CN108586941A - A kind of PP-R pipe formula of special material with high flame resistance - Google Patents

A kind of PP-R pipe formula of special material with high flame resistance Download PDF

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Publication number
CN108586941A
CN108586941A CN201810296892.2A CN201810296892A CN108586941A CN 108586941 A CN108586941 A CN 108586941A CN 201810296892 A CN201810296892 A CN 201810296892A CN 108586941 A CN108586941 A CN 108586941A
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CN
China
Prior art keywords
parts
flame resistance
high flame
special material
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810296892.2A
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Chinese (zh)
Inventor
安德烈·别洛乌索夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QINGDAO BLUE OCEAN NEW HIGH TECHNOLOGY Co Ltd
Original Assignee
QINGDAO BLUE OCEAN NEW HIGH TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QINGDAO BLUE OCEAN NEW HIGH TECHNOLOGY Co Ltd filed Critical QINGDAO BLUE OCEAN NEW HIGH TECHNOLOGY Co Ltd
Priority to CN201810296892.2A priority Critical patent/CN108586941A/en
Publication of CN108586941A publication Critical patent/CN108586941A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/10Peculiar tacticity
    • C08L2207/14Amorphous or atactic polypropylene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of PP R special material for tube formulas with high flame resistance, formula include PP R monomers, fire retardant, lubricant, dispersant, Antidrip agent, antioxidant, light stabilizer, and the parts by weight of each component are specially in the formula:20~25 parts of 50~65 parts of PP R, fire retardant PDBPP, 5~8 parts of activated carbon, 8~12 parts of stearic acid, 5~10 parts of dispersant ethylene group bis-stearamides, pure 5~15 parts of powder type polytetrafluoroethylene (PTFE), 5~8 parts of calcium stearate, 1~5 part of antioxidant, 0.3~1 part of light stabilizer.The present invention provides a kind of PP R special material for tube formulas with high flame resistance, by the way that the auxiliary agents such as fire retardant PDBPP, lubricant stearic acid, dispersant ethylene group bis-stearamides, Antidrip agent polytetrafluoroethylene (PTFE) are added in PP R, to improve the anti-flammability of PP R tubing, the requirement of construction material B1 flame retardant ratings is reached.

Description

A kind of PP-R pipe formula of special material with high flame resistance
Technical field
The present invention relates to PP-R pipe technical field, especially a kind of PP-R pipe PP Pipe Compound with high flame resistance is matched Side.
Background technology
PP-R also known as three type PA tubes, atactic copolymerized polypropene become pipe using atactic copolymerized polypropene is extrudable Material can also be molded as pipe fitting.Its toughness of products is good, and shock resistance is strong, and processing performance is excellent, reduces hot melt jointing temp, It is essentially identical with homopolymer in terms of chemical stability, water vapour isolation performance simultaneously.PP-R can be widely applied to squeeze out, blow Modeling, injection molding, film and sheet extrusion manufacture field, can be used as packaging material for food, medical packaging material and common consumer product.
Currently, the fire protection pipeline in building uses coating steel pipe, but coating steel pipe gets rusty easily, corrodes, and leads to pipeline system System leak, increases the cost safeguarded and replaced, and coating steel pipe weight is big, transport and installation complexity.PP-R pipe and tradition Coating steel pipe compare, have that energy-saving and environmental protection, light high-strength, corrosion-resistant, inner wall smooth non-scaling, installation and repair are easy, make The advantages that with long lifespan, is widely used in the fields such as building water supply and drainage, town and country plumbing, city gas.However, giving in building Water piping system belongs to inflammable raw material, easy tos produce fire using common PP-R materials, significantly limits PP-R pipes The use of material.
Invention content
In order to overcome the inflammable defect of PP-R pipe existing in the prior art, the flame retardant rating of PP-R pipe, this hair are improved It is bright that a kind of PP-R pipe formula of special material with high flame resistance is provided, by adding fire retardant PDBPP, lubrication in PP-R The auxiliary agents such as agent stearic acid, dispersant ethylene group bis-stearamides, Antidrip agent polytetrafluoroethylene (PTFE), improve the fire-retardant of PP-R pipe Property, to reach the requirement of construction material B1 flame retardant ratings, and there is obdurability, high stability and corrosion resistance.
The technical solution adopted by the present invention to solve the technical problems is:A kind of PP-R pipe with high flame resistance is special With material formula, including PP-R monomers, fire retardant, lubricant, dispersant, Antidrip agent, antioxidant, light stabilizer, each component Parts by weight are:
A kind of above-mentioned PP-R pipe formula of special material with high flame resistance, the dispersant are that ethylene group is double hard Acyl amine.
A kind of above-mentioned PP-R pipe formula of special material with high flame resistance, the Antidrip agent polytetrafluoroethylene (PTFE) are Pure powder type.
A kind of above-mentioned PP-R pipe formula of special material with high flame resistance, the antioxidant are antioxidant 1010 four [3- (3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 10176 β of pentaerythritol resin or antioxidant-(3,5- di-t-butyl -4- hydroxyls Base phenyl) propionic acid octadecanol fat.
A kind of above-mentioned PP-R pipe formula of special material with high flame resistance, the light stabilizer are ultraviolet radiation absorption Agent UV-531 2-hydroxy-4-n-octoxybenzophenones or light stabilizer AM-101 2,2'- thiobis (4- t-octyl phenol oxygen Base) nickel.
The invention has the advantages that a kind of PP-R pipe formula of special material with high flame resistance of the present invention, by PP- R is by increasing the auxiliary agents such as fire retardant, lubricant, dispersant, Antidrip agent, to reach wanting for construction material B1 flame retardant ratings It asks, by the tubing of this formula production, not only flame retardant property is good, light weight, corrosion-resistant, and material has obdurability and height steady It is qualitative, it may be used at fire resistance rating and requires high place, fire-fighting pipe-line system and automatic sprinkler fire-extinguishing system.
Specific implementation mode
To make those skilled in the art be better understood from technical scheme of the present invention, With reference to embodiment to this Invention elaborates.
【Embodiment 1】
A kind of PP-R pipe formula of special material with high flame resistance, including PP-R monomers, fire retardant, lubricant, point The parts by weight of powder, Antidrip agent, antioxidant, light stabilizer, each component are:
Specifically, the dispersant is ethylene group bis-stearamides, the polytetrafluoroethylene (PTFE) is pure powder type, the antioxygen Agent is antioxidant 1010 four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol resin, and the light stabilizer is purple Ultraviolet absorbers UV-531 2-hydroxy-4-n-octoxybenzophenones.
【Embodiment 2】
A kind of PP-R pipe formula of special material with high flame resistance, including PP-R monomers, fire retardant, lubricant, point The parts by weight of powder, Antidrip agent, antioxidant, light stabilizer, each component are:
Specifically, the dispersant is ethylene group bis-stearamides, the polytetrafluoroethylene (PTFE) is pure powder type, the antioxygen Agent is 10176 β of antioxidant-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol fat, and the light stabilizer is stablized for light Agent AM-101 2,2'- thiobis (4- t-octyl phenol oxygroup) nickel.
【Embodiment 3】
A kind of PP-R pipe formula of special material with high flame resistance, including PP-R monomers, fire retardant, lubricant, point The parts by weight of powder, Antidrip agent, antioxidant, light stabilizer, each component are:
Specifically, the dispersant is ethylene group bis-stearamides, the polytetrafluoroethylene (PTFE) is pure powder type, the antioxygen Agent is antioxidant 1010 four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol resin, and the light stabilizer is light Stabilizer AM-101 2,2'- thiobis (4- t-octyl phenol oxygroup) nickel.
Above example is only exemplary embodiment of the present invention, is not used in the limitation present invention, protection scope of the present invention It is defined by the claims.Those skilled in the art can within the spirit and scope of the present invention make respectively the present invention Kind modification or equivalent replacement, this modification or equivalent replacement also should be regarded as being within the scope of the present invention.

Claims (5)

1. a kind of PP-R pipe formula of special material with high flame resistance, including PP-R monomers, fire retardant, lubricant, dispersion Agent, Antidrip agent, antioxidant, light stabilizer, which is characterized in that the parts by weight of each component are:
2. a kind of PP-R pipe formula of special material with high flame resistance according to claim 1, which is characterized in that institute The dispersant stated is ethylene group bis-stearamides.
3. a kind of PP-R pipe formula of special material with high flame resistance according to claim 1, which is characterized in that institute It is pure powder type to state Antidrip agent polytetrafluoroethylene (PTFE).
4. a kind of PP-R pipe formula of special material with high flame resistance according to claim 1, which is characterized in that institute It is specially antioxidant 1010 or antioxidant 10176 to state antioxidant.
5. a kind of PP-R pipe formula of special material with high flame resistance according to claim 1, which is characterized in that institute It is ultraviolet absorbent UV-531 or light stabilizer AM-101 to state light stabilizer.
CN201810296892.2A 2018-04-04 2018-04-04 A kind of PP-R pipe formula of special material with high flame resistance Pending CN108586941A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810296892.2A CN108586941A (en) 2018-04-04 2018-04-04 A kind of PP-R pipe formula of special material with high flame resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810296892.2A CN108586941A (en) 2018-04-04 2018-04-04 A kind of PP-R pipe formula of special material with high flame resistance

Publications (1)

Publication Number Publication Date
CN108586941A true CN108586941A (en) 2018-09-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810296892.2A Pending CN108586941A (en) 2018-04-04 2018-04-04 A kind of PP-R pipe formula of special material with high flame resistance

Country Status (1)

Country Link
CN (1) CN108586941A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105542298A (en) * 2015-12-11 2016-05-04 合肥会通新材料有限公司 Low-smoke flame-retardant reinforced polypropylene material used for buckle of elevator and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105542298A (en) * 2015-12-11 2016-05-04 合肥会通新材料有限公司 Low-smoke flame-retardant reinforced polypropylene material used for buckle of elevator and preparation method thereof

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Application publication date: 20180928