CN108587355A - Water paint and preparation method thereof - Google Patents
Water paint and preparation method thereof Download PDFInfo
- Publication number
- CN108587355A CN108587355A CN201810493143.9A CN201810493143A CN108587355A CN 108587355 A CN108587355 A CN 108587355A CN 201810493143 A CN201810493143 A CN 201810493143A CN 108587355 A CN108587355 A CN 108587355A
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- Prior art keywords
- water paint
- water
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- present
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Abstract
The present invention provides a kind of water paint and preparation method thereof, water paint includes at least following component, and the mass fraction proportion range of each component is respectively:Water:15‑20;Acrylic emulsion:30‑45;Dispersant:0.25‑0.9;Wetting agent:0.1‑0.6;Phthalocyanine blue toner:1‑2;Filler:10‑30;Surfactant:0.1‑0.2;Wax emulsion:2‑8.Novel water-based paint provided by the invention can preferably improve the permeability of existing water paint, and coating is non-water-tight caused by solving the problems, such as existing water paint.Water paint using the present invention can not only make metope become new by old, and coating is also more easy to clean, have it is long-term it is mould proof, prevent water penetration function.The water paint of the present invention can also be eliminated clean pollution to environment with detergent, with preferable antifouling property.
Description
Technical field
The present invention relates generally to technical field of coatings, and in particular to a kind of water paint and preparation method thereof.
Background technology
Water paint is to use water as solvent or the coating of decentralized medium.Compared with the coating of organic solvent type, aqueous painting
Material can reduce the discharge of volatile organic solvent and save resource and the energy, while convenience in transport and storage.With people
Related environmental regulation is more and more tighter to what is used for the enhancing of environmental consciousness and the production of chemical products, and water paint has become
The main flow direction of modern coatings industrial development, is widely used in all trades and professions.For example, all coating for internal and external wall, metallic paint,
Automobile coating etc. has corresponding water paint product.However, existing water paint is mostly using polyvinyl alcohol as base-material, due to polyethylene
Contain many hydroxy functional groups in alcohol so that the permeability of existing water paint is poor, causes coating non-watertight.
Invention content
A kind of water paint of present invention offer and preparation method thereof.Water paint provided by the invention is by adding predetermined group
The nano-titanium dioxide and nano zine oxide divided has the function of sterilizing and removing pollutants in air.
One aspect of the present invention provides a kind of water paint, and the water paint includes at least following component, the matter of each component
Measuring number specific gravity range is respectively:
Water:15-20;
Acrylic emulsion:30-45;
Dispersant:0.25-0.9;
Wetting agent:0.1-0.6;
Phthalocyanine blue toner:1-2;
Filler:10-30;
Surfactant:0.1-0.2;
Wax emulsion:2-8.
Further, the mass fraction specific gravity range of the wax emulsion component is:Wax emulsion:3-5.
Further, the wax in the wax emulsion includes or mixtures thereof solid paraffin, polyethylene wax.
Further, the filler is one or more kinds of combinations in calcium carbonate, talcum powder and zinc stearate.
Further, the water paint also comprises the following components, and the mass fraction proportion range of each component is respectively:
Hydroxyethyl cellulose:2-4;
Antifoaming agent:0.2-0.6;
Levelling agent:0.15-55;
Preservative:0.1-0.25;
Coalescents:1-1.5;
Ethylene glycol ethyl ether:1.5-2.
Further, the preservative is potassium sorbate, methyl p-hydroxybenzoate, butyl p-hydroxybenzoate and card
It is one or more in pine.
Further, the water paint also comprises the following components, and the mass fraction proportion range of each component is respectively:
Fireproof agent:0.2-0.4;
Antiseptic:0.1-0.3.
Another aspect of the present invention also provides a kind of preparation method of water paint comprising following steps:
(1) water and wax emulsion are mixed and heated to 60-90 DEG C of formation emulsion;Add dispersant ultrasonic disperse 20-30
Temperature is reduced after minute to 30-50 DEG C;Phthalocyanine blue toner is added and continues stirring 5-10 minutes;
(2) acrylic emulsion and surfactant are mixed, is heated to 40-60 DEG C, in 200-400 revs/min turn
Speed lower stirring 30-50 minutes;
(3) wetting agent and filler are uniformly mixed, the material in step (1) and step (2) are added, with 200-300
Rev/min rotating speed stir evenly.
Further, it is additionally added hydroxyethyl cellulose in the step (1) and carries out ultrasonic disperse, is gone back in the step (2)
Ethylene glycol ethyl ether is added to be mixed, in the step (3), is additionally added antifoaming agent, levelling agent, preservative and coalescents mixing
Uniformly.
Further, it is additionally added fireproof agent in the step (3) and antiseptic is mixed.
The present invention at least has the advantages that:
Water paint provided by the invention is bonded as one using acrylic emulsion as base fluid, by each component in water paint
It is whole, system surface tension can be reduced, the preferable permeability for improving water paint solves to apply caused by existing water paint
The non-water-tight problem of layer.Volatile chemical containing minute quantity in the available material of water paint of the present invention, and it is more
Water itself evaporate into air and has no adverse effects to environment, and the feature of environmental protection is good, low smell, and brushing impact on environmental and human body is small.It keeps away
Exempted from the prior art with solvent based coating renovate metope caused by the smell is awful, the harmful effect of VOC high.The present invention's is aqueous
Coating not only makes metope become new by old, and coating is also more easy to clean, have it is long-term it is mould proof, prevent water penetration function.The present invention's
Water paint can also be eliminated cleans pollution to environment with detergent, has preferable antifouling property.
Specific implementation mode
The existing various exemplary embodiment that the present invention will be described in detail, the detailed description are not considered as the limit to the present invention
System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
It should be understood that heretofore described term is only to describe special embodiment, being not intended to limit this hair
It is bright.In addition, for the numberical range in the present invention, it is thus understood that specifically disclose the range upper and lower bound and they it
Between each median.Median and any other statement value in any statement value or stated ranges or in the range
Smaller range is also included in the present invention each of between interior median.These small range of upper and lower bounds can be independent
Ground includes or excludes in range.
Unless otherwise stated, all technical and scientific terms used herein has the routine in field of the present invention
The normally understood identical meanings of technical staff.Although the present invention only describes preferred method and material, the present invention's
Implement or can also be used and similar or equivalent any method and material described herein in testing.The institute mentioned in this specification
There is document to be incorporated by reference into, to disclosure and description and the relevant method of the document and/or material.It is incorporated to any
When document conflicts, it is subject to the content of this specification.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
It is the term of opening, i.e., about "comprising" used herein, " comprising ", " having ", " containing " etc.
Mean including but not limited to.
Heretofore described " part " unless otherwise instructed, by mass.
Embodiment 1
The embodiment of the present invention provides a kind of water paint, and the water paint of the present embodiment includes at least following component, each group
Point mass fraction proportion be respectively:
Water:15;
Acrylic emulsion:30;
Dispersant:0.25;
Wetting agent:0.1;
Phthalocyanine blue toner:1;
Filler:10;
Surfactant:0.1;
Wax emulsion:2.
It should be noted that the wetting agent in the present embodiment has emulsifiability.The proportion of said components is practical application
It is middle that a small amount of floating, the specific gravity range that the present embodiment provides is allowed to be optimization selection.
Water paint provided in this embodiment is bonded as one using acrylic emulsion as base fluid, by each component in water paint
A entirety can reduce system surface tension, and the preferable permeability for improving water paint solves caused by existing water paint
The non-water-tight problem of coating.Acrylic emulsion is nontoxic, non-stimulated, harmless, the high photopolymer resin of non-film, so that this reality
The water paint applied in example meets environmental requirement, has excellent gloss and the transparency, resistance to blocking can be good.
The wetting agent of water paint provided in this embodiment is a kind of surfactant with low surface tension, and right
Greasy dirt has certain emulsification;After the surface of wall of oil pollution, wetting agent penetrates into oil for the water paint brushing of the present invention
Oil is emulsified into droplet by dirty surface, into coating, becomes the filler of coating together with filler, it is clean to reach beautification
Purpose.In addition, the water paint of the present invention can also be eliminated clean pollution to environment with detergent, with preferable antipollution
Performance.
Specifically, in the present embodiment, wax emulsion can make coating at smooth paint film, improve and increase coating well
Slippery.
It is appreciated that the filler in the present embodiment only serves filling effect, during water paint dried coating film not
Reaction is participated in, the form of filler itself does not have any variation.In practical applications, filler can be specifically calcium carbonate, cunning
One or more kinds of combinations in mountain flour and zinc stearate.
Volatile chemical containing minute quantity in the available material of water paint of the present invention, and more water itself is waved
It is dealt into air and has no adverse effects to environment, the feature of environmental protection is good, low smell, and brushing impact on environmental and human body is small.It avoids existing
The smell is awful caused by solvent based coating renovation metope in technology, the harmful effect of VOC high.The water paint of the present invention is with third
Olefin(e) acid lotion is base fluid, and each component in water paint is bonded as an entirety, can reduce system surface tension, preferably
Improve the permeability of water paint, coating is non-water-tight caused by solving the problems, such as existing water paint.The water paint of the present invention
So that metope is become new by old, and coating is also more easy to clean, have it is long-term it is mould proof, prevent water penetration function.The present invention's is aqueous
Coating can also be eliminated cleans pollution to environment with detergent, has preferable antifouling property.
It can be used in the environment of wide in range property in order to ensure the water paint of the embodiment of the present invention, also need addition portion
Divide auxiliary agent, these auxiliary agents can ensure that coating uses within the scope of different temperatures, different humidity, and ensure what coating stored for a long time
Stability.
The water paint of the present embodiment also comprises the following components, and the mass fraction proportion of each component is respectively:
Hydroxyethyl cellulose:2;
Antifoaming agent:0.2;
Levelling agent:0.15;
Preservative:0.1;
Coalescents:1;
Ethylene glycol ethyl ether:1.5.
In the present embodiment, due to adding levelling agent, it can preferably improve the lubricity and permeability of water paint, and
And the water paint in the present embodiment can use in different temperature, humidity range, stability is preferable when storage for a long time.
There are fire prevention and antibacterial functions in order to ensure the water paint of the embodiment of the present invention, the water paint of the present embodiment is also
Including following component, the mass fraction proportion of each component is respectively:
Fireproof agent:0.2;
Antiseptic:0.1.
The preparation method of water paint includes the following steps in the present embodiment:
(1) water and wax emulsion are mixed and heated to 60-90 DEG C of formation emulsion;Add dispersant and hydroxyethyl cellulose
Ultrasonic disperse reduces temperature to 30-50 DEG C after 20-30 minutes;Phthalocyanine blue toner is added and continues stirring 5-10 minutes;
(2) acrylic emulsion, surfactant and ethylene glycol ethyl ether are mixed, is heated to 40-60 DEG C, in 200-
It is stirred 30-50 minutes under 400 revs/min of rotating speed;
(3) wetting agent, filler, antifoaming agent, levelling agent, preservative and coalescents are uniformly mixed, add step
(1) and the material in step (2) it, is stirred evenly with 200-300 revs/min of rotating speed.
Embodiment 2
The embodiment of the present invention provides a kind of water paint, and the water paint of the present embodiment includes at least following component, each group
Point mass fraction proportion be respectively:
Water:18;
Acrylic emulsion:38;
Dispersant:0.58;
Wetting agent:0.35;
Phthalocyanine blue toner:1.5;
Filler:20;
Surfactant:0.15;
Wax emulsion:5.
Wherein, the wax in wax emulsion includes or mixtures thereof solid paraffin, polyethylene wax.Filler is calcium carbonate, talcum
One or more kinds of combinations in powder and zinc stearate.Preservative is potassium sorbate, methyl p-hydroxybenzoate, to hydroxyl
It is one or more in butyl benzoate and Kathon CG.
It can be used in the environment of wide in range property in order to ensure the water paint of the embodiment of the present invention, also need addition portion
Divide auxiliary agent, these auxiliary agents can ensure that coating uses within the scope of different temperatures, different humidity, and ensure what coating stored for a long time
Stability.
The water paint of the present embodiment also comprises the following components, and the mass fraction proportion of each component is respectively:
Hydroxyethyl cellulose:3;
Antifoaming agent:0.4;
Levelling agent:27;
Preservative:0.18;
Coalescents:1.25;
Ethylene glycol ethyl ether:1.75.
There are fire prevention and antibacterial functions in order to ensure the water paint of the embodiment of the present invention, the water paint of the present embodiment is also
Including following component, the mass fraction proportion of each component is respectively:
Fireproof agent:0.3;
Antiseptic:0.2.
The preparation method is the same as that of Example 1 for water paint in the present embodiment, and details are not described herein.
Embodiment 3
The embodiment of the present invention provides a kind of water paint, and the water paint of the present embodiment includes at least following component, each group
Point mass fraction proportion be respectively:
Water:20;
Acrylic emulsion:45;
Dispersant:0.9;
Wetting agent:0.6;
Phthalocyanine blue toner:2;
Filler:30;
Surfactant:0.2;
Wax emulsion:8.
Wherein, the wax in wax emulsion includes or mixtures thereof solid paraffin, polyethylene wax.Filler is calcium carbonate, talcum
One or more kinds of combinations in powder and zinc stearate.Preservative is potassium sorbate, methyl p-hydroxybenzoate, to hydroxyl
It is one or more in butyl benzoate and Kathon CG.
It can be used in the environment of wide in range property in order to ensure the water paint of the embodiment of the present invention, also need addition portion
Divide auxiliary agent, these auxiliary agents can ensure that coating uses within the scope of different temperatures, different humidity, and ensure what coating stored for a long time
Stability.
The water paint of the present embodiment also comprises the following components, and the mass fraction proportion of each component is respectively:
Hydroxyethyl cellulose:4;
Antifoaming agent:0.6;
Levelling agent:55;
Preservative:0.25;
Coalescents:1.5;
Ethylene glycol ethyl ether:2.
There are fire prevention and antibacterial functions in order to ensure the water paint of the embodiment of the present invention, the water paint of the present embodiment is also
Including following component, the mass fraction proportion of each component is respectively:
Fireproof agent:0.4;
Antiseptic:0.3.
The preparation method is the same as that of Example 1 for water paint in the present embodiment, and details are not described herein.
Through experiment test, water paint made of the embodiment of the present invention 1~3 can reach following technical indicator:
Project | Technical indicator | Test result |
State in a reservoir | It is in uniform state without lump, after stirring | Normally |
Application property | It is accessible to brush two | Normally |
Low-temperature stability (3 cycles) | It never degenerates | It never degenerates |
Appearance of film | Normally | Normally |
Drying time (surface drying)/h | <=2 | 1h |
Contrast ratio (white and light color) | >=0.93 | 0.97 |
Alkali resistance (for 24 hours) | It is without exception | It is without exception |
Abrasion resistance/time | >=5000 | 7500 |
The resistance to accumulation of salt in the surface soil (48h) | It is without exception | It is without exception |
Salting-out resistance (72h) | It is without exception | 135h is without exception |
In conclusion the water paint component proportion science of the present invention, can preferably improve oozing for existing water paint
Permeability, coating is non-water-tight caused by solving the problems, such as existing water paint.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
Claims (10)
1. a kind of water paint, which is characterized in that the water paint includes at least following component, the quality parts ratio of each component
Range is respectively again:
Water:15-20;
Acrylic emulsion:30-45;
Dispersant:0.25-0.9;
Wetting agent:0.1-0.6;
Phthalocyanine blue toner:1-2;
Filler:10-30;
Surfactant:0.1-0.2;
Wax emulsion:2-8.
2. water paint according to claim 1, which is characterized in that the mass fraction specific gravity range of the wax emulsion component
For:Wax emulsion:3-5.
3. water paint according to claim 1, which is characterized in that the wax in the wax emulsion includes solid paraffin, gathers
Or mixtures thereof ethylene waxes.
4. water paint according to claim 1, which is characterized in that the filler is calcium carbonate, talcum powder and tristearin
One or more kinds of combinations in sour zinc.
5. water paint according to claim 1 or 2 or 3 or 4, which is characterized in that the water paint further includes as follows
The mass fraction proportion range of component, each component is respectively:
Hydroxyethyl cellulose:2-4;
Antifoaming agent:0.2-0.6;
Levelling agent:0.15-55;
Preservative:0.1-0.25;
Coalescents:1-1.5;
Ethylene glycol ethyl ether:1.5-2.
6. water paint according to claim 5, which is characterized in that the preservative is potassium sorbate, para hydroxybenzene first
It is one or more in sour methyl esters, butyl p-hydroxybenzoate and Kathon CG.
7. water paint according to claim 1 or 2 or 3 or 4, which is characterized in that the water paint further includes as follows
The mass fraction proportion range of component, each component is respectively:
Fireproof agent:0.2-0.4;
Antiseptic:0.1-0.3.
8. a kind of preparation method of water paint, which is characterized in that include the following steps:
(1) water and wax emulsion are mixed and heated to 60-90 DEG C of formation emulsion;Add dispersant ultrasonic disperse 20-30 minutes
Temperature is reduced afterwards to 30-50 DEG C;Phthalocyanine blue toner is added and continues stirring 5-10 minutes;
(2) acrylic emulsion and surfactant are mixed, is heated to 40-60 DEG C, under 200-400 revs/min of rotating speed
Stirring 30-50 minutes;
(3) wetting agent and filler are uniformly mixed, the material in step (1) and step (2) are added, with 200-300 revs/min
Rotating speed stir evenly.
9. the preparation method of water paint according to claim 8, which is characterized in that be additionally added hydroxyl in the step (1)
Ethyl cellulose carries out ultrasonic disperse, and being additionally added ethylene glycol ethyl ether in the step (2) is mixed, in the step (3), also
Antifoaming agent, levelling agent, preservative and coalescents are added to be uniformly mixed.
10. the preparation method of water paint according to claim 8, which is characterized in that be additionally added in the step (3) anti-
Fiery agent and antiseptic are mixed.
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CN201810493143.9A CN108587355A (en) | 2018-05-22 | 2018-05-22 | Water paint and preparation method thereof |
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CN201810493143.9A CN108587355A (en) | 2018-05-22 | 2018-05-22 | Water paint and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111945461A (en) * | 2020-08-24 | 2020-11-17 | 广东彩乐智能包装科技有限公司 | Water-based paint replacing film, preparation method and packaging box |
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CN107955460A (en) * | 2017-12-15 | 2018-04-24 | 苏州赛斯德工程设备有限公司 | A kind of abrasion-resistance water coating |
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CN101698770A (en) * | 2009-10-30 | 2010-04-28 | 广东嘉宝莉化工有限公司 | Aqueous anti-doodling paint and preparation method thereof |
CN103614032A (en) * | 2013-12-10 | 2014-03-05 | 广州富美奥涂料有限公司 | Water-based paint |
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Application publication date: 20180928 |