hydroxide particles, benzoyl peroxide, sodium lignin sulfonate；The gibbsite type aluminum hydroxide particles, mistake
Benzoyl Oxide, the weight ratio of sodium lignin sulfonate are (1-3)：(0.02-0.04)：(2-4).
Further, the weight ratio of the gibbsite type aluminum hydroxide particles, benzoyl peroxide, sodium lignin sulfonate
It is 2:0.03:3.
Further, the industrial detergent containing Organic fluoride is as unit of parts by weight, including following raw material：1-3 parts of soap base,
1-3 parts of dodecyl benzene sulfonic acid, 1-2 parts of fatty alcohol polyoxyethylene ether, 0.1-1 parts of cocoanut fatty acid diethanolamide, lemon
Sour sodium 5-15 parts, 3-7 parts of sodium tripolyphosphate, 0.5-1.5 parts of carboxymethyl cellulose, 5-15 parts of sodium metasilicate, 10% NaOH1-3
Part, NaCl0.5-1.5 parts, 0.05-0.15 parts of fluorescent bleaches, 10% the two fluoro- pyridine -2- oxygen second of chloro- 6- of 4- amino -3,5-
Sour sodium 0.03-0.09 parts, 60-70 parts of deionized water, 1-3 parts of gibbsite type aluminum hydroxide particles, benzoyl peroxide 0.02-
0.04 part, 2-4 parts of sodium lignin sulfonate.
Further, the primary particle diameter of the gibbsite type aluminum hydroxide particles is 0.01 μm -0.3 μm.
Further, the fluorescent bleaches is double triazine amino-stilbenes.
Further, the soap base is reacted by sodium hydroxide with one kind in olive oil, palm oil in water.
The present invention also provides a kind of preparation methods of the above-mentioned industrial detergent containing Organic fluoride, include the following steps：
S1：Configure 10% NaOH, the 10% two fluoro- pyridine -2- Fratols solution for standby of chloro- 6- of 4- amino -3,5-；
S2：By soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, lemon
Sour sodium, sodium tripolyphosphate, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% two chloro- 6- of 4- amino -3,5- it is fluoro-
After pyridine -2- Fratols, deionized water, sodium lignin sulfonate are sufficiently mixed, carboxymethyl cellulose, gibbsite type hydrogen is added
Aluminium oxide particles are thoroughly mixed；
S3：It is added after benzoyl peroxide is sufficiently stirred and is stored in shady place.
Further, it is stirred in the step S2 and is mixed using 1200 revs/min of blender.
The invention has the advantages that：
(1) by the data of embodiment 1-3 and comparative example 5 as it can be seen that the industrial detergent containing Organic fluoride made from embodiment 1-3
Washing performance and oily separation property are significantly higher than the washing performance of detergent made from comparative example 5 and oily separation property；Simultaneously by embodiment 1-3
Data as it can be seen that embodiment 1 be optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-4 as it can be seen that gibbsite type aluminum hydroxide particles, benzoyl peroxide first
Acyl, sodium lignin sulfonate play synergistic effect in preparing industrial detergent containing Organic fluoride, and collaboration improves work containing Organic fluoride
The washing performance of industry detergent and oily separation property；This is：
Gibbsite type aluminum hydroxide particles are amphoteric hydroxides, and the aluminum hydroxide particles of particulate form are in detergent
Can be as absorption core, absorption oil phase is to reinforce the effect of separation of oil, while aluminium hydroxide encounters acid or alkaline scale,
Inorganic particulate can be resolved into, to increase friction effect in washing process, to realize disengaging dirt, enhances washing effect；Wood
Quality sodium sulfonate is a kind of natural polymers, and anionic surfactant has very strong dispersibility, and being suitable for will
Solid is dispersed in aqueous medium, and it is adsorbed on hydrogen bond energy on the surface of aluminum hydroxide particles, is deposited in institutional framework
In various active groups, have the effect of adsorbing grease well, when aluminium hydroxide rubs washings surface, can faster remove
Grease on washings surface, to enhance aluminium hydroxide friction clean effect, while it is with strong emulsifying effectiveness, can be by oil phase
Emulsion state is agglomerated into, separation of oil effect is realized to enhance；Benzoyl peroxide is a kind of organic peroxide, is had
Oxygenolysis effect, in washing process acting on enhancing with fabric surface is detached from effect, and due to its unstability, with hydrogen
After aluminium oxide cooperation, is acted on using the hydroxyl and weak complexing on aluminum hydroxide particle surface, consolidate its molecular structure, prevent it in height
It is decomposed under temperature or poor environment, so as to enhance stability, and it acts on its better is dispersed in sodium lignin sulfonate and washes
It washs in agent, to enhance washing performance and separation of oil effect.
(3) by the data of comparative example 6-8 as it can be seen that gibbsite type aluminum hydroxide particles, benzoyl peroxide, sulfomethylated lignin
The weight ratio of sour sodium is not at (1-3)：(0.02-0.04)：When in (2-4) range, the washing performance and oil of detergent obtained detach
Property numerical value and embodiment 1-3 numerical value be very different, be much smaller than embodiment 1-3 numerical value, the number with the prior art (comparative example 5)
Value is suitable.Gibbsite type aluminum hydroxide particles of the present invention, benzoyl peroxide, sodium lignin sulfonate are real as reinforcement system
Apply a 1-3 when preparing industrial detergent containing Organic fluoride by add gibbsite type aluminum hydroxide particles, benzoyl peroxide,
The weight ratio of sodium lignin sulfonate is (1-3)：(0.02-0.04)：(2-4) is realized and is utilized gibbsite type in reinforcement system
Aluminum hydroxide particles accelerate dirt to be detached from rate and separation of oil effect as oil suction core and friction particles；Benzoyl peroxide first
Acyl is used together with sodium lignin sulfonate, is improved in the oily separation property of the industrial detergent containing Organic fluoride, organic matter discomposing effect；Wood
Quality sodium sulfonate improves the dispersibility and stability of gibbsite type aluminum hydroxide particles, benzoyl peroxide, improves containing organic
The features such as washing performance of fluorine industrial detergent and oily separation property so that gibbsite type aluminum hydroxide particles, benzoyl peroxide,
The reinforcement system that sodium lignin sulfonate is constituted improves industrial washing containing Organic fluoride in the industrial detergent containing Organic fluoride of the present invention
The washing performance of agent and oily separation property.
Specific implementation mode
For ease of more fully understanding the present invention, it is illustrated by the following examples, these examples belong to the protection of the present invention
Range, but do not limit the scope of the invention.
In embodiment, the industrial detergent containing Organic fluoride, as unit of parts by weight, including following raw material：Soap base 1-3
Part, 1-3 parts of dodecyl benzene sulfonic acid, 1-2 parts of fatty alcohol polyoxyethylene ether, 0.1-1 parts of cocoanut fatty acid diethanolamide, lemon
5-15 parts of lemon acid sodium, 3-7 parts of sodium tripolyphosphate, 0.5-1.5 parts of carboxymethyl cellulose, 5-15 parts of sodium metasilicate, 10% NaOH1-3
Part, NaCl0.5-1.5 parts, 0.05-0.15 parts of fluorescent bleaches, 10% the two fluoro- pyridine -2- oxygen second of chloro- 6- of 4- amino -3,5-
Sour sodium 0.03-0.09 parts, 60-70 parts of deionized water, 1-3 parts of gibbsite type aluminum hydroxide particles, benzoyl peroxide 0.02-
0.04 part, 2-4 parts of sodium lignin sulfonate..
The primary particle diameter of the gibbsite type aluminum hydroxide particles is 0.01 μm -0.3 μm.
The fluorescent bleaches is double triazine amino-stilbenes.
The soap base is reacted by sodium hydroxide with one kind in olive oil, palm oil in water.
The preparation method of the industrial detergent containing Organic fluoride, includes the following steps：
S1：Configure 10% NaOH, the 10% two fluoro- pyridine -2- Fratols solution for standby of chloro- 6- of 4- amino -3,5-；
S2：By soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, lemon
Sour sodium, sodium tripolyphosphate, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% two chloro- 6- of 4- amino -3,5- it is fluoro-
After pyridine -2- Fratols, deionized water, sodium lignin sulfonate are sufficiently mixed, carboxymethyl cellulose, gibbsite type hydrogen is added
Aluminium oxide particles are thoroughly mixed；
S3：It is added after benzoyl peroxide is sufficiently stirred and is stored in shady place.
Embodiment 1
A kind of industrial detergent containing Organic fluoride, as unit of parts by weight, including following raw material：2 parts of soap base, detergent alkylate
2 parts of sulfonic acid, 1.5 parts of fatty alcohol polyoxyethylene ether, 0.5 part of cocoanut fatty acid diethanolamide, 10 parts of sodium citrate, trimerization phosphorus
5 parts of sour sodium, 1 part of carboxymethyl cellulose, 10 parts of sodium metasilicate, 10% 2 parts of NaOH, 1 part of NaCl, 0.1 part of fluorescent bleaches,
10% fluoro- 0.06 part of pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, 65 parts of deionized water, gibbsite type hydrogen-oxygen
Change 2 parts of aluminum particulate, 0.03 part of benzoyl peroxide, 3 parts of sodium lignin sulfonate..
The primary particle diameter of the gibbsite type aluminum hydroxide particles is 0.01 μm -0.3 μm.
The fluorescent bleaches is double triazine amino-stilbenes.
The soap base is reacted by sodium hydroxide with olive oil in water.
The preparation method of the industrial detergent containing Organic fluoride, includes the following steps：
S1：Configure 10% NaOH, the 10% two fluoro- pyridine -2- Fratols solution for standby of chloro- 6- of 4- amino -3,5-；
S2：By soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, lemon
Sour sodium, sodium tripolyphosphate, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% two chloro- 6- of 4- amino -3,5- it is fluoro-
After pyridine -2- Fratols, deionized water, sodium lignin sulfonate are sufficiently mixed, carboxymethyl cellulose, gibbsite type hydrogen is added
Aluminium oxide particles are thoroughly mixed；
S3：It is added after benzoyl peroxide is sufficiently stirred and is stored in shady place.
Embodiment 2
A kind of industrial detergent containing Organic fluoride, as unit of parts by weight, including following raw material：1 part of soap base, detergent alkylate
3 parts of sulfonic acid, 1 part of fatty alcohol polyoxyethylene ether, 1 part of cocoanut fatty acid diethanolamide, 5 parts of sodium citrate, sodium tripolyphosphate 7
Part, 0.5 part of carboxymethyl cellulose, 15 parts of sodium metasilicate, 10% NaOH1 parts, 1.5 parts of NaCl, 0.05 part of fluorescent bleaches,
10% fluoro- 0.09 part of pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, 60 parts of deionized water, gibbsite type hydrogen-oxygen
Change 3 parts of aluminum particulate, 0.02 part of benzoyl peroxide, 4 parts of sodium lignin sulfonate..
The primary particle diameter of the gibbsite type aluminum hydroxide particles is 0.01 μm -0.3 μm.
The fluorescent bleaches is double triazine amino-stilbenes.
The soap base is reacted by sodium hydroxide with palm oil in water.
The preparation method of the industrial detergent containing Organic fluoride, includes the following steps：
S1：Configure 10% NaOH, the 10% two fluoro- pyridine -2- Fratols solution for standby of chloro- 6- of 4- amino -3,5-；
S2：By soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, lemon
Sour sodium, sodium tripolyphosphate, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% two chloro- 6- of 4- amino -3,5- it is fluoro-
After pyridine -2- Fratols, deionized water, sodium lignin sulfonate are sufficiently mixed, carboxymethyl cellulose, gibbsite type hydrogen is added
Aluminium oxide particles are thoroughly mixed；
S3：It is added after benzoyl peroxide is sufficiently stirred and is stored in shady place.
Embodiment 3
A kind of industrial detergent containing Organic fluoride, as unit of parts by weight, including following raw material：3 parts of soap base, detergent alkylate
1 part of sulfonic acid, 2 parts of fatty alcohol polyoxyethylene ether, 0.1 part of cocoanut fatty acid diethanolamide, 15 parts of sodium citrate, tripolyphosphate
3 parts of sodium, 1.5 parts of carboxymethyl cellulose, 5 parts of sodium metasilicate, 10% 3 parts of NaOH, NaCl0.5 parts, 0.15 part of fluorescent bleaches,
10% fluoro- 0.03 part of pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, 70 parts of deionized water, gibbsite type hydrogen-oxygen
Change 3 parts of aluminum particulate, 0.02 part of benzoyl peroxide, 4 parts of sodium lignin sulfonate..
The primary particle diameter of the gibbsite type aluminum hydroxide particles is 0.01 μm -0.3 μm.
The fluorescent bleaches is double triazine amino-stilbenes.
The soap base is reacted by sodium hydroxide with olive oil in water.
The preparation method of the industrial detergent containing Organic fluoride, includes the following steps：
S1：Configure 10% NaOH, the 10% two fluoro- pyridine -2- Fratols solution for standby of chloro- 6- of 4- amino -3,5-；
S2：By soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, lemon
Sour sodium, sodium tripolyphosphate, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% two chloro- 6- of 4- amino -3,5- it is fluoro-
After pyridine -2- Fratols, deionized water, sodium lignin sulfonate are sufficiently mixed, carboxymethyl cellulose, gibbsite type hydrogen is added
Aluminium oxide particles are thoroughly mixed；
S3：It is added after benzoyl peroxide is sufficiently stirred and is stored in shady place.
Comparative example 1
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
In lack gibbsite type aluminum hydroxide particles, benzoyl peroxide, sodium lignin sulfonate.
Comparative example 2
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
In lack gibbsite type aluminum hydroxide particles.
Comparative example 3
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
In lack benzoyl peroxide.
Comparative example 4
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
In lack sodium lignin sulfonate.
Comparative example 5
Using the Chinese patent literature " detergent (Authorization Notice No. containing organofluoro surfactants：CN1070227C in) "
Method described in specific embodiment 1 prepares detergent.
Comparative example 6
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
Middle gibbsite type aluminum hydroxide particles are 0.5 part, benzoyl peroxide is 1 part, sodium lignin sulfonate is 6 parts.
Comparative example 7
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
Middle gibbsite type aluminum hydroxide particles are 5 parts, benzoyl peroxide is 0.01 part, sodium lignin sulfonate is 1 part.
Comparative example 8
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the raw material of the industrial detergent containing Organic fluoride
Middle gibbsite type aluminum hydroxide particles are 0.5 part, benzoyl peroxide is 1 part, sodium lignin sulfonate is 1 part.
Washing performance is carried out to product made from embodiment 1-3 and comparative example 1-8 and oily separation property is tested, as a result such as following table institute
Show.Washing force evaluation method and evaluation criteria：Removal rate (%)=(A-B)/A × 100 are (in formula：A is the dirt of attachment before experiment
Object weight is contaminated, B is the pollutant weight adhered to after washing force is tested).The evaluation method and evaluation criteria of oil-water separativeness：Grease
Separation property (%)=(A-B)/A × 100 are (in formula：A is the COD before water-oil separating, and B is the COD of the water layer after water-oil separating).
As seen from the above table：(1) by the data of embodiment 1-3 and comparative example 5 as it can be seen that containing Organic fluoride made from embodiment 1-3
The washing performance of industrial detergent and oily separation property are significantly higher than the washing performance of detergent made from comparative example 5 and oily separation property；Together
When by the data of embodiment 1-3 as it can be seen that embodiment 1 be optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-4 as it can be seen that gibbsite type aluminum hydroxide particles, benzoyl peroxide first
Acyl, sodium lignin sulfonate play synergistic effect in preparing industrial detergent containing Organic fluoride, and collaboration improves work containing Organic fluoride
The washing performance of industry detergent and oily separation property；This is：
Gibbsite type aluminum hydroxide particles are amphoteric hydroxides, and the aluminum hydroxide particles of particulate form are in detergent
Can be as absorption core, absorption oil phase is to reinforce the effect of separation of oil, while aluminium hydroxide encounters acid or alkaline scale,
Inorganic particulate can be resolved into, to increase friction effect in washing process, to realize disengaging dirt, enhances washing effect；Wood
Quality sodium sulfonate is a kind of natural polymers, and anionic surfactant has very strong dispersibility, and being suitable for will
Solid is dispersed in aqueous medium, and it is adsorbed on hydrogen bond energy on the surface of aluminum hydroxide particles, is deposited in institutional framework
In various active groups, have the effect of adsorbing grease well, when aluminium hydroxide rubs washings surface, can faster remove
Grease on washings surface, to enhance aluminium hydroxide friction clean effect, while it is with strong emulsifying effectiveness, can be by oil phase
Emulsion state is agglomerated into, separation of oil effect is realized to enhance；Benzoyl peroxide is a kind of organic peroxide, is had
Oxygenolysis effect, in washing process acting on enhancing with fabric surface is detached from effect, and due to its unstability, with hydrogen
After aluminium oxide cooperation, is acted on using the hydroxyl and weak complexing on aluminum hydroxide particle surface, consolidate its molecular structure, prevent it in height
It is decomposed under temperature or poor environment, so as to enhance stability, and it acts on its better is dispersed in sodium lignin sulfonate and washes
It washs in agent, to enhance washing performance and separation of oil effect.
(3) by the data of comparative example 6-8 as it can be seen that gibbsite type aluminum hydroxide particles, benzoyl peroxide, sulfomethylated lignin
The weight ratio of sour sodium is not at (1-3)：(0.02-0.04)：When in (2-4) range, the washing performance and oil of detergent obtained detach
Property numerical value and embodiment 1-3 numerical value be very different, be much smaller than embodiment 1-3 numerical value, the number with the prior art (comparative example 5)
Value is suitable.Gibbsite type aluminum hydroxide particles of the present invention, benzoyl peroxide, sodium lignin sulfonate are real as reinforcement system
Apply a 1-3 when preparing industrial detergent containing Organic fluoride by add gibbsite type aluminum hydroxide particles, benzoyl peroxide,
The weight ratio of sodium lignin sulfonate is (1-3)：(0.02-0.04)：(2-4) is realized and is utilized gibbsite type in reinforcement system
Aluminum hydroxide particles accelerate dirt to be detached from rate and separation of oil effect as oil suction core and friction particles；Benzoyl peroxide first
Acyl is used together with sodium lignin sulfonate, is improved in the oily separation property of the industrial detergent containing Organic fluoride, organic matter discomposing effect；Wood
Quality sodium sulfonate improves the dispersibility and stability of gibbsite type aluminum hydroxide particles, benzoyl peroxide, improves containing organic
The features such as washing performance of fluorine industrial detergent and oily separation property so that gibbsite type aluminum hydroxide particles, benzoyl peroxide,
The reinforcement system that sodium lignin sulfonate is constituted improves industrial washing containing Organic fluoride in the industrial detergent containing Organic fluoride of the present invention
The washing performance of agent and oily separation property.
The above content is it cannot be assumed that present invention specific implementation is confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all answers
When being considered as belonging to present invention scope of patent protection determined by the appended claims.
Claims (8)
1. a kind of industrial detergent containing Organic fluoride, which is characterized in that including following raw material：Soap base, dodecyl benzene sulfonic acid, fat
Alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, sodium citrate, sodium tripolyphosphate, carboxymethyl cellulose, sodium metasilicate,
10% NaOH, NaCl, fluorescent bleaches, the 10% fluoro- pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, deionization
Water, gibbsite type aluminum hydroxide particles, benzoyl peroxide, sodium lignin sulfonate；The gibbsite type aluminum hydroxide
Particle, benzoyl peroxide, sodium lignin sulfonate weight ratio be (1-3)：(0.02-0.04)：(2-4).
2. industrial detergent containing Organic fluoride according to claim 1, which is characterized in that the gibbsite type aluminum hydroxide
Particle, benzoyl peroxide, sodium lignin sulfonate weight ratio be 2:0.03:3.
3. industrial detergent containing Organic fluoride according to claim 1, which is characterized in that the industrial detergent containing Organic fluoride
As unit of parts by weight, including following raw material：1-3 parts of soap base, 1-3 parts of dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether 1-2
Part, 0.1-1 parts of cocoanut fatty acid diethanolamide, 5-15 parts of sodium citrate, 3-7 parts of sodium tripolyphosphate, carboxymethyl cellulose
0.5-1.5 parts, 5-15 parts of sodium metasilicate, 10% NaOH1-3 parts, NaCl0.5-1.5 parts, 0.05-0.15 parts of fluorescent bleaches,
10% fluoro- 0.03-0.09 parts of pyridine -2- Fratols of two chloro- 6- of 4- amino -3,5-, 60-70 parts of deionized water, three water aluminium
1-3 parts of stone-type aluminum hydroxide particles, 0.02-0.04 parts of benzoyl peroxide, 2-4 parts of sodium lignin sulfonate.
4. industrial detergent containing Organic fluoride according to claim 1, which is characterized in that the gibbsite type aluminum hydroxide
The primary particle diameter of particle is 0.01 μm -0.3 μm.
5. industrial detergent containing Organic fluoride according to claim 1, which is characterized in that the fluorescent bleaches is double triazines
Amino-stilbene.
6. industrial detergent containing Organic fluoride according to claim 1, which is characterized in that the soap base is by sodium hydroxide and olive
One kind in olive oil, palm oil is reacted in water.
7. a kind of preparation method according to claim 1-6 any one of them industrial detergent containing Organic fluoride, which is characterized in that
Include the following steps：
S1：Configure 10% NaOH, the 10% two fluoro- pyridine -2- Fratols solution for standby of chloro- 6- of 4- amino -3,5-；
S2：By soap base, dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether, cocoanut fatty acid diethanolamide, citric acid
Sodium, sodium tripolyphosphate, sodium metasilicate, 10% NaOH, NaCl, fluorescent bleaches, 10% the two chloro- fluoro- pyrroles of 6- of 4- amino -3,5-
After pyridine -2- Fratols, deionized water, sodium lignin sulfonate are sufficiently mixed, carboxymethyl cellulose, gibbsite type hydrogen-oxygen is added
Change aluminum particulate to be thoroughly mixed；
S3：It is added after benzoyl peroxide is sufficiently stirred and is stored in shady place.
8. the preparation method of the industrial detergent according to claim 7 containing Organic fluoride, which is characterized in that in the step S2
It is stirred and is mixed using 1200 revs/min of blender.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113502193A (en) * | 2021-07-05 | 2021-10-15 | 安徽海顺化工有限公司 | Anionic surface active industrial detergent and preparation method thereof |
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