CN108587385A - A kind of impact resistance waterproof epoxy coating - Google Patents
A kind of impact resistance waterproof epoxy coating Download PDFInfo
- Publication number
- CN108587385A CN108587385A CN201810537055.4A CN201810537055A CN108587385A CN 108587385 A CN108587385 A CN 108587385A CN 201810537055 A CN201810537055 A CN 201810537055A CN 108587385 A CN108587385 A CN 108587385A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- humic acid
- water
- impact resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of impact resistance waterproof epoxy coatings, including component A, B component, and the weight ratio between component A and B component is 0.1 0.2:1;Component A includes by weight:13 parts of iron oxide red, 0.4 0.9 parts of trbasic zinc phosphate, 0.1 0.4 parts of aluminium triphosphate, 26 parts of diatomite, 12 parts of vinyltrimethoxysilane, 10 20 parts of filler, 12 parts of acrylic type thickener, 1.5 2.5 parts of crosslinking agent, 12 parts of thixotropic agent, 12 parts of antifoaming agent, 12 parts of dispersant, 60 100 parts of water;B component includes by weight:80 100 parts of water-base epoxy phenolic resin, 20 40 parts of epoxy polyurethane resin, 50 100 parts of water.Filler includes by weight:5 12 parts of flyash, 29 parts of hollow glass microballoon, 4 10 parts of humic acid complex.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of impact resistance waterproof epoxy coatings.
Background technology
Although reinforcing bar in concrete structure is a kind of substance for being easy to be etched, but if surrounding enviroment can be kept
Stablize alkalinity, steel would not suffer erosion.Once and chlorion, water, acid ion penetrate into concrete, the acid-base value of concrete
Since 11 be reduced to 7 hereinafter, reinforcing bar in concrete structure just corrode.Therefore water resistance is to influence the concrete structure service life
One of most important factor.
Conventional waterproof material, emulsified asphalt, polyurethane etc. are thin in one layer of waterproof of concrete structural surface formation
Film can play good waterproof action in concrete topping.Due to stress, concrete topping waterproof conjunctiva is highly prone to brokenly
Bad, concrete structure can be again confronted with the threat that is corroded.
Invention content
Technical problems based on background technology, the present invention propose a kind of impact resistance waterproof epoxy coating, shock resistance
Intensity is high, is not easy to be destroyed, and water resistance is good, while can be degradable, safety and environmental protection.
A kind of impact resistance waterproof epoxy coating proposed by the present invention, including component A, B component, between component A and B component
Weight ratio is 0.1-0.2:1;
Component A includes by weight:1-3 parts of iron oxide red, 0.4-0.9 parts of trbasic zinc phosphate, 0.1-0.4 parts of aluminium triphosphate,
2-6 parts of diatomite, 1-2 parts of vinyltrimethoxysilane, 10-20 parts of filler, 1-2 parts of acrylic type thickener, crosslinking agent
1.5-2.5 parts, 1-2 parts of thixotropic agent, 1-2 parts of antifoaming agent, 1-2 parts of dispersant, 60-100 parts of water;
B component includes by weight:80-100 parts of water-base epoxy phenolic resin, 20-40 parts of epoxy polyurethane resin, water
50-100 parts.
Preferably, in component A, crosslinking agent includes by weight:0.1-0.3 parts of tert-butyl hydroperoxide, dimethyl benzylamine
1-2 parts.
Preferably, in component A, filler includes by weight:5-12 parts of flyash, 2-9 parts of hollow glass microballoon, humic
Sour compound 4-10 parts.
Preferably, in component A, humic acid complex is prepared using following technique:Humic acid, Gluten, water are mixed, risen
Sodium hydroxide is added under stirring and is uniformly mixed for temperature stirring, cooling, add epoxychloropropane be uniformly mixing to obtain it is prefabricated
Material;Epoxychloropropane, sorbester p17, atoleine are uniformly mixed, acrylic acid chlorine, prefabricated material is added, heating stirring filters, will
Solid product obtains humic acid complex in natural drying at room temperature.
Preferably, in the humic acid complex preparation process of component A, humic acid, Gluten, water, sodium hydroxide, epoxy chlorine
The weight ratio of propane is 6-12:1-2:30-60:0.5-1.4:1-3.
Preferably, in the humic acid complex preparation process of component A, epoxychloropropane, sorbester p17, atoleine, propylene
Sour chlorine, prefabricated material weight ratio be 1-2:0.5-1.2:60-100:1.2-1.6:35-45.
Preferably, in component A, humic acid complex is prepared using following technique:Humic acid, Gluten, water are mixed, risen
Temperature is down to room temperature to 85-92 DEG C of stirring 30-50min, and sodium hydroxide, which is added, under stirring is uniformly mixed, and adds epoxy chlorine
Propane is uniformly mixing to obtain prefabricated material;Epoxychloropropane, sorbester p17, atoleine are uniformly mixed, acrylic acid chlorine, prefabricated is added
Material is warming up to 60-70 DEG C of stirring 2-4h, mixing speed 500-560r/min, filters, by solid product in natural drying at room temperature
Obtain humic acid complex.
The present invention is used as major ingredient, then is used dimethylbenzyl using water-base epoxy phenolic resin, epoxy polyurethane resin compounding
Amine is cured, and coating can be made to have fabulous mechanical performance, shock resistance fabulous;Filler and water-base epoxy phenolic aldehyde tree
Fat, epoxy polyurethane resin compounding, effect of dissolving each other is good, and permeance property is stablized, and initial infiltration is good when construction, is less prone to intensity
The defect of low, easy delamination, while toughness is high after solidification, there is no easy to aging, brittleness rebound phenomenons, and waterproof layer to be caused to destroy,
And the dispersion of flyash, hollow glass microballoon is wherein, the anti-corrosion of coating, wear-resisting and heat-resisting quantity are extremely excellent.The humic of the present invention
In sour compound, humic acid is fixed therein to form micro-sphere structure by Gluten and humic acid good dispersion under certain condition,
And the double bond of acrylic acid chlorine can carry out Gluten N- acylations, introduce double bond of side chain, it on the one hand can be with the tertiary butyl in crosslinking agent
Hydrogen peroxide is crosslinked, and bond strength is high, excellent in cushion effect, on the other hand cheap environmentally friendly fully biodegradable, safety
Environmental protection.
Volatile organic content is few in the present invention, can meet environmental requirement, of low cost, and by reducing organic matter
Consumption is stored and is significantly improved using process safety.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of impact resistance waterproof epoxy coating, including component A, B component, the weight ratio between component A and B component are 0.1:
1;
Component A includes:Iron oxide red 3kg, trbasic zinc phosphate 0.4kg, aluminium triphosphate 0.4kg, diatomite 2kg, vinyl three
Methoxy silane 2kg, filler 10kg, acrylic type thickener 2kg, crosslinking agent 1.5kg, thixotropic agent 2kg, antifoaming agent 1kg, point
Powder 2kg, water 60kg;Crosslinking agent is 0.3 in mass ratio by tert-butyl hydroperoxide and dimethyl benzylamine:1 composition;Filler by
Flyash, hollow glass microballoon, humic acid complex are 12 in mass ratio:2:10 compositions;
Humic acid complex is prepared using following technique:6kg humic acid, 2kg Glutens, 30kg water are mixed, are warming up to
92 DEG C of stirring 30min, are down to room temperature, and 1.4kg sodium hydroxides, which are added, under stirring is uniformly mixed, and adds 1kg epoxy chloropropionates
Alkane is uniformly mixing to obtain prefabricated material;2kg epoxychloropropane, 0.5kg sorbester p17s, 100kg atoleines are uniformly mixed, are added
1.2kg acrylic acid chlorine, the prefabricated material of 45kg are warming up to 60 DEG C of stirrings 4h, mixing speed 500r/min, filter, by solid product
Humic acid complex is obtained in natural drying at room temperature.
B component includes:Water-base epoxy phenolic resin 100kg, epoxy polyurethane resin 20kg, water 100kg.
Embodiment 2
A kind of impact resistance waterproof epoxy coating, including component A, B component, the weight ratio between component A and B component are 0.2:
1;
Component A includes:Iron oxide red 1kg, trbasic zinc phosphate 0.9kg, aluminium triphosphate 0.1kg, diatomite 6kg, vinyl three
Methoxy silane 1kg, filler 20kg, acrylic type thickener 1kg, crosslinking agent 2.5kg, thixotropic agent 1kg, antifoaming agent 2kg, point
Powder 1kg, water 100kg;Crosslinking agent is 0.1 in mass ratio by tert-butyl hydroperoxide and dimethyl benzylamine:2 compositions;Filler
It is 5 in mass ratio by flyash, hollow glass microballoon, humic acid complex:9:4 compositions;
Humic acid complex is prepared using following technique:12kg humic acid, 1kg Glutens, 60kg water are mixed, are warming up to
85 DEG C of stirring 50min, are down to room temperature, and 0.5kg sodium hydroxides, which are added, under stirring is uniformly mixed, and adds 3kg epoxy chloropropionates
Alkane is uniformly mixing to obtain prefabricated material;1kg epoxychloropropane, 1.2kg sorbester p17s, 60kg atoleines are uniformly mixed, are added
1.6kg acrylic acid chlorine, the prefabricated material of 35kg are warming up to 70 DEG C of stirrings 2h, mixing speed 560r/min, filter, by solid product
Humic acid complex is obtained in natural drying at room temperature.
B component includes:Water-base epoxy phenolic resin 80kg, epoxy polyurethane resin 40kg, water 50kg.
Embodiment 3
A kind of impact resistance waterproof epoxy coating, including component A, B component, the weight ratio between component A and B component are
0.12:1;
Component A includes:Iron oxide red 2.5kg, trbasic zinc phosphate 0.5kg, aluminium triphosphate 0.3kg, diatomite 3kg, vinyl
Trimethoxy silane 1.8kg, filler 12kg, acrylic type thickener 1.7kg, crosslinking agent 1.8kg, thixotropic agent 1.8kg, defoaming
Agent 1.3kg, dispersant 1.6kg, water 70kg;Crosslinking agent is 0.25 in mass ratio by tert-butyl hydroperoxide and dimethyl benzylamine:
1.2 composition;Filler is 10 in mass ratio by flyash, hollow glass microballoon, humic acid complex:4:8 compositions;
Humic acid complex is prepared using following technique:8kg humic acid, 1.8kg Glutens, 40kg water are mixed, heating
To 90 DEG C of stirring 35min, it is down to room temperature, 1.2kg sodium hydroxides, which are added, under stirring is uniformly mixed, and adds 1.5kg epoxies
Chloropropane is uniformly mixing to obtain prefabricated material;1.8kg epoxychloropropane, 0.6kg sorbester p17s, 90kg atoleines are uniformly mixed,
1.3kg acrylic acid chlorine, the prefabricated material of 42kg is added, is warming up to 64 DEG C of stirrings 3.5h, mixing speed 520r/min, filters, will consolidate
Body product obtains humic acid complex in natural drying at room temperature.
B component includes:Water-base epoxy phenolic resin 95kg, epoxy polyurethane resin 25kg, water 80kg.
Embodiment 4
A kind of impact resistance waterproof epoxy coating, including component A, B component, the weight ratio between component A and B component are
0.18:1;
Component A includes:Iron oxide red 1.5kg, trbasic zinc phosphate 0.8kg, aluminium triphosphate 0.2kg, diatomite 5kg, vinyl
Trimethoxy silane 1.2kg, filler 18kg, acrylic type thickener 1.3kg, crosslinking agent 2.2kg, thixotropic agent 1.2kg, defoaming
Agent 1.7kg, dispersant 1.4kg, water 90kg;Crosslinking agent is 0.15 in mass ratio by tert-butyl hydroperoxide and dimethyl benzylamine:
1.8 composition;Filler is 6 in mass ratio by flyash, hollow glass microballoon, humic acid complex:8:6 compositions;
Humic acid complex is prepared using following technique:10kg humic acid, 1.2kg Glutens, 50kg water are mixed, heating
To 88 DEG C of stirring 45min, it is down to room temperature, 0.8kg sodium hydroxides, which are added, under stirring is uniformly mixed, and adds 2.5kg epoxies
Chloropropane is uniformly mixing to obtain prefabricated material;1.2kg epoxychloropropane, 1kg sorbester p17s, 70kg atoleines are uniformly mixed, added
Enter 1.5kg acrylic acid chlorine, the prefabricated material of 38kg, is warming up to 66 DEG C of stirrings 2.5h, mixing speed 540r/min, filters, by solid
Product obtains humic acid complex in natural drying at room temperature.
B component includes:Water-base epoxy phenolic resin 85kg, epoxy polyurethane resin 35kg, water 60kg.
Embodiment 5
A kind of impact resistance waterproof epoxy coating, including component A, B component, the weight ratio between component A and B component are
0.15:1;
Component A includes:Iron oxide red 2kg, trbasic zinc phosphate 0.65kg, aluminium triphosphate 0.25kg, diatomite 4kg, vinyl
Trimethoxy silane 1.5kg, filler 15kg, acrylic type thickener 1.5kg, crosslinking agent 2kg, thixotropic agent 1.5kg, antifoaming agent
1.5kg, dispersant 1.5kg, water 80kg;Crosslinking agent is 0.2 in mass ratio by tert-butyl hydroperoxide and dimethyl benzylamine:1.5
Composition;Filler is 8 in mass ratio by flyash, hollow glass microballoon, humic acid complex:6:7 compositions;
Humic acid complex is prepared using following technique:9kg humic acid, 1.5kg Glutens, 45kg water are mixed, heating
To 89 DEG C of stirring 40min, it is down to room temperature, 1kg sodium hydroxides, which are added, under stirring is uniformly mixed, and adds 2kg epoxy chloropropionates
Alkane is uniformly mixing to obtain prefabricated material;1.5kg epoxychloropropane, 0.8kg sorbester p17s, 80kg atoleines are uniformly mixed, are added
1.4kg acrylic acid chlorine, the prefabricated material of 40kg are warming up to 65 DEG C of stirrings 3h, mixing speed 530r/min, filter, by solid product
Humic acid complex is obtained in natural drying at room temperature.
B component includes:Water-base epoxy phenolic resin 90kg, epoxy polyurethane resin 30kg, water 70kg.
5 gained impact resistance waterproof epoxy coating of embodiment is compared with common waterproof epoxy coating, result is as follows:
Embodiment 5 | Common waterproof epoxy coating | |
Impact strength, kgcm | 45 | 32 |
Impermeability (0.3Mpa, 30min) | It is waterproof | It is permeable |
Impervious (mortar back side), Mpa | 1.4 | 0.9 |
Heat resistance (100 DEG C of water, 5h) | Without cracking, peel off | Cracking peels off |
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of impact resistance waterproof epoxy coating, which is characterized in that including component A, B component, the weight between component A and B component
Amount is than being 0.1-0.2:1;
Component A includes by weight:1-3 parts of iron oxide red, 0.4-0.9 parts of trbasic zinc phosphate, 0.1-0.4 parts of aluminium triphosphate, diatom
It is 2-6 parts native, 1-2 parts of vinyltrimethoxysilane, 10-20 parts of filler, 1-2 parts of acrylic type thickener, crosslinking agent 1.5-
2.5 parts, 1-2 parts of thixotropic agent, 1-2 parts of antifoaming agent, 1-2 parts of dispersant, 60-100 parts of water;
B component includes by weight:80-100 parts of water-base epoxy phenolic resin, 20-40 parts of epoxy polyurethane resin, water 50-100
Part.
2. impact resistance waterproof epoxy coating according to claim 1, which is characterized in that in component A, crosslinking agent wraps by weight
It includes:0.1-0.3 parts of tert-butyl hydroperoxide, 1-2 parts of dimethyl benzylamine.
3. impact resistance waterproof epoxy coating according to claim 1, which is characterized in that in component A, filler wraps by weight
It includes:5-12 parts of flyash, 2-9 parts of hollow glass microballoon, 4-10 parts of humic acid complex.
4. impact resistance waterproof epoxy coating according to claim 3, which is characterized in that in component A, humic acid complex uses
It is prepared by following technique:Humic acid, Gluten, water are mixed, heating stirring, cooling, sodium hydroxide mixing is added under stirring
Uniformly, it adds epoxychloropropane and is uniformly mixing to obtain prefabricated material;Epoxychloropropane, sorbester p17, atoleine are uniformly mixed,
Acrylic acid chlorine, prefabricated material is added, heating stirring filters, solid product is obtained humic acid complex in natural drying at room temperature.
5. impact resistance waterproof epoxy coating according to claim 4, which is characterized in that prepared by the humic acid complex of component A
In technique, humic acid, Gluten, water, sodium hydroxide, epoxychloropropane weight ratio be 6-12:1-2:30-60:0.5-1.4:
1-3。
6. the impact resistance waterproof epoxy coating according to claim 4 or 5, which is characterized in that the humic acid complex system of component A
In standby technique, epoxychloropropane, sorbester p17, atoleine, acrylic acid chlorine, prefabricated material weight ratio be 1-2:0.5-1.2:60-
100:1.2-1.6:35-45.
7. according to any one of the claim 4-6 impact resistance waterproof epoxy coatings, which is characterized in that in component A, humic acid is multiple
Object is closed to prepare using following technique:Humic acid, Gluten, water are mixed, 85-92 DEG C of stirring 30-50min is warming up to, is down to room
Sodium hydroxide is added under stirring and is uniformly mixed, adds epoxychloropropane and is uniformly mixing to obtain prefabricated material for temperature;By epoxy chlorine
Propane, sorbester p17, atoleine are uniformly mixed, and acrylic acid chlorine, prefabricated material is added, and are warming up to 60-70 DEG C of stirring 2-4h, stirring speed
Degree is 500-560r/min, filters, solid product is obtained humic acid complex in natural drying at room temperature.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810537055.4A CN108587385A (en) | 2018-05-30 | 2018-05-30 | A kind of impact resistance waterproof epoxy coating |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810537055.4A CN108587385A (en) | 2018-05-30 | 2018-05-30 | A kind of impact resistance waterproof epoxy coating |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108587385A true CN108587385A (en) | 2018-09-28 |
Family
ID=63629649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810537055.4A Withdrawn CN108587385A (en) | 2018-05-30 | 2018-05-30 | A kind of impact resistance waterproof epoxy coating |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108587385A (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040209403A1 (en) * | 2001-03-30 | 2004-10-21 | Johshi Gotoh | One-component hot setting epoxy resin composition and semiconductor mounting underfill material |
CN101130612A (en) * | 2006-08-23 | 2008-02-27 | 中国石油天然气集团公司 | Rubbery copolymer particle and method for preparing the same |
CN105199549A (en) * | 2015-10-30 | 2015-12-30 | 桂林市和鑫防水装饰材料有限公司 | Composite epoxy resin waterproof coating |
CN105854828A (en) * | 2016-05-30 | 2016-08-17 | 南京林业大学 | Humic acid microsphere as well as preparation method and application thereof |
CN106748496A (en) * | 2016-12-29 | 2017-05-31 | 寻甸民生生物工程有限责任公司 | A kind of biological organic fertilizer and preparation method thereof |
-
2018
- 2018-05-30 CN CN201810537055.4A patent/CN108587385A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040209403A1 (en) * | 2001-03-30 | 2004-10-21 | Johshi Gotoh | One-component hot setting epoxy resin composition and semiconductor mounting underfill material |
CN101130612A (en) * | 2006-08-23 | 2008-02-27 | 中国石油天然气集团公司 | Rubbery copolymer particle and method for preparing the same |
CN105199549A (en) * | 2015-10-30 | 2015-12-30 | 桂林市和鑫防水装饰材料有限公司 | Composite epoxy resin waterproof coating |
CN105854828A (en) * | 2016-05-30 | 2016-08-17 | 南京林业大学 | Humic acid microsphere as well as preparation method and application thereof |
CN106748496A (en) * | 2016-12-29 | 2017-05-31 | 寻甸民生生物工程有限责任公司 | A kind of biological organic fertilizer and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101729216B1 (en) | Accelerator for freeze protection of exothermal concrete | |
CN107804989B (en) | Bentonite filler for building material manufacture | |
CN103332955B (en) | Edible fungus chaff aerated brick and preparation method therefor | |
CN108751848B (en) | High-strength water-resistant ceramic tile adhesive and preparation method thereof | |
CN103332954B (en) | Aerated concrete block employing blast furnace slag as raw material and preparation method | |
CN103725246B (en) | A kind of glass fibre cotton hydrophobic binder | |
KR100882840B1 (en) | The water-resistant paint composite and method of manufacturing the same | |
CN114230304A (en) | Environment-friendly anti-freezing concrete and preparation method thereof | |
CN105198314A (en) | Rare-earth cement column and preparation method thereof | |
CN108587385A (en) | A kind of impact resistance waterproof epoxy coating | |
CN105503103B (en) | A kind of polymer-modified cement-based waterproof mortar | |
CN104556877A (en) | Preparation method for modified acrylic resin mortar | |
CN113896481B (en) | Normal-temperature self-crosslinking water-based epoxy resin modified cement-based mortar bi-component material | |
CN105315977A (en) | Oil well cement retarder and preparation method therefor | |
CN106278060A (en) | A kind of wall column durability concrete | |
CN110359627A (en) | Granite powder assembled steam-pressing aero-concrete Self-insulation wall plate | |
CN105082315A (en) | Processing technology of decorative plate | |
CN105541191A (en) | Anti-collapse high-strength concrete | |
CN104710954A (en) | Nail-free all-purpose adhesive and preparation method thereof | |
CN108640596B (en) | High-strength impervious concrete and preparation method thereof | |
CN107501856A (en) | A kind of preparation method of flame-retardant modified wooden fiber composite phenol formaldehyde foam | |
CN110386829A (en) | Magnesium gel material, preparation method and application for preparing glass magnesium flat plate | |
CN105110748A (en) | Autoclaved aerated brick | |
CN105330251A (en) | Flame-retardant thermal insulation mortar | |
CN110282918A (en) | A kind of inorganic fireproof heat insulating plate used for building exterior wall and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180928 |