CN108576033A - Herbicidal composition for rice field and its application - Google Patents
Herbicidal composition for rice field and its application Download PDFInfo
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- CN108576033A CN108576033A CN201810210862.5A CN201810210862A CN108576033A CN 108576033 A CN108576033 A CN 108576033A CN 201810210862 A CN201810210862 A CN 201810210862A CN 108576033 A CN108576033 A CN 108576033A
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- herbicidal composition
- rice field
- flucetosulfuron
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- sulphur humulone
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention proposes a kind of Herbicidal composition for rice field and its application, including active ingredient and auxiliary element, and active ingredient includes furans sulphur humulone and flucetosulfuron, and the weight ratio of the furans sulphur humulone and flucetosulfuron is 1:1.5~3:1.Herbicidal composition for rice field provided by the invention and its application pass through the recipe determination to furans sulphur humulone and flucetosulfuron, the two is set to show apparent synergistic effect to paddy field weed within the scope of certain compound proportion, solve limitation of the both the above herbicide in herbicide controlling spectrum, preventive effect and safety, the two mechanism of action is different, rationally compounding can delay the generation of herbicide resistance, expand herbicide controlling spectrum, extends the medicament lasting period.
Description
Technical field
The present invention relates to pesticide field more particularly to herbicide fields, and in particular to a kind of Herbicidal composition for rice field and
It is applied.
Background technology
Furans sulphur humulone belongs to benzoyl cyclohexanedione class herbicide, mainly by inhibit growing process in can not
Or scarce pigment synthesis is killed weeds, can be absorbed by root, stem, young shoot and leaf and be conducted rapidly.It is to annual and for many years
Raw weeds, including have awns cyperus iria category and have the weeds of drug resistance all largely effective sulfonylurea herbicide.Mainly
It is prevented and kill off 1 year for rice, cereal and perennial weeds and nutgrass flatsedge.
Flucetosulfuron chemical name：Chemical name：1- (- 2 base of 4,6- dimethoxypyridins) -3- [the fluoro- 1- of 2-
(methoxyl group acetoxyl group) propyl -3- pyridine sulfonyl sulfonyls base] urea.It is by LG life sciences Co., Ltd of South Korea and South Korea
A kind of sulfonylurea herbicide that chemical technology research association develops jointly.The inhibitor of acetolactate synthestase, that is, pass through
Inhibit the ALS enzymes of plant, prevents the biosynthesis of branched-chain amino acid such as valine, isoleucine, leucine, finally destroy albumen
Synthesis and cell division and the growth of DNA are interfered in the synthesis of matter.It can be absorbed by the root, stem and leaf of plant, lead to weeds
Grow stopping, chlorosis, apical meristem death.
Herbicide is the major way of current preventing and controlling weed in rice field, but applies single chemistry to continuous high dose for a long time
Herbicide, Weed Resistance, population succession and drug injury problem getting worse existing for farmland weed chemical control.Different pesticide species
Mixture, be prevent agriculture diseases, insect pests and weeds common methods.It is screened by formulation of pesticide, filters out rational formula, it can be effective
Practical control effect is improved, dosage is reduced, reduces cost, delay the generation of disease pest and weed drug resistance, is that agricultural synthesis is administered
Important means.When being directed to furans sulphur humulone and flucetosulfuron single use at present, there are certain defect and limitation.At present
There is no the compound medicines about the two, and are used for other weeding Drug Combination Effects of rice terrace nor highly desirable.
Invention content
The present invention for the above technical issues, proposes a kind of Herbicidal composition for rice field and its application.
In order to achieve the above object, the technical solution adopted by the present invention is：
Herbicidal composition for rice field, including active ingredient and auxiliary element, active ingredient include furans sulphur humulone and fluorine pyrrole
Sulphur is grand, and the weight ratio of the furans sulphur humulone and flucetosulfuron is 1:1.5~3:1.
As preferred：The weight ratio of the furans sulphur humulone and flucetosulfuron is 1:1~2:1.
As preferred：The weight ratio of the furans sulphur humulone and flucetosulfuron is 1:1.
As preferred：Active ingredient furans sulphur humulone and flucetosulfuron weight shared in the Herbicidal composition for rice field
It is 1%~75% to measure percentage composition.
As preferred：Active ingredient furans sulphur humulone and flucetosulfuron weight shared in the Herbicidal composition for rice field
It is 12%~60% to measure percentage composition.
As preferred：The auxiliary element includes carrier and auxiliary agent, the carrier be one kind in water, solvent and filler or
Several, the auxiliary agent includes at least a kind of surfactant.
As preferred：The surfactant is one or more of emulsifier, dispersant, wetting agent and bleeding agent；
The auxiliary agent further includes one or more of antifreezing agent, thickener, stabilizer, disintegrant and antifoaming agent.
As preferred：The solvent is n,N-Dimethylformamide, cyclohexanone, toluene, dimethylbenzene, dimethyl sulfoxide (DMSO), first
Alcohol, ethyl alcohol, trimethylcyclohexanone, n-octylpyrrolidone, ethanol amine, triethanolamine, isopropylamine, N-Methyl pyrrolidone,
Propyl alcohol, butanol, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, ethanol amine, isopropylamine, methyl oleate, soybean oil, corn
The mixture of oil, ethyl acetate and one or more compositions in acetonitrile.
As preferred：The filler is kaolin, diatomite, bentonite, attapulgite, white carbon, starch and lightweight carbon
The mixture of one or more compositions in sour calcium.
As preferred：The surfactant is the list of common nonionic surfactant or anion surfactant
Agent or complex preparation.
As preferred：The emulsifier is OP series phosphate (thermally coupled distillation columns), 600# phosphates
(phenyl phenol polyoxyethylene ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, three ethyl alcohol
Amine salt, agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether), peaceful breast
36# (phenethyl phenol formaldehyde resin polyoxyethyl ether), agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether), epoxy second
Alkane-propylene oxide block copolymer, OP serial (nonylphenol polyoxyethylene ether), BY serial (castor oil polyoxyethylene ether), agriculture breast
33# (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate), TWEEN Series (Sorbitan
Alcohol ester acid ester polyoxyethylene ether) and one or more of AEO serial (fatty alcohol polyoxyethylene ether) composition mixture.
As preferred：The dispersant is polycarboxylate, lignosulfonates, APES formaldehyde condensation product
Sulfate, alkyl benzene calcium sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkyl phenol polyoxyethylene ether, aliphatic amine polyoxyethylene ether, fat
The mixture of one or more compositions in fat acid polyoxyethylene ether and glycerol fatty acid ester polyoxyethylene ethe.
As preferred：The wetting agent is that lauryl sodium sulfate, neopelex, Nekal BX, wetting are oozed
The mixture of saturating agent F, spaonin powder, silkworm excrement or one or more compositions in spaonin powder.
As preferred：The bleeding agent is penetrating agent JFC (fatty alcohol polyoxyethylene ether), penetrant t (maleic acid two
Different monooctyl ester sulfonate), the mixture of azone and one or more compositions in organosilicon.
As preferred：The thickener is gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, Sodium Polyacrylate, modification
The mixture of one or more compositions in starch, xanthans, bentonite, silica and aluminum magnesium silicate.
As preferred：The antifreezing agent is the mixed of one or more compositions in ethylene glycol, propylene glycol, glycerine and urea
Close object.
As preferred：The antifoaming agent is silicone oil, silicone compound, C10~C20 saturated fat acids compound and C8
The mixture of one or more compositions in~C10 aliphatic alcohols compounds.
As preferred：The disintegrant is bentonite, urea, ammonium sulfate, aluminium chloride, low-substituted hydroxypropyl cellulose, breast
The mixture of one or more compositions in sugar, citric acid, succinic acid and sodium bicarbonate.
As preferred：The stabilizer is epoxidized soybean oil, in epoxychloropropane, BHT, ethyl acetate and triphenyl phosphate
One or more compositions mixture.
As preferred：The dosage form of the Herbicidal composition for rice field is missible oil, suspending agent, wettable powder, water-dispersible grain
Any one of agent, aqueous emulsion, microemulsion, granule, microcapsule formulations, aqua and dispersible oil-suspending agent.
A kind of application of above-mentioned Herbicidal composition for rice field, for rice terrace annual gramineous weed and broad leaved weed
Prevention.
As preferred：The method of administration of the Herbicidal composition for rice field is：In the rice 7-8 leaf phases, weeds in field 1-3 leaves
Phase carries out cauline leaf and sprays.
Compared with prior art, the advantages and positive effects of the present invention are：Agent for removing grass in paddy field combination provided by the invention
Object and its application keep the two right within the scope of certain compound proportion by the recipe determination to furans sulphur humulone and flucetosulfuron
Paddy field weed shows apparent synergistic effect, solves both the above herbicide in herbicide controlling spectrum, preventive effect and safety
Limitation, the two mechanism of action is different, and rationally compounding can delay the generation of herbicide resistance, expands herbicide controlling spectrum, extends medicament and holds
The effect phase, especially when furans sulphur humulone and flucetosulfuron are with 1:1.5~3:1 ratio compounding is miscellaneous to rice terrace annual gramineae
Grass, broad leaved weed have favorable effect.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
An embodiment of the present invention provides a kind of Herbicidal composition for rice field, including active ingredient and auxiliary element, effectively at
Point include furans sulphur humulone and flucetosulfuron, the weight ratio of the furans sulphur humulone and flucetosulfuron is 1:1.5~3:1.It is indoor
Co-toxicity test the result shows that, just to the preventive effect of barnyard grass from the point of view of, be in active ingredient furans sulphur humulone and flucetosulfuron ratio
1:1.5~3:When 1 compounding, E-E0 ＞ 10% show certain synergistic effect.Both the above herbicide is solved in herbicide
Limitation in spectrum, preventive effect and safety, the two mechanism of action is different, and rationally compounding can delay the generation of herbicide resistance, expands
Big herbicide controlling spectrum extends the medicament lasting period.
To achieve the goals above and play a role, in the preferred embodiment of the present invention, the furans sulphur humulone and
The weight ratio of flucetosulfuron is 1:1~2:1.In above range, the herbicidal effect of active ingredient show as preferable addition or
Synergistic effect, such as：The weight ratio of active ingredient furans sulphur humulone and flucetosulfuron can be：1:1、1.5:1 and 2:1.As
The weight ratio of preferred embodiment, the furans sulphur humulone and flucetosulfuron is 1:1.The furans sulphur humulone under the conditions of mixture ratios
It is most apparent with flucetosulfuron synergistic effect.
In a preferred embodiment, active ingredient furans sulphur humulone and flucetosulfuron are in the Herbicidal composition for rice field
Shared weight percentage is 1%~75%.Embodiment more preferably, active ingredient furans sulphur humulone and flucetosulfuron
Shared weight percentage is 12%~60% in the Herbicidal composition for rice field.Specific additive amount can be according to practical need
Depending on the weeds area and type of improvement, for example, the quality of furans sulphur humulone and flucetosulfuron can account for 12%, 24%, 30%,
35%, 40%, 45%, 50%, 55%, 60% etc. or above range in other any values.In a more preferred embodiment
In, the quality of the furans sulphur humulone and flucetosulfuron accounts for the 12%~24% of the Herbicidal composition for rice field gross mass.
It, can be while meeting drug effect performance, conducive to the dosage form of excellent effect is prepared within the scope of this.
In an alternative embodiment, the auxiliary element includes carrier and auxiliary agent, and the carrier is in water, solvent and filler
One or more, the auxiliary agent include at least a kind of surfactant.Wherein, water is preferably deionized water；The solvent is
N,N-Dimethylformamide, cyclohexanone, toluene, dimethylbenzene, dimethyl sulfoxide (DMSO), methanol, ethyl alcohol, trimethylcyclohexanone, N- are pungent
Base pyrrolidones, ethanol amine, triethanolamine, isopropylamine, N-Methyl pyrrolidone, propyl alcohol, butanol, ethylene glycol, diethylene glycol,
One kind in ethylene glycol monomethyl ether, butyl ether, ethanol amine, isopropylamine, methyl oleate, soybean oil, corn oil, ethyl acetate and acetonitrile or
The mixture of a variety of compositions.The filler is kaolin, diatomite, bentonite, attapulgite, white carbon, starch and lightweight carbon
The mixture of one or more compositions in sour calcium.The surfactant is common nonionic surfactant or anion
The single dose or complex preparation of surfactant.It is understood that mentioned kind is only to enumerate not exhaustive, other suitable loads
Body can also be used in the preparation process of above-mentioned composition.
In an alternative embodiment, the surfactant is one kind in emulsifier, dispersant, wetting agent and bleeding agent
Or it is several.Wherein, the emulsifier is OP series phosphate (thermally coupled distillation columns), 600# phosphate (phenyl
Phenol polyethenoxy ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt,
Agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether), peaceful breast 36#
(phenethyl phenol formaldehyde resin polyoxyethyl ether), agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-
Propylene oxide block copolymer, OP serial (nonylphenol polyoxyethylene ether), BY serial (castor oil polyoxyethylene ether), agriculture breast 33#
(alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate), TWEEN Series (Sorbitan alcohol ester
Acid ester polyoxyethylene ether) and one or more of AEO serial (fatty alcohol polyoxyethylene ether) composition mixture.Described point
Powder is polycarboxylate, lignosulfonates, APES formaldehyde condensation products sulfat, alkyl benzene calcium sulfonate, naphthalene
Sulfonic formaldehyde condensation compound sodium salt, alkyl phenol polyoxyethylene ether, aliphatic amine polyoxyethylene ether, aliphatic acid polyethenoxy ether and glyceride
The mixture of one or more compositions in fat acid ester polyoxyethylene ether.The wetting agent is lauryl sodium sulfate, dodecane
The mixing of one or more compositions in base benzene sulfonic acid sodium salt, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement or spaonin powder
Object.The bleeding agent be penetrating agent JFC (fatty alcohol polyoxyethylene ether), penetrant t (diisooctyl maleate sulfonate),
The mixture of one or more compositions in azone and organosilicon.
In an alternative embodiment, the auxiliary agent further includes in antifreezing agent, thickener, stabilizer, disintegrant and antifoaming agent
One or more.Wherein, the antifreezing agent is one or more compositions in ethylene glycol, propylene glycol, glycerine and urea
Mixture.The thickener is gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, Sodium Polyacrylate, modified starch, xanthan
The mixture of one or more compositions in glue, bentonite, silica and aluminum magnesium silicate.The stabilizer is epoxy soybean
Oil, the mixture of one or more compositions in epoxychloropropane, BHT, ethyl acetate and triphenyl phosphate.The disintegrant is
In bentonite, urea, ammonium sulfate, aluminium chloride, low-substituted hydroxypropyl cellulose, lactose, citric acid, succinic acid and sodium bicarbonate
The mixture of one or more compositions.The antifoaming agent is silicone oil, silicone compound, C10~C20 saturated fat acids chemical combination
The mixture of object and one or more compositions in C8~C10 aliphatic alcohols compounds.
Any one dosage form of suitable agricultural use can be prepared by known methods into the Herbicidal combinations of the present invention, compared with
Good dosage form is missible oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations, water
Any one of agent and dispersible oil-suspending agent.
Another embodiment of the present invention provides the application of above-mentioned Herbicidal composition for rice field, is used for the annual standing grain of rice terrace
The prevention of undergraduate course weeds and broad leaved weed.
In an alternative embodiment, the method for administration of the Herbicidal composition for rice field is：In the rice 7-8 leaf phases, field
The weeds 1-3 leaf phases carry out cauline leaf and spray.
In order to become apparent from a kind of Herbicidal composition for rice field for introducing that the embodiment of the present invention provided in detail and its application,
It is described below in conjunction with specific embodiment.
Embodiment 1：60% furans sulphur humulone flucetosulfuron wettable powder
Include the raw material components of following weight percent：45% furans sulphur humulone, 15% flucetosulfuron, 2% profit
Humectant lauryl sodium sulfate, 8% dispersant calcium lignosulfonate, surplus are filler white carbon.
Preparation method：The component and its weight percent provided according to above-described embodiment, by furans sulphur humulone, fluorine pyrrole sulphur
Grand, dispersant, wetting agent and filler are uniformly mixed, and remix obtained wettable powder after being smashed by air jet mill.Mainly set
Have mixing machine, airslide disintegrating mill.
Embodiment 2：35% furans sulphur humulone flucetosulfuron water dispersible granules
Include the raw material components of following weight percent：25% furans sulphur humulone, 10% flucetosulfuron, 3% profit
Humectant dodecylbenzene sodium sulfonate, 8% dispersant alkylnaphthalene sulfonate formaldehyde condensation products, surplus are filler attapulgite.
Preparation method：By above-described embodiment provide component and its weight percent, by furans sulphur humulone, flucetosulfuron,
Dispersant, wetting agent and filler are uniformly mixed, and add 10~25% water after being smashed by air jet mill, then through mediating, squeezing
It is granulated, drying obtains water dispersible granules.Or the powder that crushed is sprayed water in boiling granulator, is granulated, is dry, it sieves later
Divide obtained water dispersible granules.Capital equipment has mixing machine, airslide disintegrating mill, kneader, Squeezinggranulator, drying chamber or fluid bed dry
Dry or boiling granulator, screening machine.
Embodiment 3：The 24% dispersible oil-suspending agent of furans sulphur humulone flucetosulfuron
Include the raw material components of following weight percent：16% furans sulphur humulone, 8% flucetosulfuron, 7% emulsification
The methyl oleate of agent agriculture breast BY-125,8% thermally coupled distillation columns, 1.6% organobentonite, surplus.
Preparation method：The component and its weight percent provided by above-described embodiment, by furans sulphur humulone and flucetosulfuron,
Surfactant and other functional aids are sequentially placed into reaction kettle, add methyl oleate to be uniformly mixed, through high speed shear, wet method
It is sanded, it is finally homogeneous to filter up to oil-suspending agent.Capital equipment is batching kettle, colloid mill or homogeneous mixing machine, sand mill.
Embodiment 4：30% furans sulphur humulone flucetosulfuron aqueous suspension agent
Include the raw material components of following weight percent：20% furans sulphur humulone, 10% flucetosulfuron, 2% breast
Agent agriculture breast NP-10,3% dispersant polycarboxylate, 0.1% xanthans, 2% aluminium-magnesium silicate, 5% ethylene glycol,
0.2% silicone compound, the water of surplus.
Preparation method：The component and its weight percent provided by above-described embodiment, by furans sulphur humulone and flucetosulfuron,
Surfactant and other functional aids are sequentially placed into reaction kettle, are mixed with water, and through high speed shear, wet method is sanded,
It is finally homogeneous to filter up to aqueous suspension agent.Capital equipment is batching kettle, colloid mill or homogeneous mixing machine, sand mill.
Embodiment 5：12% furans sulphur humulone flucetosulfuron missible oil
Include the raw material components of following weight percent：8% furans sulphur humulone, 4% flucetosulfuron, 4% emulsification
The two of agent selection agriculture breast 500#, 5% agriculture breast OP-10,10% n,N-Dimethylformamide, 15% ethyl acetate, surplus
Toluene.
Preparation method：The component and its weight percent provided by above-described embodiment, by furans sulphur humulone and flucetosulfuron
It is added in solvent, and emulsifier is added wherein, be uniformly mixed in being stirred kettle.Kettle is stirred to can be selected
Enamel reaction still, stainless steel stirred tank etc..
Indoor biological active determination test：
Virulence coefficient of the Herbicidal composition for rice field of the indoor measurement present invention to barnyard grass.
Test method is as follows：
Reagent agent：97% furans sulphur humulone active compound, 96% flucetosulfuron active compound；
For trying target：Barnyard grass, cyperus iria；
Experimental procedure：Using potting cauline leaf process method (NY/T1155.4-2006)：In the polypots of high 6cm, diameter 9cm
Built-in quantitative soil will be placed on temperature for the 15-20 sowings of examination target weeds seed in polypots after covering the fine earth of 0.5-1cm thickness
Indoor culture waits for that weeds grew to the 2-4 leaf phases and carries out cauline leaf spraying treatment, and per alms bowl hydrojet 1mL, often processing is repeated 4 times, and is set and be free of
The processing of medicament is control.Examination is just placed in greenhouse and cultivates after processing, the growing state of routine observation target weeds, mesh after 15d
Target damage symptoms and growth inhibition situation are surveyed, and claims aerial part fresh weight or strain fresh weight, is commented with target weeds fresh weight inhibition rate
Valence medicament is to its toxicity action.
Control time：Target damage symptoms and growth inhibition situation are estimated after test process 15d, and claim aerial part fresh
Weight.
Data statistics and analysis：
According to investigation statistics, fresh weight inhibition rate (%) is calculated.
Fresh weight inhibition rate P (%)=(control fresh weight-processing fresh weight)/processing fresh weight × 100.
Synergy evaluation method：
Herbicide mode of application (NY/T1155.7-2006) is evaluated according to Gowing methods, formula is as follows：E0=X+
Y-XY/100
In formula, X is the fresh weight inhibition rate to target weeds when furans sulphur humulone is applied alone with certain dosage；
Y is the fresh weight inhibition rate to target weeds when flucetosulfuron is applied alone with certain dosage；
E0To the theoretical value of target weeds fresh weight inhibition rate for furans sulphur humulone and when two kinds of pharmacy mix of flucetosulfuron
(%)；
To the measured value of target weeds fresh weight inhibition rate when E is furans sulphur humulone and two kinds of pharmacy mix of flucetosulfuron
(%).
Evaluation criterion：Work as E-E0Synergistic effect is expressed as when ＞ 10%, as -10%≤E-E0It is expressed as being added when≤10%
Effect, works as E-E0Antagonism is expressed as when ＜ -10%.
The results are shown in Table 1 for toxicity test.
The joint toxicity measuring result of 1 furans sulphur humulone of table and flucetosulfuron compounding
Indoor co-toxicity test the result shows that, just to the preventive effect of barnyard grass from the point of view of, by active ingredient furans sulphur humulone and fluorine
The grand ratio of pyrrole sulphur is 1:1.5~3:When 1 compounding, E-E0＞ 10% shows certain synergistic effect；According to what is mentioned in upper table
- 10%≤E-E when other ratios compound0≤ 10%, summation action is shown as, and wherein furans sulphur humulone and flucetosulfuron are 1:
Synergistic effect when 1 is most apparent.Just to the preventive effect of cyperus iria from the point of view of, by active ingredient furans sulphur humulone and flucetosulfuron according to
When ratio compounds in table, -10%≤E-E0≤ 10%, show certain summation action.It is recommended that pressing suitable proportion 1:1.5~3:
1 or so complex preparation further carries out field control effectiveness test, to evaluate its field practical application effect.
Paddy field weed field control effectiveness test
Field efficacy plot experiment method is used below, is further verified furans sulphur humulone and is compounded in crop field with flucetosulfuron
Using the preventive effect to rice terrace annual gramineous weed, broad leaved weed and sedge weed.
Test medicine：The preparation-obtained Herbicidal composition for rice field of Examples 1 to 5；
Comparison medicament 1：10% flucetosulfuron suspending agent；
Comparison medicament 2：30% furans sulphur humulone suspending agent.
If artificial weeding and clear water control treatment (CK).
Application method：Uniform cauline leaf sparges in each cell after being watered 30 liters per acre.Hillslope processes are arranged using random district's groups
Row, each processing are repeated four times.
Spraying time：In the rice 7-8 leaf phases, the weeds in field 1-3 leaf phases carry out cauline leaf and spray 1 time.
Dispenser place：Jiangxi Province Yugan County
Investigation method and drug effect calculate
Investigating weeds object is：The weeds such as barnyard grass, moleplant seed, lady's-grass, Monochoria vaginalis, cyperus iria, needle spikesedge herb, 15 after investigation
It, 40 days to the strain preventive effect of weeds and 40 days fresh weight preventive effects.
The field efficacy of 2 furans sulphur humulone of table and flucetosulfuron compounding
It is preferable to broad leaved weed preventive effect that field control effectiveness test result shows that furans sulphur humulone is used alone, to standing grain such as barnyard grasses
Undergraduate course weeds and sedge weed preventive effect are slightly poor, and rationally compounding can overcome this disadvantage.Furans sulphur humulone and flucetosulfuron with
1:1.5~3:1 ratio compounding has favorable effect to rice terrace annual gramineous weed, broad leaved weed.Meanwhile the two is made
With mechanism difference, the generation that can delay herbicide resistance is rationally compounded, expands herbicide controlling spectrum, extends the medicament lasting period.Range estimation hair
Existing, each processing plant growth is normal, has no that rice plant generates apparent poisoning, illustrates that it is safety to the rice varieties of experiment
's.
To sum up indoor virulence and field control effectiveness test result verification, furans sulphur humulone be used alone to broad leaved weed preventive effect compared with
Good, slightly poor to the grassy weeds such as barnyard grass and sedge weed preventive effect, rationally compounding can overcome this disadvantage.Furans sulphur humulone
With flucetosulfuron with 1:1.5~3:1 ratio compounding has rice terrace annual gramineous weed, broad leaved weed preferably anti-
Effect.Meanwhile the two mechanism of action is different, rationally compounding can delay the generation of herbicide resistance, expand herbicide controlling spectrum, extend medicament
Lasting period.Range estimation finds that each processing plant growth is normal, has no that rice plant generates apparent poisoning, illustrates its water to experiment
Rice varieties are safe.
Claims (10)
1. Herbicidal composition for rice field, it is characterised in that：Including active ingredient and auxiliary element, active ingredient includes furans sulphur grass
The weight ratio of ketone and flucetosulfuron, the furans sulphur humulone and flucetosulfuron is 1:1.5~3:1.
2. Herbicidal composition for rice field according to claim 1, it is characterised in that：The furans sulphur humulone and flucetosulfuron
Weight ratio be 1:1~2:1.
3. Herbicidal composition for rice field according to claim 1, it is characterised in that：The furans sulphur humulone and flucetosulfuron
Weight ratio be 1:1.
4. according to claims 1 to 3 any one of them Herbicidal composition for rice field, it is characterised in that：Active ingredient furans sulphur
Humulone and flucetosulfuron weight percentage shared in the Herbicidal composition for rice field are 1%~75%.
5. Herbicidal composition for rice field according to claim 4, it is characterised in that：Active ingredient furans sulphur humulone and fluorine pyrrole
The grand shared weight percentage in the Herbicidal composition for rice field of sulphur is 12%~60%.
6. Herbicidal composition for rice field according to claim 1, it is characterised in that：The auxiliary element includes carrier and helps
Agent, the carrier are one or more of water, solvent and filler, and the auxiliary agent includes at least a kind of surfactant.
7. Herbicidal composition for rice field according to claim 6, it is characterised in that：The surfactant be emulsifier,
One or more of dispersant, wetting agent and bleeding agent；The auxiliary agent further includes antifreezing agent, thickener, stabilizer, disintegrant
One or more of with antifoaming agent.
8. Herbicidal composition for rice field according to claim 6, it is characterised in that：The agent of the Herbicidal composition for rice field
Type is missible oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations, aqua and can
Disperse any one of oil-suspending agent.
9. a kind of application of claim 1~8 any one of them Herbicidal composition for rice field, it is characterised in that：For rice
The prevention of field annual gramineous weed and broad leaved weed.
10. the application of Herbicidal composition for rice field according to claim 9, it is characterised in that：The agent for removing grass in paddy field group
Close object method of administration be：In the rice 7-8 leaf phases, the weeds in field 1-3 leaf phases carry out cauline leaf and spray.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810210862.5A CN108576033A (en) | 2018-03-14 | 2018-03-14 | Herbicidal composition for rice field and its application |
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| CN201810210862.5A CN108576033A (en) | 2018-03-14 | 2018-03-14 | Herbicidal composition for rice field and its application |
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| CN108576033A true CN108576033A (en) | 2018-09-28 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109497084A (en) * | 2018-12-28 | 2019-03-22 | 北京颖泰嘉和生物科技股份有限公司 | A kind of herbicidal composition and its application |
| CN109699668A (en) * | 2019-02-25 | 2019-05-03 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of ternary weeding composition and its application for paddy field weed |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103636644A (en) * | 2009-05-27 | 2014-03-19 | 拜尔农作物科学股份公司 | Herbicidal combinations comprising tefuryltrione for use in rice crops |
| JP2014094909A (en) * | 2012-11-08 | 2014-05-22 | Sumitomo Chemical Co Ltd | Herbicidal composition |
| CN107494555A (en) * | 2017-08-24 | 2017-12-22 | 江苏莱科化学有限公司 | A kind of Herbicidal composition for rice field |
-
2018
- 2018-03-14 CN CN201810210862.5A patent/CN108576033A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103636644A (en) * | 2009-05-27 | 2014-03-19 | 拜尔农作物科学股份公司 | Herbicidal combinations comprising tefuryltrione for use in rice crops |
| JP2014094909A (en) * | 2012-11-08 | 2014-05-22 | Sumitomo Chemical Co Ltd | Herbicidal composition |
| CN107494555A (en) * | 2017-08-24 | 2017-12-22 | 江苏莱科化学有限公司 | A kind of Herbicidal composition for rice field |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109497084A (en) * | 2018-12-28 | 2019-03-22 | 北京颖泰嘉和生物科技股份有限公司 | A kind of herbicidal composition and its application |
| CN109699668A (en) * | 2019-02-25 | 2019-05-03 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of ternary weeding composition and its application for paddy field weed |
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