CN108587463A - A kind of flame retardant type Emulsificated asphalt water-proof painting material and preparation method thereof - Google Patents
A kind of flame retardant type Emulsificated asphalt water-proof painting material and preparation method thereof Download PDFInfo
- Publication number
- CN108587463A CN108587463A CN201810475231.6A CN201810475231A CN108587463A CN 108587463 A CN108587463 A CN 108587463A CN 201810475231 A CN201810475231 A CN 201810475231A CN 108587463 A CN108587463 A CN 108587463A
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- Prior art keywords
- fire
- component
- flame retardant
- proof
- retardant type
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
The present invention discloses a kind of flame retardant type Emulsificated asphalt water-proof painting material and preparation method thereof, the water-repellent paint includes 65% first component and 35% second component, wherein, first component includes pitch, Ceramic silicon rubber powder, anionic surfactant, softening oil, deionized water, and component B includes fire-proof packing, fire retardant;The fire-proof packing is made of basic magnesium carbonate, basic copper carbonate, silica.Preparation method is as follows:Pitch and softening oil are heated to 150 DEG C, add Ceramic silicon rubber powder, anionic surfactant and deionized water, after homogeneous cooling, obtains first component;Mixing fire-proof packing and fire retardant obtain second component, and are scattered in first component.The present invention under the high temperature conditions, absorbs heat using fire-proof packing, and concurrent heat decomposition reaction generates CO2And H2O, starvation carry out internal cooling, realize fire-retardant function of independently putting out a fire, do not melt, do not drip in fire hazard environment.
Description
Technical field
The invention belongs to asphalt waterproofing paint fields, and in particular to a kind of flame retardant type Emulsificated asphalt water-proof painting material and its preparation
Method.
Background technology
Emulsificated asphalt water-proof painting material, primary raw material pitch is petroleum fractionating product, under the conditions of temperature is higher, easily certainly
Fire is ignite, the prior art generally alleviates pitch burning by adding halogenated flame retardant, but autonomous fire extinguishing cooling is still not achieved
Effect, and its decomposition product hydrogen halides is discharged into air, can cause environmental pollution, in addition, fire retardant is largely scattered in drip
In green base-material, the space structure and mechanical property of film can be destroyed, film is caused to be easy cracking, aging.
Application No. is the patent of CN201410459750.5, discloses the uncured rubber-asphalt waterproof with flame-retarding characteristic and apply
Material and preparation method thereof only adds fire retardant to improve coating fire resistance by physics, and flame retardant effect is not ideal enough, and with poly-
Ammonium phosphate, hexabromocyclododecane are generated ammonia, hydrogen bromide by thermal decomposition, pollute air as fire retardant.
Invention content
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of flame retardant type Emulsificated asphalt water-proof painting materials
And preparation method thereof.
Technical scheme of the present invention is summarized as follows:
A kind of flame retardant type Emulsificated asphalt water-proof painting material, the water-repellent paint include 65% first component and 35% second component,
In, first component includes pitch, Ceramic silicon rubber powder, anionic surfactant, softening oil, deionized water, and component B includes
Fire-proof packing, fire retardant;The fire-proof packing is made of basic magnesium carbonate, basic copper carbonate, silica.
Preferably, the first component includes following raw material:
Preferably, the anionic surfactant include at least Disodium sulfosuccinate, neopelex,
One kind in fatty alcohol-ether sodium sulfate.
Preferably, the softening oil includes at least one kind in turpentine oil, castor oil, palm oil.
Preferably, the component B includes following raw material:
100 parts of fire-proof packing;
3-7 parts of fire retardant.
Preferably, the fire-proof packing includes following weight percent component:Basic magnesium carbonate 40-50%, alkali formula carbon
Sour copper 20-25%, silica 30-35%.
Preferably, the fire retardant includes at least antimony oxide, zinc borate, pentaerythritol phosphate, tricresyl phosphate fourth
One kind in ester.
The present invention also provides a kind of above-mentioned preparation method of flame retardant type Emulsificated asphalt water-proof painting material, detailed process is as follows:It will
Pitch and softening oil are heated to 150 DEG C, add Ceramic silicon rubber powder, anionic surfactant and deionized water, homogeneous
After cooling, first component is obtained;Weight percent mixing basic magnesium carbonate, basic copper carbonate, silica, obtain fire-proof packing, then
It is stirred evenly with fire retardant, obtains second component, and be scattered in first component and applied to get the flame retardant type emulsified asphalt waterproof
Material.
Beneficial effects of the present invention:
For the present invention by Ceramic silicon rubber powder-modified asphalt, the two, which is cross-linked with each other, is solidified into stable three-dimensional ceramic network
Structure is not melted in fire hazard environment, is not dripped, and the flame retardant property and mechanical property of coating is greatly improved, and is filled out using fire prevention
Material under the high temperature conditions, absorbs heat, and concurrent heat decomposition reaction generates CO2And H2O, starvation carry out internal cooling, real
It now independently puts out a fire fire-retardant function, and does not generate any pernicious gas.
Specific implementation mode
With reference to embodiment, the present invention is described in further detail, to enable those skilled in the art with reference to specification
Word can be implemented according to this.
The present invention proposes that the flame retardant type Emulsificated asphalt water-proof painting material of an embodiment, the water-repellent paint include 65% first component
With 35% second component, wherein first component include pitch, Ceramic silicon rubber powder, anionic surfactant, softening oil, go from
Sub- water, component B include fire-proof packing, fire retardant;The fire-proof packing is by basic magnesium carbonate, basic copper carbonate, silica group
At.
Wherein, first component, using 20-40 parts of Ceramic silicon rubber powder as modifying agent, is made using 100 parts of pitches as base-material
Si-O-Si keys are introduced into pitch skeleton, improve paint structure intensity and chemical stability, and in 150 DEG C of hot conditions, further
It is solidified into hard ceramic protective layer, is adhering closely to asphaltene molecule surface, is cross-linked into stable three-dimensional ceramic network structure,
It does not melt, drip in fire hazard environment, coating fire-resistance flame retardant property and mechanical property is greatly improved.
Meanwhile using 2-8 parts of anionic surfactants as emulsifier, it is made of 15-35 parts of deionized waters for disperseing
Water phase and organic oil phase, include at least Disodium sulfosuccinate, neopelex, one in fatty alcohol-ether sodium sulfate
Kind, and asphalt softening point is reduced by 1-5 parts of softening oils, energy loss is reduced, turpentine oil, castor oil, palm oil are included at least
In one kind.
Wherein, component B is using 100 parts of fire-proof packings as base-material, by 40-50% basic magnesium carbonates, 20-25% basic carbonates
Copper, 30-35% silica composition, when a fire, on the one hand basic magnesium carbonate and basic copper carbonate in filler can be inhaled
Heat is received, film ambient temperature is reduced, extends required time when film reaches ignition point, races against time for fire control, it is another
Aspect, basic magnesium carbonate and basic copper carbonate are when heated, the effect of decomposing, and generate CO2, it is filled in coating structure, drops
Oxygen concentration that is low and completely cutting off film ectonexine achievees the effect that fire smothering, decomposition reaction equation are as follows: Reaction life
At water again can Self-extinguishing cooling, realize waterproof coating independently put out a fire it is fire-retardant, and using 3-7 parts of fire retardants as auxiliary material, further
The fire retardant performance of coating is improved, is included at least in antimony oxide, zinc borate, pentaerythritol phosphate, tributyl phosphate
One kind.
The present invention also provides a kind of above-mentioned preparation method of flame retardant type Emulsificated asphalt water-proof painting material, detailed process is as follows:It will
Pitch and softening oil are heated to 150 DEG C, add Ceramic silicon rubber powder, anionic surfactant and deionized water, homogeneous
After cooling, first component is obtained;Weight percent mixing basic magnesium carbonate, basic copper carbonate, silica, obtain fire-proof packing, then
It is stirred evenly with fire retardant, obtains second component, and be scattered in first component and applied to get the flame retardant type emulsified asphalt waterproof
Material.
Following table lists the performance parameter of the specific formula and obtained water-repellent paint of different embodiments:
Subordinate list:
As seen from the above table, water-repellent paint flame retardant property produced by the invention is good, and self-extinguishing cooling is realized in 40s, and
With excellent mechanical property and tolerance.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details.
Claims (8)
1. a kind of flame retardant type Emulsificated asphalt water-proof painting material, which is characterized in that the water-repellent paint includes 65% first component and 35%
Second component, wherein first component includes pitch, Ceramic silicon rubber powder, anionic surfactant, softening oil, deionized water, second
Component includes fire-proof packing, fire retardant;The fire-proof packing is made of basic magnesium carbonate, basic copper carbonate, silica.
2. a kind of flame retardant type Emulsificated asphalt water-proof painting material according to claim 1, which is characterized in that the first component include with
Lower raw material:
3. according to a kind of arbitrary flame retardant type Emulsificated asphalt water-proof painting material of claims 1 or 2, which is characterized in that it is described it is cloudy from
Sub- surfactant includes at least one kind in Disodium sulfosuccinate, neopelex, fatty alcohol-ether sodium sulfate.
4. according to a kind of arbitrary flame retardant type Emulsificated asphalt water-proof painting material of claims 1 or 2, which is characterized in that the softening
Oil includes at least one kind in turpentine oil, castor oil, palm oil.
5. a kind of flame retardant type Emulsificated asphalt water-proof painting material according to claim 1, which is characterized in that the component B include with
Lower raw material:
100 parts of fire-proof packing;
3-7 parts of fire retardant.
6. according to claim 1 or a kind of 5 arbitrary flame retardant type Emulsificated asphalt water-proof painting materials, which is characterized in that the fire prevention
Filler includes following weight percent component:Basic magnesium carbonate 40-50%, basic copper carbonate 20-25%, silica 30-
35%.
7. according to claim 1 or a kind of 5 arbitrary flame retardant type Emulsificated asphalt water-proof painting materials, which is characterized in that described fire-retardant
Agent includes at least one kind in antimony oxide, zinc borate, pentaerythritol phosphate, tributyl phosphate.
8. a kind of preparation method of flame retardant type Emulsificated asphalt water-proof painting material as described in claim any one of 1-7, which is characterized in that
Detailed process is as follows:Pitch and softening oil are heated to 150 DEG C, add Ceramic silicon rubber powder, anionic surfactant
And deionized water, after homogeneous cooling, obtain first component;Weight percent mixing basic magnesium carbonate, basic copper carbonate, titanium dioxide
Silicon obtains fire-proof packing, then is stirred evenly with fire retardant, obtains second component, and is scattered in first component to get the flame retardant type
Emulsificated asphalt water-proof painting material.
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CN201810475231.6A CN108587463A (en) | 2018-05-17 | 2018-05-17 | A kind of flame retardant type Emulsificated asphalt water-proof painting material and preparation method thereof |
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CN201810475231.6A CN108587463A (en) | 2018-05-17 | 2018-05-17 | A kind of flame retardant type Emulsificated asphalt water-proof painting material and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109836834A (en) * | 2019-01-24 | 2019-06-04 | 苏州拓博琳新材料科技有限公司 | Emulsifier, emulsifier preparation method, fire-retardant emulsified asphalt and preparation method thereof |
CN109849468A (en) * | 2019-01-30 | 2019-06-07 | 江苏诺贝尔塑业有限公司 | A kind of flame retardant type silicone pipes |
CN113292316A (en) * | 2021-05-10 | 2021-08-24 | 江苏苏嘉集团新材料有限公司 | Refractory brick capable of permeating water and reducing temperature at high temperature and processing technology |
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CN103666259A (en) * | 2013-09-12 | 2014-03-26 | 宁波镭纳涂层技术有限公司 | Flame-retarding asphalt base mixing macromolecule waterproof paint and preparation method thereof |
CN104194629A (en) * | 2014-09-11 | 2014-12-10 | 北京东方雨虹防水技术股份有限公司 | Non-cured rubber asphalt waterproofing coating with flame retardance property and preparation method thereof |
CN204614488U (en) * | 2015-05-23 | 2015-09-02 | 李和良 | A kind of environment-friendly type insulated anticorrosion shielded type cable |
CN107090248A (en) * | 2017-04-17 | 2017-08-25 | 上海禹术防水工程技术有限公司 | A kind of uncured rubber asphalt waterproof coating of flame retardant type and preparation method thereof |
CN107129759A (en) * | 2017-04-17 | 2017-09-05 | 上海禹术防水工程技术有限公司 | A kind of flame retardant type spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof |
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Patent Citations (6)
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CN103102134A (en) * | 2013-02-20 | 2013-05-15 | 上海宏胜电线电缆有限公司 | Fireproof and flame retardant mineral compound filling material and cable containing the same |
CN103666259A (en) * | 2013-09-12 | 2014-03-26 | 宁波镭纳涂层技术有限公司 | Flame-retarding asphalt base mixing macromolecule waterproof paint and preparation method thereof |
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CN107129759A (en) * | 2017-04-17 | 2017-09-05 | 上海禹术防水工程技术有限公司 | A kind of flame retardant type spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109836834A (en) * | 2019-01-24 | 2019-06-04 | 苏州拓博琳新材料科技有限公司 | Emulsifier, emulsifier preparation method, fire-retardant emulsified asphalt and preparation method thereof |
CN109849468A (en) * | 2019-01-30 | 2019-06-07 | 江苏诺贝尔塑业有限公司 | A kind of flame retardant type silicone pipes |
CN113292316A (en) * | 2021-05-10 | 2021-08-24 | 江苏苏嘉集团新材料有限公司 | Refractory brick capable of permeating water and reducing temperature at high temperature and processing technology |
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