CN108587704A - A kind of vehicle-use alcohol gasoline E10 constituents - Google Patents
A kind of vehicle-use alcohol gasoline E10 constituents Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
- C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only
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- Oil, Petroleum & Natural Gas (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to the preparations of 93#, 97# vehicle-use alcohol gasoline E10 constituents, it includes anaerobic gasoline base material or light aromatic hydrocarbons and dimethylbenzene, alcohol fuel, biphenyl, polyethers amine type detergent-dispersant additive, all technical indicators of quaternary ammonium salt cation fluorocarbon surfactant and friction improver, vehicle-use alcohol gasoline E10 constituents of the present invention meet state six " vehicle-use alcohol gasoline E10 " standard.The power of vehicle-use alcohol gasoline E10 constituents of the present invention improves 5% or more, fuel-efficient 5% or more than E10 93#, the E10 97# " vehicle-use alcohol gasoline E10 " of market supply, and exhaust emission declines 40% or more.
Description
Technical field
The present invention relates to the preparations of clean energy resource field more particularly to 93# and 97# vehicle-use alcohol gasoline E10 constituents.
Background technology
Having " vehicle-use alcohol gasoline E10 " substantially oil plant first uses catalytic cracking, the devices such as Atmospheric vacuum to produce not
Oil reconciles into national standard E10-93#, E10-97# with 10% alcohol fuel again based on oxygen containing nine component oil by four~carbon of carbon
Vehicle-use alcohol gasoline.Vehicle-use alcohol gasoline E10 great advantages are that oxygen content is up to 3.5%m/m.Octane number is high, burning is filled completely
Point, pollutant emission is than 40% or more state's six gasoline decline in tail gas.It is a kind of environmental-friendly vehicle-use alcohol gasoline E10.
But, vehicle-use alcohol gasoline E10 and regular gasoline more also have several drawbacks in that, ethyl alcohol calorific value lower than gasoline 35% actually makes
With middle power dropping 3%-5%, acceleration is slow in reacting, and fuel consumption of 100km improves 3%-5%, and ethyl alcohol is hygroscopic, to hair
Each component of motivation has corrosiveness.Gasoline filter element and atomizer can be blocked when serious.Using vehicle-use alcohol gasoline E10 can increase into
Carbon is tied in valve and combustion chamber.
Invention content
For the shortcoming of above-mentioned vehicle-use alcohol gasoline E10, the present invention utilizes gasoline polyethers amine type detergent-dispersant additive,
Friction improver, quaternary ammonium salt cation fluorocarbon surfactant are re-dubbed a kind of vehicle-use alcohol gasoline E10 constituents, will
With the presence of vehicle-use alcohol gasoline E10 disadvantages can thoroughly solve.
To achieve the above object, the present invention provides a kind of " vehicle-use alcohol gasoline E10 ", is prepared by the following method,
With oily 300 parts by weight of C4-C9 light components, 250 parts by weight of isooctane (alkylate oil), 350 parts by weight of aromatic hydrocarbons, alcohol fuel
100 parts by weight, 0.6 parts by weight of biphenyl, 0.4 parts by weight of polyethers amine type cleaning dispersant for gasoline, quaternary ammonium salt cation fluorine carbon table
0.4 parts by weight of face activating agent, 8825A friction improvers, 0.6 parts by weight.One kind is reconciled into online through oil plant pipe-line mixer
Octane number 93#, density 0.74,1100 kilocalories of calorific value ＞/kilogram " vehicle-use alcohol gasoline E10 ".
The present invention provides another " vehicle-use alcohol gasoline E10 ", is prepared by the following method, uses light aromatic hydrocarbons 750
Parts by weight, 150 parts by weight of dimethylbenzene, 100 parts by weight of alcohol fuel, 0.45 parts by weight of biphenyl, polyethers amine type detergent-dispersant additive 0.4
Parts by weight, 0.3 parts by weight of quaternary ammonium salt cation fluorocarbon surfactant, high activity oil-soluble phosphate MAX-P160.45 weights
Measure part.A kind of octane number 97# " vehicle-use alcohol gasoline E10 " is reconciled into online through oil plant pipe-line mixer.
" the vehicle-use alcohol gasoline E10 " reconciled with the production of this preparation method, all technical indicators meet " the automobile-used second of state six
Alcohol gasoline E10 " standards, research octane number (RON)：Bis- kinds of specifications of 93# and 97#, sulfur content ＜ 10PPM (mass fraction), benzene content
＜ 0.8% (mass fraction), alkene ＜ 18% (mass fraction), aromatic hydrocarbons ＜ 35% (mass fraction), 3.5% (matter of oxygen content ＜
Measure score), 40 DEG C of -190 DEG C of metals of boiling range and all technical are met the requirements of the standard.E10- of the power than market supply
93#, E10-97# " vehicle-use alcohol gasoline E10 " improve 5% or more, fuel-efficient 5% or more, and exhaust emission is than commercially available vehicle ethanol
Gasoline E10 declines 40% or more.It is a kind of " vehicle-use alcohol gasoline E10 ".
C4-C9 light components oil is the lighter by-products that oil plant produces or tops or isomerized oil, alkane, cycloalkanes
The compositions such as hydrocarbon, light aromatic hydrocarbons, alkene, component oil of the boiling range at 40 DEG C -190 DEG C, between 0.66-0.72, octane number exists density
Between 70-80, color water white, free from extraneous odour.Because octane number is low, motor petrol use cannot be made, be a kind of tune of motor petrol
And component.
Isooctane is being commonly called as 2.2.4 trimethylpentanes, is a kind of isomers of octane, chemical formula：(CH3) 2CHCH2C
(CH3)3, molecular weight 114.23, octane number 100,99.2 DEG C of boiling point, density (20 DEG C) 0.69,417 DEG C of self-ignition point, be iso-butane and
Isobutene is reacted in the presence of anhydrous hydrogen fluoride and is obtained.Isooctane is also referred to as alkylate oil, not olefin-containing, aromatic hydrocarbons and oxygen, is Gaoxin
The additive of alkane value motor petrol.
Aromatic hydrocarbons refers to the hydrocarbon containing benzene ring structure in molecule, is one kind of closed chain class.There is a kind of fragrance,
So these hydrocarbons are referred to as aromatic hydrocarbon.Abbreviation aromatic hydrocarbons has good dissolubility.It is main in " vehicle-use alcohol gasoline E10 "
If containing toluene, ethylbenzene, dimethylbenzene, trimethylbenzene aromatic hydrocarbon.Octane number is between 110-130.110-170 DEG C of boiling point is
The important component of " vehicle-use alcohol gasoline E10 ".
Alcohol fuel generally refers to the absolute ethyl alcohol that volumetric concentration reaches 99.5% or more, is a kind of Gaoxin of combustion cleaning
Alkane value fuel, is regenerative resource.It is a kind of oil product of gasoline modifying agent.Ethyl alcohol oxygen-containing 35%, fully burning reach energy saving and ring
The purpose of guarantor.10% alcohol fuel is added in " motor petrol ".3 unit octane numbers, the methyl in motor petrol can be improved
Tertbutyl ether (methyl tert-bulyl ether, abbreviation MTBE) anti-knock agent is a kind of nondegradable substance, after leakage
It can serious polluted underground water.MTBE, which is substituted, with ethyl alcohol had both solved China's grain in storage for years inventory problem, it is often more important that environmental protection,
It is a kind of best available environmental protection measure.
Light aromatic hydrocarbons are the byproducts of oil plant aromatisation production, are the short chain component compositions of benzene chain link alkane or alkene
, the component oil that 40 DEG C -190 DEG C of boiling range, density is between 0.71-0.73, octane number 92, color water white, and free from extraneous odour is vehicle
With a kind of blend component of gasoline.
Biphenyl, alias：Symbasis benzene, phenylbenzene, molecular formula C12H10, molecular weight 154.21,68 DEG C -70 DEG C of molten point is a kind of
High-energy fuel, preservative and conduction oil raw material belong to lower toxicity product, and being added in " vehicle-use alcohol gasoline E10 " makes engine produce
Raw synchronousing combustion improves piston and pushes pressure, can improve engine power and inhibit ethyl alcohol to corrosion of metal.Product is by river
Su Zhongneng Chemical Co., Ltd.s produce.
Detergent-dispersant additive be by polyetheramine be primary raw material compounding elimination carbonizing of engine, cleaning fuel system colloid and
Cleaning atomizer stockpiles object, and ethanol vapor water content in oil is disperseed, and engine is made to restore the detersive of new car working condition.Product is used
The 8829H gasoline cleaning agents of Lu Borun chemistry limited liability company production or the polyethers amine type production of BASF Aktiengesellschaft's production
Product use polyetheramine Detergent best results.
Quaternary ammonium salt cation fluorocarbon surfactant is a kind of fluorocarbon surface of quaternary ammonium salt cation containing fluoroalkyl amide
Activating agent (CF3)2CF(CF2)6CH2CH(OH)CH2N+(CH3)3I-Cation fluorine carbon surface active agent does not change under 500 DEG C of high temperature
Become using effect, can effectively reduce " vehicle-use alcohol gasoline E10 " surface tension, keep atomizer oil atomizing unimpeded.Raising is started
Machine working efficiency.Factory：Shanghai You Sheng Environmental Protection Technology Co., Ltd.
Friction improver is the 8825A friction improvers of Lu Borun chemistry limited liability company life.High activity can also be used
Oil-soluble phosphate MAX-P16, it is a kind of oil-soluble friction improver, can reduce piston ring, piston skirt and cylinder wall it
Between friction.Friction between bent axle and engine crankshaft bush connecting rod and pull rod watt.The output power of engine 4% or so can be improved.
Manufacturer：Jiangsu Hai'an Petrochemical Plant.
The present invention relates to a kind of preparation methods of " vehicle-use alcohol gasoline E10 " constituent, it is characterized in that calculate in parts by weight,
Including following component：(composition 1)-(composition 4), wherein detergent-dispersant additive, friction improver etc., component is as defined above to be stated.
(composition 1)
(composition 2)
(composition 3)
(composition 4)
Advantages of the present invention：
The present invention utilizes gasoline polyethers amine type detergent-dispersant additive, friction improver, quaternary ammonium salt cation fluorocarbon surface
Activating agent is re-dubbed a kind of vehicle-use alcohol gasoline E10 constituents, by existing vehicle-use alcohol gasoline E10 there are disadvantages can be thorough
Bottom solves.
Specific implementation mode
The embodiment of the present invention is described below in detail, the embodiment is only used for explaining the present invention, and should not be understood as pair
The limitation of the present invention.
Specific embodiments of the present invention are as described below.
Embodiment 1
A kind of preparation method of " vehicle-use alcohol gasoline E10 " constituent, it is characterized in that calculate in parts by weight, including such as the following group
Point：
Wherein polyetheramine detergent-dispersant additive is German BASF product.
Wherein quaternary ammonium salt cation fluorocarbon surfactant is it has been observed that it is quaternary ammonium salt cation containing fluoroalkyl amide
Surfactant (CF3)2CF(CF2)6CH2CH(OH)CH2N+(CH3)3I-, factory is Shanghai You Sheng Environmental Protection Technology Co., Ltd.
Friction improver is the 8825A friction improvers of Lu Borun chemistry limited liability company production.
As a result：It not will produce phenomenon of detonation.It is most suitable for exhaust gas turbocharge, high compression engine is right through cooperateing with compatibility
It molten of rubber and is all close with regular gasoline to metal erosion.
Embodiment 2：
A kind of preparation of " vehicle-use alcohol gasoline E10 " constituent, it is characterized in that calculate in parts by weight, including following component：
Lighter hydrocarbons are the light hydrocarbon component refined in oil plant downstream product or methanol-to-olefins (MTO), density (20 DEG C)
0.66-0.70,40 DEG C -160 DEG C of boiling range, octane number 75 or so cannot directly do motor petrol use.Isooctane need to be added, virtue
Hydrocarbon and alcohol fuel, compound and become " vehicle-use alcohol gasoline E10 " according to the above ratio.
Polyetheramine is the special detergent-dispersant additive of vehicle-use alcohol gasoline, is produced by Linzi, Shandong Chemical Engineering Technology Co., Ltd." vehicle
With the inaccurate gasoline cleaning agents prepared using polyisobutylene amine of ethanol petrol E10 ".
Isooctane, aromatic hydrocarbons, biphenyl, quaternary ammonium salt cationic fluorocarbon surfactant, high activity oil-soluble phosphate ester MXA-
P16, it is such as aforementioned.
As a result：It not will produce phenomenon of detonation.It is most suitable for exhaust gas turbocharge, high compression engine is right through cooperateing with compatibility
It molten of rubber and is all close with regular gasoline to metal erosion.
Embodiment 3
A kind of constituent preparation method of 93# " vehicle-use alcohol gasoline E10 ", it is characterized in that calculate in parts by weight, including such as
Lower component：
Alcohol fuel used in the present embodiment, biphenyl, quaternary ammonium salt cation fluorocarbon surfactant, friction improver
It is identical with used in embodiment 1.It is identical used in polyetheramine used in the present embodiment and embodiment 2.
Ethanol petrol base oil is the base oil that oil plant aims at production " vehicle-use alcohol gasoline E10 " production, the base oil
The oxygen containing feeds such as MTBE are not added.
As a result：It not will produce phenomenon of detonation.It is most suitable for exhaust gas turbocharge, high compression engine is right through cooperateing with compatibility
It molten of rubber and is all close with regular gasoline to metal erosion.
Embodiment 4
A kind of constituent preparation method of 97# " vehicle-use alcohol gasoline E10 ".It is characterized in that calculate in parts by weight, including such as
Lower component：
Light aromatic hydrocarbons are the short carbon chain components of phenyl ring connection alkane or alkene, are a kind of gasoline blend component oil.Dimethylbenzene is
Colourless transparent liquid, chemical formula C8H10, be on phenyl ring two hydrogen by methyl substituted product, there are it is o-, m-, to three kinds of isomers
Mixture.Research octane number (RON) 130 or so is a kind of lower toxicity gasoline important component.
High activity oil-soluble phosphate MAX-P16 is that the friction of Jiangsu Hai'an petrochemical industry Co., Ltd., Factory production improves
Agent.
Used in detergent-dispersant additive polyetheramine, biphenyl, quaternary ammonium salt cationic fluorocarbon surfactant and embodiment 1
It is identical.
As a result：It not will produce phenomenon of detonation.It is most suitable for exhaust gas turbocharge, high compression engine is right through cooperateing with compatibility
It molten of rubber and is all close with regular gasoline to metal erosion.
Embodiment 5
A kind of preparation of " vehicle-use alcohol gasoline E10 " quality improver, it is characterized in that calculate in parts by weight, including with the following group
Point：
The detergent-dispersant additive that the present embodiment uses is polyetheramine；Used quaternary ammonium salt cation fluorocarbon surfactant
It is a kind of fluorocarbon surfactant of quaternary ammonium salt cation containing fluoroalkyl amide (CF3)2CF(CF2)6CH2CH(OH)CH2N+
(CH3)3I-Cation fluorine carbon surface active agent.8825A friction improvers are the production of Lu Borun chemistry limited liability company.
By above 5 kinds of raw materials, mixture is put into rustless steel container in proportion, with blender, is heated, is stirred on one side on one side,
40 DEG C or so (summer is not required to heat) are warmed to, limpid transparent quality improver is stirred into, petrol drum is packed into, presses when in use
4kg quality improvers are added in 1000kg " vehicle-use alcohol gasoline E10 ", stir evenly.
Dimethylbenzene is mutual solvent, and aromatic hydrocarbons can also be used and make solvent.
With above example 5, automobile-used 93# ethanol petrols E10 is added by 4/1000ths parts by weight in quality improver.
As a result：It not will produce phenomenon of detonation.It is most suitable for exhaust gas turbocharge, high compression engine is right through cooperateing with compatibility
It molten of rubber and is all close with regular gasoline to metal erosion.
Embodiment 6
A kind of preparation of " vehicle-use alcohol gasoline E10 " quality improver, it is characterized in that calculate in parts by weight, including with the following group
Point：
The detergent-dispersant additive that the present embodiment uses is polyetheramine；Used quaternary ammonium salt cation fluorocarbon surfactant
It is a kind of fluorocarbon surfactant of quaternary ammonium salt cation containing fluoroalkyl amide (CF3)2CF(CF2)6CH2CH(OH)CH2N+
(CH3)3I-Cation fluorine carbon surface active agent.8825A friction improvers are the production of Lu Borun chemistry limited liability company.
By above 6 kinds of raw materials, mixture is put into rustless steel container in proportion, with blender, is heated, is stirred on one side on one side,
40 DEG C or so (summer is not required to heat) are warmed to, limpid transparent quality improver is stirred into, petrol drum is packed into, presses when in use
4kg quality improvers are added in 1000kg " vehicle-use alcohol gasoline E10 ", stir evenly.
Dimethylbenzene is mutual solvent, and aromatic hydrocarbons can also be used and make solvent.
With above example 6, automobile-used 93# ethanol petrols E10 is added by 4/1000ths parts by weight in quality improver.
As a result：It not will produce phenomenon of detonation.It is most suitable for exhaust gas turbocharge, high compression engine is right through cooperateing with compatibility
It molten of rubber and is all close with regular gasoline to metal erosion, cold-starting such as regular gasoline.
To sum up, the present invention provides a kind of " vehicle-use alcohol gasoline E10 ", is prepared by the following method, light with C4-C9
300 parts by weight of matter component oil, 250 parts by weight of isooctane (alkylate oil), 350 parts by weight of aromatic hydrocarbons, 100 parts by weight of alcohol fuel,
0.6 parts by weight of biphenyl, 0.4 parts by weight of polyethers amine type cleaning dispersant for gasoline, quaternary ammonium salt cation fluorocarbon surfactant 0.4
Parts by weight, 8825A friction improvers, 0.6 parts by weight.A kind of octane number 93# is reconciled into online through oil plant pipe-line mixer, it is close
Degree 0.74,1100 kilocalories of calorific value ＞/kilogram " vehicle-use alcohol gasoline E10 ".
The present invention provides another " vehicle-use alcohol gasoline E10 ", is prepared by the following method, uses light aromatic hydrocarbons 750
Parts by weight, 150 parts by weight of dimethylbenzene, 100 parts by weight of alcohol fuel, 0.45 parts by weight of biphenyl, polyethers amine type detergent-dispersant additive 0.4
Parts by weight, 0.3 parts by weight of quaternary ammonium salt cation fluorocarbon surfactant, high activity oil-soluble phosphate MAX-P160.45 weights
Measure part.A kind of octane number 97# " vehicle-use alcohol gasoline E10 " is reconciled into online through oil plant pipe-line mixer.
" the vehicle-use alcohol gasoline E10 " reconciled with the production of this preparation method, all technical indicators meet " the automobile-used second of state six
Alcohol gasoline E10 " standards, research octane number (RON)：Bis- kinds of specifications of 93# and 97#, sulfur content ＜ 10PPM (mass fraction), benzene content
＜ 0.8% (mass fraction), alkene ＜ 18% (mass fraction), aromatic hydrocarbons ＜ 35% (mass fraction), 3.5% (matter of oxygen content ＜
Measure score), 40 DEG C of -190 DEG C of metals of boiling range and all technical are met the requirements of the standard.E10- of the power than market supply
93#, E10-97# " vehicle-use alcohol gasoline E10 " improve 5% or more, fuel-efficient 5% or more, and exhaust emission is than commercially available vehicle ethanol
Gasoline E10 declines 40% or more.It is a kind of " vehicle-use alcohol gasoline E10 ".
It should be noted that the foregoing is merely the preferred specific embodiment of the present invention,
If conception under this invention changes, the function generated, the spirit still covered without departing from specification
When, it should all be within the scope of the invention.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example
Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not
Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any
One or more embodiments or example in can be combined in any suitable manner.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that：Not
In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, this
The range of invention is limited by claim and its equivalent.
Claims (5)
1. a kind of 93# " vehicle-use alcohol gasoline E10 " constituent, it is characterized in that calculate in parts by weight, including following component：
The polyethers amine type detergent-dispersant additive is Lu Borun chemistry limited liability company 8829H products or BASF Aktiengesellschaft's polyethers
Amine product or polyetheramine；The friction improver is 8825A friction improvers or the Jiangsu of Lu Borun chemistry limited liability company
The high activity oil-soluble phosphide MAX-P16 products of Hai'an petrochemical plant.
2. a kind of 97# " vehicle-use alcohol gasoline E10 " constituent, it is characterized in that calculate in parts by weight, including following component：
The polyethers amine type detergent-dispersant additive is Lu Borun chemistry limited liability company product 8829H gasoline cleaning agents or German Bath
Husband company polyethers amine type gasoline cleaning agent product or polyetheramine；The friction improver is Lu Borun chemistry limited liability company
The high activity oil-soluble phosphide MAX-P16 products of 8825A friction improvers or Jiangsu Hai'an petrochemical plant.
3. " vehicle-use alcohol gasoline E10 " constituent as claimed in claim 2, which is a kind of density (20 DEG C) 0.71-
0.73kg/ liters, octane number 92,40 DEG C -190 DEG C of boiling range are the light aromatic hydrocarbons of short chain.
4. " vehicle-use alcohol gasoline E10 " constituent as claimed in claim 1,2 or 3, it is characterised in that：
The quaternary ammonium salt cation fluorocarbon surfactant is a kind of fluorocarbon surface of quaternary ammonium salt cation containing fluoroalkyl amide work
Property agent (CF3)2CF(CF2)6CH2CH(OH)CH2N+(CH3)3I-。
5. claim 1-4 any one of them constituents, it is characterised in that:
Further comprise：
0.3 parts by weight of isomerous tridecanol polyoxyethylene ether.
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| CN201810483554.XA CN108587704A (en) | 2018-05-18 | 2018-05-18 | A kind of vehicle-use alcohol gasoline E10 constituents |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810483554.XA CN108587704A (en) | 2018-05-18 | 2018-05-18 | A kind of vehicle-use alcohol gasoline E10 constituents |
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Cited By (6)
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| CN109456806A (en) * | 2018-11-20 | 2019-03-12 | 萍乡亨厚新材科技有限公司 | A kind of gasoline additive |
| CN109694760A (en) * | 2019-01-31 | 2019-04-30 | 中实投石化科技有限公司 | A kind of enhancing fuel-economizing piece |
| CN109705937A (en) * | 2019-01-31 | 2019-05-03 | 中实投石化科技有限公司 | A kind of vehicular petrol engine exhaust gas purifying liquid |
| CN113462436A (en) * | 2021-07-07 | 2021-10-01 | 中改低碳科技(上海)有限公司 | Gasoline power propellant for plateau field operation automobile and manufacturing method thereof |
| WO2022041412A1 (en) * | 2020-08-22 | 2022-03-03 | 上海千茂化工科技有限公司 | Vehicle fuel exhaust emission reduction synergist |
| CN116925823A (en) * | 2023-07-27 | 2023-10-24 | 山东京博新能源控股发展有限公司 | High-grade E5 ethanol gasoline emission test standard oil and preparation method thereof |
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| CN109456806A (en) * | 2018-11-20 | 2019-03-12 | 萍乡亨厚新材科技有限公司 | A kind of gasoline additive |
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| CN116925823A (en) * | 2023-07-27 | 2023-10-24 | 山东京博新能源控股发展有限公司 | High-grade E5 ethanol gasoline emission test standard oil and preparation method thereof |
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Application publication date: 20180928 |