CN108587340A - Special-purpose aqueous anticorrosive paint of container and preparation method thereof - Google Patents
Special-purpose aqueous anticorrosive paint of container and preparation method thereof Download PDFInfo
- Publication number
- CN108587340A CN108587340A CN201810568315.4A CN201810568315A CN108587340A CN 108587340 A CN108587340 A CN 108587340A CN 201810568315 A CN201810568315 A CN 201810568315A CN 108587340 A CN108587340 A CN 108587340A
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- crystalline flake
- flake graphite
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003063 flame retardant Substances 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 239000010445 mica Substances 0.000 claims abstract description 12
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 12
- 239000002480 mineral oil Substances 0.000 claims abstract description 12
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 12
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical class [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- 229920000142 Sodium polycarboxylate Polymers 0.000 claims abstract description 11
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 11
- 150000001298 alcohols Chemical class 0.000 claims abstract description 8
- 125000000118 dimethyl group Polymers [H]C([H])([H])* 0.000 claims abstract description 7
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 63
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 62
- 239000010439 graphite Substances 0.000 claims description 62
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 19
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 17
- -1 γ-aminopropyl trimethoxy silicon Alkane Chemical class 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 11
- 238000013019 agitation Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000012286 potassium permanganate Substances 0.000 claims description 9
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 8
- 238000006392 deoxygenation reaction Methods 0.000 claims description 6
- YACKEPLHDIMKIO-UHFFFAOYSA-L methylphosphonate(2-) Chemical compound CP([O-])([O-])=O YACKEPLHDIMKIO-UHFFFAOYSA-L 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000004575 stone Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 13
- 239000011248 coating agent Substances 0.000 abstract description 12
- 238000005260 corrosion Methods 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 230000007797 corrosion Effects 0.000 abstract description 4
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 abstract description 3
- 238000002161 passivation Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012065 filter cake Substances 0.000 description 16
- 206010001497 Agitation Diseases 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000012528 membrane Substances 0.000 description 8
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical compound [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 238000010422 painting Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- QCMYYKRYFNMIEC-UHFFFAOYSA-N COP(O)=O Chemical class COP(O)=O QCMYYKRYFNMIEC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical compound OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 description 1
- XCJXQCUJXDUNDN-UHFFFAOYSA-N chlordene Chemical group C12C=CCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl XCJXQCUJXDUNDN-UHFFFAOYSA-N 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses special-purpose aqueous anticorrosive paint of a kind of container and preparation method thereof, the special-purpose aqueous anticorrosive paint of container includes following weight parts raw material composition：40 50 parts of waterborne styrene-acrylic emulsions, 25 parts of alcohol esters, 12,12 parts of propylene glycol, 0.5 1.5 parts of isothiazolinone, 12 parts of fire retardants, 12 parts of trbasic zinc phosphates, 0.5 1.5 parts of aluminium triphosphates, 12 parts of mica powders, 12 parts of silica, 23 parts of crystalline flake graphites, 0.05 0.25 parts of mineral oil defoaming agents, 0.5 1.2 parts of sodium polycarboxylate dipersants, 0.1 0.5 parts of polyether-modified dimethyl silicone polymer class levelling agents, 5 20 parts of water.The special-purpose aqueous anticorrosive paint of container of the present invention, the contact that corrosive medium can be isolated with metal by forming fine and close coating in metal surface, to reach anti-corrosion purpose, and metallic surface performance can be changed, make passivation of metal surfaces, to achieve the purpose that delay corrosion, while there is excellent fire-retardant fireproof and flexibility.
Description
Technical field：
The present invention relates to paint fields more particularly to a kind of special-purpose aqueous anticorrosive paint of container and preparation method thereof.
Background technology：
Application of the water-based anticorrosive paint in terms of anticorrosive paint field is in rising trend, such as infrastructure, oil gas and electricity
Lixing industry, and industrial tank, ship and chemical industry etc..
Practical application shows that aqueous industrial anticorrosive coating can in extreme conditions be effectively protected steel offer.
It is primary solvent since water is for they, water can also be used to clean and dilute water paint, they are almost without solvent taste, together
When, lower cost can be also brought to user using water paint, if quick-drying can save the time, low flame properties can reduce insurance
Expense, less room ventilation can reduce energy consumption, and not need the cost on solvent and cleaning agent, be matched using signal layer coating
Set, can save the expense etc. of downtime and erecting scaffold.
Metal erosion all can cause huge destruction to machinery, equipment etc. every year, economic damage caused by order to reduce corrosion
It loses, generally can coat anticorrosive paint in metal surface, play shielding, passivation, electro-chemical protection.With holding for national economy
The market scale of supervention exhibition, China's anticorrosive paint has been only second to building coating, occupies second, it is contemplated that arrives the year two thousand twenty China anti-corrosion
The market scale of coating will break through 1,000,000 high pointes t.Currently, anticorrosive paint is solvent based coating substantially, containing big in coating
The volatile organic compounds (VOC) of amount, it is inflammable, it can cause damages to human body and environment.On March 31st, 2013, Guangdong Province was formal
It implements《Aqueous polyurethane anticorrosive paint (bi-component) standard》, which is the first water-based anticorrosive paint standard that China is put into effect；
The State Tax Administration of the Ministry of Finance notice from 2 1st, 2015 for Construction State under VOC content more than 420g/L coating levy
Receive the consumption tax.The appearance of these standards and regulation embodies attention of the China to environmental problem, promotes coatings industry hydrotropismization
Direction is developed, and the structural adjustment of coating industry and the upgrading of product have also been pushed.
Container refers to that there is some strength, rigidity and specification to specialize in the large-scale goods container being used in turn.Use packaging
Case transshipment cargo can directly freight in the warehouse of consignor, transport to the warehouse unloading of consignee, more change trains halfway, ship time, without
Cargo is taken out out of case and is changed the outfit.The standard dry cargo container of domestic product accounts for 95% of world wide production or more, container production and marketing
Amount is always maintained at the first in the world during the last ten years.Container and packaging container of metal manufacturing are a sons under metal product industry
Industry occupies an important position in national economy.With the recovery of world economy, the especially height of International Shipping Industry in recent years
Speed development, as the mating industry for providing packaging for numerous industries, container and packaging container of metal manufacturing will welcome one
The new period of a development.There is also a huge problem of corrosion-resistant, generally uses to spray the special-purpose aqueous anti-corrosion of container for container
Coating is achieved.
However, the special-purpose aqueous anticorrosive paint of container in the prior art, it is bad that there are fire retardant performances, and flexibility is not
The shortcomings of good.
Invention content：
For deficiencies of the prior art, the present invention provides a kind of special-purpose aqueous anticorrosive paint of container and its
Preparation method.
The specific technical solution of the present invention is as follows：
The present invention provides a kind of special-purpose aqueous anticorrosive paints of container, including following weight parts raw material to form： 40-50
Part waterborne styrene-acrylic emulsion, 2-5 parts of alcohol esters 12,1-2 parts of propylene glycol, 0.5-1.5 parts of isothiazolinone, 1-2 parts of fire retardants, 1-2
Part trbasic zinc phosphate, 0.5-1.5 parts of aluminium triphosphates, 1-2 parts of mica powders, 1-2 parts of silica, 2-3 parts of crystalline flake graphites, 0.05-
0.25 part of mineral oil defoaming agent, 0.5-1.2 parts of sodium polycarboxylate dipersants, 0.1-0.5 parts of polyether-modified polydimethylsiloxanes
Alkanes levelling agent, 5-20 part water.
Preferably, the crystalline flake graphite is modified crystalline flake graphite.
The modified crystalline flake graphite is prepared using following methods：
(1) it is 1 in mass ratio by crystalline flake graphite, potassium permanganate：(0.1-0.5) is mixed, and crystalline flake graphite weight 2.5- is added
4.5 times of 60-80wt% hypochloric acid water solution, is stirred to react 1-2h；
(2) water that 12-18 times of crystalline flake graphite weight is added is uniformly mixed, and is filtered, drying, obtains pretreatment crystalline flake graphite；
It (3) will pretreatment crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, γ-aminopropyltrimethoxysilane, tetrahydrochysene
Furans is 1 in mass ratio：(0.8-1.1)：(0.1-0.2)：(1-2)：(35-45) is mixed, and is ultrasonically treated 20-40min, reflux
React 30-40h；
(4) products therefrom is filtered, is washed with tetrahydrofuran, dried, obtain the modified crystalline flake graphite.
Further, the modified crystalline flake graphite is prepared using following methods：Crystalline flake graphite, potassium permanganate are pressed into matter
Amount is than being 1：(0.1-0.5) is uniformly mixed, and the 60-80wt% hypochloric acid water solution of 2.5-4.5 times of crystalline flake graphite weight is added, and is protected
Hold temperature be 25-35 DEG C with rotating speed be 100-300r/min magnetic agitations react 1-2h, after reaction, be added crystalline flake graphite weight
The water of 12-18 times of amount is uniformly mixed, and is filtered, drying, obtains pretreatment crystalline flake graphite；It will pretreatment crystalline flake graphite, chlordene ring three
Phosphonitrile, sodium hydroxide, γ-aminopropyltrimethoxysilane, tetrahydrofuran are 1 in mass ratio：(0.8-1.1)：
(0.1-0.2)：(1-2)：(35-45) is added in three-necked flask and is sufficiently mixed, and is ultrasonically treated 20-40min, leads to nitrogen
Take rotating speed as back flow reaction 30-40h under 100-300r/min magnetic agitations at 60-70 DEG C, reaction terminates after deoxygenation 15-25min
Afterwards, products therefrom is filtered, tetrahydrofuran is used in combination to wash 1-4 times, drying obtains the modified crystalline flake graphite.
The fire retardant is methylol phosphono heterocycle shape methyl phosphonate and/or chlorine-containing methyl silicate flame retardant.Into one
Step ground, the fire retardant is by 60-70wt% methylol phosphono heterocycle shape methyl phosphonates and 30-40wt% silicic acid containing chloromethyl
Ester fire retardant forms.
The present invention also provides a kind of preparation methods of the special-purpose aqueous anticorrosive paint of container, include the following steps：By 40-
50 parts by weight waterborne styrene-acrylic emulsions, 2-5 parts by weight alcohol ester 12,1-2 parts by weight of propylene glycol, 0.5-1.5 parts by weight isothiazolines
Ketone, 1-2 parts by weight of flame retardant are that 500-700r/min stirs 5-15min with rotating speed；Then be added 1-2 parts by weight of phosphoric acid zinc,
0.5-1.5 parts by weight aluminium triphosphate, 1-2 parts by weight mica powder, 1-2 parts by weight of silica, 2-3 parts by weight crystalline flake graphite with
Rotating speed is that 900-1100r/min stirs 15-25min；Then 0.05-0.25 parts by weight mineral oil defoaming agent, 0.5- is added
1.2 parts by weight sodium polycarboxylate dipersants, the polyether-modified dimethyl silicone polymer class levelling agent of 0.1-0.5 parts by weight, 5-20 weights
It is that 500-700r/min stirs 5-15min to get the special-purpose aqueous anticorrosive paint of the container that part water, which is measured, with rotating speed.
The special-purpose aqueous anticorrosive paint of container of the present invention can be isolated by forming fine and close coating in metal surface
Contact of the corrosive medium with metal to reach anti-corrosion purpose, and can change metallic surface performance, keep metal surface blunt
Change, to achieve the purpose that delay corrosion, while there is excellent fire-retardant fireproof and flexibility.
Specific implementation mode
Embodiment 1
The preparation method of the special-purpose aqueous anticorrosive paint of container, includes the following steps：By 45 parts by weight waterborne styrene-acrylic emulsions,
3.5 parts by weight alcohol esters 12,1.5 parts by weight of propylene glycol, 1 parts by weight isothiazolinone, 1.5 parts by weight of flame retardant are with rotating speed
600r/min stirs 10min；Then be added 1.5 parts by weight of phosphoric acid zinc, 1 parts by weight aluminium triphosphate, 1.5 parts by weight mica powder,
1.5 parts by weight of silica, 2.5 part by weight modified crystalline flake graphites are that 1000r/min stirs 20min with rotating speed；Then it is added 0.1
Parts by weight mineral oil defoaming agent, 0.8 parts by weight sodium polycarboxylate dipersant, the polyether-modified polydimethylsiloxanes of 0.2 parts by weight
Alkanes levelling agent, 10 parts by weight of deionized water are that 600r/min stirs 10min to get the special-purpose aqueous anti-corrosion painting of container with rotating speed
Material.
The fire retardant is methylol phosphono heterocycle shape methyl phosphonate.
The preparation method of the modified crystalline flake graphite is：It is 1 in mass ratio by crystalline flake graphite, potassium permanganate：0.25 mixing
Uniformly, the hypochloric acid water solution that the mass fraction of 3.5 times of crystalline flake graphite weight is 70% is added, keeps temperature for 30 DEG C with rotating speed
1.5h is reacted for 180r/min magnetic agitations, after reaction, the deionized water that 15 times of crystalline flake graphite weight is added is uniformly mixed,
It is filtered by vacuum with 0.45 μm of filter membrane, being 65 DEG C in temperature by filter cake dries 48h, obtains pretreatment crystalline flake graphite；It will be pre-
It is 1 to handle crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, γ-aminopropyltrimethoxysilane, tetrahydrofuran in mass ratio：
1：0.15：1.5：40 addition three-necked flasks in be sufficiently mixed, ultrasonic power be 300W, supersonic frequency be 35kHz be ultrasonically treated
30min is back flow reaction 35h under 180r/min magnetic agitations with rotating speed after leading to nitrogen deoxygenation 20min at 65 DEG C, and reaction terminates
Afterwards, products therefrom is filtered by vacuum with 0.45 μm of filter membrane, and filter cake is washed 3 times with tetrahydrofuran, wash four every time
Hydrogen furans dosage is 2 times of filter cake weight, then is 65 DEG C in temperature by filter cake and dries 48h, obtains modified crystalline flake graphite.
Embodiment 2
The preparation method of the special-purpose aqueous anticorrosive paint of container, includes the following steps：By 45 parts by weight waterborne styrene-acrylic emulsions,
3.5 parts by weight alcohol esters 12,1.5 parts by weight of propylene glycol, 1 parts by weight isothiazolinone, 1.5 parts by weight of flame retardant are with rotating speed
600r/min stirs 10min；Then be added 1.5 parts by weight of phosphoric acid zinc, 1 parts by weight aluminium triphosphate, 1.5 parts by weight mica powder,
1.5 parts by weight of silica, 2.5 parts by weight crystalline flake graphites are that 1000r/min stirs 20min with rotating speed；Then 0.1 weight is added
Part mineral oil defoaming agent, 0.8 parts by weight sodium polycarboxylate dipersant, the polyether-modified dimethyl silicone polymer class of 0.2 parts by weight
Levelling agent, 10 parts by weight of deionized water are that 600r/min stirs 10min to get the special-purpose aqueous anticorrosive paint of container with rotating speed.
The fire retardant is methylol phosphono heterocycle shape methyl phosphonate.
Embodiment 3
The preparation method of the special-purpose aqueous anticorrosive paint of container, includes the following steps：By 45 parts by weight waterborne styrene-acrylic emulsions,
3.5 parts by weight alcohol esters 12,1.5 parts by weight of propylene glycol, 1 parts by weight isothiazolinone, 1.5 parts by weight of flame retardant are with rotating speed
600r/min stirs 10min；Then be added 1.5 parts by weight of phosphoric acid zinc, 1 parts by weight aluminium triphosphate, 1.5 parts by weight mica powder,
1.5 parts by weight of silica, 2.5 part by weight modified crystalline flake graphites are that 1000r/min stirs 20min with rotating speed；Then it is added 0.1
Parts by weight mineral oil defoaming agent, 0.8 parts by weight sodium polycarboxylate dipersant, the polyether-modified polydimethylsiloxanes of 0.2 parts by weight
Alkanes levelling agent, 10 parts by weight of deionized water are that 600r/min stirs 10min to get the special-purpose aqueous anti-corrosion painting of container with rotating speed
Material.
The fire retardant is methylol phosphono heterocycle shape methyl phosphonate.
The preparation method of the modified crystalline flake graphite is：It is 1 in mass ratio by crystalline flake graphite, potassium permanganate：0.25 mixing
Uniformly, the hypochloric acid water solution that the mass fraction of 3.5 times of crystalline flake graphite weight is 70% is added, keeps temperature for 30 DEG C with rotating speed
1.5h is reacted for 180r/min magnetic agitations, after reaction, the deionized water that 15 times of crystalline flake graphite weight is added is uniformly mixed,
It is filtered by vacuum with 0.45 μm of filter membrane, being 65 DEG C in temperature by filter cake dries 48h, obtains pretreatment crystalline flake graphite；It will be pre-
It is 1 to handle crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, tetrahydrofuran in mass ratio：1：0.15：40 are added three-necked flask
In be sufficiently mixed, ultrasonic power is 300W, supersonic frequency is that 35kHz is ultrasonically treated 30min, after leading to nitrogen deoxygenation 20min,
65 DEG C are back flow reaction 35h under 180r/min magnetic agitations with rotating speed, after reaction, by 0.45 μm of filter membrane of products therefrom
It is filtered by vacuum, and filter cake is washed 3 times with tetrahydrofuran, wash 2 times that tetrahydrofuran dosage is filter cake weight every time, then
Filter cake is 65 DEG C in temperature and dries 48h, obtains modified crystalline flake graphite.
Embodiment 4
The preparation method of the special-purpose aqueous anticorrosive paint of container, includes the following steps：By 45 parts by weight waterborne styrene-acrylic emulsions,
3.5 parts by weight alcohol esters 12,1.5 parts by weight of propylene glycol, 1 parts by weight isothiazolinone, 1.5 parts by weight of flame retardant are with rotating speed
600r/min stirs 10min；Then be added 1.5 parts by weight of phosphoric acid zinc, 1 parts by weight aluminium triphosphate, 1.5 parts by weight mica powder,
1.5 parts by weight of silica, 2.5 part by weight modified crystalline flake graphites are that 1000r/min stirs 20min with rotating speed；Then it is added 0.1
Parts by weight mineral oil defoaming agent, 0.8 parts by weight sodium polycarboxylate dipersant, the polyether-modified polydimethylsiloxanes of 0.2 parts by weight
Alkanes levelling agent, 10 parts by weight of deionized water are that 600r/min stirs 10min to get the special-purpose aqueous anti-corrosion painting of container with rotating speed
Material.
The fire retardant is chlorine-containing methyl silicate flame retardant.
The preparation method of the modified crystalline flake graphite is：It is 1 in mass ratio by crystalline flake graphite, potassium permanganate：0.25 mixing
Uniformly, the hypochloric acid water solution that the mass fraction of 3.5 times of crystalline flake graphite weight is 70% is added, keeps temperature for 30 DEG C with rotating speed
1.5h is reacted for 180r/min magnetic agitations, after reaction, the deionized water that 15 times of crystalline flake graphite weight is added is uniformly mixed,
It is filtered by vacuum with 0.45 μm of filter membrane, being 65 DEG C in temperature by filter cake dries 48h, obtains pretreatment crystalline flake graphite；It will be pre-
It is 1 to handle crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, γ-aminopropyltrimethoxysilane, tetrahydrofuran in mass ratio：
1：0.15：1.5：40 addition three-necked flasks in be sufficiently mixed, ultrasonic power be 300W, supersonic frequency be 35kHz be ultrasonically treated
30min is back flow reaction 35h under 180r/min magnetic agitations with rotating speed after leading to nitrogen deoxygenation 20min at 65 DEG C, and reaction terminates
Afterwards, products therefrom is filtered by vacuum with 0.45 μm of filter membrane, and filter cake is washed 3 times with tetrahydrofuran, wash four every time
Hydrogen furans dosage is 2 times of filter cake weight, then is 65 DEG C in temperature by filter cake and dries 48h, obtains modified crystalline flake graphite.
Embodiment 5
The preparation method of the special-purpose aqueous anticorrosive paint of container, includes the following steps：By 45 parts by weight waterborne styrene-acrylic emulsions,
3.5 parts by weight alcohol esters 12,1.5 parts by weight of propylene glycol, 1 parts by weight isothiazolinone, 1.5 parts by weight of flame retardant are with rotating speed
600r/min stirs 10min；Then be added 1.5 parts by weight of phosphoric acid zinc, 1 parts by weight aluminium triphosphate, 1.5 parts by weight mica powder,
1.5 parts by weight of silica, 2.5 part by weight modified crystalline flake graphites are that 1000r/min stirs 20min with rotating speed；Then it is added 0.1
Parts by weight mineral oil defoaming agent, 0.8 parts by weight sodium polycarboxylate dipersant, the polyether-modified polydimethylsiloxanes of 0.2 parts by weight
Alkanes levelling agent, 10 parts by weight of deionized water are that 600r/min stirs 10min to get the special-purpose aqueous anti-corrosion painting of container with rotating speed
Material.
The fire retardant is hindered by 65wt% methylol phosphono heterocycle shape methyl phosphonates and 35wt% chlorine-containing methyl silicates
Combustion agent mixes.
The preparation method of the modified crystalline flake graphite is：It is 1 in mass ratio by crystalline flake graphite, potassium permanganate：0.25 mixing
Uniformly, the hypochloric acid water solution that the mass fraction of 3.5 times of crystalline flake graphite weight is 70% is added, keeps temperature for 30 DEG C with rotating speed
1.5h is reacted for 180r/min magnetic agitations, after reaction, the deionized water that 15 times of crystalline flake graphite weight is added is uniformly mixed,
It is filtered by vacuum with 0.45 μm of filter membrane, being 65 DEG C in temperature by filter cake dries 48h, obtains pretreatment crystalline flake graphite；It will be pre-
It is 1 to handle crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, γ-aminopropyltrimethoxysilane, tetrahydrofuran in mass ratio：
1：0.15：1.5：40 addition three-necked flasks in be sufficiently mixed, ultrasonic power be 300W, supersonic frequency be 35kHz be ultrasonically treated
30min is back flow reaction 35h under 180r/min magnetic agitations with rotating speed after leading to nitrogen deoxygenation 20min at 65 DEG C, and reaction terminates
Afterwards, products therefrom is filtered by vacuum with 0.45 μm of filter membrane, and filter cake is washed 3 times with tetrahydrofuran, wash four every time
Hydrogen furans dosage is 2 times of filter cake weight, then is 65 DEG C in temperature by filter cake and dries 48h, obtains modified crystalline flake graphite.
Test case 1
The special-purpose aqueous anticorrosive paint of container prepared by embodiment 1-5 is tested for the property.
The fire resisting that the special-purpose aqueous anticorrosive paint coating thickness of container is 2mm is detected according to the method for GB14907-2002
Time.
The special-purpose aqueous anticorrosive paint flexibility of container is detected according to the method for GB/T1731-93.
Container special-purpose aqueous anticorrosive paint drying time is detected according to GB/T1728-89 methods.
Specific test data is shown in Table 1.
Table 1：The special-purpose aqueous anticorrosive paint test result table of container
Each embodiment is raw materials used as follows：
Waterborne styrene-acrylic emulsion is according to method system shown in embodiment in the Chinese patent application No. is 201210450902.6 one
It is standby.
Alcohol ester 12, No. CAS：25265-77-4.
Propylene glycol, i.e. 1,2-PD, No. CAS：57-55-6.
Isothiazolinone, No. CAS：55965-84-9.
Trbasic zinc phosphate is the 800 mesh PHOSPHORIC ACID TECH.GRADE zinc that Changzhou Rong Ao new chemical materials Co., Ltd provides.
Aluminium triphosphate is the 325 mesh technical grade aluminium triphosphates that Shijiazhuang City Xin Sheng Chemical Co., Ltd.s provide.
Mica powder is the 4000 mesh mica powders that Lingshou County Rui Da mining industry Co., Ltd provides.
Silica is the silica for the model R9722 that Shandong Jia Ying Chemical Industry Science Co., Ltd provides, and grain size is
50-60nm。
Crystalline flake graphite is the 325 mesh natural flake graphites that Qingdao Dong Kai graphite Co., Ltd provides.
Potassium permanganate, No. CAS：7722-64-7.
Hexachlorocyclotriph,sphazene, No. CAS：940-71-6.
γ-aminopropyltrimethoxysilane, No. CAS：13822-56-5.
Tetrahydrofuran, No. CAS：109-99-9.
Sodium polycarboxylate dipersant is the polycarboxylate sodium for the model SN-5040 that the eternally happy Chemical Co., Ltd. in Nantong provides
Dispersant.
Mineral oil defoaming agent is the antifoaming agent for the model F-111 that TaiWan, China Central Asia Chemical Co., Ltd. provides, and is
Mineral oil emulsion derivative species antifoaming agent.
Polyether-modified dimethyl silicone polymer class levelling agent is the model BYK- that German Byk Chemie GmbH provides
333 levelling agent, ingredient：Polyether-modified dimethyl silicone polymer.
Isothiazolinone, No. CAS：55965-84-9.
Chlorine-containing methyl silicate flame retardant is according to shown in embodiment in the Chinese patent application No. is 201110042943.7 6
It is prepared by method.
Methylol phosphono heterocycle shape methyl phosphonate in the Chinese patent application No. is 201510404785.3 according to implementing
It is prepared by method shown in example 3.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the protection scope of the present invention.Therefore, of the invention
Protection domain should be determined by the scope of protection defined in the claims.
Claims (6)
1. a kind of special-purpose aqueous anticorrosive paint of container, which is characterized in that formed including following weight parts raw material：40-50 parts of water
Property styrene-acrylic emulsion, 2-5 parts of alcohol esters 12,1-2 parts of propylene glycol, 0.5-1.5 parts of isothiazolinone, 1-2 parts of fire retardants, 1-2 parts of phosphorus
Sour zinc, 0.5-1.5 part aluminium triphosphate, 1-2 parts of mica powders, 1-2 parts of silica, 2-3 parts of crystalline flake graphites, 0.05-0.25 parts
Mineral oil defoaming agent, 0.5-1.2 parts of sodium polycarboxylate dipersants, 0.1-0.5 parts of polyether-modified dimethyl silicone polymer class streams
Flat agent, 5-20 parts of water.
2. the special-purpose aqueous anticorrosive paint of container as described in claim 1, which is characterized in that the crystalline flake graphite is modified squama
Piece graphite.
3. the special-purpose aqueous anticorrosive paint of container as claimed in claim 2, which is characterized in that the modified crystalline flake graphite uses
Following methods are prepared：
(1) it is 1 in mass ratio by crystalline flake graphite, potassium permanganate：(0.1-0.5) is mixed, and 2.5-4.5 times of crystalline flake graphite weight is added
60-80wt% hypochloric acid water solution, be stirred to react 1-2h；
(2) water that 12-18 times of crystalline flake graphite weight is added is uniformly mixed, and is filtered, drying, obtains pretreatment crystalline flake graphite；
It (3) will pretreatment crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, γ-aminopropyltrimethoxysilane, tetrahydrofuran
It is 1 in mass ratio：(0.8-1.1)：(0.1-0.2)：(1-2)：(35-45) is mixed, and is ultrasonically treated 20-40min, back flow reaction
30-40h；
(4) products therefrom is filtered, is washed with tetrahydrofuran, dried, obtain the modified crystalline flake graphite.
4. the special-purpose aqueous anticorrosive paint of container as claimed in claim 3, which is characterized in that the modified crystalline flake graphite uses
Following methods are prepared：It is 1 in mass ratio by crystalline flake graphite, potassium permanganate：(0.1-0.5) is uniformly mixed, and scale stone is added
The 60-80wt% hypochloric acid water solution of 2.5-4.5 times of black weight, keep temperature be 25-35 DEG C with rotating speed for 100-300r/min
Magnetic agitation reacts 1-2h, and after reaction, the water that 12-18 times of crystalline flake graphite weight is added is uniformly mixed, and is filtered, and drying obtains
To pretreatment crystalline flake graphite；It will pretreatment crystalline flake graphite, hexachlorocyclotriph,sphazene, sodium hydroxide, γ-aminopropyl trimethoxy silicon
Alkane, tetrahydrofuran are 1 in mass ratio：(0.8-1.1)：(0.1-0.2)：(1-2)：(35-45) is added fully mixed in three-necked flask
It closes, is ultrasonically treated 20-40min, after leading to nitrogen deoxygenation 15-25min, stirred for 100-300r/min magnetic force with rotating speed at 60-70 DEG C
It mixes lower back flow reaction 30-40h after reaction to filter products therefrom, tetrahydrofuran is used in combination to wash 1-4 times, drying obtains
The modified crystalline flake graphite.
5. the special-purpose aqueous anticorrosive paint of container as described in any one of claim 1-4, which is characterized in that the fire retardant
For methylol phosphono heterocycle shape methyl phosphonate and/or chlorine-containing methyl silicate flame retardant.
6. the preparation method of the special-purpose aqueous anticorrosive paint of the container as described in any one of claim 1-5, which is characterized in that packet
Include following step：
By 40-50 parts by weight waterborne styrene-acrylic emulsion, 2-5 parts by weight alcohol ester 12,1-2 parts by weight of propylene glycol, 0.5-1.5 parts by weight
Isothiazolinone, 1-2 parts by weight of flame retardant are that 500-700r/min stirs 5-15min with rotating speed；Then 1-2 parts by weight phosphorus is added
Sour zinc, 0.5-1.5 parts by weight aluminium triphosphate, 1-2 parts by weight mica powder, 1-2 parts by weight of silica, 2-3 parts by weight scales
Graphite stirs 15-25min with the rotating speed of 900-1100r/min；Then be added 0.05-0.25 parts by weight mineral oil defoaming agents,
0.5-1.2 parts by weight sodium polycarboxylates dipersant, the polyether-modified dimethyl silicone polymer class levelling agent of 0.1-0.5 parts by weight, 5-
20 parts by weight water are that 500-700r/min stirs 5-15min to get the special-purpose aqueous anticorrosive paint of the container with rotating speed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810568315.4A CN108587340B (en) | 2018-06-05 | 2018-06-05 | Special water-based anticorrosive paint for container and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810568315.4A CN108587340B (en) | 2018-06-05 | 2018-06-05 | Special water-based anticorrosive paint for container and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108587340A true CN108587340A (en) | 2018-09-28 |
| CN108587340B CN108587340B (en) | 2024-01-12 |
Family
ID=63630784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810568315.4A Active CN108587340B (en) | 2018-06-05 | 2018-06-05 | Special water-based anticorrosive paint for container and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108587340B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024021366A1 (en) * | 2022-07-25 | 2024-02-01 | 潍坊佳诚数码材料有限公司 | Fire-resistant coating material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153780A (en) * | 2011-02-23 | 2011-08-17 | 苏州科技学院 | Chlorine-containing methyl silicate flame retardant and preparation method thereof |
| CN104592821A (en) * | 2015-01-31 | 2015-05-06 | 广东华兹卜化学工业有限公司 | Water-based industrial anti-corrosion paint and preparation method thereof |
| CN104926873A (en) * | 2015-07-07 | 2015-09-23 | 苏州凯马化学科技有限责任公司 | Fire retardant hydroxymethyl phosphonyl hybrid ring-shaped methylphosphonate compound and preparing method thereof |
| CN105037801A (en) * | 2015-08-03 | 2015-11-11 | 苏州大学 | Phosphorus-containing hybridization graphene oxide and preparation method thereof |
-
2018
- 2018-06-05 CN CN201810568315.4A patent/CN108587340B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153780A (en) * | 2011-02-23 | 2011-08-17 | 苏州科技学院 | Chlorine-containing methyl silicate flame retardant and preparation method thereof |
| CN104592821A (en) * | 2015-01-31 | 2015-05-06 | 广东华兹卜化学工业有限公司 | Water-based industrial anti-corrosion paint and preparation method thereof |
| CN104926873A (en) * | 2015-07-07 | 2015-09-23 | 苏州凯马化学科技有限责任公司 | Fire retardant hydroxymethyl phosphonyl hybrid ring-shaped methylphosphonate compound and preparing method thereof |
| CN105037801A (en) * | 2015-08-03 | 2015-11-11 | 苏州大学 | Phosphorus-containing hybridization graphene oxide and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024021366A1 (en) * | 2022-07-25 | 2024-02-01 | 潍坊佳诚数码材料有限公司 | Fire-resistant coating material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108587340B (en) | 2024-01-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107987680B (en) | Water-based epoxy graphene anticorrosive paint | |
| CN103666201B (en) | Long-acting acid and alkali-resistance, solvent-free anticorrosive paint and preparation method thereof and application | |
| CN102002298A (en) | Aqueous antifouling adhesive preventing coating and production method thereof | |
| CN103360951B (en) | A kind of black water heat resistance paint and preparation method thereof | |
| CN104725969B (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| CN102268221A (en) | Double-component aqueous inorganic non-expandable fireproof coating and preparation method thereof | |
| CN102702963B (en) | Sulfur-containing flue anticorrosion paint and preparation method thereof | |
| CN1986711A (en) | Acid-proof wear-proof anticorrosive paint and its preparing method | |
| CN105440821A (en) | Antirust paint for pump valve | |
| CN104119708A (en) | Inorganic zinc-rich anticorrosive paint | |
| CN108395743A (en) | Method for preparing environment-friendly water-based ceramic coating | |
| CN108587340A (en) | Special-purpose aqueous anticorrosive paint of container and preparation method thereof | |
| CN104910794A (en) | Waterproof anticorrosive coating for coastal environment wooden ancient buildings and preparation method of waterproof anticorrosive coating | |
| CN103073969A (en) | Epoxy resin antirust paint and preparation method thereof | |
| CN102816486A (en) | Rust-removing-free environment-friendly acrylic acid zinc phosphate organic composite ceramic anticorrosive paint and preparation method thereof | |
| CN105273454B (en) | Nano inorganic zinc-rich composite anticorrosion coating and preparation method thereof | |
| CN103131316B (en) | A kind of clear wood lacquer and its preparation method thoroughly | |
| CN104893544A (en) | Fireproof wind-sand-resistant paint for desert environment wood ancient building and preparation method of fireproof wind-sand-resistant paint | |
| CN101348689B (en) | Aqueous Malay paint | |
| CN102993794B (en) | A kind of wheel refractory anti-rust paint peculiar to vessel and preparation method thereof | |
| CN105838186B (en) | A kind of novel anticorrosion coating and preparation method thereof | |
| CN101691457A (en) | Inorganic zinc-rich paint and preparation method thereof | |
| CN100523103C (en) | Preparation process of blast furnace dust-based antiwear anticorrosive paint | |
| CN103666375A (en) | Environment-friendly dust suppressant containing modified hyperbranched polyester and preparation method thereof | |
| CN104212258A (en) | Specific anticorrosion paint for chemical equipment and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20231213 Address after: 528000, Room 403 and 404, Building 28, Shunde Zhifu Garden, No. 8 Second Ring Road, Gaozan Village, Xingtan Town, Shunde District, Foshan City, Guangdong Province (Residence Declaration) Applicant after: Guangdong Jinyao New Materials Co.,Ltd. Address before: 200080 Room C, 14th floor, 309 Tanggu Road, Hongkou District, Shanghai Applicant before: SHANGHAI MINGANG MACHINERY TECHNOLOGY Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |